CN104177009A - Antique brick and production method thereof - Google Patents
Antique brick and production method thereof Download PDFInfo
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- CN104177009A CN104177009A CN201410409658.8A CN201410409658A CN104177009A CN 104177009 A CN104177009 A CN 104177009A CN 201410409658 A CN201410409658 A CN 201410409658A CN 104177009 A CN104177009 A CN 104177009A
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- slag
- imitation tiles
- antique imitation
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000011449 brick Substances 0.000 title abstract description 12
- 239000002893 slag Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000010881 fly ash Substances 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004568 cement Substances 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000006004 Quartz sand Substances 0.000 claims abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000006835 compression Effects 0.000 claims description 21
- 238000007906 compression Methods 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 12
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 10
- 238000012423 maintenance Methods 0.000 claims description 9
- 230000002706 hydrostatic effect Effects 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 7
- 229920001971 elastomer Polymers 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 7
- 239000005060 rubber Substances 0.000 claims description 7
- -1 960~1100 parts Substances 0.000 claims description 6
- 238000005660 chlorination reaction Methods 0.000 claims description 6
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims description 6
- 230000008014 freezing Effects 0.000 claims description 4
- 238000007710 freezing Methods 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- 238000010257 thawing Methods 0.000 claims description 4
- 230000004075 alteration Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 238000005056 compaction Methods 0.000 abstract 1
- 239000010431 corundum Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
Abstract
The invention relates to an antique brick and a production method thereof. The antique brick is prepared from the following raw materials in parts by weight: 290-305 parts of cement, 960-1100 parts of fly ash, 280-300 parts of corundum and/or quartz sand, 370-390 parts of mine slag or steel slag, 3.8-4.2 parts of chloride early-strength admixture and 0.5-0.8 part of iron oxide black. The production method comprises the following steps: mixing, adding water, and stirring uniformly to prepare a mixture with the water content of 0.6-1.0 wt%; adding the mixture into a mold, and carrying out pressure vibratory compaction or static pressure molding in a forming machine; stripping; and curing.
Description
Technical field
The present invention relates to a kind of material of construction and production method thereof, especially relate to a kind of Antique Imitation Tiles and production method thereof.
Background technology
Antique Imitation Tiles is copied pattern in the past and is done oldly, uses the sight that is attracting people with classic unique charm, and for embodying the vicissitudes, historical thick and heavy in years, Antique Imitation Tiles, by pattern, color, pattern, is built the atmosphere of missing old times or old friends.What is called is modelled after an antique, refers to the effect of brick, has the brick of antique effect.
At present, Antique Imitation Tiles is more and more applied to building trade, the reparation of cultural attractions, the modern architecture of style modelled after an antique also needs such material of construction to decorate, current Antique Imitation Tiles, in order to improve its intensity and antique effect, can use the mineral wealth of high-quality mostly, forms through high temperature sintering, production cost is too high, and complex manufacturing.
China Patent Publication No. CN103073263A, denomination of invention is the patent of " a kind of method of utilizing many kinds of solids refuse to manufacture ceramic antique bricks ", in on May 1st, 2013 the disclosed many kinds of solids refuse that utilizes manufacture the method for ceramic antique bricks: in its body recipe, contain useless mud, useless brick, polishing slag and flyash, and useless mud, useless brick, polishing slag, flyash weight sum account for the more than 40% of base substrate total amount.In refining process, 1185~1195 DEG C of firing temperatures, firing time is 40~75 minutes.
China Patent Publication No. CN101654948A, the patent that denomination of invention is " utilizing ceramic antique bricks of taking construction waste stone powder as raw material and preparation method thereof ", disclose with discarded building stones 18~22%, stone flour 8~13%, sand 25~30%, high alumina mud 30~42%, talcum powder 2~3%, waste material 2~5%, 1203~1210 DEG C of maximum sintering temperatures, the scheme of making Antique Imitation Tiles under the firing period technique of 25~30 minutes.
The technical scheme of the pseudo-classic brick of existing production, the general 1200 degree left and right of finished product firing temperature, are unfavorable for saving energy and reduce the cost.
Summary of the invention
In order to overcome the defect of prior art, the invention provides a kind of Antique Imitation Tiles and production method thereof, without sintering process, and the product making has good performance.
In order to solve the problems of the technologies described above, on the one hand, the invention provides a kind of Antique Imitation Tiles, its raw material at least comprises following weight part material: 0.5~0.8 part of 290~305 parts of cement, 960~1100 parts, flyash, silicon carbide and/or 280~300 parts of quartz sands, 3.8~4.2 parts of chlorination system hardening accelerator, slag or 370~390 parts, slag, iron oxide black, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) described compound is packed in mould into pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement technical scheme: Antique Imitation Tiles provided by the invention, described Antique Imitation Tiles raw material also comprises 19.5~20.5 weight part resistance to compression auxiliary agents, and described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample after 25 freezing and thawing tests, front ixoderm and damaged maximal projection size≤10mm, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, through-wall crack, layering do not have, aberration is not obvious.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15~0.6mm.
In order to solve the problems of the technologies described above, on the other hand, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement technical scheme, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, resistance to compression auxiliary agent 19.5~20.5 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
In the situation that not conflicting, above-mentioned improvement or preferred version can be implemented alone or in combination.
In the present invention, the ultimate compression strength of Antique Imitation Tiles, freezing and thawing test is undertaken by the method for GB/T2542-2012 " Test methods for wall bricks " regulation.
Preferably 1/mould of hydrostatic profile in the present invention, pressurization and vibration moulding is 15/mould preferably, and the rated operating pressure of two forming methods is 21~25Mpa.
The beneficial effect that the present invention brings: Antique Imitation Tiles provided by the invention, ultimate compression strength is good, freezing and thawing performance is good, utilize flyash, slag or slag to do raw material production Antique Imitation Tiles, not only can fundamentally prevent from polluting and occur, and can effectively utilize waste resource, and turn waste into wealth, meet low-carbon economy requirement.In Antique Imitation Tiles production process, do not need sintering process, saved the energy, protected environment simultaneously.
Embodiment
Embodiments of the invention and explanation thereof are used for explaining the present invention, do not form inappropriate limitation of the present invention.
Embodiment 1:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 290 parts of cement, 1100 parts, flyash, 280 parts, silicon carbide, CaCl
23.8 parts of hardening accelerator, 390 parts, slag, 20.5 parts of resistance to compression auxiliary agents, iron black 0.5 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1 part of polyvinyl alcohol, 3.5 parts of butadiene-styrene rubbers, 7 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%;
2) compound is packed in the steel die of 2l6 × l05 × 43mm, through 25Mpa hydrostatic profile
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 2:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 305 parts of cement, 960 parts, flyash, 300 parts of quartz sands, CaCl
24.2 parts of hardening accelerator, 370 parts, slag, resistance to compression auxiliary agent 19.5 weight parts, iron black 0.8 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 4 parts of polyvinyl alcohol, 2 parts of butadiene-styrene rubbers, 5 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 1.0wt%;
2) compound is packed in the steel die of 15/mould, each piece is of a size of 2l6 × l05 × 43mm, pressurization and vibration moulding under 21Mpa pressure;
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 3:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 300 parts of cement, 1020 parts, flyash, 150 parts, silicon carbide, 140 parts of quartz sands, CaCl
24 parts of hardening accelerator, 190 parts, slag, 190 parts, slag, 20 parts of resistance to compression auxiliary agents, 0.6 part of iron oxide black, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 2.5 parts of polyvinyl alcohol, 2.7 parts of butadiene-styrene rubbers, 6 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.8wt%;
2) compound is packed in the steel die of 15/mould, each piece is of a size of 2l6 × l05 × 43mm, pressurization and vibration moulding under 23Mpa pressure;
3) demoulding;
4) maintenance 28 days after depanning.
Comparative example 1: on the basis of embodiment 1, do not use resistance to compression auxiliary agent.
Comparative example 2: on the basis of embodiment 2, do not use resistance to compression auxiliary agent.
Comparative example 3: on the basis of embodiment 3, do not use resistance to compression auxiliary agent.
The quality index detected result of embodiment product and comparative example product is as follows:
The invention is not restricted to above preferred implementation, also can, in the spirit of the claims in the present invention and specification sheets restriction, carry out conversion and the improvement of various ways, can solve same technical problem, and obtain the technique effect of expection, therefore do not repeat.Those of ordinary skill in the art can be from content disclosed by the invention directly or all schemes of associating, as long as within the spirit limiting in claim, also belong to protection scope of the present invention.
Claims (6)
1. an Antique Imitation Tiles, it is characterized in that: its raw material at least comprises following weight part material: 0.5~0.8 part of 290~305 parts of cement, 960~1100 parts, flyash, silicon carbide and/or 280~300 parts of quartz sands, 3.8~4.2 parts of chlorination system hardening accelerator, slag or 370~390 parts, slag, iron oxide black, described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) described compound is packed in mould into pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
2. Antique Imitation Tiles according to claim 1, it is characterized in that: described Antique Imitation Tiles raw material also comprises 19.5~20.5 weight part resistance to compression auxiliary agents, and described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens.
3. Antique Imitation Tiles according to claim 1, is characterized in that: the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample after 25 freezing and thawing tests, front ixoderm and damaged maximal projection size≤10mm, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, through-wall crack, layering do not have, aberration is not obvious.
4. Antique Imitation Tiles according to claim 1, is characterized in that: the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15~0.6mm.
5. a production method for Antique Imitation Tiles, is characterized in that, comprises the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
6. a production method for Antique Imitation Tiles, is characterized in that, comprises the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, resistance to compression auxiliary agent 19.5~20.5 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
Priority Applications (1)
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CN201410409658.8A CN104177009B (en) | 2014-08-20 | 2014-08-20 | A kind of Antique Imitation Tiles and production method thereof |
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CN201410409658.8A CN104177009B (en) | 2014-08-20 | 2014-08-20 | A kind of Antique Imitation Tiles and production method thereof |
Publications (2)
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CN104177009A true CN104177009A (en) | 2014-12-03 |
CN104177009B CN104177009B (en) | 2016-03-02 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105906287A (en) * | 2016-05-04 | 2016-08-31 | 桂林电子科技大学 | Formula of antique facing black brick and production method of formula |
CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
CN106380171A (en) * | 2016-08-31 | 2017-02-08 | 昆明钢铁控股有限公司 | Slag antique building block and production method thereof |
CN107200533A (en) * | 2017-06-20 | 2017-09-26 | 肥西县碧涛建材有限公司 | A kind of Antique Imitation Tiles and preparation method thereof |
CN107244862A (en) * | 2017-07-11 | 2017-10-13 | 合肥尚涵装饰工程有限公司 | Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof |
CN107417278A (en) * | 2017-07-31 | 2017-12-01 | 贞丰县恒山建材有限责任公司 | A kind of Antique Imitation Tiles and preparation method thereof |
CN108675722A (en) * | 2018-06-05 | 2018-10-19 | 郑州天罡实业有限公司 | Utilize Antique Imitation Tiles and preparation method thereof made from slag |
CN109020452A (en) * | 2018-10-09 | 2018-12-18 | 河南能工巧匠网络科技有限公司 | A method of utilizing the clay standby Antique Imitation Tiles of saw |
CN109369078A (en) * | 2018-11-21 | 2019-02-22 | 长春市宇实仿古建材有限公司 | A kind of energy conservation and environmental protection baking-free imitation of ancient watt and preparation method thereof |
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CN101003154A (en) * | 2007-02-05 | 2007-07-25 | 梁林华 | Machine-made archaized blue bricks |
CN101033120A (en) * | 2007-02-05 | 2007-09-12 | 刘洪军 | Formulation for producing concrete brick from foundry waste sand and producing method thereof |
KR101145174B1 (en) * | 2010-03-31 | 2012-05-14 | 우성세라믹스공업 주식회사 | An antique feel provided clay bricks and pavers, and method for manufacturing the same |
CN103936340A (en) * | 2013-01-22 | 2014-07-23 | 金正义 | Archaized blue brick and its preparation method |
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CN101003154A (en) * | 2007-02-05 | 2007-07-25 | 梁林华 | Machine-made archaized blue bricks |
CN101033120A (en) * | 2007-02-05 | 2007-09-12 | 刘洪军 | Formulation for producing concrete brick from foundry waste sand and producing method thereof |
KR101145174B1 (en) * | 2010-03-31 | 2012-05-14 | 우성세라믹스공업 주식회사 | An antique feel provided clay bricks and pavers, and method for manufacturing the same |
CN103936340A (en) * | 2013-01-22 | 2014-07-23 | 金正义 | Archaized blue brick and its preparation method |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105906287A (en) * | 2016-05-04 | 2016-08-31 | 桂林电子科技大学 | Formula of antique facing black brick and production method of formula |
CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
CN105967760B (en) * | 2016-05-05 | 2018-08-10 | 江门市华陶陶瓷有限公司 | A kind of production method of Antique Imitation Tiles |
CN106380171A (en) * | 2016-08-31 | 2017-02-08 | 昆明钢铁控股有限公司 | Slag antique building block and production method thereof |
CN107200533A (en) * | 2017-06-20 | 2017-09-26 | 肥西县碧涛建材有限公司 | A kind of Antique Imitation Tiles and preparation method thereof |
CN107244862A (en) * | 2017-07-11 | 2017-10-13 | 合肥尚涵装饰工程有限公司 | Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof |
CN107417278A (en) * | 2017-07-31 | 2017-12-01 | 贞丰县恒山建材有限责任公司 | A kind of Antique Imitation Tiles and preparation method thereof |
CN108675722A (en) * | 2018-06-05 | 2018-10-19 | 郑州天罡实业有限公司 | Utilize Antique Imitation Tiles and preparation method thereof made from slag |
CN109020452A (en) * | 2018-10-09 | 2018-12-18 | 河南能工巧匠网络科技有限公司 | A method of utilizing the clay standby Antique Imitation Tiles of saw |
CN109369078A (en) * | 2018-11-21 | 2019-02-22 | 长春市宇实仿古建材有限公司 | A kind of energy conservation and environmental protection baking-free imitation of ancient watt and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN104177009B (en) | 2016-03-02 |
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