CN104478273A - Fireproof artificial quartz stone sheet and manufacturing method thereof - Google Patents
Fireproof artificial quartz stone sheet and manufacturing method thereof Download PDFInfo
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- CN104478273A CN104478273A CN201410778687.1A CN201410778687A CN104478273A CN 104478273 A CN104478273 A CN 104478273A CN 201410778687 A CN201410778687 A CN 201410778687A CN 104478273 A CN104478273 A CN 104478273A
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Abstract
The invention discloses a fireproof artificial quartz stone sheet and a manufacturing method thereof. The artificial quartz stone sheet comprises the following components in parts by weight: 30-80 parts of 6-100mesh quartz stone, 30-60 parts of 325mesh quartz powder, 5-10 parts of broken glass, 10-20 parts of 50-100mesh red-silica powder or white afrodite powder, 5-15 parts of 100-150mesh kyanite powder or andalusite powder or sillimanite powder, 1-10 parts of 100-200mesh zirconium silicate powder or yttrium-stabilized zirconium oxide powder, 5-10 parts of unsaturated resin, 0.3-0.5 part of an additive and 0.3-0.8 part of a pigment. During the preparation, by adding red-silica powder or white afrodite powder, kyanite powder or andalusite powder or sillimanite powder and zirconium silicate powder or yttrium-stabilized zirconium oxide powder, the compressive strength and fireproof and fire-retardant properties of the artificial quartz stone sheet disclosed by the invention are increased and meanwhile, the manufacturing method is simple and is suitable for industrial production and has broad market prospects.
Description
Technical field
The invention belongs to material of construction manufacturing technology field, specifically, refer to a kind of fireproof artificial quartz stone sheet material and manufacture method thereof.
Background technology
Artificial quartz stone plate is compared with artificial marble sheet material, there is the features such as sinuousness is high, compressive strength is high, Mohs' hardness is high, water-intake rate is low, gradually like by domestic and international users, be widely applied to cabinet, bathroom, the ground of office and megastore, wall decoration and household industry.However, also there is certain drawback in artificial quartz stone plate, such as fire resistance is not good.In artificial quartz in lump production process, general resin content is all more than 6%, because resin is combustiblesubstance, when artificial quartz in lump resin content reaches more than 3%, its product fire resistance is extremely low, and then significantly limit the application of artificial quartz in lump at various complex condition, particularly in the use in large common facility and the high place of fire protection requirement.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, provides a kind of fireproof artificial quartz stone sheet material and manufacture method thereof, adopts the artificial quartz stone plate of manufacture of the present invention to have excellent compressive property and fire retardant performance.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: fireproof artificial quartz stone sheet material, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 8 parts, 50 ~ 100 order red beach powder or 12 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 8 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 5 parts, yttrium stable zirconium oxide powder, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
Further, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, phenolphthalein blue powder, Lan Shuizhong one or more.
The manufacture method of fireproof artificial quartz stone sheet material, comprise following processing step: the component taking following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
Further, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
The invention has the beneficial effects as follows:
(1) fire prevention, resistance to compression: the highest refractory temperature of red beach powder and white afrodite powder all reaches more than 1700 DEG C.Aquamaine stone flour, andaluzite powder, sillimanite powder are also good refractory materialss, and they can improve refractory temperature, prolongation fire resistance period, the increase ultimate compression strength of artificial quartz stone plate of the present invention.The fusing point of zirconium silicate powder is 2500 DEG C, and hardness is 7.5 ~ 8.0, and the fusing point of same yttrium stable zirconium oxide powder and hardness are also very high, and they can play the effect improving refractory temperature, increase ultimate compression strength.
(2) manufacture method of the present invention is simple, and wide market, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 6 ~ 100 order quartzite 30kg, 325 order silica powder 60kg, glass cullet 5kg, 50 ~ 100 order red beach powder 20kg, 100 ~ 150 order sillimanite powder 5kg, 100 ~ 200 order zirconium silicate powder 10kg, epoxy resin 5kg, part by weight is the γ-methacryloxypropyl trimethoxy silane (KH570) of 4:1 and the 0.5kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.3kg, and described pigment is made up of according to mass ratio 18:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " white board " artificial quartz stone plate.
Embodiment 2:
Take 6 ~ 100 order quartzite 80kg, 325 order silica powder 30kg, glass cullet 10kg, 50 ~ 100 order white afrodite powder 10kg, 100 ~ 150 order aquamaine stone flour 15kg, 100 ~ 200 order yttrium stable zirconium oxide powder 1kg, resol 10kg, part by weight is the γ-aminopropyl triethoxysilane (KH550) of 4:1 and the 0.3kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.8kg, described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, iron oxide yellow powder, iron black powder, phenolphthalein blue powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " light gray plate " artificial quartz stone plate.
Embodiment 3:
Take 6 ~ 100 order quartzite 65kg, 325 order silica powder 45kg, glass cullet 8kg, 50 ~ 100 order white afrodite powder 12kg, 100 ~ 150 order andaluzite powder 8kg, 100 ~ 200 order zirconium silicate powder 5kg, urethane resin 8kg, part by weight is the γ-glycidyl ether oxygen propyl trimethoxy silicane of 4:1 and the 0.4kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.5kg, described pigment is made up of according to mass ratio 300:30:1:2:27 titanium dioxide, middle network bloom, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " gorgeous yellow plate " artificial quartz stone plate.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. fireproof artificial quartz stone sheet material, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
2. fireproof artificial quartz stone sheet material according to claim 1, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 8 parts, 50 ~ 100 order red beach powder or 12 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 8 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 5 parts, yttrium stable zirconium oxide powder, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
3. fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
4. fireproof artificial quartz stone sheet material according to claim 1 and 2, it is characterized in that, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
5. fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, phenolphthalein blue powder, Lan Shuizhong one or more.
6. the manufacture method of fireproof artificial quartz stone sheet material, it is characterized in that, comprise following processing step: the component taking following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
7. the manufacture method of fireproof artificial quartz stone sheet material according to claim 6, is characterized in that, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
8. the manufacture method of fireproof artificial quartz stone sheet material according to claim 6, is characterized in that, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
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| CN201410778687.1A CN104478273A (en) | 2014-12-15 | 2014-12-15 | Fireproof artificial quartz stone sheet and manufacturing method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106186822A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of wear-resisting quartzite slate and preparation technology thereof |
| CN109650804A (en) * | 2019-03-04 | 2019-04-19 | 枣庄市博源人造石有限公司 | A kind of preparation method of high fire-retardance artificial quartz stone plate |
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| JPH09255880A (en) * | 1996-03-22 | 1997-09-30 | Takahashi Seisakusho:Kk | Biodegradable plastic composition |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102390953A (en) * | 2011-08-12 | 2012-03-28 | 新云石业（云浮）有限公司 | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
-
2014
- 2014-12-15 CN CN201410778687.1A patent/CN104478273A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09255880A (en) * | 1996-03-22 | 1997-09-30 | Takahashi Seisakusho:Kk | Biodegradable plastic composition |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102390953A (en) * | 2011-08-12 | 2012-03-28 | 新云石业（云浮）有限公司 | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106186822A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of wear-resisting quartzite slate and preparation technology thereof |
| CN109650804A (en) * | 2019-03-04 | 2019-04-19 | 枣庄市博源人造石有限公司 | A kind of preparation method of high fire-retardance artificial quartz stone plate |
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Application publication date: 20150401 |