CN102390953A - Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof - Google Patents
Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof Download PDFInfo
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- CN102390953A CN102390953A CN2011102311001A CN201110231100A CN102390953A CN 102390953 A CN102390953 A CN 102390953A CN 2011102311001 A CN2011102311001 A CN 2011102311001A CN 201110231100 A CN201110231100 A CN 201110231100A CN 102390953 A CN102390953 A CN 102390953A
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- quartz stone
- stone slab
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- artificial quartz
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Abstract
The invention discloses a raw material of an antibacterial superhard artificial quartz stone plate, comprising the following components in parts by weight: 7-8 parts of modified unsaturated resin, 0.42-0.52 part of assistant, 45-65 parts of calcined quartz sand with particle size smaller than or equal to 6mm, 8-10 parts of tourmaline of20-80 meshes, 0-12 parts of 80-mesh quartz sand, 24-27 parts of 325-mesh quartz powder and 0.01-0.1 part of pigment. The invention also discloses an artificial quartz stone plate made of the raw material and a preparation method thereof. In the invention, a certain quantity of tourmaline and calcined quartz stone is added in the production process of the quartz stone plate so that the produced plate not only is high in hardness, good in wear resistance, not easy to scrape and long in service life, but also has an antibacterial effect.
Description
Technical field
The present invention relates to rostone and preparation method thereof, be specifically related to a kind of antibiotic, exceptional hardness synthetic quartz stone slab raw material, synthetic quartz stone slab and preparation method thereof.
Background technology
The artificial slabstone in existing building finishing material market, safety, low-carbon (LC), environmental protection, high hardness wear-resisting etc. have become the selected key factor of people.At present, the artificial quartz in lump stone slab hardness ratio on the market is lower, wears no resistance, and also exists to be prone to scratch, and is prone to problems such as fragmentation, nor has anti-microbial effect.
Summary of the invention
The present invention is in order to overcome the shortcoming and defect that exists in the above-mentioned prior art, provides a kind of exceptional hardness, wear resistance good, and has synthetic quartz stone slab raw material, synthetic quartz stone slab of anti-microbial effect and preparation method thereof.
In order to solve the problems of the technologies described above, the present invention realizes by following technical scheme:
A kind of synthetic quartz stone slab raw material, a kind of synthetic quartz stone slab raw material is made up of the component of following weight part: modification modified unsaturated resin 7-8 part; Auxiliary agent 0.42-0.52 part; Particle diameter is smaller or equal to calcining quartz sand 45-65 part of 6mm, 20-80 order tourmalinite 8-10 part, 80 order silica sand 0-12 parts; 325 order silica powder 24-27 parts, pigment 0.01-0.1 part.
Preferably, described calcining quartz sand is that silica sand forms through 1500 ℃ of-1900 ℃ of high-temperature calcinations.
Preferably, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of said silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4: 1.
The synthetic quartz stone slab that obtains by synthetic quartz stone slab feedstock production.
A kind of preparation method of artificial quartz in lump comprises the steps: above-mentioned each component uniform mixing, and the material that mixes is sent in the material distributing machine cloth system template die; Then the making sheet mould is sent into Vakuumkammer, vacuumize, vibratory compaction; Send into curing oven again, promptly make the synthetic quartz stone slab.
Preferably, said solidified temperature is 85 ℃-95 ℃, and the time is 40-45 minute.
Preferably, the pressure during said vibratory compaction is 1.8-3MPa, and molding time is 2-3 minute.
Compared with prior art, the invention has the beneficial effects as follows:
(1) antibiotic.Tourmalinite has unique physical and chemical performances such as piezoelectricity and pyroelectricity, can produce the electromagnetic radiation and the negative oxygen ion of far infrared band, has antibiotic, de-odorised function.The present invention adds 8-10% 20-80 order tourmalinite in raw material, can increase the bacterinertness of sheet material effectively, and antibiotic effect is for a long time special.
(2) exceptional hardness.Calcining quartz sand of the present invention is to form through 1500 ℃ of-1900 ℃ of high-temperature calcinations, and its original oxidation, weathering material are burnt, and makes its density better fused, is a kind of exceptional hardness material.In raw material, add the 45-66% particle diameter smaller or equal to 6mm calcining quartz sand, increased substantially sheet material hardness, make it more wear-resisting, be difficult for scratching, increasing work-ing life.
Embodiment
Embodiment 1
Synthetic quartz stone slab raw material, form by the raw material of following weight:
Modified unsaturated resin 8kg; Weight ratio is γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.48kg of 4: 1,20-80 order tourmalinite 10kg; Particle diameter is smaller or equal to the calcining quartz sand 45.47kg of 6mm; 80 order silica sand 12kg, 325 order silica powder 24kg, blue pigments 0.05kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its lining system template die, be conveyed into Vakuumkammer then; When vacuumizing air pressure reach-during 0.1Mpa; Vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing; Treat the sheet material cooling after the completion, the fixed thick sanding and polishing of hair plates is promptly made " turquoise diamond stone " synthetic quartz stone slab.
It is 300mm that above-mentioned synthetic quartz stone slab that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done each item performance test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer control electronics universal testing machine; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
Contrast experiment's data by above table can know that synthetic quartz stone slab of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all has raising with respect to the various aspects of performance of existing sheet material.
Embodiment 2
Synthetic quartz stone slab raw material, form by the raw material of following weight:
Modified unsaturated resin 7kg; Weight ratio is 4: 1 γ-(2; 3-epoxy third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.42kg, 80 order tourmalinite 8kg, particle diameter is smaller or equal to the calcining quartz sand 59.5kg of 6mm; 325 order silica powder 25kg, black pigment 0.08kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its lining system template die, be conveyed into Vakuumkammer then; When vacuumizing air pressure reach-during 0.1Mpa; Vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing; Treat the sheet material cooling after the completion, the fixed thick sanding and polishing of hair plates is promptly made " black pearl " synthetic quartz stone slab.
It is 300mm that above-mentioned synthetic quartz stone slab that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done each item performance test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer control electronics universal testing machine; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
Contrast experiment's data by above table can know that synthetic quartz stone slab of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all has raising with respect to the various aspects of performance of existing sheet material.
Embodiment 3
Synthetic quartz stone slab raw material, form by the raw material of following weight:
Modified unsaturated resin 8kg; Weight ratio is 4: 1 γ-(2; 3-epoxy third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.42kg, 80 order tourmalinite 8kg, particle diameter is smaller or equal to 2mm calcining quartz sand 65.31kg; 325 order silica powder 27kg, black pigment 0.01kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its lining system template die, be conveyed into Vakuumkammer then; When vacuumizing air pressure reach-during 0.1Mpa; Vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing; Treat the sheet material cooling after the completion, the fixed thick sanding and polishing of hair plates is promptly made " ash fiber crops " synthetic quartz stone slab.
It is 300mm that above-mentioned synthetic quartz stone slab that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done each item performance test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer control electronics universal testing machine; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
Contrast experiment's data by above table can know that synthetic quartz stone slab of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all has raising with respect to the various aspects of performance of existing sheet material.
Embodiment 4
Synthetic quartz stone slab raw material, form by the raw material of following weight:
Modified unsaturated resin 7.5kg; Weight ratio is 4: 1 γ-(2; 3-epoxy third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.48kg, 20-80 order tourmalinite 10kg, particle diameter is smaller or equal to 2mm calcining quartz sand 54.97kg; 325 order silica powder 27kg, red pigment 0.05kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its lining system template die, be conveyed into Vakuumkammer then; When vacuumizing air pressure reach-during 0.1Mpa; Vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing; Treat the sheet material cooling after the completion, the fixed thick sanding and polishing of hair plates is promptly made " Chinese red " synthetic quartz stone slab.
It is 300mm that above-mentioned synthetic quartz stone slab that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done each item performance test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer control electronics universal testing machine; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
Contrast experiment's data by above table can know that synthetic quartz stone slab of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all has raising with respect to the various aspects of performance of existing sheet material.
The foregoing description is a preferred embodiments of the present invention; But embodiment of the present invention is not restricted to the described embodiments; Other any do not deviate from change, the decoration done under spirit of the present invention and the principle, substitutes, combination, simplify; All should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (7)
1. synthetic quartz stone slab raw material; Component by following weight part is formed: modification modified unsaturated resin 7-8 part, and auxiliary agent 0.42-0.52 part, particle diameter is smaller or equal to calcining quartz sand 45-65 part of 6mm; 20-80 order tourmalinite 8-10 part; 80 order silica sand 0-12 parts, 325 order silica powder 24-27 parts, pigment 0.01-0.1 part.
2. artificial quartz in lump according to claim 1 is characterized in that: described calcining quartz sand is that silica sand forms through 1500 ℃ of-1900 ℃ of high-temperature calcinations.
3. artificial quartz in lump according to claim 1 is characterized in that: described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of said silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4: 1.
4. by any synthetic quartz stone slab that the described synthetic quartz stone slab of claim feedstock production obtains of claim 1-3.
5. artificial quartz in lump preparation of plates method; It is characterized in that comprising the steps: described each the component uniform mixing of claim 1 is sent into the material that mixes in the material distributing machine cloth system template die, then the making sheet mould is sent into Vakuumkammer; Vacuumize; Curing oven is sent in vibratory compaction again, promptly makes the synthetic quartz stone slab.
6. the preparation method of artificial quartz in lump according to claim 5, it is characterized in that: said solidified temperature is 85 ℃-95 ℃, and the time is 40-45 minute.
7. the preparation method of artificial quartz in lump according to claim 5 is characterized in that: the pressure during said vibratory compaction is 1.8-3MPa, and molding time is 2-3 minute.
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| CN 201110231100 CN102390953B (en) | 2011-08-12 | 2011-08-12 | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof |
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| CN102390953B CN102390953B (en) | 2013-02-06 |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739235A (en) * | 2013-12-18 | 2014-04-23 | 广州戈兰迪高分子材料有限公司 | Crack-resistant quartz stone plate and manufacturing method thereof |
| CN103922640A (en) * | 2014-04-01 | 2014-07-16 | 安庆市凯立金刚石科技有限公司 | Artificial quartz raw material and forming production process thereof |
| CN104478273A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Fireproof artificial quartz stone sheet and manufacturing method thereof |
| CN104478292A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Artificial quartz stone sheet and preparation method thereof |
| CN104496273A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN104529248A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Artificial quartz stone panel and preparation method thereof |
| CN104529240A (en) * | 2015-01-12 | 2015-04-22 | 广州市奥维装饰材料有限公司 | Quartz stone board and manufacturing method of quartz stone board |
| CN104529245A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab |
| CN104529244A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Anti-aging and antibacterial artificial quartzite board and manufacturing method thereof |
| CN104529246A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Antibacterial and fireproof artificial quartzite board and preparation method thereof |
| CN104529247A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof |
| CN105801004A (en) * | 2016-04-21 | 2016-07-27 | 太仓市建兴石英玻璃厂 | Preparation method of health-care man-made quartz stone plate |
| CN105884260A (en) * | 2016-04-21 | 2016-08-24 | 太仓市建兴石英玻璃厂 | Healthcare artificial quartzite board |
| CN106145768A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of spontaneous heating antibacterial artificial quartz |
| CN106810106A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of antibacterial quartz and preparation method thereof |
| CN107586059A (en) * | 2017-10-02 | 2018-01-16 | 镇江市星耀智能装备有限公司 | A kind of compound additive for being used to prepare artificial slabstone |
| CN110228963A (en) * | 2019-07-09 | 2019-09-13 | 云浮市盈拓石业有限公司 | A kind of novel artificial quartzite plate |
| CN115490463A (en) * | 2022-09-16 | 2022-12-20 | 广东佳之朋科技有限公司 | Artificial stone material distribution process |
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| CN102030497A (en) * | 2010-11-01 | 2011-04-27 | 新云石业（云浮）有限公司 | Quartzite material, artificial quartzite plate and manufacturing process thereof |
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| CN2271695Y (en) * | 1996-07-20 | 1997-12-31 | 刘景潮 | Square quartz calciner |
| CN101195537A (en) * | 2007-06-08 | 2008-06-11 | 汪滔 | Material capable of generating negative ion far-infrared antimicrobial ceramic product and uses thereof |
| CN102030497A (en) * | 2010-11-01 | 2011-04-27 | 新云石业（云浮）有限公司 | Quartzite material, artificial quartzite plate and manufacturing process thereof |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739235A (en) * | 2013-12-18 | 2014-04-23 | 广州戈兰迪高分子材料有限公司 | Crack-resistant quartz stone plate and manufacturing method thereof |
| CN103739235B (en) * | 2013-12-18 | 2016-04-06 | 广州戈兰迪高分子材料有限公司 | A kind of Crack-resistant quartz stone plate and manufacture method thereof |
| CN103922640A (en) * | 2014-04-01 | 2014-07-16 | 安庆市凯立金刚石科技有限公司 | Artificial quartz raw material and forming production process thereof |
| CN104529244A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Anti-aging and antibacterial artificial quartzite board and manufacturing method thereof |
| CN104529247A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof |
| CN104529248A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Artificial quartz stone panel and preparation method thereof |
| CN104478273A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Fireproof artificial quartz stone sheet and manufacturing method thereof |
| CN104529245A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab |
| CN104478292A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Artificial quartz stone sheet and preparation method thereof |
| CN104529246A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Antibacterial and fireproof artificial quartzite board and preparation method thereof |
| CN104496273A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN104529240A (en) * | 2015-01-12 | 2015-04-22 | 广州市奥维装饰材料有限公司 | Quartz stone board and manufacturing method of quartz stone board |
| CN106810106A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of antibacterial quartz and preparation method thereof |
| CN105801004A (en) * | 2016-04-21 | 2016-07-27 | 太仓市建兴石英玻璃厂 | Preparation method of health-care man-made quartz stone plate |
| CN105884260A (en) * | 2016-04-21 | 2016-08-24 | 太仓市建兴石英玻璃厂 | Healthcare artificial quartzite board |
| CN106145768A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of spontaneous heating antibacterial artificial quartz |
| CN107586059A (en) * | 2017-10-02 | 2018-01-16 | 镇江市星耀智能装备有限公司 | A kind of compound additive for being used to prepare artificial slabstone |
| CN110228963A (en) * | 2019-07-09 | 2019-09-13 | 云浮市盈拓石业有限公司 | A kind of novel artificial quartzite plate |
| CN115490463A (en) * | 2022-09-16 | 2022-12-20 | 广东佳之朋科技有限公司 | Artificial stone material distribution process |
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