CN1042439C - 含有变构淀粉的以聚合物为基料的混合组合物及其产品 - Google Patents
含有变构淀粉的以聚合物为基料的混合组合物及其产品 Download PDFInfo
- Publication number
- CN1042439C CN1042439C CN90103463A CN90103463A CN1042439C CN 1042439 C CN1042439 C CN 1042439C CN 90103463 A CN90103463 A CN 90103463A CN 90103463 A CN90103463 A CN 90103463A CN 1042439 C CN1042439 C CN 1042439C
- Authority
- CN
- China
- Prior art keywords
- starch
- composition
- melt
- components
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 145
- 229920002472 Starch Polymers 0.000 title claims abstract description 143
- 235000019698 starch Nutrition 0.000 title claims abstract description 143
- 239000008107 starch Substances 0.000 title claims abstract description 142
- 229920000642 polymer Polymers 0.000 title claims abstract description 31
- 239000000654 additive Substances 0.000 claims abstract description 14
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- -1 alkylether radicals Chemical class 0.000 claims description 46
- 239000000126 substance Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 40
- 229920001577 copolymer Polymers 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 28
- 229920001169 thermoplastic Polymers 0.000 claims description 22
- 238000001125 extrusion Methods 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- 238000012545 processing Methods 0.000 claims description 15
- 239000004416 thermosoftening plastic Substances 0.000 claims description 15
- 238000001746 injection moulding Methods 0.000 claims description 14
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000006260 foam Substances 0.000 claims description 12
- 239000005977 Ethylene Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 230000003281 allosteric effect Effects 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 8
- 230000007704 transition Effects 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000006467 substitution reaction Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 238000005187 foaming Methods 0.000 claims description 5
- 238000009740 moulding (composite fabrication) Methods 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- 229920006324 polyoxymethylene Polymers 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
- 239000002775 capsule Substances 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 238000003856 thermoforming Methods 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 229920000945 Amylopectin Polymers 0.000 claims description 2
- 229920000856 Amylose Polymers 0.000 claims description 2
- 229920002488 Hemicellulose Polymers 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 claims description 2
- 229920000090 poly(aryl ether) Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 229920006259 thermoplastic polyimide Polymers 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 abstract description 22
- 239000005017 polysaccharide Substances 0.000 abstract description 21
- 125000004185 ester group Chemical group 0.000 abstract description 7
- 229920003176 water-insoluble polymer Polymers 0.000 abstract description 7
- 230000002209 hydrophobic effect Effects 0.000 abstract description 6
- 230000000704 physical effect Effects 0.000 abstract description 6
- 125000005011 alkyl ether group Chemical group 0.000 abstract 1
- 150000004676 glycans Chemical class 0.000 abstract 1
- 150000004804 polysaccharides Chemical class 0.000 description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 18
- 238000002347 injection Methods 0.000 description 17
- 239000007924 injection Substances 0.000 description 17
- 239000002245 particle Substances 0.000 description 14
- 238000009864 tensile test Methods 0.000 description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 235000010980 cellulose Nutrition 0.000 description 5
- 238000007385 chemical modification Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 5
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 5
- 150000002924 oxiranes Chemical class 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- 239000004373 Pullulan Substances 0.000 description 4
- 229920001218 Pullulan Polymers 0.000 description 4
- 240000004584 Tamarindus indica Species 0.000 description 4
- 235000004298 Tamarindus indica Nutrition 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 235000019439 ethyl acetate Nutrition 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 229920001477 hydrophilic polymer Polymers 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 235000019423 pullulan Nutrition 0.000 description 4
- 229920001221 xylan Polymers 0.000 description 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002168 alkylating agent Substances 0.000 description 3
- 229940100198 alkylating agent Drugs 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000012768 molten material Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 229920008262 Thermoplastic starch Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000004628 starch-based polymer Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- YPPQJONJOISODE-UHFFFAOYSA-N 1-ethyl-9h-xanthene Chemical compound O1C2=CC=CC=C2CC2=C1C=CC=C2CC YPPQJONJOISODE-UHFFFAOYSA-N 0.000 description 1
- TURGQPDWYFJEDY-UHFFFAOYSA-N 1-hydroperoxypropane Chemical compound CCCOO TURGQPDWYFJEDY-UHFFFAOYSA-N 0.000 description 1
- WWIKWOJUJQCHIZ-UHFFFAOYSA-N 1-methyl-9h-xanthene Chemical compound O1C2=CC=CC=C2CC2=C1C=CC=C2C WWIKWOJUJQCHIZ-UHFFFAOYSA-N 0.000 description 1
- RPZANUYHRMRTTE-UHFFFAOYSA-N 2,3,4-trimethoxy-6-(methoxymethyl)-5-[3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane;1-[[3,4,5-tris(2-hydroxybutoxy)-6-[4,5,6-tris(2-hydroxybutoxy)-2-(2-hydroxybutoxymethyl)oxan-3-yl]oxyoxan-2-yl]methoxy]butan-2-ol Chemical compound COC1C(OC)C(OC)C(COC)OC1OC1C(OC)C(OC)C(OC)OC1COC.CCC(O)COC1C(OCC(O)CC)C(OCC(O)CC)C(COCC(O)CC)OC1OC1C(OCC(O)CC)C(OCC(O)CC)C(OCC(O)CC)OC1COCC(O)CC RPZANUYHRMRTTE-UHFFFAOYSA-N 0.000 description 1
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- JDFDHBSESGTDAL-UHFFFAOYSA-N 3-methoxypropan-1-ol Chemical compound COCCCO JDFDHBSESGTDAL-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- UXDDRFCJKNROTO-UHFFFAOYSA-N Glycerol 1,2-diacetate Chemical compound CC(=O)OCC(CO)OC(C)=O UXDDRFCJKNROTO-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 229920005176 Hostaform® Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000005264 aryl amine group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000001743 benzylic group Chemical group 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- SYUXAJSOZXEFPP-UHFFFAOYSA-N glutin Natural products COc1c(O)cc2OC(=CC(=O)c2c1O)c3ccccc3OC4OC(CO)C(O)C(O)C4O SYUXAJSOZXEFPP-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002772 monosaccharides Chemical group 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004616 structural foam Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Cosmetics (AREA)
- Confectionery (AREA)
- Polyesters Or Polycarbonates (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40764389A | 1989-07-18 | 1989-07-18 | |
| US407,643 | 1989-07-18 | ||
| US44931389A | 1989-12-08 | 1989-12-08 | |
| US449,313 | 1989-12-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1048860A CN1048860A (zh) | 1991-01-30 |
| CN1042439C true CN1042439C (zh) | 1999-03-10 |
Family
ID=27019951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN90103463A Expired - Lifetime CN1042439C (zh) | 1989-07-18 | 1990-07-11 | 含有变构淀粉的以聚合物为基料的混合组合物及其产品 |
Country Status (20)
| Country | Link |
|---|---|
| EP (1) | EP0409781B1 (enExample) |
| JP (1) | JPH0725941B2 (enExample) |
| KR (1) | KR0178391B1 (enExample) |
| CN (1) | CN1042439C (enExample) |
| AT (1) | ATE106432T1 (enExample) |
| AU (1) | AU631091B2 (enExample) |
| BR (1) | BR9003344A (enExample) |
| CA (1) | CA2020895C (enExample) |
| DE (1) | DE69009327T2 (enExample) |
| DK (1) | DK0409781T3 (enExample) |
| ES (1) | ES2055400T3 (enExample) |
| FI (1) | FI102480B (enExample) |
| HU (1) | HU211427B (enExample) |
| IE (1) | IE64058B1 (enExample) |
| IL (1) | IL95041A (enExample) |
| NO (1) | NO304154B1 (enExample) |
| NZ (1) | NZ234454A (enExample) |
| PL (1) | PL286006A1 (enExample) |
| PT (1) | PT94657B (enExample) |
| YU (1) | YU134490A (enExample) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL93620A0 (en) * | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
| IT1233599B (it) * | 1989-05-30 | 1992-04-06 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
| IT1234783B (it) * | 1989-05-30 | 1992-05-27 | Butterfly Srl | Procedimento per la produzione di composizioni a base di amido destrutturato e composizioni cosi ottenute |
| US5288765A (en) * | 1989-08-03 | 1994-02-22 | Spherilene S.R.L. | Expanded articles of biodegradable plastics materials and a method for their production |
| US5409973A (en) * | 1989-08-07 | 1995-04-25 | Butterfly S.R.L. | Polymer composition including destructured starch and an ethylene copolymer |
| IT1232910B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
| IT1240503B (it) * | 1990-07-25 | 1993-12-17 | Butterfly Srl | Miscela polimerica amidacea particolarmente per la produzione di film e simili e procedimento per la sua produzione. |
| IT1242722B (it) * | 1990-08-09 | 1994-05-17 | Butterfly Srl | Film stratificato a matrice amidacea e di bassa permeabilita' e procedimento per la sua produzione. |
| AU9080791A (en) * | 1990-11-20 | 1992-06-11 | E.I. Du Pont De Nemours And Company | Expandable and expanded (foamed) solid products |
| US5292782A (en) * | 1991-02-20 | 1994-03-08 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
| CA2065966A1 (en) * | 1991-04-23 | 1992-10-24 | Robert J. Petcavich | Disposable recyclable plastic articles and moldable synthetic resin blends for making the same |
| IT1245485B (it) * | 1991-05-03 | 1994-09-20 | Butterfly Srl | Membrane permselettive e loro impiego |
| US5412005A (en) * | 1991-05-03 | 1995-05-02 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
| IT1256693B (it) * | 1992-03-10 | 1995-12-12 | Novamont Spa | Composizione polimerica amidacea filmabile, ed articoli sagomati, particolarmente film e foglie ottenibili da tale composizione, aventi elevato effetto barriera e procedimento relativo. |
| EP0525245A1 (en) * | 1991-08-01 | 1993-02-03 | NOVAMONT S.p.A. | Disposable absorbent articles |
| DE4116404A1 (de) * | 1991-05-18 | 1992-11-19 | Tomka Ivan | Polymermischung fuer die herstellung von folien |
| DE4117628C3 (de) * | 1991-05-29 | 1999-02-11 | Inventa Ag | Verfahren und Vorrichtung zur Herstellung von Stärkeschmelze sowie nach diesem Verfahren erhältliche Produkte |
| DE4119915C2 (de) * | 1991-06-17 | 1994-07-21 | Inventa Ag | Stärke-Polymer-Mischung, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| PL173320B1 (pl) * | 1991-06-26 | 1998-02-27 | Procter & Gamble | Folia ulegajaca rozkładowi biologicznemu i nieprzenikalna dla płynów |
| US5217803A (en) * | 1991-06-26 | 1993-06-08 | Tredegar Industries, Inc. | Disposable absorbent articles with biodegradable backsheets |
| HK1006423A1 (en) * | 1991-06-26 | 1999-02-26 | The Procter & Gamble Company | Disposable absorbent articles with biodegradable backsheets |
| US5254607A (en) * | 1991-06-26 | 1993-10-19 | Tredegar Industries, Inc. | Biodegradable, liquid impervious films |
| DE4133335C2 (de) * | 1991-10-08 | 1995-11-02 | Inventa Ag | Stärkemischung, Verfahren zu ihrer Herstellung sowie Verwendung derselben |
| SG47625A1 (en) † | 1991-11-14 | 1998-04-17 | Bio Tech Biolog Naturverparkun | Biodegradable mould material |
| DE4200485C1 (enExample) * | 1992-01-10 | 1993-07-22 | Buck Werke Gmbh & Co, 7347 Bad Ueberkingen, De | |
| NL9200077A (nl) * | 1992-01-16 | 1993-08-16 | Avebe Coop Verkoop Prod | Werkwijze voor het vervaardigen van gedestructureerd zetmeel. |
| KR100262356B1 (ko) * | 1992-06-26 | 2000-09-01 | 데이비드 엠 모이어 | 생분해성 액체 불투과성 다층 필름 조성물 |
| US5939467A (en) * | 1992-06-26 | 1999-08-17 | The Procter & Gamble Company | Biodegradable polymeric compositions and products thereof |
| DE4237535C2 (de) * | 1992-11-06 | 2000-05-25 | Biotec Biolog Naturverpack | Biologisch abbaubare Polymermischung, ein Verfahren und eine Folie |
| US5844023A (en) | 1992-11-06 | 1998-12-01 | Bio-Tec Biologische Naturverpackungen Gmbh | Biologically degradable polymer mixture |
| US5869647A (en) * | 1993-07-27 | 1999-02-09 | Evercorn, Inc. | Method of preparing biodegradable modified-starch moldable products and films |
| AT399883B (de) * | 1993-07-29 | 1995-08-25 | Markus Dipl Ing Rettenbacher | Formkörper aus bzw. mit einem umweltverträglichen werkstoff, verfahren zu dessen herstellung sowie dessen verwendung |
| DE4404840A1 (de) * | 1994-02-16 | 1995-08-17 | Wolff Walsrode Ag | Thermoplastische biologisch abbaubare Polysaccharidderivate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP0704495A3 (en) * | 1994-09-28 | 1997-01-15 | Japan Maize Prod | Biodegradable compositions |
| IT1272871B (it) * | 1995-01-10 | 1997-07-01 | Novamont Spa | Composizioni termoplastiche compredenti amido ed altre componenti di origine naturale |
| JP3107830B2 (ja) | 1995-04-07 | 2000-11-13 | ビオ−テック ビオロギッシェ ナトゥーアフェアパックンゲン ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト | 生物学的に分解可能なポリマー混合物 |
| DE19624641A1 (de) | 1996-06-20 | 1998-01-08 | Biotec Biolog Naturverpack | Biologisch abbaubarer Werkstoff, bestehend im wesentlichen aus oder auf Basis thermoplastischer Stärke |
| US6210710B1 (en) | 1997-04-28 | 2001-04-03 | Hercules Incorporated | Sustained release polymer blend for pharmaceutical applications |
| EP0955277A1 (en) * | 1998-04-28 | 1999-11-10 | Coöperatieve Verkoop- en Productievereniging van Aardappelmeel en Derivaten 'AVEBE' B.A. | Self-consolidating concrete comprising a polysaccharide additive |
| US6231970B1 (en) * | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
| US7985420B2 (en) | 2000-04-28 | 2011-07-26 | Reckitt Benckiser Inc. | Sustained release of guaifenesin combination drugs |
| US7838032B2 (en) | 2000-04-28 | 2010-11-23 | Reckitt Benckiser Inc. | Sustained release of guaifenesin |
| US8012504B2 (en) | 2000-04-28 | 2011-09-06 | Reckitt Benckiser Inc. | Sustained release of guaifenesin combination drugs |
| US6372252B1 (en) | 2000-04-28 | 2002-04-16 | Adams Laboratories, Inc. | Guaifenesin sustained release formulation and tablets |
| US6955821B2 (en) | 2000-04-28 | 2005-10-18 | Adams Laboratories, Inc. | Sustained release formulations of guaifenesin and additional drug ingredients |
| US6375981B1 (en) | 2000-06-01 | 2002-04-23 | A. E. Staley Manufacturing Co. | Modified starch as a replacement for gelatin in soft gel films and capsules |
| US7887838B2 (en) | 2002-01-18 | 2011-02-15 | Banner Pharmacaps, Inc. | Non-gelatin film and method and apparatus for producing same |
| US6949256B2 (en) | 2002-01-18 | 2005-09-27 | Banner Pharmacaps, Inc. | Non-gelatin capsule shell formulation |
| EP1400533A1 (en) * | 2002-09-11 | 2004-03-24 | Fresenius Kabi Deutschland GmbH | HASylated polypeptides, especially HASylated erythropoietin |
| JP2007528357A (ja) | 2003-04-14 | 2007-10-11 | エフ エム シー コーポレーション | ゲルフィルムを製造するための方法 |
| US7816341B2 (en) | 2003-04-14 | 2010-10-19 | Fmc Corporation | Homogeneous, thermoreversible gel containing reduced viscosity carrageenan and products made therefrom |
| US9840066B2 (en) | 2005-06-09 | 2017-12-12 | United States Gypsum Company | Light weight gypsum board |
| US9802866B2 (en) | 2005-06-09 | 2017-10-31 | United States Gypsum Company | Light weight gypsum board |
| US7731794B2 (en) | 2005-06-09 | 2010-06-08 | United States Gypsum Company | High starch light weight gypsum wallboard |
| USRE44070E1 (en) | 2005-06-09 | 2013-03-12 | United States Gypsum Company | Composite light weight gypsum wallboard |
| US11338548B2 (en) | 2005-06-09 | 2022-05-24 | United States Gypsum Company | Light weight gypsum board |
| US11306028B2 (en) | 2005-06-09 | 2022-04-19 | United States Gypsum Company | Light weight gypsum board |
| FR2937039B1 (fr) * | 2008-10-13 | 2011-11-18 | Roquette Freres | Compositions elastomeriques a base d'esters d'une matiere amylacee et procede de preparation de telles compositions |
| WO2013073402A1 (ja) | 2011-11-15 | 2013-05-23 | 昭和電工株式会社 | 生分解性樹脂組成物及び生分解性フィルム |
| CN103906809B (zh) | 2011-11-15 | 2016-06-29 | 昭和电工株式会社 | 生物降解性树脂组合物和生物降解性膜 |
| GB201506755D0 (en) | 2015-04-21 | 2015-06-03 | Reckitt Benckiser Llc | Novel pharmaceutical formulation |
| JP2016196536A (ja) | 2015-04-02 | 2016-11-24 | 昭和電工株式会社 | 樹脂組成物及びそのフィルム |
| US11278506B2 (en) | 2015-10-09 | 2022-03-22 | Rb Health (Us) Llc | Pharmaceutical formulation |
| CN105440631A (zh) * | 2015-12-22 | 2016-03-30 | 芜湖恒坤汽车部件有限公司 | 离合器油壶材料及其制备方法 |
| CN105504744A (zh) * | 2015-12-22 | 2016-04-20 | 芜湖恒坤汽车部件有限公司 | 离合器塑料齿轮及其制备方法 |
| CN105482422A (zh) * | 2015-12-22 | 2016-04-13 | 芜湖恒坤汽车部件有限公司 | 离合器泵活塞材料及其制备方法 |
| CN105419287A (zh) * | 2015-12-22 | 2016-03-23 | 芜湖恒坤汽车部件有限公司 | 离合器塑料齿轮材料及其制备方法 |
| CN105482418A (zh) * | 2015-12-22 | 2016-04-13 | 芜湖恒坤汽车部件有限公司 | 离合器泵活塞及其制备方法 |
| AU2018250333A1 (en) * | 2017-04-07 | 2019-10-17 | Kwik Lok Corporation | Biodegradable polystyrene composites and use thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE739630C (de) * | 1937-07-07 | 1943-09-30 | Ferdinand Sichel A G | Verfahren zur Herstellung wasserloeslicher Celluloseaether in Pulverform |
| NL276258A (enExample) * | 1961-03-23 | |||
| JPS5644902A (en) * | 1979-09-20 | 1981-04-24 | Mitsubishi Heavy Ind Ltd | Triple signal selecting circuit |
| IN160476B (enExample) * | 1983-02-18 | 1987-07-11 | Warner Lambert Co | |
| GB2205323B (en) * | 1987-03-09 | 1991-01-30 | Warner Lambert Co | Destructurized starch and process for making same |
| GB2208651B (en) * | 1987-08-18 | 1991-05-08 | Warner Lambert Co | Shaped articles made from pre-processed starch |
| KR910002990A (ko) * | 1989-07-18 | 1991-02-26 | 토마스 디. 몰리터노 | 분해된 전분을 함유하는 중합체 기초 혼합 조성물 |
-
1990
- 1990-07-11 IL IL9504190A patent/IL95041A/en not_active IP Right Cessation
- 1990-07-11 JP JP2181675A patent/JPH0725941B2/ja not_active Expired - Fee Related
- 1990-07-11 NO NO903087A patent/NO304154B1/no not_active IP Right Cessation
- 1990-07-11 PL PL28600690A patent/PL286006A1/xx unknown
- 1990-07-11 CN CN90103463A patent/CN1042439C/zh not_active Expired - Lifetime
- 1990-07-11 NZ NZ234454A patent/NZ234454A/xx unknown
- 1990-07-11 HU HU904168A patent/HU211427B/hu not_active IP Right Cessation
- 1990-07-11 YU YU134490A patent/YU134490A/sh unknown
- 1990-07-11 FI FI903499A patent/FI102480B/fi active IP Right Grant
- 1990-07-11 CA CA002020895A patent/CA2020895C/en not_active Expired - Lifetime
- 1990-07-11 KR KR1019900010480A patent/KR0178391B1/ko not_active Expired - Fee Related
- 1990-07-11 PT PT94657A patent/PT94657B/pt not_active IP Right Cessation
- 1990-07-11 IE IE253090A patent/IE64058B1/en not_active IP Right Cessation
- 1990-07-12 BR BR909003344A patent/BR9003344A/pt not_active IP Right Cessation
- 1990-07-12 DE DE69009327T patent/DE69009327T2/de not_active Expired - Fee Related
- 1990-07-12 DK DK90810533.1T patent/DK0409781T3/da active
- 1990-07-12 EP EP90810533A patent/EP0409781B1/en not_active Expired - Lifetime
- 1990-07-12 AT AT90810533T patent/ATE106432T1/de not_active IP Right Cessation
- 1990-07-12 ES ES90810533T patent/ES2055400T3/es not_active Expired - Lifetime
- 1990-07-16 AU AU59064/90A patent/AU631091B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| KR910002991A (ko) | 1991-02-26 |
| PT94657A (pt) | 1991-03-20 |
| KR0178391B1 (ko) | 1999-05-15 |
| AU5906490A (en) | 1991-01-24 |
| EP0409781A2 (en) | 1991-01-23 |
| DK0409781T3 (da) | 1994-09-19 |
| FI903499A0 (fi) | 1990-07-11 |
| NZ234454A (en) | 1991-08-27 |
| PL286006A1 (enExample) | 1991-03-11 |
| IL95041A (en) | 1994-11-28 |
| EP0409781B1 (en) | 1994-06-01 |
| ATE106432T1 (de) | 1994-06-15 |
| IE64058B1 (en) | 1995-07-12 |
| DE69009327D1 (de) | 1994-07-07 |
| NO304154B1 (no) | 1998-11-02 |
| AU631091B2 (en) | 1992-11-12 |
| HU211427B (en) | 1995-11-28 |
| EP0409781A3 (en) | 1991-07-31 |
| HU904168D0 (en) | 1990-12-28 |
| IE902530A1 (en) | 1991-02-13 |
| CA2020895A1 (en) | 1991-01-19 |
| BR9003344A (pt) | 1991-08-27 |
| CN1048860A (zh) | 1991-01-30 |
| CA2020895C (en) | 2004-02-17 |
| DE69009327T2 (de) | 1994-10-13 |
| YU134490A (sh) | 1992-09-07 |
| JPH0374446A (ja) | 1991-03-29 |
| FI102480B1 (fi) | 1998-12-15 |
| ES2055400T3 (es) | 1994-08-16 |
| FI102480B (fi) | 1998-12-15 |
| NO903087L (no) | 1991-01-21 |
| PT94657B (pt) | 1997-02-28 |
| JPH0725941B2 (ja) | 1995-03-22 |
| NO903087D0 (no) | 1990-07-11 |
| IL95041A0 (en) | 1991-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1042439C (zh) | 含有变构淀粉的以聚合物为基料的混合组合物及其产品 | |
| CN1048861A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1048864A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1048552A (zh) | 含有变性淀粉的聚合物基掺合组合物 | |
| CN1063698A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1104467C (zh) | 生物可降解的包含淀粉和热塑性聚合物的聚合组合物 | |
| CN1048712A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1049020A (zh) | 含有破坏淀粉的聚合物基共混组合物 | |
| CN1048863A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1176956C (zh) | 包含乙烯酯和聚醚的聚合物的硬胶囊、其用途和生产方法 | |
| CN1048549A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1129638C (zh) | 降解树脂组合物及其制造方法和应用 | |
| CN1048862A (zh) | 含有无序结构淀粉的以聚合物为基料的混合组合物 | |
| CN1072245C (zh) | 纤维素酯和脂族－芳族共聚多酯的共混料 | |
| CN1048550A (zh) | 含有破坏淀粉的聚合物基共混组合物 | |
| CN1098881C (zh) | 热塑性复合料 | |
| CN1175805C (zh) | 乳化体系和乳剂 | |
| CN1267487C (zh) | 生物降解淀粉树脂母料 | |
| CN1202165C (zh) | 包含淀粉组合物的纤维或长丝及其制备方法 | |
| CN1934191A (zh) | 热塑性树脂组合物以及使用该组合物的成型品 | |
| CN1298801C (zh) | 基于豆类淀粉的水性粘合剂组合物 | |
| CN1788021A (zh) | 豆类淀粉阳离子化的方法、由此获得的阳离子淀粉及其应用 | |
| CN1025203C (zh) | 乙烯-乙烯醇共聚物基的掺混组合物 | |
| CN1100088C (zh) | 可生物降解的淀粉树脂组合物，制备该组合物的方法及设备 | |
| CN1043513A (zh) | 提高了性能的聚合物共混物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters |