CN104428325B - 基于二烯的聚合物胶乳的氢化 - Google Patents
基于二烯的聚合物胶乳的氢化 Download PDFInfo
- Publication number
- CN104428325B CN104428325B CN201380033098.4A CN201380033098A CN104428325B CN 104428325 B CN104428325 B CN 104428325B CN 201380033098 A CN201380033098 A CN 201380033098A CN 104428325 B CN104428325 B CN 104428325B
- Authority
- CN
- China
- Prior art keywords
- hydrogenation
- diene
- catalyst
- alkyl
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12173165.7A EP2676971B1 (en) | 2012-06-22 | 2012-06-22 | Hydrogenation of a diene-based polymer latex |
| EP12173165.7 | 2012-06-22 | ||
| PCT/IB2013/001319 WO2013190373A1 (en) | 2012-06-22 | 2013-06-21 | Hydrogenation of a diene-based polymer latex |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104428325A CN104428325A (zh) | 2015-03-18 |
| CN104428325B true CN104428325B (zh) | 2017-09-08 |
Family
ID=46331066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380033098.4A Active CN104428325B (zh) | 2012-06-22 | 2013-06-21 | 基于二烯的聚合物胶乳的氢化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9657113B2 (cg-RX-API-DMAC10.html) |
| EP (2) | EP2676971B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP6246802B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR101987519B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN104428325B (cg-RX-API-DMAC10.html) |
| BR (1) | BR112014032310A2 (cg-RX-API-DMAC10.html) |
| IN (1) | IN2014DN10686A (cg-RX-API-DMAC10.html) |
| WO (1) | WO2013190373A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105175581B (zh) * | 2015-09-25 | 2017-01-18 | 北京化工大学 | 一种亲水性氨基化氢化丁腈橡胶的制备方法及所得产物 |
| CN107851800B (zh) * | 2015-12-10 | 2021-02-09 | 株式会社Lg化学 | 导电材料分散液和使用其制造的锂二次电池 |
| JP6414937B2 (ja) * | 2016-12-22 | 2018-10-31 | 株式会社レヂテックス | 水素化天然ゴムラテックスの製造方法 |
| JP7282776B2 (ja) * | 2017-12-18 | 2023-05-29 | アランセオ・ドイチュランド・ゲーエムベーハー | ニトリルブタジエンゴムラテックスの水素化 |
| CN110540609B (zh) * | 2018-05-28 | 2022-12-23 | 王辉 | 制备氢化二烯基纳米乳液的方法和双子表面活性剂的用途 |
| JP7513610B2 (ja) | 2018-12-17 | 2024-07-09 | アランセオ・ドイチュランド・ゲーエムベーハー | Pegアクリレート-hnbrコポリマーを製造するためのプロセス |
| KR102845314B1 (ko) | 2018-12-17 | 2025-08-13 | 아란세오 도이치란드 게엠베하 | 대체 용매를 이용하여 hnbr 용액을 제조하기 위한 공정 |
| CN110862467B (zh) * | 2019-09-25 | 2022-03-04 | 青岛科技大学 | 一种共轭二烯烃胶乳选择性加氢方法 |
| CN110627928B (zh) * | 2019-10-14 | 2021-10-26 | 山东京博石油化工有限公司 | 一种共轭二烯烃加氢制备氢化共聚物的方法 |
| CN111019018B (zh) * | 2019-12-25 | 2022-03-04 | 山东京博石油化工有限公司 | 一种氢化二烯烃基橡胶的制备方法 |
| CN111363066A (zh) * | 2020-01-10 | 2020-07-03 | 山东京博中聚新材料有限公司 | 一种共轭二烯烃胶乳选择性加氢方法 |
| CN111690080B (zh) * | 2020-01-10 | 2023-05-30 | 山东京博中聚新材料有限公司 | 一种共轭二烯烃胶乳选择性加氢方法 |
| CN112940185B (zh) * | 2021-03-29 | 2022-04-22 | 黄河三角洲京博化工研究院有限公司 | 一种共聚物胶乳的选择性加氢方法 |
| CN113429499B (zh) * | 2021-08-09 | 2022-05-31 | 中国科学院兰州化学物理研究所 | 一种腈橡胶的催化氢化方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358201A (zh) * | 1999-05-27 | 2002-07-10 | 巴斯福股份公司 | 聚合物中烯属不饱和双键的选择性氢化 |
| WO2011029732A1 (en) * | 2009-08-31 | 2011-03-17 | Lanxess Deutschland Gmbh | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454644A (en) | 1966-05-09 | 1969-07-08 | Shell Oil Co | Homogeneous hydrogenation process employing a complex of ruthenium or osmium as catalyst |
| US4452950A (en) | 1983-02-22 | 1984-06-05 | The Goodyear Tire & Rubber Company | Process for hydrogenation of carbon-carbon double bonds in an unsaturated polymer in latex form |
| DE3803450A1 (de) | 1988-02-05 | 1989-08-17 | Hoechst Ag | Emissionsarme dispersionsfarben, anstrichmittel und kunststoffdispersionsputze sowie verfahren zu ihrer herstellung |
| DE3834734A1 (de) | 1988-10-12 | 1990-04-19 | Basf Ag | Verfahren zur herstellung von polymerisaten aus olefinisch ungesaettigten monomeren |
| JP2732273B2 (ja) | 1988-12-29 | 1998-03-25 | 日本ゼオン株式会社 | ニトリル基含有水素化重合体の製造方法 |
| DE3902103A1 (de) | 1989-01-25 | 1990-08-02 | Roehm Gmbh | Bindemittel fuer waessrige glanzfarben |
| US5039737A (en) | 1990-02-22 | 1991-08-13 | The Goodyear Tire & Rubber Company/Olin Corp. | Ozonolysis of hydrogenated latices |
| US5057581A (en) | 1990-05-02 | 1991-10-15 | University Of Waterloo | Polymer hydrogenation process |
| CA2091128C (en) | 1992-03-08 | 1999-07-27 | Michael A. Taylor | Removal of organic volatiles from polymer solutions and dispersions |
| DE4213967A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersion |
| DE4213969A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersion |
| DE4213965A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersion |
| DE4213964A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersionen |
| DE4213968A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Waessrige polymerisatdispersion |
| US5424356A (en) | 1994-03-21 | 1995-06-13 | The Goodyear Tire & Rubber Company | Process for the preparation of hydrogenated rubber |
| DE4435423A1 (de) | 1994-10-04 | 1996-04-11 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| DE4419518A1 (de) | 1994-06-03 | 1995-12-07 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| CN1120180C (zh) | 1994-06-03 | 2003-09-03 | 巴斯福股份公司 | 聚合物水分散液的制备 |
| DE4435422A1 (de) | 1994-10-04 | 1996-04-18 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| KR100201228B1 (ko) | 1995-10-17 | 1999-06-15 | 박찬구 | 리빙중합체의 수첨방법 |
| US5705571A (en) | 1996-05-17 | 1998-01-06 | Taiwan Synthetic Rubber Corporation | Process for selective hydrogenation of conjugated diene polymer |
| DE19753302A1 (de) | 1997-12-01 | 1999-06-02 | Basf Ag | Verfahren zur selektiven Hydrierung von ethylenisch ungesättigten Doppelbindungen in Polymerisaten |
| ATE235515T1 (de) | 1998-08-11 | 2003-04-15 | Dsm Nv | Verfahren zur hydrierung eines polymeren aufgebaut aus dienmonomeren und nitrilgruppen enthaltenden monomeren und hydriertes polymer |
| KR100348761B1 (ko) | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
| NL1014197C2 (nl) | 2000-01-27 | 2001-07-30 | Dsm Nv | Werkwijze voor de hydrogenering van een polymeer dat is opgebouwd uit dieenmonomeereenheden en monomeereenheden die een nitrilgroep bevatten. |
| JP4459374B2 (ja) | 2000-04-03 | 2010-04-28 | 電気化学工業株式会社 | クロロプレン系重合体の水素化方法 |
| DE10019215A1 (de) | 2000-04-18 | 2001-10-25 | Basf Ag | Neue Schlagzähmodifier auf Basis von (teil)hydrierten butadienhaltigen Dispersionen |
| US6838489B2 (en) | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
| CA2350280A1 (en) | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
| CN1265882C (zh) | 2001-08-01 | 2006-07-26 | 加州理工学院 | 六配位钌或锇金属卡宾易位催化剂 |
| JP2003126698A (ja) | 2001-10-25 | 2003-05-07 | Mitsubishi Rayon Co Ltd | 不飽和ポリマー水素化触媒および水素化ポリマーラテックスの製造方法 |
| CA2462005A1 (en) | 2004-02-23 | 2005-08-23 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| US7385010B2 (en) | 2005-03-18 | 2008-06-10 | Lanxess Inc. | Hydrogenation of diene-based polymer latex |
| EP2075263A1 (en) | 2007-12-17 | 2009-07-01 | Lanxess Inc. | Hydrogenation of a diene-based polymer latex |
| EP2072535A1 (en) * | 2007-12-17 | 2009-06-24 | Lanxess Inc. | Hydrogenation of diene-based polymer latex |
| EP2289947A1 (en) * | 2009-08-26 | 2011-03-02 | University Of Waterloo | Nano-sized hydrogenated diene-based latex particles |
-
2012
- 2012-06-22 EP EP12173165.7A patent/EP2676971B1/en active Active
-
2013
- 2013-06-21 KR KR1020147035713A patent/KR101987519B1/ko active Active
- 2013-06-21 EP EP13807616.1A patent/EP2864372A4/en not_active Withdrawn
- 2013-06-21 BR BR112014032310A patent/BR112014032310A2/pt not_active IP Right Cessation
- 2013-06-21 US US14/408,593 patent/US9657113B2/en active Active
- 2013-06-21 IN IN10686DEN2014 patent/IN2014DN10686A/en unknown
- 2013-06-21 CN CN201380033098.4A patent/CN104428325B/zh active Active
- 2013-06-21 WO PCT/IB2013/001319 patent/WO2013190373A1/en not_active Ceased
- 2013-06-21 JP JP2015517869A patent/JP6246802B2/ja active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358201A (zh) * | 1999-05-27 | 2002-07-10 | 巴斯福股份公司 | 聚合物中烯属不饱和双键的选择性氢化 |
| WO2011029732A1 (en) * | 2009-08-31 | 2011-03-17 | Lanxess Deutschland Gmbh | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
Non-Patent Citations (1)
| Title |
|---|
| Metathesis hydrogenation of natural rubber latex;KONGPARAKUL Suwadee et al.;《Applied Catalysis A: General》;20110805;第405卷(第1-2期);129-136 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US9657113B2 (en) | 2017-05-23 |
| US20150183892A1 (en) | 2015-07-02 |
| JP6246802B2 (ja) | 2017-12-13 |
| IN2014DN10686A (cg-RX-API-DMAC10.html) | 2015-08-28 |
| BR112014032310A2 (pt) | 2017-06-27 |
| KR20150022861A (ko) | 2015-03-04 |
| EP2864372A1 (en) | 2015-04-29 |
| EP2676971A1 (en) | 2013-12-25 |
| WO2013190373A1 (en) | 2013-12-27 |
| EP2864372A4 (en) | 2016-03-02 |
| EP2676971B1 (en) | 2015-04-08 |
| JP2015526542A (ja) | 2015-09-10 |
| CN104428325A (zh) | 2015-03-18 |
| KR101987519B1 (ko) | 2019-06-10 |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |