RU2622300C2 - Цеолитные материалы и способы их получения с применением алкенилтриаммониевых соединений - Google Patents

Цеолитные материалы и способы их получения с применением алкенилтриаммониевых соединений Download PDF

Info

Publication number
RU2622300C2
RU2622300C2 RU2014146901A RU2014146901A RU2622300C2 RU 2622300 C2 RU2622300 C2 RU 2622300C2 RU 2014146901 A RU2014146901 A RU 2014146901A RU 2014146901 A RU2014146901 A RU 2014146901A RU 2622300 C2 RU2622300 C2 RU 2622300C2
Authority
RU
Russia
Prior art keywords
zeolite material
present
mixture
range
propen
Prior art date
Application number
RU2014146901A
Other languages
English (en)
Russian (ru)
Other versions
RU2014146901A (ru
Inventor
Матиас ФАЙЕН
Ульрих Мюллер
Андрей-Николае ПАРВУЛЕСКУ
Бернд Бастиан ШААК
Зебастиан Аренс
Дирк ГЕРХАРД
Зунгхее ЗОН
Габриэле ИФФЛАНД
Бианка ЗЕЕЛИГ
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of RU2014146901A publication Critical patent/RU2014146901A/ru
Application granted granted Critical
Publication of RU2622300C2 publication Critical patent/RU2622300C2/ru

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/082—Gallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2014146901A 2012-04-24 2013-04-24 Цеолитные материалы и способы их получения с применением алкенилтриаммониевых соединений RU2622300C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12165356.2 2012-04-24
EP12165356 2012-04-24
PCT/EP2013/058481 WO2013160345A1 (en) 2012-04-24 2013-04-24 Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds

Publications (2)

Publication Number Publication Date
RU2014146901A RU2014146901A (ru) 2016-06-10
RU2622300C2 true RU2622300C2 (ru) 2017-06-14

Family

ID=48325622

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2014146901A RU2622300C2 (ru) 2012-04-24 2013-04-24 Цеолитные материалы и способы их получения с применением алкенилтриаммониевых соединений

Country Status (12)

Country Link
EP (1) EP2841383B1 (enExample)
JP (1) JP6177880B2 (enExample)
KR (1) KR102062748B1 (enExample)
CN (1) CN104379504B (enExample)
BR (1) BR112014026543A2 (enExample)
ES (1) ES2615057T3 (enExample)
MX (1) MX354648B (enExample)
MY (1) MY166378A (enExample)
RU (1) RU2622300C2 (enExample)
SG (1) SG11201406841SA (enExample)
WO (1) WO2013160345A1 (enExample)
ZA (1) ZA201408564B (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2675018C1 (ru) * 2018-02-08 2018-12-14 Ирина Игоревна Иванова Гранулированный без связующего кристаллический цеолит mfi и способ его получения
RU2805109C2 (ru) * 2019-05-29 2023-10-11 Сумитомо Кемикал Компани, Лимитед Способ получения содержащего титан оксида кремния, способ получения эпоксида и содержащий титан оксид кремния

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105848781B (zh) 2013-10-23 2020-07-17 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
CN105084385B (zh) * 2014-05-23 2017-06-30 中国石油化工股份有限公司 一种含钛分子筛、制备方法及其应用
CN107840344B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
CN107840347B (zh) * 2016-09-21 2020-08-18 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
US20220168704A1 (en) * 2019-04-01 2022-06-02 Csp Technologies, Inc. Polymer compositions containing zeolite for enhanced water adsorption
KR102811135B1 (ko) * 2019-05-29 2025-05-21 스미또모 가가꾸 가부시끼가이샤 티탄 함유 규소 산화물의 제조 방법, 에폭시드의 제조 방법, 및 티탄 함유 규소 산화물
WO2026104463A1 (en) 2024-11-13 2026-05-21 Basf Se Improved epoxidation catalyst
WO2026104452A1 (en) 2024-11-13 2026-05-21 Basf Se Catalyst for epoxidation of propylene

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5783321A (en) * 1992-06-05 1998-07-21 Exxon Chemical Patents Inc. ZSM-5 zeolite
US5919430A (en) * 1996-06-19 1999-07-06 Degussa Aktiengesellschaft Preparation of crystalline microporous and mesoporous metal silicates, products produced thereby and use thereof
RU2377180C1 (ru) * 2006-03-24 2009-12-27 Юоп Ллк Способ приготовления наноразмерных цеолитов
WO2010150996A2 (en) * 2009-06-22 2010-12-29 Korea Advanced Institute Of Science And Technology Regularly stacked multilamellar and randomly aligned unilamellar zeolite nanosheets, and their analogue materials whose framework thickness were corresponding to one unit cell size or less than 10 unit cell size

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US4565681A (en) * 1984-05-03 1986-01-21 Mobil Oil Corporation Synthetic zeolite ZSM-5 having a dimethylethylpropylammonium component
EP0473509A3 (fr) * 1990-08-29 1992-03-18 Rhone-Poulenc Chimie Procédé de préparation de zéolithes à base de silice et éventuellement d'oxydes d'éléments tétravalents
DE19624340A1 (de) * 1996-06-19 1998-01-08 Degussa Verfahren zur Herstellung von kristallinen mikro- und mesoporösen Metallsilicaten, verfahrensgemäß erhältliche Produkte und deren Verwendung
CN1401569A (zh) * 2002-08-26 2003-03-12 大连理工大学 一种纳米级钛硅分子筛催化剂的快速合成方法及应用
DE10356184A1 (de) 2003-12-02 2005-07-07 Basf Ag Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung
DE102004017915A1 (de) 2004-04-13 2005-11-03 Basf Ag Mikroporöses Gerüstsilikat und Verfahren zu seiner Herstellung
US8048402B2 (en) 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
ES2685497T3 (es) 2006-09-25 2018-10-09 Chevron U.S.A. Inc. Preparación de tamices moleculares utilizando un agente director de estructura y un catión de amonio cuaternario de N,N,N-trialquil bencilo
US8057782B2 (en) 2006-12-27 2011-11-15 Chevron U.S.A. Inc. Preparation of small pore molecular sieves
CN101935053B (zh) * 2009-06-30 2012-07-18 中国石油化工股份有限公司 一种zsm-5沸石及其合成方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5783321A (en) * 1992-06-05 1998-07-21 Exxon Chemical Patents Inc. ZSM-5 zeolite
US5919430A (en) * 1996-06-19 1999-07-06 Degussa Aktiengesellschaft Preparation of crystalline microporous and mesoporous metal silicates, products produced thereby and use thereof
RU2377180C1 (ru) * 2006-03-24 2009-12-27 Юоп Ллк Способ приготовления наноразмерных цеолитов
WO2010150996A2 (en) * 2009-06-22 2010-12-29 Korea Advanced Institute Of Science And Technology Regularly stacked multilamellar and randomly aligned unilamellar zeolite nanosheets, and their analogue materials whose framework thickness were corresponding to one unit cell size or less than 10 unit cell size

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2675018C1 (ru) * 2018-02-08 2018-12-14 Ирина Игоревна Иванова Гранулированный без связующего кристаллический цеолит mfi и способ его получения
RU2805109C2 (ru) * 2019-05-29 2023-10-11 Сумитомо Кемикал Компани, Лимитед Способ получения содержащего титан оксида кремния, способ получения эпоксида и содержащий титан оксид кремния

Also Published As

Publication number Publication date
MX2014013006A (es) 2015-08-06
ES2615057T3 (es) 2017-06-05
ZA201408564B (en) 2016-08-31
EP2841383B1 (en) 2016-11-09
WO2013160345A1 (en) 2013-10-31
CN104379504B (zh) 2016-10-12
MX354648B (es) 2018-03-14
KR20150016250A (ko) 2015-02-11
MY166378A (en) 2018-06-25
JP2015519282A (ja) 2015-07-09
EP2841383A1 (en) 2015-03-04
SG11201406841SA (en) 2014-11-27
CN104379504A (zh) 2015-02-25
JP6177880B2 (ja) 2017-08-09
BR112014026543A2 (pt) 2017-06-27
KR102062748B1 (ko) 2020-01-06
RU2014146901A (ru) 2016-06-10

Similar Documents

Publication Publication Date Title
US10793443B2 (en) Synthesis of a boron-containing zeolite with an MWW framework structure
EP3640207B1 (en) Molecular sieve scm-15, synthesis method therefor and use thereof
CN104379504B (zh) 沸石材料及其利用烯基三烷基铵化合物的制备方法
US10266417B2 (en) Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds
RU2740186C2 (ru) Синтетический цеолит, содержащий каталитический металл
EP3640208B1 (en) Molecular sieve scm-14, synthesis method therefor and use thereof
RU2601462C2 (ru) Молекулярное сито емм-22, его синтез и применение
JP2019112301A (ja) Ｍｗｗフレームワーク構造を有するチタン含有ゼオライト材料を製造するための方法
CN109689572B (zh) 具有mww骨架结构的含硼沸石的固热合成
JP2019511990A (ja) 小結晶で高表面積のｅｍｍ−３０ゼオライト、それらの合成および使用
KR20250160340A (ko) Emm-74 분자체 조성물, 합성 및 용도
CN113966251A (zh) Iwr骨架结构类型的硅铝酸盐沸石材料的直接合成及其在催化中的用途
KR20140067323A (ko) 메조기공을 갖는 ｍｒｅ 구조의 제올라이트 또는 유사 ｍｒｅ 제올라이트 물질 및 그의 제조 방법
CN112573535B (zh) Scm-32分子筛及其制备方法和应用
WO2014076032A1 (en) Process for the conversion of oxygenates to olefins
CN117651692B (zh) 1-甲基-6,7-二氢-5h-环戊[b]吡啶-1-鎓阳离子作为结构导向剂用于制备沸石的用途以及用其得到的沸石
US10183285B2 (en) Process for preparing a molecular sieve
US20150274540A1 (en) Process for the production of a zeolitic material employing elemental precursors