CN104379255B - 甲醇制造用催化剂及其制造方法以及甲醇的制造方法 - Google Patents

甲醇制造用催化剂及其制造方法以及甲醇的制造方法 Download PDF

Info

Publication number
CN104379255B
CN104379255B CN201380029240.8A CN201380029240A CN104379255B CN 104379255 B CN104379255 B CN 104379255B CN 201380029240 A CN201380029240 A CN 201380029240A CN 104379255 B CN104379255 B CN 104379255B
Authority
CN
China
Prior art keywords
catalyst
copper
methanol
zinc
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380029240.8A
Other languages
English (en)
Chinese (zh)
Other versions
CN104379255A (zh
Inventor
后藤友哉
高桥尚也
吉永胜己
村上雅美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemical Industry Co Ltd
Original Assignee
Mitsui Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=49711969&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN104379255(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mitsui Chemical Industry Co Ltd filed Critical Mitsui Chemical Industry Co Ltd
Publication of CN104379255A publication Critical patent/CN104379255A/zh
Application granted granted Critical
Publication of CN104379255B publication Critical patent/CN104379255B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380029240.8A 2012-06-04 2013-06-03 甲醇制造用催化剂及其制造方法以及甲醇的制造方法 Active CN104379255B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012-127031 2012-06-04
JP2012127031 2012-06-04
PCT/JP2013/065325 WO2013183577A1 (ja) 2012-06-04 2013-06-03 メタノール製造用触媒とその製造方法、およびメタノールの製造方法

Publications (2)

Publication Number Publication Date
CN104379255A CN104379255A (zh) 2015-02-25
CN104379255B true CN104379255B (zh) 2017-05-03

Family

ID=49711969

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380029240.8A Active CN104379255B (zh) 2012-06-04 2013-06-03 甲醇制造用催化剂及其制造方法以及甲醇的制造方法

Country Status (8)

Country Link
US (1) US9314774B2 (enExample)
EP (1) EP2857095B1 (enExample)
JP (1) JP5863964B2 (enExample)
CN (1) CN104379255B (enExample)
CA (1) CA2875353C (enExample)
IN (1) IN2014DN10249A (enExample)
SG (1) SG11201408066UA (enExample)
WO (1) WO2013183577A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI739254B (zh) 2019-12-26 2021-09-11 財團法人工業技術研究院 將碳氧化合物轉化為甲醇的觸媒及製程
US12409444B2 (en) 2020-10-02 2025-09-09 Johnson Matthey Public Limited Company Method for making copper-containing catalysts

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201418475D0 (en) * 2014-10-17 2014-12-03 Johnson Matthey Plc Catalyst and process
EA202190012A1 (ru) 2018-06-12 2021-03-16 Хальдор Топсёэ А/С Способ получения метанола с применением катализатора с низким содержанием железа
GB201905293D0 (en) * 2019-04-15 2019-05-29 Johnson Matthey Plc Copper-containing catalysts
CN109999817A (zh) * 2019-04-22 2019-07-12 盐城工学院 一种Cu/ZnO-ZrO2固溶体催化剂及其辉光放电等离子体辅助制备方法与应用
CN110694631A (zh) * 2019-10-12 2020-01-17 中国科学院山西煤炭化学研究所 一种合成甲醇的催化剂及其制备方法和应用
CN115053021A (zh) * 2020-01-27 2022-09-13 国立研究开发法人理化学研究所 阴极电极、阴极电极与基材的复合体、及阴极电极与基材的复合体的制造方法
AU2021334758A1 (en) 2020-08-31 2023-05-04 Sumitomo Chemical Company, Limited Methanol production method
GB202015635D0 (en) 2020-10-02 2020-11-18 Johnson Matthey Plc Method for making copper-containing catalysts
GB202016050D0 (en) * 2020-10-09 2020-11-25 Johnson Matthey Plc Hydrogen process
CN115990472A (zh) * 2021-10-19 2023-04-21 中国石油化工股份有限公司 二氧化碳加氢制甲醇联产二甲醚的催化剂及其制备和应用
US20250041835A1 (en) 2021-11-16 2025-02-06 Basf Se A catalyst for the conversion of co2-rich syngas to methanol and conventional syngas to dimethyl ether
US20250108363A1 (en) * 2021-12-30 2025-04-03 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Plasma-treated catalyst, production method thereof and use of the catalyst
AU2023317346A1 (en) * 2022-08-04 2025-02-13 Mitsui Mining & Smelting Co., Ltd. Composite oxide, catalyst for methanol production, and composite oxide production method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6048820A (en) * 1997-03-11 2000-04-11 Agency Of Industrial Of Sciences And Technology Copper-based catalyst and method for production thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5932949A (ja) 1982-08-13 1984-02-22 Mitsubishi Gas Chem Co Inc メタノ−ル合成用触媒
JPS6339287A (ja) 1986-08-04 1988-02-19 Matsushita Electric Ind Co Ltd 高能率動画像符号化装置
JP2976716B2 (ja) 1992-08-25 1999-11-10 工業技術院長 メタノール合成用触媒及びその製造方法
JP3163374B2 (ja) 1992-12-11 2001-05-08 経済産業省産業技術総合研究所長 メタノール合成用触媒
JPH08299796A (ja) * 1995-05-11 1996-11-19 Mitsubishi Gas Chem Co Inc メタノール合成触媒の製造法
EP0800062A3 (de) 1996-04-04 1998-04-15 Georg Fischer Rohrleitungssysteme AG Vorrichtung zur Messung der Strömungsgeschwindigkeit eines Fluides
CN101306369B (zh) * 2008-07-11 2010-04-14 西南化工研究设计院 合成甲醇催化剂及其制备方法
CN101322940B (zh) 2008-07-23 2010-06-02 大连瑞克科技有限公司 用于甲醇合成的催化剂及其制备方法
JP5258618B2 (ja) 2009-02-23 2013-08-07 三井化学株式会社 銅系触媒の製造方法
JP2010194420A (ja) 2009-02-23 2010-09-09 Mitsui Chemicals Inc 銅系触媒およびその前処理方法
JP5258617B2 (ja) 2009-02-23 2013-08-07 三井化学株式会社 銅系触媒の製造方法
WO2010095599A1 (ja) 2009-02-23 2010-08-26 三井化学株式会社 銅系触媒の製造方法、銅系触媒およびその前処理方法
WO2011048976A1 (ja) * 2009-10-23 2011-04-28 三菱瓦斯化学株式会社 メタノール合成触媒
CN102302934B (zh) 2011-05-12 2013-01-30 大连理工大学 一种新型助剂改性的二氧化碳催化加氢制甲醇的催化剂及制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6048820A (en) * 1997-03-11 2000-04-11 Agency Of Industrial Of Sciences And Technology Copper-based catalyst and method for production thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI739254B (zh) 2019-12-26 2021-09-11 財團法人工業技術研究院 將碳氧化合物轉化為甲醇的觸媒及製程
US12397285B2 (en) 2019-12-26 2025-08-26 Industrial Technology Research Institute Process for converting carbon oxide into methanol
US12409444B2 (en) 2020-10-02 2025-09-09 Johnson Matthey Public Limited Company Method for making copper-containing catalysts

Also Published As

Publication number Publication date
EP2857095A1 (en) 2015-04-08
JP5863964B2 (ja) 2016-02-17
CA2875353C (en) 2016-11-22
IN2014DN10249A (enExample) 2015-08-07
US9314774B2 (en) 2016-04-19
EP2857095A4 (en) 2016-02-17
EP2857095B1 (en) 2023-11-08
SG11201408066UA (en) 2015-03-30
WO2013183577A1 (ja) 2013-12-12
CA2875353A1 (en) 2013-12-12
JPWO2013183577A1 (ja) 2016-01-28
US20150111975A1 (en) 2015-04-23
CN104379255A (zh) 2015-02-25

Similar Documents

Publication Publication Date Title
CN104379255B (zh) 甲醇制造用催化剂及其制造方法以及甲醇的制造方法
CN1274637C (zh) 稳定氧化锆的制造方法
CN106102905A (zh) 用于高温二氧化碳氢化、用于组合高温二氧化碳氢化和重整和/或用于重整的含钇催化剂，和用于高温二氧化碳氢化，用于组合高温二氧化碳氢化和重整和/或用于重整的方法
CN1200767C (zh) 基于钴的催化剂及其在费－托反应中的应用
CN1791554A (zh) 金属氧化物固溶体及其制备方法和用途
EP2492008A1 (en) Methanol synthesis catalyst
WO2018069759A1 (en) Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution
JP6854477B2 (ja) ペロブスカイト型複合酸化物の製造方法
AU2021243959A1 (en) Heterometallic doped cerium oxide and production method therefor
WO2022186319A1 (ja) 還元剤、ガスの製造方法および変換効率増加方法
FR3022235A1 (fr) Gel haute dispersibilite et son procede de preparation
CN102161492B (zh) 一种拟薄水铝石组合物和由其制备的氧化铝
WO2022065339A1 (ja) 酸素キャリア、酸素キャリアの製造方法およびガスの製造方法
CN103977783B (zh) 一种锆类稀土储氧材料及其制备方法
JP5628016B2 (ja) 銅触媒の製造方法および銅触媒前駆体の熟成方法
JP4061679B2 (ja) ジルコニア微粉末及びその製造方法
JP6004856B2 (ja) メタノール製造用触媒とその製造方法、およびメタノール製造方法
JP6085780B2 (ja) オレフィン製造用触媒の調製方法及びオレフィンの製造方法
TWI523943B (zh) A method for producing abrasive material, abrasive material and grinding method
JP7168751B2 (ja) 還元剤、ガスの製造方法および変換効率増加方法
張涛 Studies on direct synthesis of alcohols from syngas over metal oxides catalysts
WO2023277127A1 (ja) 酸化チタン粒子及びその製造方法
JP2025033504A (ja) 複合酸化物粒子および酸硫化物の粒子の製造方法
JP2011194362A (ja) 一酸化炭素転換用触媒の製造方法
CN102275961B (zh) 一种拟薄水铝石组合物和由其制备的氧化铝

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant