CN103889569B - 用于选择性催化还原氮的氧化物的催化剂组合物及方法 - Google Patents

用于选择性催化还原氮的氧化物的催化剂组合物及方法 Download PDF

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Publication number
CN103889569B
CN103889569B CN201280052240.5A CN201280052240A CN103889569B CN 103889569 B CN103889569 B CN 103889569B CN 201280052240 A CN201280052240 A CN 201280052240A CN 103889569 B CN103889569 B CN 103889569B
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zeolite
acidic
catalyst
zeolites
component
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Chinese (zh)
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CN103889569A (zh
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A.Y.斯塔克希夫
M.格里尔
A.库斯托夫
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On Shares LP
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Haldor Topsoe AS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CN201280052240.5A 2011-10-24 2012-05-02 用于选择性催化还原氮的氧化物的催化剂组合物及方法 Active CN103889569B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/EP2011/005344 WO2013060341A1 (en) 2011-10-24 2011-10-24 Catalyst composition for use in selective catalytic reduction of nitrogen oxides
EPPCT/EP2011/005344 2011-10-24
PCT/EP2012/058003 WO2013060487A1 (en) 2011-10-24 2012-05-02 Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides

Publications (2)

Publication Number Publication Date
CN103889569A CN103889569A (zh) 2014-06-25
CN103889569B true CN103889569B (zh) 2017-02-15

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JP (1) JP6112734B2 (enExample)
KR (1) KR101789114B1 (enExample)
CN (1) CN103889569B (enExample)
AU (1) AU2012327482A1 (enExample)
BR (1) BR112014008669B1 (enExample)
CA (1) CA2853154C (enExample)
CL (1) CL2014000993A1 (enExample)
IN (1) IN2014CN02950A (enExample)
MX (1) MX2014004494A (enExample)
RU (1) RU2608616C2 (enExample)
WO (2) WO2013060341A1 (enExample)

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CN104014324B (zh) * 2014-05-14 2016-08-17 华东理工大学 氧化铈基负载型烟气脱硝催化剂及其制备方法
CN105435789A (zh) * 2014-09-09 2016-03-30 中国石油化工股份有限公司 一种Cu基甲醇合成催化剂大比表面载体的制备方法
CN104525216B (zh) * 2014-12-11 2017-01-04 清华大学 用于宽温度窗口高硫条件下的脱硝催化剂及其制备方法
CN104437540A (zh) * 2014-12-31 2015-03-25 安徽省元琛环保科技有限公司 一种抗磷低温scr脱硝催化剂及其制备方法
WO2017034920A1 (en) * 2015-08-21 2017-03-02 Basf Corporation Exhaust gas treatment catalysts
JP6755306B2 (ja) * 2015-09-29 2020-09-16 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ すす触媒とｓｃｒ触媒を有する触媒フィルタ
CN108348871B (zh) 2015-10-30 2021-11-05 蓝移材料有限公司 高度支化的非交联气凝胶、其制备方法及用途
CN108699277B (zh) 2016-06-08 2022-12-02 蓝移材料有限公司 具有改善的机械性能和热性能的聚合物气凝胶
EP3281698A1 (de) 2016-08-11 2018-02-14 Umicore AG & Co. KG Scr-aktives material
EP3496854A1 (de) 2016-08-11 2019-06-19 Umicore AG & Co. KG Scr-aktives material mit erhöhter thermischer stabilität
TW201838708A (zh) * 2017-03-02 2018-11-01 丹麥商托普索公司 用於移除來自工廠的廢氣所含有的硫氧化物和氮氧化物的方法
CA3079886A1 (en) 2017-12-05 2019-06-13 Blueshift Materials, Inc. Thermally treated polyamic amide aerogel
DE102018100834A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
DE102018100833A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
JP7584727B2 (ja) * 2018-02-19 2024-11-18 ビーエーエスエフ モバイル エミッションズ カタリスツ エルエルシー 上流ｓｃｒ触媒を有する排気ガス処理システム
CN109126817B (zh) * 2018-11-07 2021-07-16 东北大学 一种铁、钨、锌改良氧化铈/氧化锰scr脱硝催化剂及其制备方法
EP3791955A1 (de) 2019-09-10 2021-03-17 Umicore Ag & Co. Kg Kupfer-zeolith- und kupfer/alumina-haltiges katalytisches material für die scr, abgasreinigungsverfahren mit diesem material und verfahren zur herstellung dieses materials
CN110586176B (zh) * 2019-09-27 2020-11-17 中国环境科学研究院 一种电解锰渣基微介孔zsm-5催化剂及制备方法
CN110917829A (zh) * 2019-12-13 2020-03-27 西安润川环保科技有限公司 一种脱硫脱硝的烟气深度处理方法
CN111111429A (zh) * 2019-12-16 2020-05-08 山东金城柯瑞化学有限公司 一种利用单活性中心多相催化剂技术治理乙酰呋喃氧化尾气的方法
CN111389454B (zh) * 2020-04-29 2022-09-20 陕西延长石油（集团）有限责任公司 一种合成气与甲苯制备对甲基苯甲醛的催化剂及方法
US11989661B1 (en) * 2023-07-24 2024-05-21 Morgan Stanley Services Group Inc. Dynamic rules for rules engines

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EP2123355A1 (en) * 2008-05-20 2009-11-25 Ibiden Co., Ltd. Honeycomb structure
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CN101443116A (zh) * 2007-01-09 2009-05-27 田中贵金属工业株式会社 氨scr催化剂及使用该催化剂的方法
US20090304566A1 (en) * 2007-01-09 2009-12-10 Golden Stephen J Ammonia scr catalyst and method of using the catalyst
EP2123355A1 (en) * 2008-05-20 2009-11-25 Ibiden Co., Ltd. Honeycomb structure
CN101722059A (zh) * 2008-10-31 2010-06-09 中国石油化工股份有限公司 脱除烟气中硫和/或氮氧化物的吸附剂组合物再生方法

Also Published As

Publication number Publication date
MX2014004494A (es) 2014-07-11
IN2014CN02950A (enExample) 2015-07-03
CL2014000993A1 (es) 2014-08-22
AU2012327482A1 (en) 2014-05-15
WO2013060341A1 (en) 2013-05-02
JP2015501210A (ja) 2015-01-15
CA2853154A1 (en) 2013-05-02
RU2608616C2 (ru) 2017-01-23
BR112014008669B1 (pt) 2019-07-02
BR112014008669A2 (pt) 2017-04-18
WO2013060487A1 (en) 2013-05-02
RU2014120917A (ru) 2015-12-10
KR101789114B1 (ko) 2017-10-23
KR20140095512A (ko) 2014-08-01
JP6112734B2 (ja) 2017-04-12
CA2853154C (en) 2018-04-03
CN103889569A (zh) 2014-06-25

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