CN104379504B - 沸石材料及其利用烯基三烷基铵化合物的制备方法 - Google Patents

沸石材料及其利用烯基三烷基铵化合物的制备方法 Download PDF

Info

Publication number
CN104379504B
CN104379504B CN201380033336.1A CN201380033336A CN104379504B CN 104379504 B CN104379504 B CN 104379504B CN 201380033336 A CN201380033336 A CN 201380033336A CN 104379504 B CN104379504 B CN 104379504B
Authority
CN
China
Prior art keywords
zeolitic material
mixture
zeolitic
range
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380033336.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN104379504A (zh
Inventor
M·费延
U·穆勒
安德烈-尼古拉·帕乌莱斯库
B·B·沙克
S·阿伦斯
D·葛哈德
孙成熙
G·伊夫兰德
B·西利格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN104379504A publication Critical patent/CN104379504A/zh
Application granted granted Critical
Publication of CN104379504B publication Critical patent/CN104379504B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/082—Gallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380033336.1A 2012-04-24 2013-04-24 沸石材料及其利用烯基三烷基铵化合物的制备方法 Active CN104379504B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12165356 2012-04-24
EP12165356.2 2012-04-24
PCT/EP2013/058481 WO2013160345A1 (en) 2012-04-24 2013-04-24 Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds

Publications (2)

Publication Number Publication Date
CN104379504A CN104379504A (zh) 2015-02-25
CN104379504B true CN104379504B (zh) 2016-10-12

Family

ID=48325622

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380033336.1A Active CN104379504B (zh) 2012-04-24 2013-04-24 沸石材料及其利用烯基三烷基铵化合物的制备方法

Country Status (12)

Country Link
EP (1) EP2841383B1 (enExample)
JP (1) JP6177880B2 (enExample)
KR (1) KR102062748B1 (enExample)
CN (1) CN104379504B (enExample)
BR (1) BR112014026543A2 (enExample)
ES (1) ES2615057T3 (enExample)
MX (1) MX354648B (enExample)
MY (1) MY166378A (enExample)
RU (1) RU2622300C2 (enExample)
SG (1) SG11201406841SA (enExample)
WO (1) WO2013160345A1 (enExample)
ZA (1) ZA201408564B (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG10201803332YA (en) 2013-10-23 2018-06-28 Basf Se Molding for a hydrophobic zeolitic material and process for its production
CN105084385B (zh) * 2014-05-23 2017-06-30 中国石油化工股份有限公司 一种含钛分子筛、制备方法及其应用
CN107840347B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
CN107840344B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
RU2675018C1 (ru) * 2018-02-08 2018-12-14 Ирина Игоревна Иванова Гранулированный без связующего кристаллический цеолит mfi и способ его получения
US20220168704A1 (en) * 2019-04-01 2022-06-02 Csp Technologies, Inc. Polymer compositions containing zeolite for enhanced water adsorption
WO2020241052A1 (ja) * 2019-05-29 2020-12-03 住友化学株式会社 チタン含有珪素酸化物の製造方法、エポキシドの製造方法、及びチタン含有珪素酸化物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1089574A (zh) * 1992-06-05 1994-07-20 埃克森化学专利公司 Zsm-5沸石
CN1168860A (zh) * 1996-06-19 1997-12-31 德古萨股份公司 微孔和中孔晶状金属硅酸盐的制备方法，由该方法得到的产物及其应用
CN1401569A (zh) * 2002-08-26 2003-03-12 大连理工大学 一种纳米级钛硅分子筛催化剂的快速合成方法及应用
WO2010150996A2 (en) * 2009-06-22 2010-12-29 Korea Advanced Institute Of Science And Technology Regularly stacked multilamellar and randomly aligned unilamellar zeolite nanosheets, and their analogue materials whose framework thickness were corresponding to one unit cell size or less than 10 unit cell size
CN101935053A (zh) * 2009-06-30 2011-01-05 中国石油化工股份有限公司石油化工科学研究院 一种zsm-5沸石及其合成方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US4565681A (en) * 1984-05-03 1986-01-21 Mobil Oil Corporation Synthetic zeolite ZSM-5 having a dimethylethylpropylammonium component
EP0473509A3 (fr) * 1990-08-29 1992-03-18 Rhone-Poulenc Chimie Procédé de préparation de zéolithes à base de silice et éventuellement d'oxydes d'éléments tétravalents
US5919430A (en) * 1996-06-19 1999-07-06 Degussa Aktiengesellschaft Preparation of crystalline microporous and mesoporous metal silicates, products produced thereby and use thereof
DE10356184A1 (de) 2003-12-02 2005-07-07 Basf Ag Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung
DE102004017915A1 (de) 2004-04-13 2005-11-03 Basf Ag Mikroporöses Gerüstsilikat und Verfahren zu seiner Herstellung
US8048402B2 (en) 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
US20070224113A1 (en) * 2006-03-24 2007-09-27 Willis Richard R Process for Preparing Nano Size Zeolites
KR101398291B1 (ko) 2006-09-25 2014-05-22 셰브런 유.에스.에이.인크. 구조지향제 및 ｎ,ｎ,ｎ-트리알킬 벤질 4차 암모늄 양이온을 이용한 분자체 제조 방법
US8057782B2 (en) 2006-12-27 2011-11-15 Chevron U.S.A. Inc. Preparation of small pore molecular sieves

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1089574A (zh) * 1992-06-05 1994-07-20 埃克森化学专利公司 Zsm-5沸石
CN1168860A (zh) * 1996-06-19 1997-12-31 德古萨股份公司 微孔和中孔晶状金属硅酸盐的制备方法，由该方法得到的产物及其应用
CN1401569A (zh) * 2002-08-26 2003-03-12 大连理工大学 一种纳米级钛硅分子筛催化剂的快速合成方法及应用
WO2010150996A2 (en) * 2009-06-22 2010-12-29 Korea Advanced Institute Of Science And Technology Regularly stacked multilamellar and randomly aligned unilamellar zeolite nanosheets, and their analogue materials whose framework thickness were corresponding to one unit cell size or less than 10 unit cell size
CN101935053A (zh) * 2009-06-30 2011-01-05 中国石油化工股份有限公司石油化工科学研究院 一种zsm-5沸石及其合成方法

Also Published As

Publication number Publication date
EP2841383B1 (en) 2016-11-09
JP2015519282A (ja) 2015-07-09
CN104379504A (zh) 2015-02-25
ES2615057T3 (es) 2017-06-05
JP6177880B2 (ja) 2017-08-09
MY166378A (en) 2018-06-25
WO2013160345A1 (en) 2013-10-31
EP2841383A1 (en) 2015-03-04
RU2622300C2 (ru) 2017-06-14
MX354648B (es) 2018-03-14
RU2014146901A (ru) 2016-06-10
SG11201406841SA (en) 2014-11-27
MX2014013006A (es) 2015-08-06
ZA201408564B (en) 2016-08-31
BR112014026543A2 (pt) 2017-06-27
KR20150016250A (ko) 2015-02-11
KR102062748B1 (ko) 2020-01-06

Similar Documents

Publication Publication Date Title
US10266417B2 (en) Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds
CN104379504B (zh) 沸石材料及其利用烯基三烷基铵化合物的制备方法
EP3640207B1 (en) Molecular sieve scm-15, synthesis method therefor and use thereof
RU2601462C2 (ru) Молекулярное сито емм-22, его синтез и применение
JP6461807B2 (ja) ゼオライト材料の製造方法及び酸素含有物質のオレフィンへの転化方法におけるゼオライト材料の使用
CN106536411B (zh) 具有mww骨架结构的含硼沸石的合成
CN109890756B (zh) 铝取代的分子筛cit-13
CN110914195B (zh) 分子筛ssz-112、其合成及应用
JP2016519043A (ja) Ｅｍｍ−２５モレキュラーシーブ材料、その合成および使用
KR20180116336A (ko) 소결정 고-표면적 emm-30 제올라이트, 이의 합성 및 용도
JP7267537B2 (ja) Ｍｗｗ型ゼオライト及びその製造方法、並びにクラッキング触媒
JP6842544B2 (ja) モレキュラーシーブｓｓｚ−４１の合成
JP2020523266A (ja) モレキュラーシーブｓｓｚ−１１１、その合成及び使用
KR20250160340A (ko) Emm-74 분자체 조성물, 합성 및 용도
EP4412957B1 (en) Emm-68 aluminosilicate zeolites, syntheses, and uses
KR20240134905A (ko) Emm-70 제올라이트 조성물, 합성 및 용도
EP4355691B1 (en) Use of 1-methyl-6,7-dihydro-5h-cyclopenta[b]pyridine-1-ium cation as structure directing agent for the preparation of emm-64
CN108640122A (zh) 利用元素前驱体制备沸石材料的方法
KR20240065295A (ko) Emm-63 알루미노실리케이트 제올라이트, 합성 및 용도
JP2025506962A (ja) Ｅｍｍ－７３モレキュラー・シーブの組成物、合成および使用
JP2025506180A (ja) 分子篩の調製用の構造指向剤としての１，２，３，５－テトラメチルベンゾイミダゾリウムおよび１，２，３，４，５－ペンタメチルベンゾイミダゾリウムから選択されるカチオンの使用およびこれを用いて得られる分子篩
CN116075364A (zh) 分子筛ssz-123、其合成和用途

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant