CN103958144B - 用于清洗成形加工机的热塑性树脂组合物 - Google Patents

用于清洗成形加工机的热塑性树脂组合物 Download PDF

Info

Publication number
CN103958144B
CN103958144B CN201380004140.XA CN201380004140A CN103958144B CN 103958144 B CN103958144 B CN 103958144B CN 201380004140 A CN201380004140 A CN 201380004140A CN 103958144 B CN103958144 B CN 103958144B
Authority
CN
China
Prior art keywords
composition
thermoplastic resin
resin
cleaning
forming maker
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380004140.XA
Other languages
English (en)
Other versions
CN103958144A (zh
Inventor
胁田直树
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis Co ltd
Original Assignee
DAICEL HIGH POLYMER Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAICEL HIGH POLYMER Inc filed Critical DAICEL HIGH POLYMER Inc
Publication of CN103958144A publication Critical patent/CN103958144A/zh
Application granted granted Critical
Publication of CN103958144B publication Critical patent/CN103958144B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/70—Maintenance
    • B29C33/72—Cleaning
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/362—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

本发明提供一种清洗挤出机、注塑成形设备等热塑性树脂成形加工设备的内部时，其清洗性和作业性良好的用于清洗成形加工机的热塑性树脂组合物。所述用于清洗成形加工机的热塑性树脂组合物含有：(A)烯烃类树脂、(B)与(A)成分烯烃类树脂没有相容性的热塑性树脂、(C)用于使(A)烯烃类树脂和(B)成分热塑性树脂相容化的热塑性树脂、(D)脂肪酸的碱金属盐、(E)非离子性表面活性剂及(F)酸性磷酸酯的金属盐。

Description

用于清洗成形加工机的热塑性树脂组合物
技术领域
本发明涉及一种用于清洗挤出机、注塑成形机等成形加工机的、用于清洗成形加工机的热塑性树脂组合物。
背景技术
作为用于热塑性树脂的成形加工机的清洗剂，已知有组合基体树脂和其它的成分而得到的清洗剂。
在日本特开2010-95624号公报、日本特开2010-95625号公报、日本特开2011-46808号公报、日本特开平10-279816号公报及日本特开2007-21765号公报中，公开有一种组合基体树脂和阴离子表面活性剂而得到的清洗剂组合物。
发明内容
本发明的课题在于，通过组合基体树脂和表面活性剂来提供一种清洗性能进一步提高的用于清洗成形加工机的热塑性树脂组合物。
本发明发现：将基体树脂成分和表面活性剂组合在一起时，通过组合非离子表面活性剂，进而组合酸性磷酸酯的金属盐，可进一步提高清洗性能，作业性也得以改善，从而完成了本发明。
本发明提供一种用于清洗成形加工机的热塑性树脂组合物，其含有：
(A)烯烃类树脂；
(B)与(A)成分烯烃类树脂没有相容性的热塑性树脂；
(C)用于使(A)烯烃类树脂和(B)成分热塑性树脂相容化的热塑性树脂；
(D)脂肪酸的碱金属盐；
(E)非离子性表面活性剂；及
(F)酸性磷酸酯的金属盐。
本发明提供一种将上述热塑性树脂组合物用于清洗成形加工机的用途。
具体实施方式
根据本发明的清洗用热塑性树脂组合物，清洗挤出机、注塑成形设备等热塑性树脂成形加工设备的内部时，其清洗性和作业性良好。
<(A)成分>
(A)成分为烯烃类树脂。
(A)成分烯烃类树脂优选选自HDPE、LDPE、LLDPE及聚丙烯均聚物、乙烯和丙烯的共聚物、乙烯和/或丙烯和可与它们共聚的单体的共聚物等中的1种以上。
<(B)成分>
(B)成分为与(A)成分烯烃类树脂没有相容性的热塑性树脂。
(B)成分热塑性树脂优选选自AS树脂、MS树脂、甲基丙烯酸甲酯-马来酸酐-苯乙烯共聚物及PMMA树脂中的1种以上。
<(C)成分>
(C)成分为用于使(A)烯烃类树脂和(B)成分热塑性树脂相容化的热塑性树脂。
(C)成分热塑性树脂优选选自EEA、EMA、EMMA、EBA中的1种以上。
对组合物中的(A)～(C)成分的比例而言，
(A)成分优选30～90质量％，更优选40～80质量％，
(B)成分优选8～60质量％，更优选15～50质量％，
(C)成分优选2～20质量％，更优选5～15质量％。
<(D)成分>
(D)脂肪酸的碱金属盐优选碳原子数为10～22的饱和或不饱和脂肪酸的Na、K、Li、Cs盐。脂肪酸可以为直链，也可以为支链。
其中，更优选碳原子数为12～18的脂肪酸(月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、油酸)的Na盐。
相对于(A)～(C)成分的合计100质量份，组合物中的(D)成分脂肪酸的碱金属盐的含有比例为0.5～10质量份，优选为1～10质量份，更优选为1～6质量份。
<(E)成分>
(E)成分非离子性表面活性剂，可以举出选自氧乙烯链型表面活性剂、山梨糖醇酐酯型表面活性剂、甘油酯类(甘油(单、二)脂肪酸酯类)表面活性剂、12-羟基硬脂酸酯、丙二醇脂肪酸酯、蔗糖脂肪酸酯、烷基甘油基醚、烷基糖苷等的物质。
其中，优选选自山梨糖醇酐脂肪酸酯、甘油脂肪酸酯、12-羟基硬脂酸酯中的1种以上。
相对于(A)～(C)成分的合计100质量份，组合物中的(E)成分非离子性表面活性剂的含有比例为0.5～10质量份，优选为1～10质量份，更优选为1～6质量份。
(D)成分和(E)成分的总量中的(D)成分的含有比例优选30～70质量％，更优选40～60质量％，(E)成分的含有比例为剩余比例。
<(F)成分>
(F)成分为酸性磷酸酯的金属盐。(F)成分为下述成分：在并用(D)成分和(E)成分时，为了防止(E)成分由于(D)成分所含的碱金属的作用被分解产生气体(含有脂肪酸等的气体)而发挥作用的成分。
(F)成分可以使用例如日本特开2010-189515号公报的段落编号0021～段落编号0032中所记载的通式(I)或(II)所示的酸性磷酸酯的盐。
作为(F)成分，优选酸式磷酸硬脂基酯镁盐、酸式磷酸硬脂基酯钙盐、酸式磷酸硬脂基酯锌盐、酸式磷酸硬脂基酯铝盐等。
作为(F)成分，可以使用市售品，例如可以使用：酸式磷酸硬脂基酯锌盐(堺化学工业(株)制LBT1830)、酸式磷酸硬脂基酯铝盐(堺化学工业(株)制LBT1813)、酸式磷酸硬脂基酯钙盐(堺化学工业(株)制LBT1820)、酸式磷酸硬脂基酯镁盐(LBT-1812)等。
相对于(D)成分和(E)成分的总量100质量份，组合物中的(F)成分的含有比例优选10～100质量份，更优选10～80质量份。
<其它成分>
本发明的组合物还可以含有无机填料。作为无机填料，除公知的玻璃纤维、金属纤维以外，还可以举出选自日本特开2006-257297号公报中记载的熔渣、钢铁矿渣或它们的破碎物、人造矿物纤维中的填料，可以使用纤维状的填料、非纤维状的填料(粉末状、粒状、破碎物等)。
本发明的组合物还可以含有日本特开2006-257297号公报中记载的亚烷基二醇脂肪酸酯、有机磷化合物、多元醇、金属皂。
本发明的组合物通过亨舍尔混合机、转鼓式混合机、捏合机等混合机将上述各成分预混合后，通过挤出机混炼，或通过加热辊、班伯里密炼机熔融混炼来进行制造。
实施例
实施例及比较例
用转鼓式混合机将表1所示组成的各成分混合后，通过挤出机熔融混炼，得到颗粒状的树脂组合物。使用这些组合物，通过下述的方法进行清洗试验。将结果示于表1。
在注塑成形机(住友重机械工业公司制“SH100”；料筒温度230℃)中，将作为现有使用树脂HDPE的着红色品(红色色素浓度0.5％)1kg注塑成形。
然后，使用表1的各组合物，重复进行测量和注塑的操作，将红色消失的时刻设为清洗结束，根据直至清洗结束时的组合物的用量(kg)评价清洗性。
另外，在清洗结束后，通过流过AS树脂(DAICEL POLYMER株式会社制的CEVIAN N050SF)时是否出现之前使用的树脂(前面的材料即HDPE)的红色来评价清洗性(前面的材料有无残留)。
[表1]
(A)成分
LLDPE：东曹株式会社Nipolon-L T240F
HDPE：东曹株式会社Nipolon Hard6000
(B)成分
PMMA：三菱丽阳株式会社Acrypet MF
MS：DAICEL POLYMER株式会社CEVIAN MAS30
(C)成分
EMA：三井-杜邦聚化学株式会社Elvaloy AC1820
EBA：Arkema株式会社LOTRYL30BA02
(D)成分
硬脂酸Na
(E)成分
非离子表面活性剂1：硬脂酸二甘油酯
非离子表面活性剂2：山梨糖醇酐硬脂酸酯
(F)成分
酸性磷酸酯盐：酸式磷酸硬脂基酯锌盐(堺化学工业(株)制LBT-1830)

Claims (18)

1.一种用于清洗成形加工机的热塑性树脂组合物，其含有：
(A)烯烃类树脂；
(B)与(A)成分烯烃类树脂没有相容性的热塑性树脂；
(C)用于使(A)烯烃类树脂和(B)成分热塑性树脂相容化的热塑性树脂；
(D)脂肪酸的碱金属盐；
(E)非离子性表面活性剂；及
(F)酸性磷酸酯的金属盐。
2.根据权利要求1所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(D)成分和(E)成分的总量中的(D)成分的含有比例为30～70质量％，(E)成分的含有比例为70～30质量％，
相对于(D)成分和(E)成分的总量100质量份，(F)成分的含有比例为10～100质量份。
3.根据权利要求1所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(F)成分酸性磷酸酯盐选自酸式磷酸硬脂基酯镁盐、酸式磷酸硬脂基酯钙盐、酸式磷酸硬脂基酯锌盐、酸式磷酸硬脂基酯铝盐。
4.根据权利要求2所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(F)成分酸性磷酸酯盐选自酸式磷酸硬脂基酯镁盐、酸式磷酸硬脂基酯钙盐、酸式磷酸硬脂基酯锌盐、酸式磷酸硬脂基酯铝盐。
5.根据权利要求1所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(E)成分非离子性表面活性剂选自山梨糖醇酐脂肪酸酯、甘油脂肪酸酯中的1种以上。
6.根据权利要求2所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(E)成分非离子性表面活性剂选自山梨糖醇酐脂肪酸酯、甘油脂肪酸酯中的1种以上。
7.根据权利要求3所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(E)成分非离子性表面活性剂选自山梨糖醇酐脂肪酸酯、甘油脂肪酸酯中的1种以上。
8.根据权利要求1所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(B)成分热塑性树脂选自AS树脂、MS树脂、甲基丙烯酸甲酯-马来酸酐-苯乙烯共聚物及PMMA树脂中的1种以上。
9.根据权利要求2所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(B)成分热塑性树脂选自AS树脂、MS树脂、甲基丙烯酸甲酯-马来酸酐-苯乙烯共聚物及PMMA树脂中的1种以上。
10.根据权利要求3所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(B)成分热塑性树脂选自AS树脂、MS树脂、甲基丙烯酸甲酯-马来酸酐-苯乙烯共聚物及PMMA树脂中的1种以上。
11.根据权利要求5所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(B)成分热塑性树脂选自AS树脂、MS树脂、甲基丙烯酸甲酯-马来酸酐-苯乙烯共聚物及PMMA树脂中的1种以上。
12.根据权利要求1所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(C)成分热塑性树脂选自EEA、EMA、EMMA、EBA中的1种以上。
13.根据权利要求2所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(C)成分热塑性树脂选自EEA、EMA、EMMA、EBA中的1种以上。
14.根据权利要求3所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(C)成分热塑性树脂选自EEA、EMA、EMMA、EBA中的1种以上。
15.根据权利要求5所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(C)成分热塑性树脂选自EEA、EMA、EMMA、EBA中的1种以上。
16.根据权利要求8所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(C)成分热塑性树脂选自EEA、EMA、EMMA、EBA中的1种以上。
17.根据权利要求1～16中任一项所述的用于清洗成形加工机的热塑性树脂组合物，其中，
(A)成分烯烃类树脂选自HDPE、LDPE、LLDPE及聚丙烯均聚物中的1种以上。
18.一种将权利要求1～16中任一项所述的热塑性树脂组合物用于清洗成形加工机的用途。
CN201380004140.XA 2012-01-27 2013-01-15 用于清洗成形加工机的热塑性树脂组合物 Active CN103958144B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012-014737 2012-01-27
JP2012014737A JP5792647B2 (ja) 2012-01-27 2012-01-27 成形加工機洗浄用の熱可塑性樹脂組成物
PCT/JP2013/050510 WO2013111632A1 (ja) 2012-01-27 2013-01-15 成形加工機洗浄用の熱可塑性樹脂組成物

Publications (2)

Publication Number Publication Date
CN103958144A CN103958144A (zh) 2014-07-30
CN103958144B true CN103958144B (zh) 2016-09-07

Family

ID=48873353

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380004140.XA Active CN103958144B (zh) 2012-01-27 2013-01-15 用于清洗成形加工机的热塑性树脂组合物

Country Status (8)

Country Link
US (1) US9920285B2 (zh)
EP (1) EP2808148B1 (zh)
JP (1) JP5792647B2 (zh)
KR (1) KR101940114B1 (zh)
CN (1) CN103958144B (zh)
IN (1) IN2014DN05966A (zh)
TW (1) TWI582228B (zh)
WO (1) WO2013111632A1 (zh)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5839564B2 (ja) * 2012-01-27 2016-01-06 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
EP4129062A1 (en) 2015-09-16 2023-02-08 Apeel Technology, Inc. Method for forming a protective coating by applying fatty acid glyceride compounds to a surface
EP3407713A1 (en) 2016-01-26 2018-12-05 Apeel Technology, Inc. Method for preparing and preserving sanitized products
CN106117768A (zh) * 2016-07-01 2016-11-16 湖北洋田塑料制品有限公司 一种注塑机用清洗材料及其制备方法
JP6780189B2 (ja) * 2017-01-17 2020-11-04 ダイセルミライズ株式会社 押出機の洗浄および清掃方法
KR102472098B1 (ko) * 2017-03-03 2022-12-01 다이셀폴리머 주식회사 성형 가공기 세정용의 열가소성 수지 조성물
JP6957244B2 (ja) * 2017-07-06 2021-11-02 世紀株式会社 洗浄剤組成物、及び成形原料
JP6957243B2 (ja) * 2017-07-06 2021-11-02 世紀株式会社 洗浄剤組成物、及び成形原料
WO2019069798A1 (ja) * 2017-10-02 2019-04-11 旭化成株式会社 射出成形機及び金型用洗浄剤樹脂組成物
EP4114181A1 (en) 2020-03-04 2023-01-11 Apeel Technology, Inc. Coated agricultural products and corresponding methods
IL302360B1 (en) 2020-10-30 2024-09-01 Apeel Tech Inc Preparations and methods of their preparation
EP4408920A2 (en) * 2021-09-30 2024-08-07 ExxonMobil Chemical Patents Inc. Fluorine-free polymer processing aid blends

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0827335A (ja) * 1994-07-15 1996-01-30 Idemitsu Petrochem Co Ltd 成形機用樹脂洗浄剤
CN1166523A (zh) * 1996-04-26 1997-12-03 巴斯福公司 用作塑料加工设备清洗物的取代吡咯烷酮增塑的热塑树酯
JP2002001734A (ja) * 2000-06-23 2002-01-08 Daicel Chem Ind Ltd 洗浄用樹脂組成物
DE10334293A1 (de) * 2003-07-25 2005-03-03 Lieberum, Evelyne Reinigungszusammensetzung für kunstoffverarbeitende Maschinen, Verfahren und Anwendung
CN1754953A (zh) * 2004-10-01 2006-04-05 花王株式会社 洗涤剂组合物

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04239099A (ja) * 1991-01-09 1992-08-26 Chisso Corp 洗浄用組成物および洗浄方法
JPH04246443A (ja) 1991-01-31 1992-09-02 Chisso Corp 洗浄用組成物
JP3874487B2 (ja) 1997-04-02 2007-01-31 チッソ株式会社 熱可塑性樹脂用成形機内の洗浄に使用する洗浄用熱可塑性樹脂組成物
JP4619840B2 (ja) 2005-03-17 2011-01-26 ダイセルポリマー株式会社 洗浄用樹脂組成物
JP2007021765A (ja) 2005-07-12 2007-02-01 Nippon A & L Kk 成形機洗浄用樹脂組成物および洗浄方法
JP4917566B2 (ja) * 2008-04-09 2012-04-18 株式会社テクノプラス プラスチック成形機洗浄用樹脂組成物
JP5550226B2 (ja) 2008-10-16 2014-07-16 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
JP5329907B2 (ja) 2008-10-16 2013-10-30 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
JP5343607B2 (ja) 2009-02-17 2013-11-13 堺化学工業株式会社 高級脂肪酸金属塩ブロック
JP2010208131A (ja) * 2009-03-10 2010-09-24 Daicel Polymer Ltd 樹脂成形加工機用の洗浄用樹脂組成物
JP5667754B2 (ja) 2009-08-26 2015-02-12 ダイセルポリマー株式会社 洗浄用の熱可塑性樹脂組成物
JP5755444B2 (ja) * 2010-12-28 2015-07-29 ダイセルポリマー株式会社 洗浄用の熱可塑性樹脂組成物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0827335A (ja) * 1994-07-15 1996-01-30 Idemitsu Petrochem Co Ltd 成形機用樹脂洗浄剤
CN1166523A (zh) * 1996-04-26 1997-12-03 巴斯福公司 用作塑料加工设备清洗物的取代吡咯烷酮增塑的热塑树酯
JP2002001734A (ja) * 2000-06-23 2002-01-08 Daicel Chem Ind Ltd 洗浄用樹脂組成物
DE10334293A1 (de) * 2003-07-25 2005-03-03 Lieberum, Evelyne Reinigungszusammensetzung für kunstoffverarbeitende Maschinen, Verfahren und Anwendung
CN1754953A (zh) * 2004-10-01 2006-04-05 花王株式会社 洗涤剂组合物

Also Published As

Publication number Publication date
KR101940114B1 (ko) 2019-01-18
EP2808148B1 (en) 2016-10-05
IN2014DN05966A (zh) 2015-06-26
KR20140117358A (ko) 2014-10-07
WO2013111632A1 (ja) 2013-08-01
JP2013154484A (ja) 2013-08-15
EP2808148A4 (en) 2015-09-23
CN103958144A (zh) 2014-07-30
JP5792647B2 (ja) 2015-10-14
EP2808148A1 (en) 2014-12-03
TWI582228B (zh) 2017-05-11
US9920285B2 (en) 2018-03-20
US20150021802A1 (en) 2015-01-22
TW201335360A (zh) 2013-09-01

Similar Documents

Publication Publication Date Title
CN103958144B (zh) 用于清洗成形加工机的热塑性树脂组合物
CN103237641B (zh) 清洗用热塑性树脂组合物
CN102070843A (zh) 一种高抗冲、低浮纤长玻纤增强聚丙烯材料
CN101817978A (zh) 一种高温尼龙ppa增强材料及其制备方法
CN104479353B (zh) 一种新型无卤阻燃组合物、无卤阻燃pbt工程塑料复合材料及其制备方法
CN102482621A (zh) 清洗用热塑性树脂组合物
JP5329907B2 (ja) 成形加工機洗浄用の熱可塑性樹脂組成物
CN101622308A (zh) 清洗用树脂组合物
CN103958145B (zh) 用于清洗成形加工机的热塑性树脂组合物
CN102731835A (zh) 一种阻燃剂
CN102171286A (zh) 用于清洗成型加工机的热塑性树脂组合物
TW201420749A (zh) 成形加工機洗淨用之熱塑性樹脂組成物
CN107987273A (zh) 一种聚酰胺及其制备方法和应用
CN106317827A (zh) 一种pc合金材料及其制备方法和应用
CN108047572A (zh) 一种功能型滑石粉母粒
CN101759916A (zh) 一种云母填充改性聚丙烯组合物及其制备方法
JP6084803B2 (ja) 成形加工機洗浄用の熱可塑性樹脂組成物
JP5067293B2 (ja) ポリオレフィン樹脂組成物
JP2013028730A (ja) ポリフェニレンエーテル系樹脂組成物および成形体
JP2000159928A (ja) 洗浄用熱可塑性樹脂組成物
CN104845204A (zh) 高性能环保阻燃聚对苯二甲酸丙二醇酯

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CP03 Change of name, title or address

Address after: Tokyo, Japan

Patentee after: Dairyu Meihua Co.,Ltd.

Country or region after: Japan

Address before: Tokyo, Japan

Patentee before: DAICEL FINECHEM Ltd.

Country or region before: Japan

CP03 Change of name, title or address
TR01 Transfer of patent right

Effective date of registration: 20240925

Address after: Tokyo, Japan

Patentee after: DAICEL FINECHEM Ltd.

Country or region after: Japan

Address before: Tokyo, Japan

Patentee before: DAICEL POLYMER LTD.

Country or region before: Japan

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20241008

Address after: Tokyo, Japan

Patentee after: Novartis Co.,Ltd.

Country or region after: Japan

Address before: Tokyo, Japan

Patentee before: Dairyu Meihua Co.,Ltd.

Country or region before: Japan