CN110128058A - A kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation - Google Patents
A kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation Download PDFInfo
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- CN110128058A CN110128058A CN201910415902.4A CN201910415902A CN110128058A CN 110128058 A CN110128058 A CN 110128058A CN 201910415902 A CN201910415902 A CN 201910415902A CN 110128058 A CN110128058 A CN 110128058A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
- C04B2111/545—Artificial marble
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The present invention discloses a kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation, the artificial marble is made of following composition by weight: using unsaturated polyester resin as 38-45 parts of binder, 50-58 parts of aggregate based on processing of stone waste material, using the organic fiber of textile fabric as 19-25 parts of reinforcing agent, 1-2 parts of curing agent, 1-2 parts of promotor, 1-2 parts of coupling agent, 0.1-0.2 parts of light stabilizer.The regenerants such as waste and old terylene textile fabric are not only efficiently utilized in artificial marble of the invention, also addition light stabilizer, increase the weatherability and ageing resistance of the artificial stone, while designing using sandwich type, reduce cost of manufacture, artificial stone meets building material industry standard.
Description
Technical field
The invention belongs to the technical fields of construction material, also belong to resource high-qualityization and utilize field, and in particular to Yi Zhongyong
The artificial marble and preparation method thereof of discarded terylene textile fabric preparation.
Background technique
With the fast development of China's economic society, inhabitant's consumption level is continuously improved, terylene demand continuous rise.It washs
Synthetic fibre textile fabric main component is polyester fiber PET, and PET molecule is because of its fusing point, tensile strength, rigidity and hardness with higher etc.
Excellent performance is used widely, and the recycling and reusing of the discarded terylene textile fabric of consequent faces huge challenge.
Currently, terylene recovery method mainly has physiochemical mutagens and chemical recovery, traditional physical recovery method is cut as squeezed
It cuts, be granulated etc., substantially reduce material property, being typically only capable to degrade uses, and it is limited to recycle duplicate number.And chemistry returns
Receipts technology is to be broken the ester chain in PET strand by chemical reaction, is converted into molecular weight relatively low intermediate or list
Body molecule, then polycondensation is made other products again.Compared with physical recovery method, chemical recovery can be from high molecular material sheet
It sets out in matter, resource is maximally utilized, really realize resources circulation, therefore chemical recovery techniques are preferred consideration directions.
Artificial marble is to be stirred varigrained natural granite or river sand etc. using modified resin etc. as binder
It is made after mixing, grind and polishing, is a kind of novel composite material.It has strong resistance to chemical corrosion, while having good
Environmental adaptability, adjustable color, be conducive to facing decorate, be the ideal ornament materials of modern architecture.The present invention is not using
Saturated polyester resin, the aggregate based on processing of stone waste material, using waste textile organic fiber as reinforcing agent, obtained people
Marble is made, building material industry standard is met, waste and old terylene textile fabric is efficiently utilized, the high-qualityization utilization for resource in industry mentions
For using for reference, meanwhile, light stabilizer is introduced in the present invention, and design using sandwich type, not only increase the weatherability of the artificial stone
And ageing resistance, while more save the cost, extend the service life of the artificial stone, green building material theory is better achieved.
Summary of the invention
Aiming at the problem that above-mentioned background technique, the purpose of the present invention aims to solve the problem that waste and old terylene material is difficult to recycling and reusing
The problem of, a kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation is provided.
To achieve the above object, the present invention uses following scheme:
1. a kind of artificial marble with discarded terylene textile fabric preparation, which is characterized in that group becomes as follows by mass fraction:
38-45 parts of unsaturated polyester resin
50-58 parts of processing of stone waste material
19-25 parts of organic fiber
1-2 parts of curing agent
1-2 parts of promotor
1-2 parts of coupling agent
0.1-0.2 parts of light stabilizer.
It is the unsaturated polyester resin that prepare of raw material or modification unsaturation that the unsaturated polyester resin, which is selected from using r-PET,
Polyester resin.
The processing of stone waste material is the waste material or leftover pieces in process, and partial size is 20-100 mesh after processing.
The promotor is selected from cobalt naphthenate, cobalt iso-octoate or zinc Isoocatanoate.
The organic fiber is waste textile fiber, and length 8-45mm is selected from terylene textile fabric or with terylene
It is main one or both of blended.
The curing agent is organic peroxide, is selected from peroxidized t-butyl perbenzoate, 1,1-, bis- t-amyl peroxy
Hexamethylene or benzoyl peroxide.
The coupling agent is selected from aluminate coupling agent, titanate coupling agent or silane coupling agent.
The artificial marble is sandwich type.
The light stabilizer is selected from benzotriazole or Benzophenones.
Steps are as follows for a kind of preparation method of artificial marble with discarded terylene textile fabric preparation of the present invention:
A. pan type physico chemical reactor is added in the processing of stone waste material that partial size is 0.8-5mm to mill, while control loop is cold
But 20-100 mesh microlith powder is made at 5-25 DEG C, revolving speed 10-150rpm, mill to death 10-55 times in coolant-temperature gage;It is 8- by length
Pan type physico chemical reactor is added in the organic fiber of 45mm, control loop coolant-temperature gage at 5-35 DEG C, revolving speed 30-150rpm,
Mill to death 5-15 times obtained fine strip shape organic fiber;
B. processing of stone waste material and organic fiber after step A drying and processing are weighed, is sequentially added in reaction kettle A, in 400-
It is uniformly mixed under the mixing speed of 600rpm;
C. processing of stone waste material, organic fiber and the light stabilizer after step A drying and processing are weighed, reaction kettle B is sequentially added
In, it is uniformly mixed under the mixing speed of 600-800rpm;
D. mixing speed is increased to 1000-2000rpm, and unsaturated polyester resin, coupling agent, curing agent and promotor are fallen respectively
Enter reaction kettle A and reaction kettle B, quickly stirs 1-5min and form uniform mixture, obtain regeneration concrete A and regeneration concrete respectively
B;
E. mold is warming up to 100-130 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half to mold
In, the regeneration concrete B of half accounts for the 25% of mold capacity, continues to pour regeneration concrete A after fast vibration is smooth, regeneration is mixed
Solidifying soil A accounts for the 50% of mold capacity, and that pours remaining half after vibration is smooth again builds growing concrete B, after fast vibration compacting storage,
Guan Bi mould curing molding, pressure maintaining 90-180s;
F. artificial marble is made in abjection mold and deburring.
The invention has the benefit that 1) unsaturated polyester resin that the present invention quotes, has digested original need at burning
The waste material of reason reduces environmental pressure;2) efficiently waste and old terylene textile fabric is utilized in the present invention, is the high-qualityization benefit of resource in industry
With offering reference, while sandwich type artificial marble is designed, reduce manufacturing cost, there is environmental economical profit;3) present invention system
Standby artificial stone has excellent weatherability and ageing resistance, extends the artificial stone on the basis of meeting building material industry standard
Service life, green building material theory is better achieved.
Detailed description of the invention
Fig. 1 is a kind of artificial marble preparation technology flow chart with discarded terylene textile fabric preparation;
Fig. 2 is the DSC curve of unsaturated polyester resin;
Fig. 3 is artificial marmorean T under different heating ratesi、TpAnd TfMatched curve.
Specific embodiment
Son is described in further details the present invention combined with specific embodiments below, but this should not be interpreted as of the invention
Range is only limitted to following embodiment.
Embodiment 1
The processing of stone waste material of the present embodiment is the waste material and leftover pieces in process, is chosen in particular from sandstone, shale stone material adds
Work waste material;Organic fiber is waste textile fiber, is selected from waste and old terylene textile fabric.
A kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation, preparation process is as follows:
A. partial size is added pan type physico chemical reactor and milled for sandstone, the shale processing waste material of 3-5mm, while control loop
80-100 mesh microlith powder can be made mill to death 50 times at 20-25 DEG C, revolving speed 150rpm in cooling water temperature;It is 30- by length
Pan type physico chemical reactor is added in the waste and old terylene textile fabric of 45mm, and control loop coolant-temperature gage is in 25-30 DEG C, revolving speed
100rpm, can be made fine strip shape organic fiber mill to death 10 times;
B. 50 parts of processing of stone waste materials after step A drying and processing and 20 parts of waste and old terylene textile fabrics are weighed, are sequentially added anti-
It answers in kettle A, is uniformly mixed under the mixing speed of 400rpm;
C. 50 parts of processing of stone waste materials after step A drying and processing, 20 parts of waste and old terylene textile fabrics and 0.1 part of UV- are weighed
320, it sequentially adds in reaction kettle B, is uniformly mixed under the mixing speed of 500rpm;
D. mixing speed is increased to 1500rpm, by 40 parts of unsaturated polyester resin (abbreviation UPR), 1.2 parts of cobalt naphthenate, aluminic acid
1 part of ester coupling agent and 1,1.2 parts of bis- t-amyl peroxy hexamethylene of 1- pours into reaction kettle A and reaction kettle B respectively, quickly stirs
2min forms uniform mixture, obtains regeneration concrete A and regeneration concrete B respectively;
E. mold is warming up to 100 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half into mold, one
Half regeneration concrete B accounts for the 25% of mold capacity, continues to pour regeneration concrete A, regeneration concrete A after fast vibration is smooth
The 50% of mold capacity is accounted for, the growing concrete B that builds for pouring remaining half after vibration is smooth again is closed mould after fast vibration compacting storage
Have curing molding, pressure maintaining 90s;
F. artificial marble is made in abjection mold and deburring.
Embodiment 2
The processing of stone waste material of the present embodiment is waste material and leftover pieces in process, and it is useless to be chosen in particular from granite building material processing
Material;Organic fiber is the waste and old blended or waste and old terylene textile fabric based on terylene.
Steps are as follows for a kind of preparation method of the artificial marble with discarded terylene textile fabric preparation:
A. pan type physico chemical reactor is added in the granite building material processing waste material that partial size is 1-5mm to mill, while control follows
50-80 mesh microlith powder can be made mill to death 30 times at 15-20 DEG C, revolving speed 120rpm in ring cooling water temperature;It is 8- by length
Pan type physico chemical reactor is added in the organic fiber of 45mm, and control loop coolant-temperature gage is at 15-20 DEG C, revolving speed 115rpm, weight
Fine strip shape organic fiber can be made by milling again 8 times;
B. 55 parts and 22 parts of organic fiber of granite building material processing waste material after step A drying and processing are weighed, is sequentially added anti-
It answers in kettle A, is uniformly mixed under the mixing speed of 500rpm;
C. 22 parts of 55 parts of granite building material processing waste material, organic fiber and UV-P 0.15 after step A drying and processing are weighed
Part, it sequentially adds in reaction kettle B, is uniformly mixed under the mixing speed of 600rpm;
D. mixing speed is increased to 1200rpm, by 42 parts of unsaturated polyester resin, 1 part of cobalt naphthenate, 1.2 parts of KH570 and mistake
Reaction kettle A and reaction kettle B are poured into 1 part of t-butyl perbenzoate of oxidation respectively, are quickly stirred 3min and are formed uniform mixture, respectively
Regeneration concrete A and regeneration concrete B;
E. mold is warming up to 115 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half into mold, one
Half regeneration concrete B accounts for the 25% of mold capacity, continues to pour regeneration concrete A, regeneration concrete A after fast vibration is smooth
The 50% of mold capacity is accounted for, the growing concrete B that builds for pouring remaining half after vibration is smooth again is closed mould after fast vibration compacting storage
Have curing molding, pressure maintaining 100s;
F. artificial marble is made in abjection mold and deburring.
Embodiment 3
The following processing of stone waste material of the present embodiment is the waste material and leftover pieces in process, is chosen in particular from processing of stone generation
Barren rock slurry;Following organic fibers is waste and old blended based on terylene.
Steps are as follows for a kind of preparation method of the artificial marble with discarded terylene textile fabric preparation:
A. pan type physico chemical reactor is added in the barren rock slurry that partial size is 1.2-3mm to mill, while control loop coolant water temperature
50-70 mesh microlith powder can be made mill to death 25 times at 10-15 DEG C, revolving speed 130rpm in degree;It is 8-45mm with terylene by length
Based on waste and old blended addition pan type physico chemical reactor, control loop coolant-temperature gage at 10-15 DEG C, revolving speed 105rpm, weight
Fine strip shape organic fiber can be made by milling again 5 times;
B. it weighs the barren rock after step A drying and processing and starches 56 parts and waste and old blended 25 parts based on terylene, sequentially add anti-
It answers in kettle A, is uniformly mixed under the mixing speed of 550rpm;
C. it weighs the barren rock after step A drying and processing and starches 56 parts, waste and old blended 25 parts based on terylene and UV-531 0.12
Part, it sequentially adds in reaction kettle B, is uniformly mixed under the mixing speed of 650rpm;
D. mixing speed is increased to 1800rpm, by 45 parts of unsaturated polyester resin, 1 part of cobalt iso-octoate, 1 part of titanate coupling agent
Pour into reaction kettle A and reaction kettle B respectively with 1 part of benzoyl peroxide, quickly stir 4min form uniform mixture, respectively again
Growing concrete A and regeneration concrete B;
E. mold is warming up to 120 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half into mold, one
Half regeneration concrete B accounts for the 25% of mold capacity, continues to pour regeneration concrete A, regeneration concrete A after fast vibration is smooth
The 50% of mold capacity is accounted for, the growing concrete B that builds for pouring remaining half after vibration is smooth again is closed mould after fast vibration compacting storage
Have curing molding, pressure maintaining 150s;
F. artificial marble is made in abjection mold and deburring.
Embodiment 4
The following processing of stone waste material of the present embodiment is the waste material and leftover pieces in process, is chosen in particular from lithotome processing
Barren rock block, the rubble of generation;Following organic fibers is waste and old terylene textile fabric.
Steps are as follows for a kind of preparation method of the artificial marble with discarded terylene textile fabric preparation:
A. pan type physico chemical reactor is added in the processing of stone waste material that partial size is 0.8-3mm to mill, while control loop is cold
But 60-100 mesh microlith powder can be made in 15-22 DEG C, revolving speed 100rpm, mill to death 45 times in coolant-temperature gage;It is 8-45mm by length
Organic fiber pan type physico chemical reactor is added, control loop coolant-temperature gage is at 15-22 DEG C, revolving speed 80rpm, mill to death
Fine strip shape organic fiber can be made 8 times;
B. 52 parts and 22 parts of organic fiber of processing of stone waste material after step A drying and processing are weighed, reaction kettle A is sequentially added
In, it is uniformly mixed under the mixing speed of 450rpmrpm;
C. 22 parts of 52 parts of processing of stone waste material, organic fiber after step A drying and processing and 0.15 part of UV-328 are weighed, according to
In secondary addition reaction kettle B, it is uniformly mixed under the mixing speed of 700rpm;
D. increase mixing speed to 1500rpm, by 40 parts of unsaturated polyester resin, 1.2 parts of zinc Isoocatanoate, 1.5 parts of KH570 and
1.2 parts of peroxidized t-butyl perbenzoate are poured into reaction kettle A and reaction kettle B respectively, are quickly stirred 3min and are formed uniform mixture, point
Regeneration concrete A and regeneration concrete B are not obtained;
E. mold is warming up to 120 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half into mold, one
Half regeneration concrete B accounts for the 25% of mold capacity, continues to pour regeneration concrete A, regeneration concrete A after fast vibration is smooth
The 50% of mold capacity is accounted for, the growing concrete B that builds for pouring remaining half after vibration is smooth again is closed mould after fast vibration compacting storage
Have curing molding, pressure maintaining 120s;
F. artificial marble is made in abjection mold and deburring.
Embodiment 5
The following processing of stone waste material of the present embodiment is the waste material and leftover pieces in process, is chosen in particular from griotte, limestone
Processing of stone waste material;Following organic fibers is waste and old terylene textile fabric.
Steps are as follows for a kind of preparation method of the artificial marble with discarded terylene textile fabric preparation:
A. partial size is added pan type physico chemical reactor and milled for griotte, the limestone processing of stone waste material of 0.8-3mm, simultaneously
6070 mesh microlith powder can be made mill to death 20 times at 20-25 DEG C, revolving speed 150rpm in control loop cooling water temperature;By length
Pan type physico chemical reactor is added for the waste and old terylene textile fabric of 8-45mm, control loop coolant-temperature gage is in 20-20 DEG C, revolving speed
100rpm, can be made fine strip shape organic fiber mill to death 15 times;
B. the griotte after step A drying and processing, 55 parts of limestone processing of stone waste material and 22 parts of waste and old terylene textile fabric are weighed,
It sequentially adds in reaction kettle A, is uniformly mixed under the mixing speed of 500rpm;
C. weigh the griotte after step A drying and processing, 55 parts of limestone processing of stone waste material, 22 parts of waste and old terylene textile fabric and
It 0.16 part of UV-328, sequentially adds in reaction kettle B, is uniformly mixed under the mixing speed of 620rpm;
D. mixing speed is increased to 2000rpm, by 42 parts of unsaturated polyester resin, 1.2 parts of cobalt iso-octoate, aluminate coupling agent 1
Part pours into reaction kettle A and reaction kettle B with 1.2 parts of benzoyl peroxide respectively, quickly stirs 3min and forms uniform mixture, respectively
Obtain regeneration concrete A and regeneration concrete B;
E. mold is warming up to 115 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half into mold, one
Half regeneration concrete B accounts for the 25% of mold capacity, continues to pour regeneration concrete A, regeneration concrete A after fast vibration is smooth
The 50% of mold capacity is accounted for, the growing concrete B that builds for pouring remaining half after vibration is smooth again is closed mould after fast vibration compacting storage
Have curing molding, pressure maintaining 130s;
F. artificial marble is made in abjection mold and deburring.
Claims (10)
1. a kind of artificial marble with discarded terylene textile fabric preparation, which is characterized in that be grouped by the group of following mass fractions
At:
38-45 parts of unsaturated polyester resin
50-58 parts of processing of stone waste material
19-25 parts of organic fiber
1-2 parts of curing agent
1-2 parts of promotor
1-2 parts of coupling agent
0.1-0.2 parts of light stabilizer.
2. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Unsaturated polyester resin be selected from the unsaturated polyester resin or modified unsaturated polyester resin that prepare using r-PET as raw material.
3. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Processing of stone waste material be process in waste material or leftover pieces, after processing partial size be 20-100 mesh.
4. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Promotor be selected from cobalt naphthenate, cobalt iso-octoate or zinc Isoocatanoate.
5. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Organic fiber be waste textile fiber, length 8-45mm, in blended selected from terylene textile fabric or based on terylene
It is one or two kinds of.
6. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Curing agent be organic peroxide, be selected from peroxidized t-butyl perbenzoate, 1,1-, bis- t-amyl peroxy hexamethylene or peroxide
Change benzoyl.
7. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Coupling agent be selected from aluminate coupling agent, titanate coupling agent or silane coupling agent.
8. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Artificial marble be sandwich type.
9. a kind of artificial marble with discarded terylene textile fabric preparation according to claim 1, which is characterized in that described
Light stabilizer be selected from benzotriazole or Benzophenones.
10. a kind of preparation method of any artificial marble with discarded terylene textile fabric preparation of claim 1-9, step
It is rapid as follows:
A. pan type physico chemical reactor is added in the processing of stone waste material that partial size is 0.8-5mm to mill, while control loop is cold
But 20-100 mesh microlith powder is made at 5-25 DEG C, revolving speed 10-150rpm, mill to death 10-55 times in coolant-temperature gage;It is 8- by length
Pan type physico chemical reactor is added in the organic fiber of 45mm, control loop coolant-temperature gage at 5-35 DEG C, revolving speed 30-150rpm,
Mill to death 5-15 times obtained fine strip shape organic fiber;
B. it weighs processing of stone waste material and organic fiber after step A drying and processing to sequentially add in reaction kettle A, in 400-
It is uniformly mixed under the mixing speed of 600rpm;
C. processing of stone waste material, organic fiber and the light stabilizer after step A drying and processing are weighed, reaction kettle B is sequentially added
In, it is uniformly mixed under the mixing speed of 600-800rpm;
D. mixing speed is increased to 1000-2000rpm, and unsaturated polyester resin, coupling agent, curing agent and promotor are fallen respectively
Enter reaction kettle A and reaction kettle B, quickly stirs 1-5min and form uniform mixture, obtain regeneration concrete A and regeneration concrete respectively
B;
E. mold is warming up to 100-130 DEG C, and smears external release agent, first pour the regeneration concrete B of above-mentioned half to mold
In, the regeneration concrete B of half accounts for the 25% of mold capacity, continues to pour regeneration concrete A after fast vibration is smooth, regeneration is mixed
Solidifying soil A accounts for the 50% of mold capacity, and that pours remaining half after vibration is smooth again builds growing concrete B, after fast vibration compacting storage,
Guan Bi mould curing molding, pressure maintaining 90-180s;
F. artificial marble is made in abjection mold and deburring.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112408859A (en) * | 2020-12-04 | 2021-02-26 | 姚智 | Environment-friendly artificial stone and preparation method thereof |
CN113942098A (en) * | 2021-11-07 | 2022-01-18 | 福建师范大学 | Method for enhancing regenerated artificial stone by modifying and opening fibers through waste textiles |
CN114195449A (en) * | 2021-12-07 | 2022-03-18 | 华南理工大学 | Wet-mixed mortar and preparation method thereof |
CN116217127A (en) * | 2022-12-30 | 2023-06-06 | 广东省科学院资源利用与稀土开发研究所 | Preparation method of blend fiber micro-alcoholysis-enhanced regenerated organic artificial stone |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010071314A2 (en) * | 2008-12-15 | 2010-06-24 | 제일모직 주식회사 | Marble chips for an artificial marble, manufacturing method thereof, and artificial marble comprising same |
CN102924002A (en) * | 2012-11-09 | 2013-02-13 | 沈阳建筑大学 | Recycled concrete made of discarded fiber and preparation method thereof |
CN104261727A (en) * | 2014-09-17 | 2015-01-07 | 常州明清新材料技术有限公司 | Method for preparing high-gloss high-permeability artificial colored quartz plate |
CN104496272A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Anti-aging artificial quartzite plate and manufacturing method thereof |
CN105563891A (en) * | 2015-12-25 | 2016-05-11 | 林铭昭 | Two-layer composite artificial stone and preparation method thereof |
CN106242360A (en) * | 2016-07-29 | 2016-12-21 | 山东康洁利人造石有限公司 | A kind of antibacterial artificial quartz and production technology thereof |
CN107188486A (en) * | 2017-05-23 | 2017-09-22 | 西安理工大学 | It is a kind of to be mixed with concrete of garment fabric and preparation method thereof |
-
2019
- 2019-05-19 CN CN201910415902.4A patent/CN110128058A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010071314A2 (en) * | 2008-12-15 | 2010-06-24 | 제일모직 주식회사 | Marble chips for an artificial marble, manufacturing method thereof, and artificial marble comprising same |
CN102924002A (en) * | 2012-11-09 | 2013-02-13 | 沈阳建筑大学 | Recycled concrete made of discarded fiber and preparation method thereof |
CN104261727A (en) * | 2014-09-17 | 2015-01-07 | 常州明清新材料技术有限公司 | Method for preparing high-gloss high-permeability artificial colored quartz plate |
CN104496272A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Anti-aging artificial quartzite plate and manufacturing method thereof |
CN105563891A (en) * | 2015-12-25 | 2016-05-11 | 林铭昭 | Two-layer composite artificial stone and preparation method thereof |
CN106242360A (en) * | 2016-07-29 | 2016-12-21 | 山东康洁利人造石有限公司 | A kind of antibacterial artificial quartz and production technology thereof |
CN107188486A (en) * | 2017-05-23 | 2017-09-22 | 西安理工大学 | It is a kind of to be mixed with concrete of garment fabric and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
王中华: "用涤纶废料制备不饱和聚脂", 《塑料工业》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112408859A (en) * | 2020-12-04 | 2021-02-26 | 姚智 | Environment-friendly artificial stone and preparation method thereof |
CN113942098A (en) * | 2021-11-07 | 2022-01-18 | 福建师范大学 | Method for enhancing regenerated artificial stone by modifying and opening fibers through waste textiles |
CN114195449A (en) * | 2021-12-07 | 2022-03-18 | 华南理工大学 | Wet-mixed mortar and preparation method thereof |
CN116217127A (en) * | 2022-12-30 | 2023-06-06 | 广东省科学院资源利用与稀土开发研究所 | Preparation method of blend fiber micro-alcoholysis-enhanced regenerated organic artificial stone |
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