CN104177009A - Antique brick and production method thereof - Google Patents

Antique brick and production method thereof Download PDF

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Publication number
CN104177009A
CN104177009A CN201410409658.8A CN201410409658A CN104177009A CN 104177009 A CN104177009 A CN 104177009A CN 201410409658 A CN201410409658 A CN 201410409658A CN 104177009 A CN104177009 A CN 104177009A
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China
Prior art keywords
parts
weight
slag
imitation tiles
antique imitation
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CN201410409658.8A
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Chinese (zh)
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CN104177009B (en
Inventor
卢汉波
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HUNAN ZHITONGXING ENVIRONMENTAL BUILDING MATERIALS Co Ltd
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HUNAN ZHITONGXING ENVIRONMENTAL BUILDING MATERIALS Co Ltd
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Priority to CN201410409658.8A priority Critical patent/CN104177009B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)

Abstract

The invention relates to an antique brick and a production method thereof. The antique brick is prepared from the following raw materials in parts by weight: 290-305 parts of cement, 960-1100 parts of fly ash, 280-300 parts of corundum and/or quartz sand, 370-390 parts of mine slag or steel slag, 3.8-4.2 parts of chloride early-strength admixture and 0.5-0.8 part of iron oxide black. The production method comprises the following steps: mixing, adding water, and stirring uniformly to prepare a mixture with the water content of 0.6-1.0 wt%; adding the mixture into a mold, and carrying out pressure vibratory compaction or static pressure molding in a forming machine; stripping; and curing.

Description

A kind of Antique Imitation Tiles and production method thereof
Technical field
The present invention relates to a kind of material of construction and production method thereof, especially relate to a kind of Antique Imitation Tiles and production method thereof.
Background technology
Antique Imitation Tiles is copied pattern in the past and is done oldly, uses the sight that is attracting people with classic unique charm, and for embodying the vicissitudes, historical thick and heavy in years, Antique Imitation Tiles, by pattern, color, pattern, is built the atmosphere of missing old times or old friends.What is called is modelled after an antique, refers to the effect of brick, has the brick of antique effect.
At present, Antique Imitation Tiles is more and more applied to building trade, the reparation of cultural attractions, the modern architecture of style modelled after an antique also needs such material of construction to decorate, current Antique Imitation Tiles, in order to improve its intensity and antique effect, can use the mineral wealth of high-quality mostly, forms through high temperature sintering, production cost is too high, and complex manufacturing.
China Patent Publication No. CN103073263A, denomination of invention is the patent of " a kind of method of utilizing many kinds of solids refuse to manufacture ceramic antique bricks ", in on May 1st, 2013 the disclosed many kinds of solids refuse that utilizes manufacture the method for ceramic antique bricks: in its body recipe, contain useless mud, useless brick, polishing slag and flyash, and useless mud, useless brick, polishing slag, flyash weight sum account for the more than 40% of base substrate total amount.In refining process, 1185~1195 DEG C of firing temperatures, firing time is 40~75 minutes.
China Patent Publication No. CN101654948A, the patent that denomination of invention is " utilizing ceramic antique bricks of taking construction waste stone powder as raw material and preparation method thereof ", disclose with discarded building stones 18~22%, stone flour 8~13%, sand 25~30%, high alumina mud 30~42%, talcum powder 2~3%, waste material 2~5%, 1203~1210 DEG C of maximum sintering temperatures, the scheme of making Antique Imitation Tiles under the firing period technique of 25~30 minutes.
The technical scheme of the pseudo-classic brick of existing production, the general 1200 degree left and right of finished product firing temperature, are unfavorable for saving energy and reduce the cost.
Summary of the invention
In order to overcome the defect of prior art, the invention provides a kind of Antique Imitation Tiles and production method thereof, without sintering process, and the product making has good performance.
In order to solve the problems of the technologies described above, on the one hand, the invention provides a kind of Antique Imitation Tiles, its raw material at least comprises following weight part material: 0.5~0.8 part of 290~305 parts of cement, 960~1100 parts, flyash, silicon carbide and/or 280~300 parts of quartz sands, 3.8~4.2 parts of chlorination system hardening accelerator, slag or 370~390 parts, slag, iron oxide black, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) described compound is packed in mould into pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement technical scheme: Antique Imitation Tiles provided by the invention, described Antique Imitation Tiles raw material also comprises 19.5~20.5 weight part resistance to compression auxiliary agents, and described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample after 25 freezing and thawing tests, front ixoderm and damaged maximal projection size≤10mm, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, through-wall crack, layering do not have, aberration is not obvious.
As optimal technical scheme: Antique Imitation Tiles provided by the invention, the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15~0.6mm.
In order to solve the problems of the technologies described above, on the other hand, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
As further improvement technical scheme, the invention provides a kind of production method of Antique Imitation Tiles, comprise the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, resistance to compression auxiliary agent 19.5~20.5 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
In the situation that not conflicting, above-mentioned improvement or preferred version can be implemented alone or in combination.
In the present invention, the ultimate compression strength of Antique Imitation Tiles, freezing and thawing test is undertaken by the method for GB/T2542-2012 " Test methods for wall bricks " regulation.
Preferably 1/mould of hydrostatic profile in the present invention, pressurization and vibration moulding is 15/mould preferably, and the rated operating pressure of two forming methods is 21~25Mpa.
The beneficial effect that the present invention brings: Antique Imitation Tiles provided by the invention, ultimate compression strength is good, freezing and thawing performance is good, utilize flyash, slag or slag to do raw material production Antique Imitation Tiles, not only can fundamentally prevent from polluting and occur, and can effectively utilize waste resource, and turn waste into wealth, meet low-carbon economy requirement.In Antique Imitation Tiles production process, do not need sintering process, saved the energy, protected environment simultaneously.
Embodiment
Embodiments of the invention and explanation thereof are used for explaining the present invention, do not form inappropriate limitation of the present invention.
Embodiment 1:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 290 parts of cement, 1100 parts, flyash, 280 parts, silicon carbide, CaCl 23.8 parts of hardening accelerator, 390 parts, slag, 20.5 parts of resistance to compression auxiliary agents, iron black 0.5 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1 part of polyvinyl alcohol, 3.5 parts of butadiene-styrene rubbers, 7 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%;
2) compound is packed in the steel die of 2l6 × l05 × 43mm, through 25Mpa hydrostatic profile
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 2:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 305 parts of cement, 960 parts, flyash, 300 parts of quartz sands, CaCl 24.2 parts of hardening accelerator, 370 parts, slag, resistance to compression auxiliary agent 19.5 weight parts, iron black 0.8 weight part, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 4 parts of polyvinyl alcohol, 2 parts of butadiene-styrene rubbers, 5 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 1.0wt%;
2) compound is packed in the steel die of 15/mould, each piece is of a size of 2l6 × l05 × 43mm, pressurization and vibration moulding under 21Mpa pressure;
3) demoulding;
4) maintenance 28 days after depanning.
Embodiment 3:
The raw material of Antique Imitation Tiles at least comprises following weight part material: 300 parts of cement, 1020 parts, flyash, 150 parts, silicon carbide, 140 parts of quartz sands, CaCl 24 parts of hardening accelerator, 190 parts, slag, 190 parts, slag, 20 parts of resistance to compression auxiliary agents, 0.6 part of iron oxide black, described resistance to compression auxiliary agent is made up of the material of following parts by weight: 2.5 parts of polyvinyl alcohol, 2.7 parts of butadiene-styrene rubbers, 6 parts of propylparabens, and described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.8wt%;
2) compound is packed in the steel die of 15/mould, each piece is of a size of 2l6 × l05 × 43mm, pressurization and vibration moulding under 23Mpa pressure;
3) demoulding;
4) maintenance 28 days after depanning.
Comparative example 1: on the basis of embodiment 1, do not use resistance to compression auxiliary agent.
Comparative example 2: on the basis of embodiment 2, do not use resistance to compression auxiliary agent.
Comparative example 3: on the basis of embodiment 3, do not use resistance to compression auxiliary agent.
The quality index detected result of embodiment product and comparative example product is as follows:
The invention is not restricted to above preferred implementation, also can, in the spirit of the claims in the present invention and specification sheets restriction, carry out conversion and the improvement of various ways, can solve same technical problem, and obtain the technique effect of expection, therefore do not repeat.Those of ordinary skill in the art can be from content disclosed by the invention directly or all schemes of associating, as long as within the spirit limiting in claim, also belong to protection scope of the present invention.

Claims (6)

1. an Antique Imitation Tiles, it is characterized in that: its raw material at least comprises following weight part material: 0.5~0.8 part of 290~305 parts of cement, 960~1100 parts, flyash, silicon carbide and/or 280~300 parts of quartz sands, 3.8~4.2 parts of chlorination system hardening accelerator, slag or 370~390 parts, slag, iron oxide black, described Antique Imitation Tiles makes through following steps:
1) each raw material is mixed by proportioning, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) described compound is packed in mould into pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
2. Antique Imitation Tiles according to claim 1, it is characterized in that: described Antique Imitation Tiles raw material also comprises 19.5~20.5 weight part resistance to compression auxiliary agents, and described resistance to compression auxiliary agent is made up of the material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens.
3. Antique Imitation Tiles according to claim 1, is characterized in that: the ultimate compression strength >=20MPa of described Antique Imitation Tiles; Sample after 25 freezing and thawing tests, front ixoderm and damaged maximal projection size≤10mm, the maximal projection size≤15mm of losing fangle, partial crack length maximal projection size≤10mm, through-wall crack, layering do not have, aberration is not obvious.
4. Antique Imitation Tiles according to claim 1, is characterized in that: the particle diameter of described silicon carbide, quartz sand, slag, slag is 0.15~0.6mm.
5. a production method for Antique Imitation Tiles, is characterized in that, comprises the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
6. a production method for Antique Imitation Tiles, is characterized in that, comprises the following steps:
1) cement 290~305 weight parts, flyash 960~1100 weight parts, silicon carbide and/or quartz sand 280~300 weight parts, slag or slag 370~390 weight parts, resistance to compression auxiliary agent 19.5~20.5 weight parts, chlorination system hardening accelerator 3.8~4.2 weight parts, iron black 0.5~0.8 weight part are mixed, add water, stir, make the compound that water ratio is 0.6wt%~1.0wt%; Described resistance to compression auxiliary agent is made up of the raw material of following parts by weight: 1~4 part of polyvinyl alcohol, 2~3.5 parts of butadiene-styrene rubbers, 5~7 parts of propylparabens;
2) compound step 1) being made packs in mould, pressurization and vibration moulding or hydrostatic profile in forming machine;
3) demoulding;
4) maintenance after depanning.
CN201410409658.8A 2014-08-20 2014-08-20 A kind of Antique Imitation Tiles and production method thereof Expired - Fee Related CN104177009B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105906287A (en) * 2016-05-04 2016-08-31 桂林电子科技大学 Formula of antique facing black brick and production method of formula
CN105967760A (en) * 2016-05-05 2016-09-28 华若延 Archaized brick manufacturing method
CN106380171A (en) * 2016-08-31 2017-02-08 昆明钢铁控股有限公司 Slag antique building block and production method thereof
CN107200533A (en) * 2017-06-20 2017-09-26 肥西县碧涛建材有限公司 A kind of Antique Imitation Tiles and preparation method thereof
CN107244862A (en) * 2017-07-11 2017-10-13 合肥尚涵装饰工程有限公司 Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof
CN107417278A (en) * 2017-07-31 2017-12-01 贞丰县恒山建材有限责任公司 A kind of Antique Imitation Tiles and preparation method thereof
CN108675722A (en) * 2018-06-05 2018-10-19 郑州天罡实业有限公司 Utilize Antique Imitation Tiles and preparation method thereof made from slag
CN109020452A (en) * 2018-10-09 2018-12-18 河南能工巧匠网络科技有限公司 A method of utilizing the clay standby Antique Imitation Tiles of saw
CN109369078A (en) * 2018-11-21 2019-02-22 长春市宇实仿古建材有限公司 A kind of energy conservation and environmental protection baking-free imitation of ancient watt and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003154A (en) * 2007-02-05 2007-07-25 梁林华 Machine-made archaized blue bricks
CN101033120A (en) * 2007-02-05 2007-09-12 刘洪军 Formulation for producing concrete brick from foundry waste sand and producing method thereof
KR101145174B1 (en) * 2010-03-31 2012-05-14 우성세라믹스공업 주식회사 An antique feel provided clay bricks and pavers, and method for manufacturing the same
CN103936340A (en) * 2013-01-22 2014-07-23 金正义 Archaized blue brick and its preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003154A (en) * 2007-02-05 2007-07-25 梁林华 Machine-made archaized blue bricks
CN101033120A (en) * 2007-02-05 2007-09-12 刘洪军 Formulation for producing concrete brick from foundry waste sand and producing method thereof
KR101145174B1 (en) * 2010-03-31 2012-05-14 우성세라믹스공업 주식회사 An antique feel provided clay bricks and pavers, and method for manufacturing the same
CN103936340A (en) * 2013-01-22 2014-07-23 金正义 Archaized blue brick and its preparation method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105906287A (en) * 2016-05-04 2016-08-31 桂林电子科技大学 Formula of antique facing black brick and production method of formula
CN105967760A (en) * 2016-05-05 2016-09-28 华若延 Archaized brick manufacturing method
CN105967760B (en) * 2016-05-05 2018-08-10 江门市华陶陶瓷有限公司 A kind of production method of Antique Imitation Tiles
CN106380171A (en) * 2016-08-31 2017-02-08 昆明钢铁控股有限公司 Slag antique building block and production method thereof
CN107200533A (en) * 2017-06-20 2017-09-26 肥西县碧涛建材有限公司 A kind of Antique Imitation Tiles and preparation method thereof
CN107244862A (en) * 2017-07-11 2017-10-13 合肥尚涵装饰工程有限公司 Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof
CN107417278A (en) * 2017-07-31 2017-12-01 贞丰县恒山建材有限责任公司 A kind of Antique Imitation Tiles and preparation method thereof
CN108675722A (en) * 2018-06-05 2018-10-19 郑州天罡实业有限公司 Utilize Antique Imitation Tiles and preparation method thereof made from slag
CN109020452A (en) * 2018-10-09 2018-12-18 河南能工巧匠网络科技有限公司 A method of utilizing the clay standby Antique Imitation Tiles of saw
CN109369078A (en) * 2018-11-21 2019-02-22 长春市宇实仿古建材有限公司 A kind of energy conservation and environmental protection baking-free imitation of ancient watt and preparation method thereof

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