CN104404568B - 利用碳酸锰矿和氧化锰矿焙烧生产电解金属锰的方法 - Google Patents
利用碳酸锰矿和氧化锰矿焙烧生产电解金属锰的方法 Download PDFInfo
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- CN104404568B CN104404568B CN201410775759.7A CN201410775759A CN104404568B CN 104404568 B CN104404568 B CN 104404568B CN 201410775759 A CN201410775759 A CN 201410775759A CN 104404568 B CN104404568 B CN 104404568B
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- manganese
- ore
- manganese oxide
- oxide ore
- manganese carbonate
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims abstract description 90
- 239000011656 manganese carbonate Substances 0.000 title claims abstract description 49
- 235000006748 manganese carbonate Nutrition 0.000 title claims abstract description 49
- 229940093474 manganese carbonate Drugs 0.000 title claims abstract description 49
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 title claims abstract description 49
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 title claims abstract description 49
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 26
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000011572 manganese Substances 0.000 claims abstract description 32
- 238000002386 leaching Methods 0.000 claims abstract description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 19
- 230000009467 reduction Effects 0.000 claims abstract description 18
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 239000000706 filtrate Substances 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002817 coal dust Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 6
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 6
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 6
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 6
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000000047 product Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 17
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 14
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 238000001514 detection method Methods 0.000 claims description 12
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 11
- 239000003245 coal Substances 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 5
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- NMCIIHHPIPGOPF-UHFFFAOYSA-N [Na].CN(C)SC(O)=S Chemical compound [Na].CN(C)SC(O)=S NMCIIHHPIPGOPF-UHFFFAOYSA-N 0.000 claims description 3
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 claims description 2
- 150000004965 peroxy acids Chemical class 0.000 claims description 2
- 238000004073 vulcanization Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000007772 electrode material Substances 0.000 abstract description 2
- VASIZKWUTCETSD-UHFFFAOYSA-N oxomanganese Chemical compound [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 13
- 239000002893 slag Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010038743 Restlessness Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/10—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of chromium or manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201410775759.7A CN104404568B (zh) | 2014-12-15 | 2014-12-15 | 利用碳酸锰矿和氧化锰矿焙烧生产电解金属锰的方法 |
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CN201410775759.7A CN104404568B (zh) | 2014-12-15 | 2014-12-15 | 利用碳酸锰矿和氧化锰矿焙烧生产电解金属锰的方法 |
Publications (2)
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CN104404568A CN104404568A (zh) | 2015-03-11 |
CN104404568B true CN104404568B (zh) | 2017-09-26 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104789755B (zh) * | 2015-04-23 | 2017-03-01 | 中南大学 | 一种用高硫锰矿清洁高效生产金属锰的方法及装置 |
CN104975167B (zh) * | 2015-07-24 | 2017-09-12 | 长沙矿冶研究院有限责任公司 | 一种含锰的多物相组成的复合锰矿提取锰的方法 |
CN106367589B (zh) * | 2016-09-19 | 2018-01-16 | 北京科技大学 | 一种短流程低消耗的高纯硫酸锰溶液制备方法 |
CN106756350B (zh) * | 2017-01-18 | 2018-11-02 | 中信锦州金属股份有限公司 | 半碳酸锰矿冶炼中低碳锰铁的生产工艺 |
CN108063247A (zh) * | 2017-12-23 | 2018-05-22 | 清远佳致新材料研究院有限公司 | 一种复合锰矿制备锰酸锂正极材料的方法 |
CN108588402B (zh) * | 2018-05-18 | 2020-01-17 | 中信大锰矿业有限责任公司 | 一种加蓬高铁氧化锰矿的环保利用方法 |
CN114108030A (zh) * | 2021-11-29 | 2022-03-01 | 靖西市锰矿有限责任公司 | 一种生产电解金属锰的方法 |
CN114480886A (zh) * | 2021-12-23 | 2022-05-13 | 四川中哲新材料科技有限公司 | 高镁杂质碳酸锰矿生产电解金属锰的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103233243A (zh) * | 2013-04-15 | 2013-08-07 | 广西有色金属集团汇元锰业有限公司 | 电解金属锰的生产方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1112451C (zh) * | 2000-11-08 | 2003-06-25 | 重庆三角滩锰业有限公司 | 用焙烧矿替代用天然二氧化锰矿电解金属锰的工艺 |
CN1804062A (zh) * | 2006-01-11 | 2006-07-19 | 黄有余 | 粗铟与活性氧化锌联产工艺 |
CN101307463B (zh) * | 2008-07-16 | 2010-06-02 | 中信锦州铁合金股份有限公司 | 利用锰渣代替部分氨水中和除铁生产电解金属锰的方法 |
CN101307462A (zh) * | 2008-07-16 | 2008-11-19 | 中信锦州铁合金股份有限公司 | 一种高铁锰矿浸出除铁的方法 |
CN102212676A (zh) * | 2011-04-27 | 2011-10-12 | 段友构 | 一种利用碳粉还原转化氧化锰矿生产电解金属锰的工艺 |
CN103014320A (zh) * | 2012-12-07 | 2013-04-03 | 中信大锰矿业有限责任公司 | 含硫碳质碳酸锰矿制取硫酸锰的方法 |
CN103014760B (zh) * | 2013-01-09 | 2015-04-15 | 广西有色金属集团汇元锰业有限公司 | 一种电解金属锰的生产方法 |
CN103074490B (zh) * | 2013-01-09 | 2014-03-12 | 广西有色金属集团汇元锰业有限公司 | 一种多矿法生产电解金属锰过程中的净化方法 |
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2014
- 2014-12-15 CN CN201410775759.7A patent/CN104404568B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103233243A (zh) * | 2013-04-15 | 2013-08-07 | 广西有色金属集团汇元锰业有限公司 | 电解金属锰的生产方法 |
Non-Patent Citations (1)
Title |
---|
某氧化锰矿还原焙烧-酸浸试验研究;龙艳等;《矿冶工程》;20121215;第32卷(第6期);1.3实验方法,3.1焙烧条件实验-3.4粗颗粒验证试验 * |
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Address after: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee after: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. Address before: 532315 Daxin Manganese Mine, Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee before: DAXIN MANGANESE MINE BRANCH OF CITIC DAMENG MINING INDUSTRIES Ltd. |
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Effective date of registration: 20211013 Address after: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee after: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. Patentee after: Nanfang Manganese Industry Group Co.,Ltd. Address before: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee before: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. |
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