CN105384391A - Energy-saving water-permeable floor tile with construction garbage added - Google Patents

Energy-saving water-permeable floor tile with construction garbage added Download PDF

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Publication number
CN105384391A
CN105384391A CN201510723002.8A CN201510723002A CN105384391A CN 105384391 A CN105384391 A CN 105384391A CN 201510723002 A CN201510723002 A CN 201510723002A CN 105384391 A CN105384391 A CN 105384391A
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China
Prior art keywords
parts
water
sand
minutes
energy
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CN201510723002.8A
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Chinese (zh)
Inventor
高翠莲
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Hefei Zhengtuo Decoration Materials Co Ltd
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Hefei Zhengtuo Decoration Materials Co Ltd
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Priority to CN201510723002.8A priority Critical patent/CN105384391A/en
Publication of CN105384391A publication Critical patent/CN105384391A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/22Natural resins, e.g. rosin
    • C04B26/24Cellulosic waste liquor, e.g. sulfite lye
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • C04B14/068Specific natural sands, e.g. sea -, beach -, dune - or desert sand
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/60Planning or developing urban green infrastructure

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses an energy-saving water-permeable floor tile with construction garbage added. The energy-saving water-permeable floor tile is prepared from, by weight, 50-53 parts of desert sand, 4-5 parts of thermoplastic phenolic resin, 0.6-0.7 part of urotropin, 0.2-0.22 part of calcium stearate, a proper amount of water, 42-45 parts of portland cement with the mark number of 42.5, 5-6 parts of coal ash, 3-4 parts of rosin resin emulsion, 100-105 parts of building waste bricks, 30-33 parts of waste concrete, 3-4 parts of pregelatinized starch, 13-15 parts of red mud, 11-13 parts of bentonite, 6-7 parts of papermaking waste liquor and 1-1.2 parts of lauryl sodium sulfate. A scientific and reasonable formulation and proper granular aggregate are added to a surface layer material and a ground layer material, the building waste bricks, the waste concrete and other construction garbage are contained, the prepared product has excellent water permeability, is resistant to abrasion and achieves skidding prevention, energy saving and environment friendliness are achieved, and the phenomenon of an urban heat island can be effectively restrained.

Description

A kind of energy-saving pervious floor tile adding building castoff
Technical field
The present invention relates to building material technical field, particularly relate to a kind of energy-saving pervious floor tile adding building castoff.
Background technology
Along with the aggravation of Development of Urbanization speed, urban surface progressively cover by the water preventing ability such as buildings and various concrete material, waterproof regional percentage is significantly increasing, and its fraction of coverage of some areas is more than 80%.Due to city drainability worse and worse, many cities one run into heavy rain, and its rainwater on road surface cannot seepage fast, is easy to cause urban waterlogging.Therefore, for solving urban surface sclerosis problem, build high-quality natural living environment, safeguard balance of city ecosystem, the building material product-water-permeable brick of environmental protection arises at the historic moment, and is developed rapidly.
At present, common on market water-permeable brick mainly contains concrete permeable brick, ceramic water-permeable brick, sand base water-permeable brick etc.And the raw material that ceramic water-permeable brick is commonly used mainly contains phase red mud for many years, gold tailings, flyash, glazed ceramic, concrete etc.And the water-permeable brick prepared by these raw materials generally all needs the high temperature sintering through 1000-1400 DEG C, waste fossil oil, and produce industrial gaseous waste and cause topsoil.Sand base water-permeable brick is the novel water permeable brick grown up in recent years, with the drift-sand in desert for aggregate.Because sand base water-permeable brick emerges just trivial several years, extensive use is not also formed, and does not more further investigate the benefit that it produces.Store a large amount of drift-sand resources in desert, these drift-sands have the advantages that particle is tiny, water ratio is low, for development sand base water-permeable brick provides cheap starting material.From the angle of research, development and the performance analysis work of carrying out sand base water-permeable brick are conducive to improving China's water-permeable brick research system, and play and promote that sand base water-permeable brick is applied; From the angle of city ecology construction, be conducive to advancing Application of Urban Rain Water paces, alleviate the situation of city water resource scarcity; From the angle of desert treatment, be conducive to alleviating Desertification, and bring huge social economy and ecological benefits.As can be seen here, the research carrying out sand base water-permeable brick has major and immediate significance.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of energy-saving pervious floor tile adding building castoff.
The present invention is achieved by the following technical solutions:
Add an energy-saving pervious floor tile for building castoff, be made up of the raw material of following weight part: Desert Sand 50-53, novolac resin 4-5, urotropine 0.6-0.7, calcium stearate 0.2-0.22, water are appropriate, label is 42.5 silicate cement 42-45, flyash 5-6, Gum Rosin emulsion 3-4, building useless fragment of brick 100-105, discarded concrete 30-33, pregelatinized Starch 3-4, red mud 13-15, wilkinite 11-13, papermaking wastewater 6-7, sodium lauryl sulphate 1-1.2.
Described a kind of energy-saving pervious floor tile adding building castoff, be made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) sodium lauryl sulphate is dissolved in the water of 5 times amount, dispersed with stirring is even, add wilkinite, put into ball mill ball milling 90 minutes, add Gum Rosin emulsion after discharging, send in mixer after stirring 30 minutes with the speed of 300 revs/min, continue to add overlay film Desert Sand, papermaking wastewater that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) useless for building fragment of brick being put into crusher, to be broken into the particle of about 3mm stand-by; The water of 4 times amount will be added in pregelatinized Starch, be heated to dissolve completely stand-by; Put into ball mill ball milling after discarded concrete being put into crusher fragmentation and proceed to stirrer after 60 minutes, add above-mentioned building to give up fragment of brick particle, pregelatinized Starch solution, 20 minutes are stirred with the speed of 300 revs/min, continue to add label be 42.5 silicate cement, red mud, all the other remaining components and total amount 10% water, to stir 20 minutes with the speed of 800 revs/min, obtain primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
Advantage of the present invention is: first the present invention carries out the process of coating thermoplastic resol to baked sand, obtain overlay film Desert Sand, the compositions such as tackiness agent are coordinated to make skin-material, give the permeable hole that water-permeable brick top layer is small, the macropore improving concrete brick body, easily by the shortcoming that mud blocks, also enhances aesthetic property; Coordinate the application of bottom concrete material, improve intensity and the water-permeable of brick body, and not only reduce production cost, also solve the environmental protection object of desert improvement.
The present invention adds in top layer and primer by scientific and reasonable formula and suitable particle level aggregate, include the useless building castoff such as fragment of brick, discarded concrete of building, the product made not only has excellent water-permeable, wear-resisting, anti-skidding, energy-conserving and environment-protective simultaneously, achieve the Sustainable development of resource, effectively can suppress " urban heat island " phenomenon.
Embodiment
Add an energy-saving pervious floor tile for building castoff, be made up of the raw material of following weight part (kilogram): the silicate cement 42 that Desert Sand 50, novolac resin 4, urotropine 0.6, calcium stearate 0.2, water are appropriate, label is 42.5, flyash 5, Gum Rosin emulsion 3, building useless fragment of brick 100, discarded concrete 30, pregelatinized Starch 3, red mud 13, wilkinite 11, papermaking wastewater 6, sodium lauryl sulphate 1.
Described a kind of energy-saving pervious floor tile adding building castoff, be made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) sodium lauryl sulphate is dissolved in the water of 5 times amount, dispersed with stirring is even, add wilkinite, put into ball mill ball milling 90 minutes, add Gum Rosin emulsion after discharging, send in mixer after stirring 30 minutes with the speed of 300 revs/min, continue to add overlay film Desert Sand, papermaking wastewater that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) useless for building fragment of brick being put into crusher, to be broken into the particle of about 3mm stand-by; The water of 4 times amount will be added in pregelatinized Starch, be heated to dissolve completely stand-by; Put into ball mill ball milling after discarded concrete being put into crusher fragmentation and proceed to stirrer after 60 minutes, add above-mentioned building to give up fragment of brick particle, pregelatinized Starch solution, 20 minutes are stirred with the speed of 300 revs/min, continue to add label be 42.5 silicate cement, red mud, all the other remaining components and total amount 10% water, to stir 20 minutes with the speed of 800 revs/min, obtain primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
Carry out properties test to the pervious floor tile that the embodiment of the present invention is made, water-retentivity is greater than 0.6g/cm 2, coefficient of permeability is 2.65 × 10 -2cm/s, bending strength is 52.0MPa, and 25 freeze-thaw cycle ultimate compression strength losses are less than 20%, meet industry standard.

Claims (2)

1. one kind is added the energy-saving pervious floor tile of building castoff, it is characterized in that, be made up of the raw material of following weight part: Desert Sand 50-53, novolac resin 4-5, urotropine 0.6-0.7, calcium stearate 0.2-0.22, water are appropriate, label is 42.5 silicate cement 42-45, flyash 5-6, Gum Rosin emulsion 3-4, building useless fragment of brick 100-105, discarded concrete 30-33, pregelatinized Starch 3-4, red mud 13-15, wilkinite 11-13, papermaking wastewater 6-7, sodium lauryl sulphate 1-1.2.
2. a kind of energy-saving pervious floor tile adding building castoff according to claim 1, is characterized in that, be made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) sodium lauryl sulphate is dissolved in the water of 5 times amount, dispersed with stirring is even, add wilkinite, put into ball mill ball milling 90 minutes, add Gum Rosin emulsion after discharging, send in mixer after stirring 30 minutes with the speed of 300 revs/min, continue to add overlay film Desert Sand, papermaking wastewater that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) useless for building fragment of brick being put into crusher, to be broken into the particle of about 3mm stand-by; The water of 4 times amount will be added in pregelatinized Starch, be heated to dissolve completely stand-by; Put into ball mill ball milling after discarded concrete being put into crusher fragmentation and proceed to stirrer after 60 minutes, add above-mentioned building to give up fragment of brick particle, pregelatinized Starch solution, 20 minutes are stirred with the speed of 300 revs/min, continue to add label be 42.5 silicate cement, red mud, all the other remaining components and total amount 10% water, to stir 20 minutes with the speed of 800 revs/min, obtain primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
CN201510723002.8A 2015-10-29 2015-10-29 Energy-saving water-permeable floor tile with construction garbage added Pending CN105384391A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106946526A (en) * 2017-03-29 2017-07-14 合肥天沃能源科技有限公司 A kind of energy saving building material and preparation method thereof
CN111056792A (en) * 2019-12-17 2020-04-24 佛山科学技术学院 Composite water absorption brick and preparation method thereof
CN113501694A (en) * 2021-07-08 2021-10-15 抚州市正兴混凝土有限公司 Anti-cracking environment-friendly concrete

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139188A (en) * 2007-08-13 2008-03-12 盐城工学院 Energy-saving heat-insulating masonry mortar and method for making same
CN101725208A (en) * 2009-11-27 2010-06-09 岳建伟 Heat-preservation and heat-insulation crack-resisting brick made from modified vitrified micro beads
CN201981461U (en) * 2011-03-28 2011-09-21 韶关学院 Structural gradient type composite pervious brick
CN102219415A (en) * 2011-03-29 2011-10-19 河海大学 Light sand without burning and preparation method thereof
CN102503201A (en) * 2011-10-21 2012-06-20 李国辉 Pre-coated sand, preparation method thereof and composite water permeable brick
CN103664060A (en) * 2012-09-06 2014-03-26 李国辉 Pre-coated new sand, preparation method thereof and composite permeable brick

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139188A (en) * 2007-08-13 2008-03-12 盐城工学院 Energy-saving heat-insulating masonry mortar and method for making same
CN101725208A (en) * 2009-11-27 2010-06-09 岳建伟 Heat-preservation and heat-insulation crack-resisting brick made from modified vitrified micro beads
CN201981461U (en) * 2011-03-28 2011-09-21 韶关学院 Structural gradient type composite pervious brick
CN102219415A (en) * 2011-03-29 2011-10-19 河海大学 Light sand without burning and preparation method thereof
CN102503201A (en) * 2011-10-21 2012-06-20 李国辉 Pre-coated sand, preparation method thereof and composite water permeable brick
CN103664060A (en) * 2012-09-06 2014-03-26 李国辉 Pre-coated new sand, preparation method thereof and composite permeable brick

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杨杨等: "《土木工程材料》", 30 June 2014 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106946526A (en) * 2017-03-29 2017-07-14 合肥天沃能源科技有限公司 A kind of energy saving building material and preparation method thereof
CN111056792A (en) * 2019-12-17 2020-04-24 佛山科学技术学院 Composite water absorption brick and preparation method thereof
CN113501694A (en) * 2021-07-08 2021-10-15 抚州市正兴混凝土有限公司 Anti-cracking environment-friendly concrete

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Application publication date: 20160309