CN105645842A - Artificial stone prepared from waste polished tile and preparation method thereof - Google Patents
Artificial stone prepared from waste polished tile and preparation method thereof Download PDFInfo
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- CN105645842A CN105645842A CN201511008961.8A CN201511008961A CN105645842A CN 105645842 A CN105645842 A CN 105645842A CN 201511008961 A CN201511008961 A CN 201511008961A CN 105645842 A CN105645842 A CN 105645842A
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- waste residues
- artificial stone
- polished tiles
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses artificial stone prepared from waste polished tile and a preparation method thereof. The artificial stone is prepared by compounding recovered waste polished tile and unsaturated polyester resin. As the waste polished tile is calcined at high temperature of 1200 DEG C and above, performance is stable and heat resistance is good. The artificial stone prepared by compounding the waste polished tile and unsaturated polyester resin has high mechanical strength, high impact strength, heat resistance, environmental stress crack resistance, good weatherability and long service life. As the waste polished tile is obtained by recovering wastes generated from polished tile production process, lots of energy needn't be consumed in comparison with a common filling material, cost is lower, and cost performance of the prepared artificial stone is better.
Description
Technical field
The present invention relates to polymeric material field, relate generally to a kind of prepare with waste residues of polished tiles artificialStone material and preparation method thereof.
Background technology
Artificial stone is taking unsaturated polyester resin as adhesive, be equipped with natural marble or calcite,The inorganic matter powders such as dolomite, silica sand, glass dust, and appropriate fire retardant, color etc., through joiningThe method forming and hardenings such as material mixing, porcelain casting, vibrocompression, extruding are made. And these powders are elongatedNeed through making by operations such as calcining, digestion, carbonization, sub-argument, dry, pulverizing, screenings,Or made through operations such as fragmentation, pulverizing, screenings by raw material, production process need to expend a large amount of energySource.
And polished bricks can produce a large amount of waste residues of polished tiles, this polishing in the process of grinding, polishingBrick waste residue is mainly the silicate such as silica, feldspar composition, feature is that granularity is very thin, intensity is high,Containing organic, lack viscosity, the unsuitable soil as plantation, is dispersity after air-dry, very easilyFloat down on the wind everywhere, understand the healthy of serious threat surrounding population, and cause the plate in periphery soilKnot, causes serious environmental pollution. Although compare for the comprehensive utilization of polishing slag at presentMany research, but still lack the correlation technique of it being carried out to extensive recycling, therefore its processingBe main mainly with landfill, environment has been caused and had a strong impact on. Polishing slag air storage also can be made environmentBecome to pollute, be unfavorable for sustainable development. And the landfill of waste residues of polished tiles, not only labor intensive, material resources,Also can polluted underground water matter, according to statistics, the large appointment of polished bricks of manufacturing 1 square metre forms 2.1 kilogramsThe waste residues of polished tiles of left and right. Therefore, the recycling of waste residues of polished tiles is those skilled in the art alwaysA difficult problem of tackling key problems.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, the object of the present invention is to provide one waste residues of polished tilesArtificial stone of preparation and preparation method thereof, recycles described waste residues of polished tiles, as artificial stoneThe filler of material, is intended to solve existing artificial stone because required filler is many, cause the required cost of filler andFiller need to expend the problem of mass energy while production, and what solve waste residues of polished tiles is difficult to reclaim profit simultaneouslyUse problem.
Technical scheme of the present invention is as follows:
An artificial stone who prepares with waste residues of polished tiles, wherein, described artificial stone is with polished brick wasteSlag is filler.
The described artificial stone who prepares with waste residues of polished tiles, wherein, described waste residues of polished tiles is usingBefore need to pass through coupling agent activation processing:
Waste residues of polished tiles is dropped into stirring and drying in high-speed mixer, make its water content lower than 0.3%; AddEnter 0.5～5% coupling agent by waste residues of polished tiles gross mass;
Described coupling agent be a kind of in silane coupler, titanate coupling agent, aluminate coupling agent orMultiple.
The described artificial stone who prepares with waste residues of polished tiles, wherein, described coupling agent is that Aluminate is evenConnection agent.
The described artificial stone who prepares with waste residues of polished tiles, wherein, described artificial stone's raw material groupBecome, according to mass fraction meter, comprise following component:
The described artificial stone who prepares with waste residues of polished tiles, wherein, described unsaturated polyester resin isThe unsaturated polyester resin being formed by saturated and undersaturated binary acid and dihydroxylic alcohols polycondensation, wherein shouldSaturated acid is adjacent benzene type, metaphenylene, p-phenyl; And this di-alcohols be ethylene glycol, propane diols,Methyl propanediol, diethylene glycol (DEG), neopentyl glycol class.
The described artificial stone who prepares with waste residues of polished tiles, wherein, describedly prepares with waste residues of polished tilesArtificial stone, its raw material composition, according to the mass fraction, also comprises following component:
1～20 part of nano material;
The described artificial stone who prepares with waste residues of polished tiles, wherein, describedly prepares with waste residues of polished tilesArtificial stone's raw material composition in also comprise appropriate mill base.
The described artificial stone who prepares with waste residues of polished tiles, wherein, described curing agent is peroxidating firstEthyl ketone and cyclohexanone peroxide.
An artificial stone's as above preparation method, wherein, comprises the following steps:
Waste residues of polished tiles is carried out to coupling agent activation processing;
Unsaturated polyester resin is put into vacuum stirring tank, then put into promoter and stir 2～5 minutes;Put into waste residues of polished tiles and stir 20～25 minutes, then add 20～25 points of curing agent vacuum uniform stirringsClock; The slurry being stirred is poured on the glass plate that framed inner surface scribbles releasing agent, through 20～25Minute curing molding, make the thick artificial stone's sheet material of 18～25mm; After the sheet material demoulding, be placed into againInterior 3～6 hours of the environment that constant temperature is 50～80 DEG C; Send into and in marble automatic polishing machine, carry out surface finish,Cutting.
Described artificial stone's preparation method, wherein, carries out coupling agent activation place to waste residues of polished tilesThe process of reason comprises the following steps:
Waste residues of polished tiles is dropped into stirring and drying in high-speed mixer, make its water content lower than 0.3%; SlowSlow 0.5～5% coupling agent adding by waste residues of polished tiles gross mass;
Described coupling agent be a kind of in silane coupler, titanate coupling agent, aluminate coupling agent orMultiple.
Beneficial effect: a kind of artificial stone who prepares with waste residues of polished tiles provided by the present invention throwsLight brick waste residue is filler, compound with unsaturated polyester resin. Due to waste residues of polished tiles through 1200 degree withUpper high temperature enure mistake, stable performance, good heat resistance, with compound make artificial of unsaturated polyester resinStone material good heat resistance and there is better weatherability longer service life. And, waste residues of polished tilesBeing that the waste residue producing in remanufacture polished bricks process is obtained, itself is that granularity is little, without passing through and beat againMill processing, only need just can be used as filler and use through super-dry, screening, therefore, and waste residues of polished tilesRecycle simple. Do not need to expend a large amount of energy compared with calcium carbonate (expense is more than 300 yuan/ton)Source is obtained, and cost is lower, and the artificial stone's cost performance making is better. Meanwhile, also solved existing throwingLight brick waste residue is difficult to recycle the problem that causes environmental pollution, has protected environment.
Detailed description of the invention
The invention provides a kind of artificial stone who prepares with waste residues of polished tiles and preparation method thereof, for making thisInvention object, technical scheme and effect clearer, clear and definite, below further detailed to the present inventionExplanation. Should be appreciated that specific embodiment described herein is only in order to explain the present invention, and need notIn limiting the present invention.
A kind of artificial stone who prepares with waste residues of polished tiles and preparation method thereof is provided in the present invention, described inArtificial stone is taking waste residues of polished tiles as filler, compound with unsaturated polyester resin, adds other auxiliary agentsCompound make. Described artificial stone is using waste residues of polished tiles as filler, solves filler and produces consumptionThe problem that the energy is large, when having reduced production cost, has solved asking that waste residues of polished tiles is recycledTopic.
Described waste residues of polished tiles is the waste residue that polished bricks produces in the process of grinding, polishing, polished bricksWaste residue is mainly the silicate such as silica, feldspar composition. Because the waste residue of polished bricks itself is polishingThe waste material going out, granularity is little, intensity is high, and waste residues of polished tiles is through the above high temperature sintering mistake of 1200 degree,Good heat resistance, structure is highly stable, therefore, only need to pass through the techniques such as simple drying, screeningJust can reclaim and be used. The compound calcium that can improve of waste residues of polished tiles and unsaturated polyester resin is moulded pipeStability, hardness, rigidity, weatherability, heat resistance and the environmental stress crack resistance of size; ImproveCalcium service life of moulding pipe; Reduce production cost. Preferably 60 orders and above polished bricks in the present inventionWaste residue, waste residues of polished tiles must carry out activation processing through coupling agent before using.
Particularly, the described artificial stone who prepares with waste residues of polished tiles provided by the invention, its raw material groupBecome, according to the mass fraction, comprise following component:
Wherein, described waste residues of polished tiles must carry out activation processing through coupling agent before coming into operation. ByIn the existence of coupling agent polar group, the model between waste residues of polished tiles and unsaturated polyester resin strandDe Huali changes look dispersion force into by simple look dispersion force and adds induction force, add coupling agent molecule withThe entanglement effect of unsaturated polyester resin chain, waste residues of polished tiles is in unsaturated polyester resin matrix like thisPlay the effect of physical crosslinking point, and incorporated the molecular entanglement network of unsaturated polyester resin.The processing procedure of coupling agent activation is as follows:
First waste residues of polished tiles stirs in high-speed mixer (be preheating to temperature of charge and reach 100～110 DEG C)Dry, uncovered 10～15 minutes, object was to drive moisture away, made filler water content lower than 0.3%; SlowlyAdd by the coupling agent of waste residue gross mass 0.5～5% chopping and (notice that not making coupling agent be stirred oar gets toInner wall of mixer), can divide three times and add, every septum secundum adds for 3 minutes, total soak time 9 minutes;Discharge is for subsequent use. Described coupling agent can be silane coupler, titanate coupling agent, aluminate coupling agentIn one or more. The preferred aluminate coupling agent DL-411 of the present invention.
The described artificial stone who prepares with waste residues of polished tiles, can also comprise appropriate in its raw material compositionMill base, can regulate the color of stone material so as required, plays different decorative effects.
Described artificial stone can adopt conventional formula, unsaturated polyester resin and auxiliary agent to make, thisIn invention, main improvement is the filler using 60 orders and above waste residues of polished tiles as product.
Described unsaturated polyester resin is by saturated contracting with undersaturated binary acid (acid anhydride) and dihydroxylic alcoholsThe unsaturated polyester resin that combinate form becomes, wherein this saturated acid can be adjacent benzene type, metaphenylene, to benzeneType; And this di-alcohols can be ethylene glycol, propane diols, methyl propanediol, diethylene glycol (DEG), new pentaGlycols.
Described curing agent and promoter are the special promoter of unsaturated polyester resin and curing agent. Described solidAgent can be methyl ethyl ketone peroxide and cyclohexanone peroxide.
The described artificial stone who prepares with waste residues of polished tiles, its raw material composition, according to the mass fraction, alsoCan comprise following component:
1～20 part of nano material.
Described nano material can be nano silicon, nano aluminium oxide, nanomete talc powder, nanometerOne or more in calcium carbonate, nano imvite. Due to its nanometer size effect of nano material, largeSpecific area and strong interfacial interaction, can eliminate waste residues of polished tiles and unsaturated polyester (UP) treeInterfacial tension between fat matrix, the bonding interface of realizing ideal, eliminates waste residue and unsaturated polyester resinThe unmatched problem of matrix two material thermal coefficient of expansion, therefore can give full play to the excellent of waste residues of polished tilesDifferent mechanical property, can be by the rigidity of waste residues of polished tiles, dimensional stability and heat endurance and unsaturatedThe performance perfect adaptations such as mylar is shock-resistant, wear-resistant, resistance to chemical attack, give the fire-retardant ripple of PVCWatt more high strength, wear-resisting, impact resistance of line, further strengthens weatherability, heat resistance, and has increasingTough effect.
In the present invention program, also provide a kind of method of preparing artificial stone with waste residues of polished tiles, bagDraw together following steps:
Step 1: the pretreatment of waste residues of polished tiles:
First waste residues of polished tiles stirs in high-speed mixer (be preheating to temperature of charge and reach 100～110 DEG C)Dry uncovered 10～15 minutes; Object is to drive moisture away, makes filler water content lower than 0.3%;
Slowly add by the coupling agent of 0.5～5% chopping of waste residues of polished tiles gross mass and (note not making idolConnection agent is stirred oar and gets to inner wall of mixer), to divide and add for three times, every septum secundum adds total activation for 3 minutes9 minutes time; Discharge is for subsequent use.
Step 2: preparation artificial stone
Unsaturated polyester resin is put into vacuum stirring tank, then puts into promoter and stir 2～5 minutes,Put into again mill base and stir 2～5 minutes, then put into waste residues of polished tiles and stir 20～25 minutes, then addEnter curing agent vacuum uniform stirring 20～25 minutes, the slurry being stirred is poured into framed inner surface and scribbleOn the glass plate of releasing agent, through the curing molding of 20～25 minutes, make 18～25mm thick artificialMasonry slab; After the sheet material demoulding, be placed into again in the environment of 50～80 DEG C of constant temperature 3～6 hours, now,Artificial stone's plate surface reaches 100% hardness completely, sends in marble automatic polishing machine, to carry out surface and throwLight, through cutting the artificial stone's sheet material that makes all size.
The present invention will be further described by the following examples.
Embodiment 1
First waste residues of polished tiles stirs in high-speed mixer (be preheating to temperature of charge and reach 100～110 DEG C)Dry, uncovered 10 minutes, make filler water content lower than 0.3%; Slowly add by waste residue gross mass 1%The aluminic acid lipoprotein coupling DL-411-A (note not making coupling agent be stirred oar and get to inner wall of mixer) of chopping,Divide and add for three times, every septum secundum adds total soak time for 3 minutes 9 minutes, and discharge is for subsequent use.
Preparation by described waste residues of polished tiles for artificial stone, its raw material composition, according to mass fractionMeter, comprises following component:
Described waste residues of polished tiles is as follows for artificial stone's preparation process:
Resin is put into vacuum stirring tank and put into again promoter stirring 2～5 minutes, then put into mill base and stirMix 2～5 minutes, then put into waste residues of polished tiles aggregate and stir 20～25 minutes, then add curing agentVacuum uniform stirring 20～25 minutes, pours framed inner surface into the slurry being stirred and scribbles releasing agentOn glass plate, through the curing molding of 20～25 minutes, make the thick artificial stone's sheet material of 18～25mm,After the sheet material demoulding, be placed into again in the environment of 50～80 DEG C of constant temperature 3～6 hours, now, artificial stone's plateSurface reaches 100% hardness completely, sends in marble automatic polishing machine and carries out surface finish, through cuttingMake artificial stone's sheet material of all size.
Experimental result: waste residues of polished tiles aggregate artificial stone, performance test results is as shown in table 1. SystemThe standby artificial stone who obtains is taking waste residues of polished tiles as aggregate, taking unsaturated polyester resin as adhesive,Make through mold, curing molding, compared with the artificial stone who adopts other aggregate to make, heat resistance,Rotproofness, resistance to ag(e)ing are better.
Table 1
| Test item | Test result |
| Heat endurance (80 DEG C/H) | ＞25 |
| Wearability (1/cm3) | ≥82 |
| Mohs' hardness (degree) | 6.5 |
| Anti-aging (year) | 20 |
Embodiment 2
First waste residues of polished tiles stirs in high-speed mixer (be preheating to temperature of charge and reach 100～110 DEG C)Dry, uncovered 10 minutes, make filler water content lower than 0.3%; Slowly add by waste residue gross mass 4%The aluminic acid lipoprotein coupling DL-411-A (note not making coupling agent be stirred oar and get to inner wall of mixer) of chopping,Divide and add for three times, every septum secundum adds total soak time for 3 minutes 9 minutes, and discharge is for subsequent use.
Preparation by described waste residues of polished tiles for artificial stone, its raw material composition, according to mass fractionMeter, comprises following component:
Described waste residues of polished tiles is as follows for artificial stone's preparation process:
Resin is put into vacuum stirring tank and put into again promoter stirring 2～5 minutes, then put into mill base and stirMix 2～5 minutes, then put into waste residues of polished tiles aggregate and stir 20～25 minutes, then add curing agentVacuum uniform stirring 20～25 minutes, pours framed inner surface into the slurry being stirred and scribbles releasing agentOn glass plate, through the curing molding of 20～25 minutes, make the thick artificial stone's sheet material of 18～25mm,After the sheet material demoulding, be placed into again in the environment of 50～80 DEG C of constant temperature 3～6 hours, now, artificial stone's plateSurface reaches 100% hardness completely, sends in marble automatic polishing machine and carries out surface finish, through cuttingMake artificial stone's sheet material of all size.
Experimental result: the artificial stone taking waste residues of polished tiles as aggregate, performance test results is as table 2Show. The artificial stone who prepares is taking waste residues of polished tiles as aggregate, taking unsaturated polyester resin as stickyMixture, makes through mold, curing molding, compared with the artificial stone who adopts other aggregate to make,Heat resistance, rotproofness, resistance to ag(e)ing are better.
Table 2
| Test item | Test result |
| Heat endurance (80 DEG C/H) | ＞25 |
| Wearability (1/cm3) | ≥82 |
| Mohs' hardness (degree) | 6.5 |
| Anti-aging (year) | 20 |
Embodiment 3
First waste residues of polished tiles stirs in high-speed mixer (be preheating to temperature of charge and reach 100～110 DEG C)Dry, uncovered 10 minutes, make filler water content lower than 0.3%; Slowly add by waste residue gross mass 2.5The aluminic acid lipoprotein coupling DL-411-A of % chopping (notices that not making coupling agent be stirred oar gets in mixerWall), to divide and add for three times, every septum secundum adds total soak time for 3 minutes 9 minutes, and discharge is for subsequent use.
Preparation by described waste residues of polished tiles for artificial stone, its raw material composition, according to mass fractionMeter, comprises following component:
Described waste residues of polished tiles is as follows for artificial stone's preparation process:
Resin is put into vacuum stirring tank and put into again promoter stirring 2～5 minutes, then put into mill base and stirMix 2～5 minutes, then put into waste residues of polished tiles aggregate and stir 20～25 minutes, then add curing agentVacuum uniform stirring 20～25 minutes, pours framed inner surface into the slurry being stirred and scribbles releasing agentOn glass plate, through the curing molding of 20～25 minutes, make the thick artificial stone's sheet material of 18～25mm,After the sheet material demoulding, be placed into again in the environment of 50～80 DEG C of constant temperature 3～6 hours, now, artificial stone's plateSurface reaches 100% hardness completely, sends in marble automatic polishing machine and carries out surface finish, through cuttingMake artificial stone's sheet material of all size.
Experimental result: waste residues of polished tiles aggregate artificial stone, performance test results is as shown in table 3. SystemThe standby artificial stone who obtains is taking waste residues of polished tiles as aggregate, taking unsaturated polyester resin as adhesive,Make through mold, curing molding, compared with the artificial stone who adopts other aggregate to make, heat resistance,Rotproofness, resistance to ag(e)ing are better.
Table 3
| Test item | Test result |
| Heat endurance (80 DEG C/H) | ＞25 |
| Wearability (1/cm3) | ≥82 |
| Mohs' hardness (degree) | 6.5 |
| Anti-aging (year) | 20 |
Should be understood that, application of the present invention is not limited to above-mentioned giving an example, to ordinary skillPersonnel, can be improved according to the above description or be converted, and all these improvement and conversion are all answeredBelong to the protection domain of claims of the present invention.
Claims (10)
1. an artificial stone who prepares with waste residues of polished tiles, is characterized in that, described artificial stone is taking waste residues of polished tiles as filler.
2. the artificial stone who prepares with waste residues of polished tiles according to claim 1, is characterized in that, described waste residues of polished tiles needs before use through coupling agent activation processing:
Waste residues of polished tiles is dropped into stirring and drying in high-speed mixer, make its water content lower than 0.3%; Add 0.5～5% coupling agent by waste residues of polished tiles gross mass;
Described coupling agent is one or more in silane coupler, titanate coupling agent, aluminate coupling agent.
3. the artificial stone who prepares with waste residues of polished tiles according to claim 2, is characterized in that, described coupling agent is aluminate coupling agent.
4. according to the arbitrary described artificial stone who prepares with waste residues of polished tiles of claim 1～3, it is characterized in that, described artificial stone's raw material composition, according to mass fraction meter, comprises following component:
5. the artificial stone who prepares with waste residues of polished tiles according to claim 4, it is characterized in that, described unsaturated polyester resin is the unsaturated polyester resin being formed by saturated and undersaturated binary acid and dihydroxylic alcohols polycondensation, and wherein this saturated acid is adjacent benzene type, metaphenylene, p-phenyl; And this di-alcohols is ethylene glycol, propane diols, methyl propanediol, diethylene glycol (DEG), neopentyl glycol class.
6. the artificial stone who prepares with waste residues of polished tiles according to claim 4, is characterized in that, the described artificial stone who prepares with waste residues of polished tiles, and its raw material composition, according to the mass fraction, also comprises following component:
1～20 part of nano material.
7. the artificial stone who prepares with waste residues of polished tiles according to claim 4, is characterized in that, in the described artificial stone's who prepares with waste residues of polished tiles raw material composition, also comprises appropriate mill base.
8. the artificial stone who prepares with waste residues of polished tiles according to claim 4, is characterized in that, described curing agent is methyl ethyl ketone peroxide and cyclohexanone peroxide.
9. the preparation method of the artificial stone as described in as arbitrary in claim 1～8, is characterized in that, comprises the following steps:
Waste residues of polished tiles is carried out to coupling agent activation processing;
Unsaturated polyester resin is put into vacuum stirring tank, then put into promoter and stir 2～5 minutes; Put into waste residues of polished tiles and stir 20～25 minutes, then add curing agent vacuum uniform stirring 20～25 minutes; The slurry being stirred is poured on the glass plate that framed inner surface scribbles releasing agent, through the curing molding of 20～25 minutes, made the thick artificial stone's sheet material of 18～25mm; After the sheet material demoulding, be placed into again in the environment of 50～80 DEG C of constant temperature 3～6 hours; Send in marble automatic polishing machine and carry out surface finish, cut.
10. artificial stone's according to claim 9 preparation method, is characterized in that, the process of waste residues of polished tiles being carried out to coupling agent activation processing comprises the following steps:
Waste residues of polished tiles is dropped into stirring and drying in high-speed mixer, make its water content lower than 0.3%; Slowly add 0.5～5% coupling agent by waste residues of polished tiles gross mass;
Described coupling agent is one or more in silane coupler, titanate coupling agent, aluminate coupling agent.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110104992A (en) * | 2019-04-12 | 2019-08-09 | 广东中旗新材料股份有限公司 | High performance artificial quartz stone and preparation method are proposed with coupling agent treatment aluminium oxide |
| CN112110665A (en) * | 2020-08-25 | 2020-12-22 | 华润电力（贺州）有限公司 | Method for preparing artificial granite by recycling artificial granite sludge |
| CN112408859A (en) * | 2020-12-04 | 2021-02-26 | 姚智 | Environment-friendly artificial stone and preparation method thereof |
| CN114474767A (en) * | 2021-12-24 | 2022-05-13 | 苏州爱得华塑化有限公司 | UP impact-resistant material and processing device thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103204663A (en) * | 2012-01-12 | 2013-07-17 | 广东东鹏控股股份有限公司 | Artificial stone made through using solid waste residues |
| CN103833265A (en) * | 2014-01-23 | 2014-06-04 | 王舒怡 | High-strength man-made quartz plate and preparation method thereof |
| CN104496281A (en) * | 2014-11-27 | 2015-04-08 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Nano artificial stone and manufacturing method thereof |
-
2015
- 2015-12-25 CN CN201511008961.8A patent/CN105645842B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103204663A (en) * | 2012-01-12 | 2013-07-17 | 广东东鹏控股股份有限公司 | Artificial stone made through using solid waste residues |
| CN103833265A (en) * | 2014-01-23 | 2014-06-04 | 王舒怡 | High-strength man-made quartz plate and preparation method thereof |
| CN104496281A (en) * | 2014-11-27 | 2015-04-08 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Nano artificial stone and manufacturing method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110104992A (en) * | 2019-04-12 | 2019-08-09 | 广东中旗新材料股份有限公司 | High performance artificial quartz stone and preparation method are proposed with coupling agent treatment aluminium oxide |
| CN112110665A (en) * | 2020-08-25 | 2020-12-22 | 华润电力（贺州）有限公司 | Method for preparing artificial granite by recycling artificial granite sludge |
| CN112408859A (en) * | 2020-12-04 | 2021-02-26 | 姚智 | Environment-friendly artificial stone and preparation method thereof |
| CN114474767A (en) * | 2021-12-24 | 2022-05-13 | 苏州爱得华塑化有限公司 | UP impact-resistant material and processing device thereof |
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| Publication number | Publication date |
|---|---|
| CN105645842B (en) | 2017-11-17 |
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