CA2875353C - Catalyst for methanol production, method of producing the same and process of methanol production - Google Patents

Catalyst for methanol production, method of producing the same and process of methanol production Download PDF

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Publication number
CA2875353C
CA2875353C CA2875353A CA2875353A CA2875353C CA 2875353 C CA2875353 C CA 2875353C CA 2875353 A CA2875353 A CA 2875353A CA 2875353 A CA2875353 A CA 2875353A CA 2875353 C CA2875353 C CA 2875353C
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Canada
Prior art keywords
catalyst
copper
zinc
methanol
silicon
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Active
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CA2875353A
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English (en)
French (fr)
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CA2875353A1 (en
Inventor
Yuya Goto
Naoya Takahashi
Masaki Yoshinaga
Masami Murakami
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Mitsui Chemicals Inc
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Mitsui Chemicals Inc
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2875353A 2012-06-04 2013-06-03 Catalyst for methanol production, method of producing the same and process of methanol production Active CA2875353C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012127031 2012-06-04
JP2012-127031 2012-06-04
PCT/JP2013/065325 WO2013183577A1 (ja) 2012-06-04 2013-06-03 メタノール製造用触媒とその製造方法、およびメタノールの製造方法

Publications (2)

Publication Number Publication Date
CA2875353A1 CA2875353A1 (en) 2013-12-12
CA2875353C true CA2875353C (en) 2016-11-22

Family

ID=49711969

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2875353A Active CA2875353C (en) 2012-06-04 2013-06-03 Catalyst for methanol production, method of producing the same and process of methanol production

Country Status (8)

Country Link
US (1) US9314774B2 (enExample)
EP (1) EP2857095B1 (enExample)
JP (1) JP5863964B2 (enExample)
CN (1) CN104379255B (enExample)
CA (1) CA2875353C (enExample)
IN (1) IN2014DN10249A (enExample)
SG (1) SG11201408066UA (enExample)
WO (1) WO2013183577A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201418475D0 (en) * 2014-10-17 2014-12-03 Johnson Matthey Plc Catalyst and process
EP3806991A1 (en) 2018-06-12 2021-04-21 Haldor Topsøe A/S A process for methanol production using a low-iron catalyst
GB201905293D0 (en) * 2019-04-15 2019-05-29 Johnson Matthey Plc Copper-containing catalysts
CN109999817A (zh) * 2019-04-22 2019-07-12 盐城工学院 一种Cu/ZnO-ZrO2固溶体催化剂及其辉光放电等离子体辅助制备方法与应用
CN110694631A (zh) * 2019-10-12 2020-01-17 中国科学院山西煤炭化学研究所 一种合成甲醇的催化剂及其制备方法和应用
TWI739254B (zh) 2019-12-26 2021-09-11 財團法人工業技術研究院 將碳氧化合物轉化為甲醇的觸媒及製程
CN115053021A (zh) * 2020-01-27 2022-09-13 国立研究开发法人理化学研究所 阴极电极、阴极电极与基材的复合体、及阴极电极与基材的复合体的制造方法
CN115943135B (zh) 2020-08-31 2025-02-28 住友化学株式会社 甲醇的制造方法
GB202015634D0 (en) * 2020-10-02 2020-11-18 Johnson Matthey Plc Method for making copper-containing catalysts
GB202015635D0 (en) * 2020-10-02 2020-11-18 Johnson Matthey Plc Method for making copper-containing catalysts
GB202016050D0 (en) * 2020-10-09 2020-11-25 Johnson Matthey Plc Hydrogen process
CN115990472A (zh) * 2021-10-19 2023-04-21 中国石油化工股份有限公司 二氧化碳加氢制甲醇联产二甲醚的催化剂及其制备和应用
US20250041835A1 (en) 2021-11-16 2025-02-06 Basf Se A catalyst for the conversion of co2-rich syngas to methanol and conventional syngas to dimethyl ether
US20250108363A1 (en) * 2021-12-30 2025-04-03 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Plasma-treated catalyst, production method thereof and use of the catalyst
WO2024029584A1 (ja) * 2022-08-04 2024-02-08 三井金属鉱業株式会社 複合酸化物、メタノール製造用触媒及び複合酸化物の製造方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
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JPS5932949A (ja) 1982-08-13 1984-02-22 Mitsubishi Gas Chem Co Inc メタノ−ル合成用触媒
JPS6339287A (ja) 1986-08-04 1988-02-19 Matsushita Electric Ind Co Ltd 高能率動画像符号化装置
JP2976716B2 (ja) 1992-08-25 1999-11-10 工業技術院長 メタノール合成用触媒及びその製造方法
JP3163374B2 (ja) 1992-12-11 2001-05-08 経済産業省産業技術総合研究所長 メタノール合成用触媒
JPH08299796A (ja) * 1995-05-11 1996-11-19 Mitsubishi Gas Chem Co Inc メタノール合成触媒の製造法
EP0800062A3 (de) 1996-04-04 1998-04-15 Georg Fischer Rohrleitungssysteme AG Vorrichtung zur Messung der Strömungsgeschwindigkeit eines Fluides
JP3232326B2 (ja) * 1997-03-11 2001-11-26 経済産業省産業技術総合研究所長 銅系触媒およびその製造法
CN101306369B (zh) * 2008-07-11 2010-04-14 西南化工研究设计院 合成甲醇催化剂及其制备方法
CN101322940B (zh) 2008-07-23 2010-06-02 大连瑞克科技有限公司 用于甲醇合成的催化剂及其制备方法
JP2010194420A (ja) 2009-02-23 2010-09-09 Mitsui Chemicals Inc 銅系触媒およびその前処理方法
JP5258618B2 (ja) 2009-02-23 2013-08-07 三井化学株式会社 銅系触媒の製造方法
JP5258617B2 (ja) 2009-02-23 2013-08-07 三井化学株式会社 銅系触媒の製造方法
US8623782B2 (en) 2009-02-23 2014-01-07 Mitsui Chemicals, Inc. Process for preparing copper-based catalyst, copper-based catalyst, and pretreatment method of the same
EP2492008A4 (en) * 2009-10-23 2017-03-15 Mitsubishi Gas Chemical Company, Inc. Methanol synthesis catalyst
CN102302934B (zh) * 2011-05-12 2013-01-30 大连理工大学 一种新型助剂改性的二氧化碳催化加氢制甲醇的催化剂及制备方法

Also Published As

Publication number Publication date
CA2875353A1 (en) 2013-12-12
JPWO2013183577A1 (ja) 2016-01-28
JP5863964B2 (ja) 2016-02-17
EP2857095A1 (en) 2015-04-08
US9314774B2 (en) 2016-04-19
IN2014DN10249A (enExample) 2015-08-07
SG11201408066UA (en) 2015-03-30
CN104379255B (zh) 2017-05-03
US20150111975A1 (en) 2015-04-23
CN104379255A (zh) 2015-02-25
WO2013183577A1 (ja) 2013-12-12
EP2857095B1 (en) 2023-11-08
EP2857095A4 (en) 2016-02-17

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