JP6177880B2 - ゼオライト材料及びその製造方法並びにその使用方法 - Google Patents

ゼオライト材料及びその製造方法並びにその使用方法 Download PDF

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JP6177880B2
JP6177880B2 JP2015507515A JP2015507515A JP6177880B2 JP 6177880 B2 JP6177880 B2 JP 6177880B2 JP 2015507515 A JP2015507515 A JP 2015507515A JP 2015507515 A JP2015507515 A JP 2015507515A JP 6177880 B2 JP6177880 B2 JP 6177880B2
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zeolitic material
material according
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JP2015519282A (ja
JP2015519282A5 (enExample
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ファイエン，マティアス
ミュラー，ウルリヒ
パルフレスク，アンドレイ−ニコラエ
バスティアン シャーク，ベルント
バスティアン シャーク，ベルント
アーレンス，ゼバスティアン
ゲルハルト，ディルク
ソン，スンヘー
イフラント，ガブリエレ
ゼーリヒ，ビアンカ
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/082—Gallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2015507515A 2012-04-24 2013-04-24 ゼオライト材料及びその製造方法並びにその使用方法 Active JP6177880B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12165356.2 2012-04-24
EP12165356 2012-04-24
PCT/EP2013/058481 WO2013160345A1 (en) 2012-04-24 2013-04-24 Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds

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JP2015519282A JP2015519282A (ja) 2015-07-09
JP2015519282A5 JP2015519282A5 (enExample) 2016-06-16
JP6177880B2 true JP6177880B2 (ja) 2017-08-09

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EP (1) EP2841383B1 (enExample)
JP (1) JP6177880B2 (enExample)
KR (1) KR102062748B1 (enExample)
CN (1) CN104379504B (enExample)
BR (1) BR112014026543A2 (enExample)
ES (1) ES2615057T3 (enExample)
MX (1) MX354648B (enExample)
MY (1) MY166378A (enExample)
RU (1) RU2622300C2 (enExample)
SG (1) SG11201406841SA (enExample)
WO (1) WO2013160345A1 (enExample)
ZA (1) ZA201408564B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105848781B (zh) 2013-10-23 2020-07-17 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
CN105084385B (zh) * 2014-05-23 2017-06-30 中国石油化工股份有限公司 一种含钛分子筛、制备方法及其应用
CN107840344B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
CN107840347B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
RU2675018C1 (ru) * 2018-02-08 2018-12-14 Ирина Игоревна Иванова Гранулированный без связующего кристаллический цеолит mfi и способ его получения
US20220168704A1 (en) * 2019-04-01 2022-06-02 Csp Technologies, Inc. Polymer compositions containing zeolite for enhanced water adsorption
KR102811135B1 (ko) * 2019-05-29 2025-05-21 스미또모 가가꾸 가부시끼가이샤 티탄 함유 규소 산화물의 제조 방법, 에폭시드의 제조 방법, 및 티탄 함유 규소 산화물
WO2026104463A1 (en) 2024-11-13 2026-05-21 Basf Se Improved epoxidation catalyst
WO2026104452A1 (en) 2024-11-13 2026-05-21 Basf Se Catalyst for epoxidation of propylene

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US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US4565681A (en) * 1984-05-03 1986-01-21 Mobil Oil Corporation Synthetic zeolite ZSM-5 having a dimethylethylpropylammonium component
EP0473509A3 (fr) * 1990-08-29 1992-03-18 Rhone-Poulenc Chimie Procédé de préparation de zéolithes à base de silice et éventuellement d'oxydes d'éléments tétravalents
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
US5919430A (en) * 1996-06-19 1999-07-06 Degussa Aktiengesellschaft Preparation of crystalline microporous and mesoporous metal silicates, products produced thereby and use thereof
DE19624340A1 (de) * 1996-06-19 1998-01-08 Degussa Verfahren zur Herstellung von kristallinen mikro- und mesoporösen Metallsilicaten, verfahrensgemäß erhältliche Produkte und deren Verwendung
CN1401569A (zh) * 2002-08-26 2003-03-12 大连理工大学 一种纳米级钛硅分子筛催化剂的快速合成方法及应用
DE10356184A1 (de) 2003-12-02 2005-07-07 Basf Ag Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung
DE102004017915A1 (de) 2004-04-13 2005-11-03 Basf Ag Mikroporöses Gerüstsilikat und Verfahren zu seiner Herstellung
US8048402B2 (en) 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
US20070224113A1 (en) * 2006-03-24 2007-09-27 Willis Richard R Process for Preparing Nano Size Zeolites
ES2685497T3 (es) 2006-09-25 2018-10-09 Chevron U.S.A. Inc. Preparación de tamices moleculares utilizando un agente director de estructura y un catión de amonio cuaternario de N,N,N-trialquil bencilo
US8057782B2 (en) 2006-12-27 2011-11-15 Chevron U.S.A. Inc. Preparation of small pore molecular sieves
KR101147008B1 (ko) * 2009-06-22 2012-05-22 한국과학기술원 단일 단위 결정 격자 한 개 또는 10개 이하가 연결되어 규칙적이거나 불규칙적이게 배열된, 다중 또는 단일 판상구조의 제올라이트 및 유사 제올라이트 물질
CN101935053B (zh) * 2009-06-30 2012-07-18 中国石油化工股份有限公司 一种zsm-5沸石及其合成方法

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MX2014013006A (es) 2015-08-06
ES2615057T3 (es) 2017-06-05
RU2622300C2 (ru) 2017-06-14
ZA201408564B (en) 2016-08-31
EP2841383B1 (en) 2016-11-09
WO2013160345A1 (en) 2013-10-31
CN104379504B (zh) 2016-10-12
MX354648B (es) 2018-03-14
KR20150016250A (ko) 2015-02-11
MY166378A (en) 2018-06-25
JP2015519282A (ja) 2015-07-09
EP2841383A1 (en) 2015-03-04
SG11201406841SA (en) 2014-11-27
CN104379504A (zh) 2015-02-25
BR112014026543A2 (pt) 2017-06-27
KR102062748B1 (ko) 2020-01-06
RU2014146901A (ru) 2016-06-10

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