CN104177009B - A kind of Antique Imitation Tiles and production method thereof - Google Patents

A kind of Antique Imitation Tiles and production method thereof Download PDF

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Publication number
CN104177009B
CN104177009B CN201410409658.8A CN201410409658A CN104177009B CN 104177009 B CN104177009 B CN 104177009B CN 201410409658 A CN201410409658 A CN 201410409658A CN 104177009 B CN104177009 B CN 104177009B
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parts
weight part
slag
imitation tiles
antique imitation
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CN104177009A (en
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卢汉波
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HUNAN ZHITONGXING ENVIRONMENTAL BUILDING MATERIALS Co Ltd
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HUNAN ZHITONGXING ENVIRONMENTAL BUILDING MATERIALS Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)

Abstract

A kind of Antique Imitation Tiles and production method thereof, with cement 290 ~ 305 weight part, flyash 960 ~ 1100 weight part, silicon carbide and/or quartz sand 280 ~ 300 weight part, slag or slag 370 ~ 390 weight part, chlorination system hardening accelerator 3.8 ~ 4.2 weight part, iron black 0.5 ~ 0.8 weight part for raw material; Through mixing, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%; Compound is loaded in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine; The demoulding; Maintenance after depanning and obtaining.

Description

A kind of Antique Imitation Tiles and production method thereof
Technical field
The present invention relates to a kind of material of construction and production method thereof, especially relate to a kind of Antique Imitation Tiles and production method thereof.
Background technology
The pattern that Antique Imitation Tiles is copied in the past does old, attracts the sight of people with the unique charm with allusion, and for embodying the vicissitudes in years, the thick and heavy of history, Antique Imitation Tiles, by pattern, color, pattern, builds the atmosphere of missing old times or old friends.So-called modelled after an antique, refer to the effect of brick, there is the brick of antique effect.
At present, Antique Imitation Tiles is more and more applied to building trade, the reparation of cultural attractions, the modern architecture of style modelled after an antique also needs such material of construction to decorate, current Antique Imitation Tiles, in order to improve its intensity and antique effect, mostly can use the mineral wealth of high-quality, form through high temperature sintering, production cost is too high, and complex manufacturing.
China Patent Publication No. CN103073263A, denomination of invention is the patent of " a kind of method utilizing many kinds of solids refuse to manufacture ceramic antique bricks ", method in utilizing many kinds of solids refuse to manufacture ceramic antique bricks disclosed in 1 day May in 2013: containing useless mud, useless brick, polishing slag and flyash in its body recipe, and useless mud, useless brick, polishing slag, flyash weight sum account for more than 40% of base substrate total amount.In refining process, firing temperature 1185 ~ 1195 DEG C, firing time is 40 ~ 75 minutes.
China Patent Publication No. CN101654948A, the patent that denomination of invention is " ceramic antique bricks utilizing taking construction waste stone powder as raw material and preparation method thereof ", disclose with waste stone 18 ~ 22%, stone flour 8 ~ 13%, sand 25 ~ 30%, high alumina mud 30 ~ 42%, talcum powder 2 ~ 3%, waste material 2 ~ 5%, maximum sintering temperature 1203 ~ 1210 DEG C, makes the scheme of Antique Imitation Tiles under the firing period technique of 25 ~ 30 minutes.
The technical scheme of the pseudo-classic brick of existing production, general about 1200 degree of finished product firing temperature, is unfavorable for saving energy and reduce the cost.
Summary of the invention
In order to overcome the defect of prior art, the invention provides a kind of Antique Imitation Tiles and production method thereof, without the need to sintering process, and obtained product has excellent performance.
In order to solve the problems of the technologies described above, on the one hand, the invention provides a kind of Antique Imitation Tiles, its raw material at least comprises following weight part material: cement 290 ~ 305 parts, 960 ~ 1100 parts, flyash, silicon carbide and/or quartz sand 280 ~ 300 parts, chlorination system hardening accelerator 3.8 ~ 4.2 parts, slag or 370 ~ 390 parts, slag, iron black 0.5 ~ 0.8 part, described Antique Imitation Tiles obtains through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%;
2) described compound is loaded in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement opportunity scheme: Antique Imitation Tiles provided by the invention, described Antique Imitation Tiles raw material also comprises 19.5 ~ 20.5 weight part resistance to compression auxiliary agents, and described resistance to compression auxiliary agent is made up of the material of following parts by weight: polyvinyl alcohol 1 ~ 4 part, butadiene-styrene rubber 2 ~ 3.5 parts, propylparaben 5 ~ 7 parts.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample is after 25 freezing and thawing tests, and the maximal projection size≤10mm of front ixoderm and defect, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, through-wall crack, layering do not have, and aberration is not obvious.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15 ~ 0.6mm.
In order to solve the problems of the technologies described above, on the other hand, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) by cement 290 ~ 305 weight part, flyash 960 ~ 1100 weight part, silicon carbide and/or quartz sand 280 ~ 300 weight part, slag or slag 370 ~ 390 weight part, chlorination system hardening accelerator 3.8 ~ 4.2 weight part, iron black 0.5 ~ 0.8 weight part mixing, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%;
2) compound obtained for step 1) is loaded in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement opportunity scheme, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) by cement 290 ~ 305 weight part, flyash 960 ~ 1100 weight part, silicon carbide and/or quartz sand 280 ~ 300 weight part, slag or slag 370 ~ 390 weight part, resistance to compression auxiliary agent 19.5 ~ 20.5 weight part, chlorination system hardening accelerator 3.8 ~ 4.2 weight part, iron black 0.5 ~ 0.8 weight part mixing, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: polyvinyl alcohol 1 ~ 4 part, butadiene-styrene rubber 2 ~ 3.5 parts, propylparaben 5 ~ 7 parts;
2) compound obtained for step 1) is loaded in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine;
3) demoulding;
4) maintenance after depanning.
When not conflicting, above-mentioned improvement or preferred version can be implemented alone or in combination.
In the present invention, the ultimate compression strength of Antique Imitation Tiles, the method that freezing and thawing test specifies by GB/T2542-2012 " Test methods for wall bricks " is carried out.
Hydrostatic profile preferably 1 piece/mould in the present invention, the shaping preferably 15 pieces/mould of pressurization and vibration, the rated operating pressure of two forming methods is 21 ~ 25Mpa.
The beneficial effect that the present invention brings: Antique Imitation Tiles provided by the invention, ultimate compression strength is good, freezing and thawing performance is excellent, flyash, slag or slag is utilized to do raw material production Antique Imitation Tiles, not only can fundamentally occur by preventing pollution, and effectively can utilize waste resource, turn waste into wealth, meet low-carbon economy requirement.In Antique Imitation Tiles production process, do not need sintering process, save the energy, protect environment simultaneously.
Embodiment
Embodiments of the invention and explanation thereof, for explaining the present invention, do not form inappropriate limitation of the present invention.
Embodiment 1:
The raw material of Antique Imitation Tiles at least comprises following weight part material: cement 290 parts, 1100 parts, flyash, 280 parts, silicon carbide, CaCl 2hardening accelerator 3.8 parts, 390 parts, slag, resistance to compression auxiliary agent 20.5 parts, iron black 0.5 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: polyvinyl alcohol 1 part, butadiene-styrene rubber 3.5 parts, propylparaben 7 parts, and described Antique Imitation Tiles obtains through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%;
2) compound is loaded in the steel die of 2l6 × l05 × 43mm, through 25Mpa hydrostatic profile
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 2:
The raw material of Antique Imitation Tiles at least comprises following weight part material: cement 305 parts, 960 parts, flyash, quartz sand 300 parts, CaCl 2hardening accelerator 4.2 parts, 370 parts, slag, resistance to compression auxiliary agent 19.5 weight part, iron black 0.8 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: polyvinyl alcohol 4 parts, butadiene-styrene rubber 2 parts, propylparaben 5 parts, and described Antique Imitation Tiles obtains through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 1.0wt%;
2) loaded by compound in the steel die of 15 pieces/mould, each block is of a size of 2l6 × l05 × 43mm, and under 21Mpa pressure, pressurization and vibration is shaping;
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 3:
The raw material of Antique Imitation Tiles at least comprises following weight part material: cement 300 parts, 1020 parts, flyash, 150 parts, silicon carbide, quartz sand 140 parts, CaCl 2hardening accelerator 4 parts, 190 parts, slag, 190 parts, slag, resistance to compression auxiliary agent 20 parts, 0.6 part, iron oxide black, described resistance to compression auxiliary agent is made up of the material of following parts by weight: polyvinyl alcohol 2.5 parts, butadiene-styrene rubber 2.7 parts, propylparaben 6 parts, and described Antique Imitation Tiles obtains through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.8wt%;
2) loaded by compound in the steel die of 15 pieces/mould, each block is of a size of 2l6 × l05 × 43mm, and under 23Mpa pressure, pressurization and vibration is shaping;
3) demoulding;
4) maintenance 28 days after depanning.
Comparative example 1: on the basis of embodiment 1, does not use resistance to compression auxiliary agent.
Comparative example 2: on the basis of embodiment 2, does not use resistance to compression auxiliary agent.
Comparative example 3: on the basis of embodiment 3, does not use resistance to compression auxiliary agent.
The quality index detected result of embodiment product and comparative example product is as follows:
The invention is not restricted to above preferred implementation, in the spirit that also can limit in the claims in the present invention and specification sheets, carry out conversion and the improvement of various ways, can same technical problem be solved, and obtain the technique effect of expection, therefore not repeat.Those of ordinary skill in the art can from content disclosed by the invention directly or all schemes associated, as long as within the spirit limited in claim, also belong to protection scope of the present invention.

Claims (4)

1. an Antique Imitation Tiles, it is characterized in that: its raw material at least comprises following weight part material: cement 290 ~ 305 parts, 960 ~ 1100 parts, flyash, silicon carbide and/or quartz sand 280 ~ 300 parts, chlorination system hardening accelerator 3.8 ~ 4.2 parts, slag or 370 ~ 390 parts, slag, iron black 0.5 ~ 0.8 part, resistance to compression auxiliary agent 19.5 ~ 20.5 parts, described resistance to compression auxiliary agent is made up of the material of following parts by weight: polyvinyl alcohol 1 ~ 4 part, butadiene-styrene rubber 2 ~ 3.5 parts, propylparaben 5 ~ 7 parts, and described Antique Imitation Tiles obtains through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%;
2) described compound is loaded in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine;
3) demoulding;
4) maintenance after depanning.
2. Antique Imitation Tiles according to claim 1, is characterized in that: the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample is after 25 freezing and thawing tests, and the maximal projection size≤10mm of front ixoderm and defect, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, do not have through-wall crack, do not have layering, aberration is not obvious.
3. Antique Imitation Tiles according to claim 1, is characterized in that: the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15 ~ 0.6mm.
4. a production method for Antique Imitation Tiles, is characterized in that, comprises the following steps:
1) by cement 290 ~ 305 weight part, flyash 960 ~ 1100 weight part, silicon carbide and/or quartz sand 280 ~ 300 weight part, slag or slag 370 ~ 390 weight part, resistance to compression auxiliary agent 19.5 ~ 20.5 weight part, chlorination system hardening accelerator 3.8 ~ 4.2 weight part, iron black 0.5 ~ 0.8 weight part mixing, add water, stir, make the compound that water ratio is 0.6wt% ~ 1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: polyvinyl alcohol 1 ~ 4 part, butadiene-styrene rubber 2 ~ 3.5 parts, propylparaben 5 ~ 7 parts;
2) by step 1) obtained compound loads in mould, the shaping or hydrostatic profile of pressurization and vibration in forming machine;
3) demoulding;
4) maintenance after depanning.
CN201410409658.8A 2014-08-20 2014-08-20 A kind of Antique Imitation Tiles and production method thereof Active CN104177009B (en)

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Publication number Priority date Publication date Assignee Title
CN105906287A (en) * 2016-05-04 2016-08-31 桂林电子科技大学 Formula of antique facing black brick and production method of formula
CN105967760B (en) * 2016-05-05 2018-08-10 江门市华陶陶瓷有限公司 A kind of production method of Antique Imitation Tiles
CN106380171B (en) * 2016-08-31 2019-04-12 云南天朗再生资源有限责任公司 A kind of steel slag building block modelled after an antique and preparation method thereof
CN107200533A (en) * 2017-06-20 2017-09-26 肥西县碧涛建材有限公司 A kind of Antique Imitation Tiles and preparation method thereof
CN107244862A (en) * 2017-07-11 2017-10-13 合肥尚涵装饰工程有限公司 Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof
CN107417278A (en) * 2017-07-31 2017-12-01 贞丰县恒山建材有限责任公司 A kind of Antique Imitation Tiles and preparation method thereof
CN108675722A (en) * 2018-06-05 2018-10-19 郑州天罡实业有限公司 Utilize Antique Imitation Tiles and preparation method thereof made from slag
CN109020452A (en) * 2018-10-09 2018-12-18 河南能工巧匠网络科技有限公司 A method of utilizing the clay standby Antique Imitation Tiles of saw
CN109369078A (en) * 2018-11-21 2019-02-22 长春市宇实仿古建材有限公司 A kind of energy conservation and environmental protection baking-free imitation of ancient watt and preparation method thereof

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CN101003154B (en) * 2007-02-05 2010-08-04 北京四方如钢混凝土制品有限公司 Machine-made archaized blue bricks
CN100480207C (en) * 2007-02-05 2009-04-22 刘洪军 Formulation for producing concrete brick from foundry waste sand and producing method thereof
KR101145174B1 (en) * 2010-03-31 2012-05-14 우성세라믹스공업 주식회사 An antique feel provided clay bricks and pavers, and method for manufacturing the same
CN103936340B (en) * 2013-01-22 2015-12-23 金正义 A kind of blue bricks modelled after an antique and preparation method thereof

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