CN106116251A - A kind of impact resistance artificial quartz in lump - Google Patents
A kind of impact resistance artificial quartz in lump Download PDFInfo
- Publication number
- CN106116251A CN106116251A CN201610481234.1A CN201610481234A CN106116251A CN 106116251 A CN106116251 A CN 106116251A CN 201610481234 A CN201610481234 A CN 201610481234A CN 106116251 A CN106116251 A CN 106116251A
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- parts
- lump
- impact resistance
- artificial quartz
- particle diameter
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of impact resistance artificial quartz in lump, is made up of the component of following weight portion: particle diameter is less than or equal to the calcinated argil 43 48 parts of 4mm, 50 100 mesh Pulvis Talci 18 26 parts, 50 100 mesh vermiculite power 18 26 parts, composite resin 10 15 parts, 12 16 parts of firming agent, titanate coupling agent 8 12 parts, toughener 8 12 parts, 46 parts of colorant less than or equal to 82 88 parts of the calcining quartz sand of 4mm, particle diameter.Artificial quartz in lump heat-resisting quantity of the present invention is good, and hardness is strong, and surface is difficult to scratch, good impact resistance, being difficult to collide with and collapse angle, rising-heat contracting-cold is very strong, and its quality is tight, will not be seeped water conjunction oil stain, is particularly suitable for kitchen range and uses, also has good antifungal effect.
Description
Technical field
The present invention relates to artificial stone's manufacture technology field, be specifically related to a kind of impact resistance artificial quartz in lump.
Background technology
Resin type Engineered stone products classification can be divided into several big class, and serviceability is by the composition of its raw material, ratio and life
The multiple conditional decisions such as product equipment, technique.Wherein raw material is the basis determining its performance quality, different raw materials and difference
Production equipment, the artificial slabstone produced just has different use value and different physical characteristics, and manufacturing cost is also
Different.Taking the lead in making filler and unsaturated-resin with calcium carbonate (marble) by Italy in the sixties in 20th century, firming agent glues
Condensation material, accompanies by the artificial synthesizing marble of DYE PRODUCTION (hilllock stone).Flow into China mid-term from the eighties, become present artificial hilllock
, there is with polyformaldehyde acrylic acid methyl ester. and aluminium hydroxide the artificial stone as raw material production the seventies in stone product.Later by improvement
Artificial slabstone is produced for UP/PMMA plate.Early 1990s unsaturated-resin and production of aluminum hydroxide out on-gauge plate
Artificial slabstone (UP plate), is provided without the industrial chemicals such as natural inorganic ore deposit and aluminium oxide such as natural stone diamond stone the nineties, the molten cellar for storing things of warp,
Flux, water rate, crystallization cave sintering make microlite.At the beginning of 21 century, there is people with natural siliceous sand powder and high-performance tree in Spain
Fat synthetically produced go out new science and technology artificial quartz stone plate.Ad initio artificial quartz in lump technique inflow China becomes a generation for renewal and builds
Material product.But, artificial quartz in lump quality is uneven in the market, is difficult to meet diversified demand.
Summary of the invention
The technical problem to be solved is to provide a kind of heat-resisting quantity good, and hardness is strong, the people of good impact resistance
Make quartz.
The technical problem to be solved realizes by the following technical solutions:
A kind of impact resistance artificial quartz in lump, is made up of the component of following weight portion: the particle diameter calcining quartz less than or equal to 4mm
Sand 82-88 part, particle diameter are less than or equal to calcinated argil 43-48 part of 4mm, 50-100 mesh Pulvis Talci 18-26 part, 50-100 mesh Vermiculitum
Powder 18-26 part, composite resin 10-15 part, firming agent 12-16 part, titanate coupling agent 8-12 part, toughener 8-12 part, colorant
4-6 part.
Described composite resin is by Research of Grafting Malaic Anhydride Onto Polyethylene, chlorine vulcanized polyethylene, N-salicylamide base phthalyl Asia
Amine, hydrogenated styrene isoprene-styrene block copolymer are mixed to prepare by equivalent part.
Described firming agent is at least one in trimethylhexamethylenediamine, isophorone diamine, methyl tetrahydro phthalic anhydride.
Described toughener is ethylene-vinyl acetate copolymer, polyethersulfone resin, methyl methacrylate-butadiene-benzene second
At least one in alkene terpolymer.
The preparation technology of a kind of impact resistance artificial quartz in lump, comprises the steps:
(1) particle diameter is less than or equal to the calcinated argil of 4mm at 1200-1400 less than or equal to the calcining quartz sand of 4mm, particle diameter
Calcine under DEG C high temperature 1 hour, then rush with 5 DEG C of cold water and water, then they are calcined under 1500-1600 DEG C of high temperature 1 hour, then
It is cooled to room temperature；
(2) in the material of step A add 50-100 mesh Pulvis Talci, 50-100 mesh vermiculite power, composite resin, firming agent,
Titanate coupling agent, toughener, colorant, each component uniformly mixes；
(3) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true
Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 92-98 DEG C in described solidification, and hardening time is 30 minutes, second stage
Solidification temperature is 80-84 DEG C, and hardening time is 20 minutes.
The invention has the beneficial effects as follows: artificial quartz in lump heat-resisting quantity of the present invention is good, hardness is strong, and surface is difficult to scratch, anti-
Impact is good, is difficult to collide with and collapses angle, and rising-heat contracting-cold is very strong, and its quality is tight, and will not seep water conjunction oil stain, is particularly suitable for
Use in kitchen range, also there is good antifungal effect.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Close specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of impact resistance artificial quartz in lump, is made up of the component of following weight portion (kg): the particle diameter calcining less than or equal to 4mm
Quartz sand 85 parts, particle diameter are less than or equal to the calcinated argil 45 parts of 4mm, 50-100 mesh Pulvis Talci 22 parts, 50-100 mesh vermiculite power 22
Part, composite resin 12 parts, 14 parts of firming agent, titanate coupling agent 10 parts, toughener 10 parts, 5 parts of colorant.
Described composite resin is by Research of Grafting Malaic Anhydride Onto Polyethylene, chlorine vulcanized polyethylene, N-salicylamide base phthalyl Asia
Amine, hydrogenated styrene isoprene-styrene block copolymer are mixed to prepare by equivalent part.
Described firming agent is at least one in trimethylhexamethylenediamine, isophorone diamine, methyl tetrahydro phthalic anhydride.
Described toughener is ethylene-vinyl acetate copolymer, polyethersulfone resin, methyl methacrylate-butadiene-benzene second
At least one in alkene terpolymer.
The preparation technology of a kind of impact resistance artificial quartz in lump, comprises the steps:
(1) particle diameter is less than or equal to the calcinated argil of 4mm at 1200-1400 less than or equal to the calcining quartz sand of 4mm, particle diameter
Calcine under DEG C high temperature 1 hour, then rush with 5 DEG C of cold water and water, then they are calcined under 1500-1600 DEG C of high temperature 1 hour, then
It is cooled to room temperature；
(2) in the material of step A add 50-100 mesh Pulvis Talci, 50-100 mesh vermiculite power, composite resin, firming agent,
Titanate coupling agent, toughener, colorant, each component uniformly mixes；
(3) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true
Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 92-98 DEG C in described solidification, and hardening time is 30 minutes, second stage
Solidification temperature is 80-84 DEG C, and hardening time is 20 minutes.
Embodiment 2
A kind of impact resistance artificial quartz in lump, is made up of the component of following weight portion (kg): the particle diameter calcining less than or equal to 4mm
Quartz sand 82 parts, particle diameter are less than or equal to the calcinated argil 43 parts of 4mm, 50-100 mesh Pulvis Talci 18 parts, 50-100 mesh vermiculite power 18
Part, composite resin 10 parts, 12 parts of firming agent, titanate coupling agent 8 parts, toughener 8 parts, 4 parts of colorant.
Described composite resin is by Research of Grafting Malaic Anhydride Onto Polyethylene, chlorine vulcanized polyethylene, N-salicylamide base phthalyl Asia
Amine, hydrogenated styrene isoprene-styrene block copolymer are mixed to prepare by equivalent part.
Described firming agent is at least one in trimethylhexamethylenediamine, isophorone diamine, methyl tetrahydro phthalic anhydride.
Described toughener is ethylene-vinyl acetate copolymer, polyethersulfone resin, methyl methacrylate-butadiene-benzene second
At least one in alkene terpolymer.
The preparation technology of a kind of impact resistance artificial quartz in lump, comprises the steps:
(1) particle diameter is less than or equal to the calcinated argil of 4mm at 1200-1400 less than or equal to the calcining quartz sand of 4mm, particle diameter
Calcine under DEG C high temperature 1 hour, then rush with 5 DEG C of cold water and water, then they are calcined under 1500-1600 DEG C of high temperature 1 hour, then
It is cooled to room temperature；
(2) in the material of step A add 50-100 mesh Pulvis Talci, 50-100 mesh vermiculite power, composite resin, firming agent,
Titanate coupling agent, toughener, colorant, each component uniformly mixes；
(3) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true
Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 92-98 DEG C in described solidification, and hardening time is 30 minutes, second stage
Solidification temperature is 80-84 DEG C, and hardening time is 20 minutes.
Embodiment 3
A kind of impact resistance artificial quartz in lump, is made up of the component of following weight portion (kg): the particle diameter calcining less than or equal to 4mm
Quartz sand 88 parts, particle diameter are less than or equal to the calcinated argil 48 parts of 4mm, 50-100 mesh Pulvis Talci 26 parts, 50-100 mesh vermiculite power 26
Part, composite resin 15 parts, 16 parts of firming agent, titanate coupling agent 12 parts, toughener 12 parts, 6 parts of colorant.
Described composite resin is by Research of Grafting Malaic Anhydride Onto Polyethylene, chlorine vulcanized polyethylene, N-salicylamide base phthalyl Asia
Amine, hydrogenated styrene isoprene-styrene block copolymer are mixed to prepare by equivalent part.
Described firming agent is at least one in trimethylhexamethylenediamine, isophorone diamine, methyl tetrahydro phthalic anhydride.
Described toughener is ethylene-vinyl acetate copolymer, polyethersulfone resin, methyl methacrylate-butadiene-benzene second
At least one in alkene terpolymer.
The preparation technology of a kind of impact resistance artificial quartz in lump, comprises the steps:
(1) particle diameter is less than or equal to the calcinated argil of 4mm at 1200-1400 less than or equal to the calcining quartz sand of 4mm, particle diameter
Calcine under DEG C high temperature 1 hour, then rush with 5 DEG C of cold water and water, then they are calcined under 1500-1600 DEG C of high temperature 1 hour, then
It is cooled to room temperature；
(2) in the material of step A add 50-100 mesh Pulvis Talci, 50-100 mesh vermiculite power, composite resin, firming agent,
Titanate coupling agent, toughener, colorant, each component uniformly mixes；
(3) material mixed is sent in material distributing machine cloth system template die, then making sheet mould is sent into vacuum chamber, take out true
Sky, vibration moulding, it is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
In two stages, first stage solidification temperature is 92-98 DEG C in described solidification, and hardening time is 30 minutes, second stage
Solidification temperature is 80-84 DEG C, and hardening time is 20 minutes.
Test
The prepared quartz of the embodiment of the present invention 1,2,3 and commonly artificial quartz in lump detection Data Comparison result such as following table institute
Show:
From contrast experiment's data of above table, the artificial quartz in lump of the present invention is than common artificial quartz in lump each side
Performance all has greatly improved.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (6)
1. an impact resistance artificial quartz in lump, it is characterised in that be made up of the component of following weight portion: particle diameter is less than or equal to 4mm
Calcining quartz sand 82-88 part, particle diameter less than or equal to calcinated argil 43-48 part of 4mm, 50-100 mesh Pulvis Talci 18-26 part,
50-100 mesh vermiculite power 18-26 part, composite resin 10-15 part, firming agent 12-16 part, titanate coupling agent 8-12 part, toughener
8-12 part, colorant 4-6 part.
2. a kind of impact resistance artificial quartz in lump as claimed in claim 1, it is characterised in that described composite resin is connect by polyethylene
Branch maleic anhydride, chlorine vulcanized polyethylene, N-salicylamide base phthalimide, hydrogenated styrene isoprene-styrene are embedding
Section copolymer is mixed to prepare by equivalent part.
3. a kind of impact resistance artificial quartz in lump as claimed in claim 1, it is characterised in that described firming agent is that trimethyl six is sub-
At least one in methanediamine, isophorone diamine, methyl tetrahydro phthalic anhydride.
4. a kind of impact resistance artificial quartz in lump as claimed in claim 1, it is characterised in that described toughener is ethyl vinyl acetate
At least one in ethylene copolymer, polyethersulfone resin, MBS terpolymer.
5. the preparation technology of an impact resistance artificial quartz in lump, it is characterised in that comprise the steps:
(1) by high at 1200-1400 DEG C less than or equal to the calcining quartz sand of 4mm, the particle diameter calcinated argil less than or equal to 4mm for particle diameter
The lower calcining of temperature 1 hour, then waters with 5 DEG C of cold water punchings, then they is calcined 1 hour under 1500-1600 DEG C of high temperature, the coldest
But to room temperature；
(2) in the material of step A, 50-100 mesh Pulvis Talci, 50-100 mesh vermiculite power, composite resin, firming agent, metatitanic acid are added
Ester coupling agent, toughener, colorant, each component uniformly mixes；
(3) material mixed is sent in material distributing machine cloth system template die, then by making sheet mould feeding vacuum chamber, evacuation,
Vibration moulding, is re-fed into curing oven, i.e. prepares artificial quartz stone plate.
The preparation technology of a kind of impact resistance artificial quartz in lump the most as claimed in claim 5, it is characterised in that described solidification divides two
In the stage, first stage solidification temperature is 92-98 DEG C, and hardening time is 30 minutes, and second stage solidification temperature is 80-84 DEG C, Gu
The change time is 20 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610481234.1A CN106116251A (en) | 2016-06-24 | 2016-06-24 | A kind of impact resistance artificial quartz in lump |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610481234.1A CN106116251A (en) | 2016-06-24 | 2016-06-24 | A kind of impact resistance artificial quartz in lump |
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| Publication Number | Publication Date |
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| CN106116251A true CN106116251A (en) | 2016-11-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610481234.1A Pending CN106116251A (en) | 2016-06-24 | 2016-06-24 | A kind of impact resistance artificial quartz in lump |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
| CN107140877A (en) * | 2017-05-19 | 2017-09-08 | 广东中旗新材料科技有限公司 | A kind of toughness artificial quartz stone plate and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478215A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Super-hardness artificial quartz stone plate and manufacturing method thereof |
| CN104529247A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof |
| CN104556838A (en) * | 2014-12-15 | 2015-04-29 | 田忠和 | Anti-aging super-hardness artificial quartz stone plate and manufacturing method thereof |
| CN105601173A (en) * | 2014-11-25 | 2016-05-25 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Artificial quartz stone board and production technology thereof |
-
2016
- 2016-06-24 CN CN201610481234.1A patent/CN106116251A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105601173A (en) * | 2014-11-25 | 2016-05-25 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Artificial quartz stone board and production technology thereof |
| CN104478215A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Super-hardness artificial quartz stone plate and manufacturing method thereof |
| CN104529247A (en) * | 2014-12-15 | 2015-04-22 | 田忠和 | Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof |
| CN104556838A (en) * | 2014-12-15 | 2015-04-29 | 田忠和 | Anti-aging super-hardness artificial quartz stone plate and manufacturing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
| CN107140877A (en) * | 2017-05-19 | 2017-09-08 | 广东中旗新材料科技有限公司 | A kind of toughness artificial quartz stone plate and preparation method thereof |
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Application publication date: 20161116 |
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