CN106145768A - A kind of spontaneous heating antibacterial artificial quartz - Google Patents

A kind of spontaneous heating antibacterial artificial quartz Download PDF

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Publication number
CN106145768A
CN106145768A CN201610480955.0A CN201610480955A CN106145768A CN 106145768 A CN106145768 A CN 106145768A CN 201610480955 A CN201610480955 A CN 201610480955A CN 106145768 A CN106145768 A CN 106145768A
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CN
China
Prior art keywords
parts
artificial quartz
spontaneous heating
mesh
antibacterial artificial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610480955.0A
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Chinese (zh)
Inventor
周汉文
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Anhui Freeston Industrial Co Ltd
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Anhui Freeston Industrial Co Ltd
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Application filed by Anhui Freeston Industrial Co Ltd filed Critical Anhui Freeston Industrial Co Ltd
Priority to CN201610480955.0A priority Critical patent/CN106145768A/en
Publication of CN106145768A publication Critical patent/CN106145768A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of spontaneous heating antibacterial artificial quartz, is made up of the component of following weight portion: 20 50 mesh quartz sands 52 58 parts, 20 50 mesh carbon fiber powder 8 12 parts, 20 50 mesh magnetic therapy fiber powder 8 12 parts, 20 50 48 parts of mesh tourmaline powder, nano-graphene 12 18 parts, composite resin 12 18 parts, accelerator 8 10 parts, modified 14 18 parts of age resistor, 68 parts of colorant.Artificial quartz in lump of the present invention is because of containing Graphene and tourmaline, so having certain spontaneous heating function, and infrared ray can be launched, health is had certain benefit, and magnetic therapy fiber has certain magnetic therapy effect to human body, Graphene has good sterilizing ability simultaneously, and killing miscellaneous bacteria in air and preventing mycete from growing has significant effect, and the present invention also has certain removing formaldehyde ability.

Description

A kind of spontaneous heating antibacterial artificial quartz
Technical field
The present invention relates to artificial stone's manufacture technology field, be specifically related to a kind of spontaneous heating antibacterial artificial quartz.
Background technology
Resin type Engineered stone products classification can be divided into several big class, and serviceability is by the composition of its raw material, ratio and life The multiple conditional decisions such as product equipment, technique.Wherein raw material is the basis determining its performance quality, different raw materials and difference Production equipment, the artificial slabstone produced just has different use value and different physical characteristics, and manufacturing cost is also Different.Taking the lead in making filler and unsaturated-resin with calcium carbonate (marble) by Italy in the sixties in 20th century, firming agent glues Condensation material, accompanies by the artificial synthesizing marble of DYE PRODUCTION (hilllock stone).Flow into China mid-term from the eighties, become present artificial hilllock , there is with polyformaldehyde acrylic acid methyl ester. and aluminium hydroxide the artificial stone as raw material production the seventies in stone product.Later by improvement Artificial slabstone is produced for UP/PMMA plate.Early 1990s unsaturated-resin and production of aluminum hydroxide out on-gauge plate Artificial slabstone (UP plate), is provided without the industrial chemicals such as natural inorganic ore deposit and aluminium oxide such as natural stone diamond stone the nineties, the molten cellar for storing things of warp, Flux, water rate, crystallization cave sintering make microlite.At the beginning of 21 century, there is people with natural siliceous sand powder and high-performance tree in Spain Fat synthetically produced go out new science and technology artificial quartz stone plate.Ad initio artificial quartz in lump technique inflow China becomes a generation for renewal and builds Material product.But, artificial quartz in lump quality is uneven in the market, is difficult to meet diversified demand.
Summary of the invention
The technical problem to be solved is to provide a kind of spontaneous heating antibacterial artificial quartz.
The technical problem to be solved realizes by the following technical solutions:
A kind of spontaneous heating antibacterial artificial quartz, is made up of the component of following weight portion: 20-50 mesh quartz sand 52-58 part, 20-50 mesh carbon fiber powder 8-12 part, 20-50 mesh magnetic therapy fiber powder 8-12 part, 20-50 mesh tourmaline powder 4-8 part, nano-graphene 12-18 part, composite resin 12-18 part, accelerator 8-10 part, modified age resistor 14-18 part, colorant 6-8 part.
Described composite resin by phenolic resin, styrenated alkyd, Benzoinum, orthophthalic polyester resin, Tea polyphenols is mixed to prepare by equivalent part.
Described accelerator is vanadium phosphate, to Chlorobenzoic Acid, N, in N-dimethyl open-chain crown ether, triethylene diamine extremely Few one.
Described modified age resistor is 6-ethyoxyl-2, and 2,4-trimethyl-1,2-dihyaroquinoline, N-Phenyl beta naphthylamine are pressed 1:1 ratio is mixed to prepare.
The preparation technology of a kind of spontaneous heating antibacterial artificial quartz, comprises the steps:
(1) each component is uniformly mixed;
(2) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 96-100 DEG C in described solidification, and hardening time is 50 minutes, second stage Solidification temperature is 92-96 DEG C, and hardening time is 30 minutes.
The invention has the beneficial effects as follows: artificial quartz in lump of the present invention is because of containing Graphene and tourmaline, so having certain Spontaneous heating function, and infrared ray can be launched, health be had certain benefit, and human body is had certain by magnetic therapy fiber Magnetic therapy effect, Graphene has good sterilizing ability simultaneously, and killing miscellaneous bacteria in air and preventing mycete from growing has significantly Effect, the present invention also has certain removing formaldehyde ability.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of spontaneous heating antibacterial artificial quartz, is made up of the component of following weight portion (kg): 20-50 mesh quartz sand 55 Part, 20-50 mesh carbon fiber powder 10 parts, 20-50 mesh magnetic therapy fiber powder 10 parts, 6 parts of 20-50 mesh tourmaline powder, nano-graphene 15 Part, composite resin 15 parts, accelerator 9 parts, modified 16 parts of age resistor, 7 parts of colorant.
Described composite resin by phenolic resin, styrenated alkyd, Benzoinum, orthophthalic polyester resin, Tea polyphenols is mixed to prepare by equivalent part.
Described accelerator is vanadium phosphate, to Chlorobenzoic Acid, N, in N-dimethyl open-chain crown ether, triethylene diamine extremely Few one.
Described modified age resistor is 6-ethyoxyl-2, and 2,4-trimethyl-1,2-dihyaroquinoline, N-Phenyl beta naphthylamine are pressed 1:1 ratio is mixed to prepare.
The preparation technology of a kind of spontaneous heating antibacterial artificial quartz, comprises the steps:
(1) each component is uniformly mixed;
(2) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 96-100 DEG C in described solidification, and hardening time is 50 minutes, second stage Solidification temperature is 92-96 DEG C, and hardening time is 30 minutes.
Embodiment 2
A kind of spontaneous heating antibacterial artificial quartz, is made up of the component of following weight portion (kg): 20-50 mesh quartz sand 52 Part, 20-50 mesh carbon fiber powder 8 parts, 20-50 mesh magnetic therapy fiber powder 8 parts, 4 parts of 20-50 mesh tourmaline powder, nano-graphene 12 parts, Composite resin 12 parts, accelerator 8 parts, modified 14 parts of age resistor, 6 parts of colorant.
Described composite resin by phenolic resin, styrenated alkyd, Benzoinum, orthophthalic polyester resin, Tea polyphenols is mixed to prepare by equivalent part.
Described accelerator is vanadium phosphate, to Chlorobenzoic Acid, N, in N-dimethyl open-chain crown ether, triethylene diamine extremely Few one.
Described modified age resistor is 6-ethyoxyl-2, and 2,4-trimethyl-1,2-dihyaroquinoline, N-Phenyl beta naphthylamine are pressed 1:1 ratio is mixed to prepare.
The preparation technology of a kind of spontaneous heating antibacterial artificial quartz, comprises the steps:
(1) each component is uniformly mixed;
(2) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 96-100 DEG C in described solidification, and hardening time is 50 minutes, second stage Solidification temperature is 92-96 DEG C, and hardening time is 30 minutes.
Embodiment 3
A kind of spontaneous heating antibacterial artificial quartz, is made up of the component of following weight portion (kg): 20-50 mesh quartz sand 58 Part, 20-50 mesh carbon fiber powder 12 parts, 20-50 mesh magnetic therapy fiber powder 12 parts, 8 parts of 20-50 mesh tourmaline powder, nano-graphene 18 Part, composite resin 18 parts, accelerator 10 parts, modified 18 parts of age resistor, 8 parts of colorant.
Described composite resin by phenolic resin, styrenated alkyd, Benzoinum, orthophthalic polyester resin, Tea polyphenols is mixed to prepare by equivalent part.
Described accelerator is vanadium phosphate, to Chlorobenzoic Acid, N, in N-dimethyl open-chain crown ether, triethylene diamine extremely Few one.
Described modified age resistor is 6-ethyoxyl-2, and 2,4-trimethyl-1,2-dihyaroquinoline, N-Phenyl beta naphthylamine are pressed 1:1 ratio is mixed to prepare.
The preparation technology of a kind of spontaneous heating antibacterial artificial quartz, comprises the steps:
(1) each component is uniformly mixed;
(2) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 96-100 DEG C in described solidification, and hardening time is 50 minutes, second stage Solidification temperature is 92-96 DEG C, and hardening time is 30 minutes.
Test
The prepared quartz of the embodiment of the present invention 1,2,3 and commonly artificial quartz in lump detection Data Comparison result such as following table institute Show:
From contrast experiment's data of above table, the artificial quartz in lump of the present invention is than common artificial quartz in lump each side Performance all has greatly improved.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (6)

1. a spontaneous heating antibacterial artificial quartz, it is characterised in that be made up of the component of following weight portion: 20-50 mesh quartz Sand 52-58 part, 20-50 mesh carbon fiber powder 8-12 part, 20-50 mesh magnetic therapy fiber powder 8-12 part, 20-50 mesh tourmaline powder 4-8 part, Nano-graphene 12-18 part, composite resin 12-18 part, accelerator 8-10 part, modified age resistor 14-18 part, colorant 6-8 part.
2. a kind of spontaneous heating antibacterial artificial quartz as claimed in claim 1, it is characterised in that described composite resin is by phenolic aldehyde Resin, styrenated alkyd, Benzoinum, orthophthalic polyester resin, tea polyphenols are mixed to prepare by equivalent part.
3. a kind of spontaneous heating antibacterial artificial quartz as claimed in claim 1, it is characterised in that described accelerator is phosphoric acid Vanadium, to Chlorobenzoic Acid, N, at least one in N-dimethyl open-chain crown ether, triethylene diamine.
4. a kind of spontaneous heating antibacterial artificial quartz as claimed in claim 1, it is characterised in that described modified age resistor is 6- Ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, N-Phenyl beta naphthylamine are mixed to prepare in 1:1 ratio.
5. the preparation technology of a spontaneous heating antibacterial artificial quartz, it is characterised in that comprise the steps:
(1) each component is uniformly mixed;
(2) material mixed is sent in material distributing machine cloth system template die, then by making sheet mould feeding vacuum chamber, evacuation, Vibration moulding, is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
The preparation technology of a kind of spontaneous heating antibacterial artificial quartz the most as claimed in claim 5, it is characterised in that described solidification In two stages, first stage solidification temperature is 96-100 DEG C, and hardening time is 50 minutes, and second stage solidification temperature is 92-96 DEG C, hardening time is 30 minutes.
CN201610480955.0A 2016-06-24 2016-06-24 A kind of spontaneous heating antibacterial artificial quartz Pending CN106145768A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108504017A (en) * 2018-05-11 2018-09-07 佛山市欧铂利复合材料有限公司 A kind of Multifunctional flower card and preparation method thereof
CN109776905A (en) * 2017-11-15 2019-05-21 北京仁创科技集团有限公司 A kind of sand plastic composite materials and preparation method
CN114426414A (en) * 2022-03-17 2022-05-03 福建铵马运动装备科技有限公司 Graphene artificial stone

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390953A (en) * 2011-08-12 2012-03-28 新云石业(云浮)有限公司 Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof
CN102408201A (en) * 2011-08-12 2012-04-11 新云石业(云浮)有限公司 Raw material for health-care man-made quartz stone slabs, man-made quartz stone slab and preparation method thereof
CN103601469A (en) * 2013-11-21 2014-02-26 太原市伦嘉生态健康家居科技有限公司 Environmental health-care functional material and preparation method thereof
CN105601173A (en) * 2014-11-25 2016-05-25 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial quartz stone board and production technology thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390953A (en) * 2011-08-12 2012-03-28 新云石业(云浮)有限公司 Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof
CN102408201A (en) * 2011-08-12 2012-04-11 新云石业(云浮)有限公司 Raw material for health-care man-made quartz stone slabs, man-made quartz stone slab and preparation method thereof
CN103601469A (en) * 2013-11-21 2014-02-26 太原市伦嘉生态健康家居科技有限公司 Environmental health-care functional material and preparation method thereof
CN105601173A (en) * 2014-11-25 2016-05-25 佛山市高明区明城镇新能源新材料产业技术创新中心 Artificial quartz stone board and production technology thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109776905A (en) * 2017-11-15 2019-05-21 北京仁创科技集团有限公司 A kind of sand plastic composite materials and preparation method
CN108504017A (en) * 2018-05-11 2018-09-07 佛山市欧铂利复合材料有限公司 A kind of Multifunctional flower card and preparation method thereof
CN114426414A (en) * 2022-03-17 2022-05-03 福建铵马运动装备科技有限公司 Graphene artificial stone

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Application publication date: 20161123

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