CN111978011B - Quartz plate and preparation method thereof - Google Patents
Quartz plate and preparation method thereof Download PDFInfo
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- CN111978011B CN111978011B CN202010890815.7A CN202010890815A CN111978011B CN 111978011 B CN111978011 B CN 111978011B CN 202010890815 A CN202010890815 A CN 202010890815A CN 111978011 B CN111978011 B CN 111978011B
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- quartz
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/23—Acid resistance, e.g. against acid air or rain
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The invention discloses a quartz plate and a preparation method thereof, and belongs to the technical field of quartz plates. The quartz plate comprises the following components in parts by weight: 700-730 parts of quartz mixture, 100-130 parts of adhesive, 80-100 parts of glass powder and 30-50 parts of toner. The quartz plate prepared by the invention has excellent high strength, acid and alkali resistance and bright visual effect.
Description
Technical Field
The invention belongs to the technical field of quartz plates, and particularly relates to a quartz plate and a preparation method thereof.
Background
With the development of society and the rise of real estate industry, more and more people begin to pay attention to the quality of decoration. The quartz plate is taken as one of a plurality of materials, is popular among people all the time, and has high decorative attractiveness. However, the strength of the existing quartz plate is slightly reduced while the existing quartz plate is attractive, and if the quartz plate is frequently replaced, the use cost is high, so that the actual requirements of people cannot be met. Therefore, it is desirable to provide a quartz plate having high strength and long service life.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a beige glaze and a method for preparing a beige glaze ceramic product by using the beige glaze.
The invention adopts the following technical scheme:
the quartz plate comprises the following components in parts by mass: 700-730 parts of quartz mixture, 100-130 parts of adhesive, 80-100 parts of glass powder and 30-50 parts of toner.
Further, the quartz mixture comprises the following components in parts by weight: 70-120 mesh quartz powder, 40-70 mesh quartz powder, 26-42 mesh quartz powder and 16-26 mesh quartz powder.
Further, the glass powder comprises the following components in parts by weight: 16-30 mesh gray bottom mirror, 8-16 mesh white glass and 6-8 mesh double-sided mirror.
Further, the adhesive comprises the following components in parts by weight: 20-26 parts of dicyclopentenyl methacrylate, 16-17 parts of polysulfone resin, 18-24 parts of acrylic resin, 7-8 parts of calcium palmitate and 6-8 parts of bismaleimide.
The preparation method of the quartz plate comprises the following steps:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
step two, preparing glass powder
Mixing 16-30 meshes of gray bottom mirror, 80-16 meshes of white glass and 6-8 meshes of double-sided mirror according to parts by weight, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
Further, the step of modifying the quartz mixture specifically comprises the following steps:
s1, mixing the 70-120 mesh quartz powder, the 40-70 mesh quartz powder, the 26-42 mesh quartz powder and the 16-26 mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 6-7 mol/L hydrochloric acid for 2-5 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1: 1.2-1.3: 0.7-0.8, and modifying for 20-30 min to obtain modified quartz powder.
Compared with the prior art, the invention has the following beneficial effects:
firstly, in order to achieve the beautiful effect of the quartz plate, quartz with different meshes is adopted as a main raw material, and glass powder with different meshes is matched to form different reflecting surfaces after mixing, so that different visual effects are achieved;
secondly, simultaneously, the light transmittance of the dicyclopentenyl methacrylate, the high-light performance and the high-temperature resistance of the polysulfone resin, the heat resistance of the acrylic resin and the bismaleimide, and the calcium palmitate as a filler have high lubricating performance, so that the quartz mixed material and the glass powder can be fully mixed, and the overall strength of the quartz plate can be improved;
fourthly, the quartz powder is modified by titanium tetrachloride and a coupling agent, so that the direct bonding performance of the quartz powder and a bonding agent is effectively improved, and the integral strength of the quartz plate is improved.
Detailed Description
The raw materials adopted by the invention are all commercial products.
As the coupling agent, commercially available coupling agents such as titanate coupling agent, aluminate coupling agent, silane coupling agent KH-590 and the like can be used.
Example 1
The quartz plate comprises the following components in parts by mass: 700 parts of quartz mixture, 100 parts of adhesive, 80 parts of glass powder and 30 parts of toner.
The quartz mixture comprises the following components in parts by weight: 70-mesh quartz powder, 40-mesh quartz powder, 26-mesh quartz powder and 16-mesh quartz powder.
The glass powder comprises the following components in parts by weight: 16 mesh gray-bottom mirror, 8 mesh white glass, 6 mesh double-sided mirror.
The adhesive comprises the following components in parts by weight: 20 parts of dicyclopentenyl methacrylate, 16 parts of polysulfone resin, 18 parts of acrylic resin, 7 parts of calcium palmitate and 6 parts of bismaleimide.
The preparation method of the quartz plate comprises the following steps:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
the modified quartz mixture is specifically as follows:
s1, mixing the 70-mesh quartz powder, the 40-mesh quartz powder, the 26-mesh quartz powder and the 16-mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 6mol/L hydrochloric acid for 2 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1:1.2:0.7, and modifying for 20min to obtain modified quartz powder;
step two, preparing glass powder
Mixing the 16-mesh gray bottom mirror, 80-mesh white glass and a 6-mesh double-sided mirror according to parts by weight, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
Example 2
The quartz plate comprises the following components in parts by mass: 710 parts of quartz mixture, 110 parts of adhesive, 90 parts of glass powder and 40 parts of toner.
The quartz mixture comprises the following components in parts by weight: 80-mesh quartz powder, 50-mesh quartz powder, 30-mesh quartz powder and 20-mesh quartz powder.
The glass powder comprises the following components in parts by weight: 20 mesh gray bottom mirror, 10 mesh white glass, 7 mesh double sided mirror.
The adhesive comprises the following components in parts by weight: 21 parts of dicyclopentenyl methacrylate, 17 parts of polysulfone resin, 20 parts of acrylic resin, 8 parts of calcium palmitate and 7 parts of bismaleimide.
The preparation method of the quartz plate comprises the following steps:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
the modified quartz mixture is specifically as follows:
s1, mixing the 80-mesh quartz powder, the 50-mesh quartz powder, the 30-mesh quartz powder and the 20-mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 7mol/L hydrochloric acid for 3 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1:1.3:0.8, and modifying for 25min to obtain modified quartz powder;
step two, preparing glass powder
Mixing the 20-mesh gray bottom mirror, the 10-mesh white glass and the 7-mesh double-sided mirror according to the parts by mass, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
Example 3
The quartz plate comprises the following components in parts by mass: 720 parts of quartz mixture, 120 parts of adhesive, 90 parts of glass powder and 45 parts of toner.
The quartz mixture comprises the following components in parts by weight: 100 meshes of quartz powder, 60 meshes of quartz powder, 40 meshes of quartz powder and 20 meshes of quartz powder.
The glass powder comprises the following components in parts by weight: 25 mesh gray-bottom mirror, 10 mesh white glass, 8 mesh double-sided mirror.
The adhesive comprises the following components in parts by weight: 25 parts of dicyclopentenyl methacrylate, 17 parts of polysulfone resin, 22 parts of acrylic resin, 7 parts of calcium palmitate and 7 parts of bismaleimide.
The preparation method of the quartz plate comprises the following steps:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
the modified quartz mixture is specifically as follows:
s1, mixing the 110-mesh quartz powder, the 60-mesh quartz powder, the 40-mesh quartz powder and the 20-mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 7mol/L hydrochloric acid for 4 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1:1.2:0.8, and modifying for 30min to obtain modified quartz powder;
step two, preparing glass powder
Mixing the 25-mesh gray bottom mirror, the 10-mesh white glass and the 8-mesh double-sided mirror according to the parts by mass, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
Example 4
The quartz plate comprises the following components in parts by mass: 730 parts of quartz mixture, 130 parts of adhesive, 100 parts of glass powder and 50 parts of toner.
The quartz mixture comprises the following components in parts by weight: 120-mesh quartz powder, 70-mesh quartz powder, 42-mesh quartz powder and 26-mesh quartz powder.
The glass powder comprises the following components in parts by weight: 30 mesh gray bottom mirror, 16 mesh white glass, 8 mesh double-sided mirror.
The adhesive comprises the following components in parts by weight: 26 parts of dicyclopentenyl methacrylate, 17 parts of polysulfone resin, 24 parts of acrylic resin, 8 parts of calcium palmitate and 8 parts of bismaleimide.
The preparation method of the quartz plate comprises the following steps:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
the modified quartz mixture is specifically as follows:
s1, mixing the 120-mesh quartz powder, the 70-mesh quartz powder, the 42-mesh quartz powder and the 26-mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 7mol/L hydrochloric acid for 5 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1:1.3:0.8, and modifying for 30min to obtain modified quartz powder;
step two, preparing glass powder
Mixing the 30-mesh gray bottom mirror, the 16-mesh white glass and the 8-mesh double-sided mirror according to the parts by mass, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
The quartz plates obtained in examples 1 to 4 were examined, wherein:
1. breaking strength: the standard is SN/T0308-1993;
2. radioactivity limit index (no radiation): the internal and external irradiation indexes conform to GB 6566-2010.
3. Water absorption: GB/T9966.3-2001
4. Shore hardness: GB/T9966.5-2001
5. Acid resistance: GB/T9966.6-2001
6. Gloss: GB/T13891 once again 2008
Table: results of testing the quartz plates obtained in examples 1 to 4
The quartz plate prepared in the embodiments 1 to 4 has a bright visual effect, high glossiness, high strength and strong acid resistance.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (3)
1. The quartz plate is characterized by comprising the following components in parts by mass: 700-730 parts of quartz mixture, 100-130 parts of adhesive, 80-100 parts of glass powder and 30-50 parts of toner;
the quartz mixture comprises the following components in parts by weight: 70-120 mesh quartz powder, 40-70 mesh quartz powder, 26-42 mesh quartz powder and 16-26 mesh quartz powder;
the glass powder comprises the following components in parts by weight: 16-30 meshes of gray bottom mirror, 8-16 meshes of white glass and 6-8 meshes of double-sided mirror;
the adhesive comprises the following components in parts by weight: 20-26 parts of dicyclopentenyl methacrylate, 16-17 parts of polysulfone resin, 18-24 parts of acrylic resin, 7-8 parts of calcium palmitate and 6-8 parts of bismaleimide.
2. The method for producing a quartz plate material as set forth in claim 1, characterized by comprising the steps of:
step one, modifying quartz mixture
Modifying the quartz mixture according to the parts by mass to obtain modified quartz powder;
step two, preparing glass powder
Mixing 16-30 meshes of gray bottom mirror, 80-16 meshes of white glass and 6-8 meshes of double-sided mirror according to parts by weight, and crushing to obtain glass powder;
step three, forming
And (3) uniformly mixing the modified quartz powder, the glass powder, the adhesive and the toner obtained in the step one to obtain a quartz plate mixture, then placing the quartz plate mixture into a mold, and solidifying to obtain the quartz plate.
3. The method for preparing the quartz plate according to claim 2, wherein the step of modifying the quartz mixture comprises the following specific steps:
s1, mixing the 70-120 mesh quartz powder, the 40-70 mesh quartz powder, the 26-42 mesh quartz powder and the 16-26 mesh quartz powder according to the mass parts to obtain a quartz powder mixture;
s2, mixing and stirring the quartz powder mixture obtained in the S1 and 6-7 mol/L hydrochloric acid for 2-5 minutes to obtain a clean quartz powder mixture;
s3, mixing, stirring and modifying the clean quartz powder mixture obtained in the step S2, titanium tetrachloride and a coupling agent according to the following mass ratio: 1: 1.2-1.3: 0.7-0.8, and modifying for 20-30 min to obtain modified quartz powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010890815.7A CN111978011B (en) | 2020-08-29 | 2020-08-29 | Quartz plate and preparation method thereof |
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| CN202010890815.7A CN111978011B (en) | 2020-08-29 | 2020-08-29 | Quartz plate and preparation method thereof |
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| CN111978011A CN111978011A (en) | 2020-11-24 |
| CN111978011B true CN111978011B (en) | 2022-03-25 |
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| CN111116097A (en) * | 2020-01-16 | 2020-05-08 | 安徽耐洁新材料科技有限公司 | Artificial quartz stone plate and preparation method thereof |
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| CN101186464B (en) * | 2007-12-07 | 2010-05-19 | 南安市广泰祥石材有限公司 | Translucent artificial marble and manufacturing method thereof |
| CN102249597A (en) * | 2010-12-17 | 2011-11-23 | 范会生 | Decorative plate and preparation method thereof |
| CN105621945A (en) * | 2014-10-27 | 2016-06-01 | 广东中旗新材料科技有限公司 | Three-color artificial quartz stone plate and production process thereof |
| CN104478293A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Synthetic quartzite plate and preparation method thereof |
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125746A (en) * | 2007-07-03 | 2008-02-20 | 陈志强 | Reflecting type broken mirror artificial stone and manufacturing technique thereof |
| CN102712538A (en) * | 2010-01-26 | 2012-10-03 | 力格奈特株式会社 | Composition for refractory brick, refractory brick, and method for producing refractory brick |
| CN104478290A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Anti-aging artificial quartz stone panel and preparation method thereof |
| CN105776951A (en) * | 2014-12-26 | 2016-07-20 | 哈尔滨润德伟业科技发展有限公司 | Method for processing high-performance artificial quartz stone |
| WO2019104700A1 (en) * | 2017-12-01 | 2019-06-06 | 朱冠军 | Antibacterial quartz stone lining plate and preparation method therefor |
| CN111116097A (en) * | 2020-01-16 | 2020-05-08 | 安徽耐洁新材料科技有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111499267A (en) * | 2020-03-24 | 2020-08-07 | 肇庆威泰石英石有限公司 | Chrysanthemum pattern quartz stone plate and preparation method thereof |
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| CN111978011A (en) | 2020-11-24 |
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