CN103858259B - 石墨烯及蓄电装置、及它们的制造方法 - Google Patents

石墨烯及蓄电装置、及它们的制造方法 Download PDF

Info

Publication number
CN103858259B
CN103858259B CN201280047563.5A CN201280047563A CN103858259B CN 103858259 B CN103858259 B CN 103858259B CN 201280047563 A CN201280047563 A CN 201280047563A CN 103858259 B CN103858259 B CN 103858259B
Authority
CN
China
Prior art keywords
active material
storage device
graphene oxide
graphene
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280047563.5A
Other languages
English (en)
Chinese (zh)
Other versions
CN103858259A (zh
Inventor
等等力弘笃
斋藤祐美子
川上贵洋
野元邦治
汤川干央
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Semiconductor Energy Laboratory Co Ltd
Original Assignee
Semiconductor Energy Laboratory Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Semiconductor Energy Laboratory Co Ltd filed Critical Semiconductor Energy Laboratory Co Ltd
Priority to CN201810081169.2A priority Critical patent/CN108101050B/zh
Publication of CN103858259A publication Critical patent/CN103858259A/zh
Application granted granted Critical
Publication of CN103858259B publication Critical patent/CN103858259B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/5835—Comprising fluorine or fluoride salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C01B32/192—Preparation by exfoliation starting from graphitic oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/21—After-treatment
    • C01B32/23—Oxidation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004—Details
    • H01G9/04—Electrodes or formation of dielectric layers thereon
    • H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Secondary Cells (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Steroid Compounds (AREA)
CN201280047563.5A 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法 Expired - Fee Related CN103858259B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810081169.2A CN108101050B (zh) 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011-217897 2011-09-30
JP2011217897 2011-09-30
PCT/JP2012/074815 WO2013047630A1 (en) 2011-09-30 2012-09-20 Graphene and power storage device, and manufacturing method thereof

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201810081169.2A Division CN108101050B (zh) 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法

Publications (2)

Publication Number Publication Date
CN103858259A CN103858259A (zh) 2014-06-11
CN103858259B true CN103858259B (zh) 2018-03-06

Family

ID=47995660

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201280047563.5A Expired - Fee Related CN103858259B (zh) 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法
CN201810081169.2A Active CN108101050B (zh) 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201810081169.2A Active CN108101050B (zh) 2011-09-30 2012-09-20 石墨烯及蓄电装置、及它们的制造方法

Country Status (6)

Country Link
US (8) US8883351B2 (https=)
JP (12) JP6157820B2 (https=)
KR (8) KR102120603B1 (https=)
CN (2) CN103858259B (https=)
TW (8) TWI705602B (https=)
WO (1) WO2013047630A1 (https=)

Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140170483A1 (en) * 2011-03-16 2014-06-19 The Regents Of The University Of California Method for the preparation of graphene/silicon multilayer structured anodes for lithium ion batteries
KR20190139340A (ko) 2011-06-03 2019-12-17 가부시키가이샤 한도오따이 에네루기 켄큐쇼 정극, 리튬 이온 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전자 기기
US9218916B2 (en) 2011-06-24 2015-12-22 Semiconductor Energy Laboratory Co., Ltd. Graphene, power storage device, and electric device
US9249524B2 (en) 2011-08-31 2016-02-02 Semiconductor Energy Laboratory Co., Ltd. Manufacturing method of composite oxide and manufacturing method of power storage device
KR102120603B1 (ko) 2011-09-30 2020-06-08 가부시키가이샤 한도오따이 에네루기 켄큐쇼 그래핀 및 축전 장치, 및 이들의 제작 방법
CN103035922B (zh) 2011-10-07 2019-02-19 株式会社半导体能源研究所 蓄电装置
US9487880B2 (en) * 2011-11-25 2016-11-08 Semiconductor Energy Laboratory Co., Ltd. Flexible substrate processing apparatus
JP6016597B2 (ja) 2011-12-16 2016-10-26 株式会社半導体エネルギー研究所 リチウムイオン二次電池用正極の製造方法
JP5719859B2 (ja) 2012-02-29 2015-05-20 株式会社半導体エネルギー研究所 蓄電装置
JP6077347B2 (ja) * 2012-04-10 2017-02-08 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9225003B2 (en) 2012-06-15 2015-12-29 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device
KR101404126B1 (ko) * 2012-08-30 2014-06-13 한국과학기술연구원 나노 입자 제조 방법, 나노 입자 및 이를 포함하는 유기 발광 소자, 태양 전지, 인쇄용 잉크, 바이오 이미지 장치 및 센서
JP6159228B2 (ja) 2012-11-07 2017-07-05 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9437897B2 (en) * 2013-02-15 2016-09-06 Green-On-Green Energy, Inc. Polar solvent based device for storage and thermal capture of electrical energy
US10298038B2 (en) 2013-02-15 2019-05-21 Green-On-Green Energy, Inc. Polar solvent based device for storage and thermal capture of electrical energy
US9673454B2 (en) 2013-02-18 2017-06-06 Semiconductor Energy Laboratory Co., Ltd. Sodium-ion secondary battery
US9490472B2 (en) 2013-03-28 2016-11-08 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing electrode for storage battery
GB2519783A (en) 2013-10-30 2015-05-06 Airbus Operations Ltd Capacitive liquid level sensor
JP2016013958A (ja) 2013-12-02 2016-01-28 株式会社半導体エネルギー研究所 素子、膜の作製方法
KR101666478B1 (ko) * 2013-12-26 2016-10-14 주식회사 엘지화학 그래핀의 제조 방법과, 그래핀의 분산 조성물
JP6353074B2 (ja) * 2013-12-31 2018-07-04 カーボン ナノ エンジニアリング システムズ コーポレイション 混合酸系による酸化グラフェン及びグラフェンの製造方法
EP3326969A1 (en) * 2013-12-31 2018-05-30 Shenzhen Cantonnet Energy Services Co. , Ltd. A preparation method of graphene
US9520243B2 (en) * 2014-02-17 2016-12-13 Korea Institute Of Energy Research Method of manufacturing flexible thin-film typer super-capacitor device using a hot-melt adhesive film, and super-capacitor device manufactured by the method
US20150325856A1 (en) * 2014-04-15 2015-11-12 New Jersey Institute Of Technology Environmentally friendly inkjet-printable lithium battery cathode formulations, methods and devices
JP6745587B2 (ja) 2014-05-29 2020-08-26 株式会社半導体エネルギー研究所 電極の製造方法
JP6329828B2 (ja) * 2014-07-04 2018-05-23 国立大学法人広島大学 熱電変換材料及びその製造方法
JP6583404B2 (ja) * 2014-08-29 2019-10-02 日本電気株式会社 リチウムイオン電池用アノード材料、該アノード材料を含む負極及びリチウムイオン電池
US9728770B2 (en) 2014-10-24 2017-08-08 Semiconductor Energy Laboratory Co., Ltd. Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
DE102014016186A1 (de) * 2014-11-03 2016-05-04 Forschungszentrum Jülich GmbH Bipolarplatte für elektrochemische Zellen sowie Verfahren zur Herstellung derselben
TWI509230B (zh) * 2014-12-25 2015-11-21 Univ Nat Cheng Kung 石墨烯光電能量感測器及使用其之光電能量感測方法
US9905370B2 (en) * 2015-03-05 2018-02-27 Tuqiang Chen Energy storage electrodes and devices
JP6592268B2 (ja) * 2015-04-01 2019-10-16 株式会社日本触媒 導電性材料及びそれを用いた熱電変換素子、熱電変換装置
CN106208810B (zh) * 2015-04-29 2018-07-24 华中科技大学 一种用于蒸发发电的发电组件的制备方法
CN106208811B (zh) * 2015-04-29 2017-11-24 华中科技大学 一种基于碳材料蒸发发电的热电转换装置
WO2016178117A1 (en) 2015-05-06 2016-11-10 Semiconductor Energy Laboratory Co., Ltd. Secondary battery and electronic device
JP2016222526A (ja) 2015-05-29 2016-12-28 株式会社半導体エネルギー研究所 膜の作製方法および素子
US10784516B2 (en) 2015-06-25 2020-09-22 Semiconductor Energy Laboratory Co., Ltd. Conductor, power storage device, electronic device, and method for forming conductor
CN105098897A (zh) * 2015-07-30 2015-11-25 京东方科技集团股份有限公司 一种可穿戴设备及终端
JP2017045726A (ja) 2015-08-27 2017-03-02 株式会社半導体エネルギー研究所 電極、及びその製造方法、蓄電池、並びに電子機器
US10411260B2 (en) 2016-04-12 2019-09-10 Green-On-Green Energy, Inc. Grid electrode for polar solvent-based hydro-pyroelectrodynamic electrical energy storage device
KR102481149B1 (ko) 2016-07-05 2022-12-23 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질, 양극 활물질의 제작 방법, 및 이차 전지
US10336619B2 (en) * 2016-07-27 2019-07-02 Sri Lanka Institute of Nanotechnology (Pvt) Ltd. Method for the synthesis of graphene oxide
US12308421B2 (en) 2016-09-12 2025-05-20 Semiconductor Energy Laboratory Co., Ltd. Electrode and power storage device comprising graphene compound
US11242250B2 (en) 2016-09-28 2022-02-08 Ohio University Electrochemical method for the production of graphene composites and cell for conducting the same
CN106629676A (zh) * 2016-09-29 2017-05-10 武汉大学 一种基于碱性电解液的石墨烯制备方法
CN116454360A (zh) 2016-10-12 2023-07-18 株式会社半导体能源研究所 正极活性物质粒子以及正极活性物质粒子的制造方法
DE102016220685A1 (de) * 2016-10-21 2018-04-26 Robert Bosch Gmbh Elektrode mit elektrisch leitendem Netzwerk auf Aktivmaterialstrukturen
CN119943936A (zh) 2017-05-12 2025-05-06 株式会社半导体能源研究所 正极活性物质粒子
KR102932867B1 (ko) 2017-05-19 2026-02-27 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질, 양극 활물질의 제작 방법, 및 이차 전지
CN107069043B (zh) * 2017-05-26 2019-07-12 中南大学 锂离子电池及其制备方法
CN118335885A (zh) 2017-06-26 2024-07-12 株式会社半导体能源研究所 正极活性物质的制造方法及二次电池
US10604422B2 (en) * 2017-11-14 2020-03-31 Vegapure Water System Inc. Water container with integrated plasma disinfection
CN110519871A (zh) * 2018-05-21 2019-11-29 无锡恺信石墨烯应用科技有限公司 一种可防止跳闸的石墨烯发热膜
KR20250048814A (ko) 2018-06-22 2025-04-10 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질, 양극, 이차 전지, 및 양극의 제작 방법
US10941041B2 (en) 2018-07-06 2021-03-09 Savannah River Nuclear Solutions, Llc Method of manufacturing graphene using photoreduction
CN108584933A (zh) * 2018-07-15 2018-09-28 石梦成 一种通过离子液体剥离制备的氟化石墨烯
CN109004209B (zh) * 2018-08-02 2020-09-11 盐城市新能源化学储能与动力电源研究中心 镉石墨烯电池以及石墨烯电池
CN109755508A (zh) * 2018-12-18 2019-05-14 湘潭大学 一种硅/石墨烯多层复合膜负极材料的制备方法
CN111899987A (zh) * 2020-07-06 2020-11-06 深圳市展旺新材料科技有限公司 一种可穿戴石墨烯超级电容器的制备方法
CN117321791A (zh) * 2021-12-15 2023-12-29 株式会社Lg新能源 阳极组合物、包含其的锂二次电池阳极以及包含阳极的锂二次电池
CN114583261B (zh) * 2022-03-10 2023-11-10 山东天润新能源材料有限公司 一种含氧化石墨烯的钠离子二次电池电解液的制备方法
CN114976205B (zh) * 2022-05-07 2025-08-29 万华化学集团股份有限公司 一种锂离子二次电池
EP4687179A1 (en) * 2024-07-31 2026-02-04 Eve Energy Co., Ltd. Lithium primary button cell, preparation method thereof, and electronic device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110183180A1 (en) * 2010-01-25 2011-07-28 Zhenning Yu Flexible asymmetric electrochemical cells using nano graphene platelet as an electrode material

Family Cites Families (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0017400B1 (en) 1979-04-05 1984-05-30 United Kingdom Atomic Energy Authority Electrochemical cell and method of making ion conductors for said cell
CA1265580A (en) 1985-05-10 1990-02-06 Akira Yoshino Secondary battery
JP3550783B2 (ja) 1994-05-16 2004-08-04 東ソー株式会社 リチウム含有遷移金属複合酸化物及びその製造方法並びにその用途
US5910382A (en) 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
TW363940B (en) 1996-08-12 1999-07-11 Toda Kogyo Corp A lithium-nickle-cobalt compound oxide, process thereof and anode active substance for storage battery
US5871866A (en) 1996-09-23 1999-02-16 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and use thereof
US5783333A (en) 1996-11-27 1998-07-21 Polystor Corporation Lithium nickel cobalt oxides for positive electrodes
US6085015A (en) 1997-03-25 2000-07-04 Hydro-Quebec Lithium insertion electrode materials based on orthosilicate derivatives
CA2270771A1 (fr) 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
JP3921931B2 (ja) 2000-09-29 2007-05-30 ソニー株式会社 正極活物質及び非水電解質電池
JP2003238131A (ja) * 2002-02-08 2003-08-27 Mitsubishi Gas Chem Co Inc 炭素からなる骨格を持つ薄膜状粒子のランダム凝集体
JP4765077B2 (ja) 2004-06-11 2011-09-07 国立大学法人東京農工大学 酸化ルテニウム内包ナノカーボン複合構造体
WO2006022254A1 (ja) 2004-08-26 2006-03-02 Matsushita Electric Industrial Co., Ltd. 電極用複合粒子およびその製造法、ならびに二次電池
ES2620809T3 (es) 2004-09-03 2017-06-29 Uchicago Argonne, Llc Electrodos compuestos de óxido de manganeso par baterías de litio
WO2006062947A2 (en) 2004-12-09 2006-06-15 Nanosys, Inc. Nanowire-based membrane electrode assemblies for fuel cells
US7939218B2 (en) 2004-12-09 2011-05-10 Nanosys, Inc. Nanowire structures comprising carbon
US7842432B2 (en) 2004-12-09 2010-11-30 Nanosys, Inc. Nanowire structures comprising carbon
US8278011B2 (en) 2004-12-09 2012-10-02 Nanosys, Inc. Nanostructured catalyst supports
KR100639889B1 (ko) 2004-12-30 2006-10-31 주식회사 소디프신소재 비탄소재료 함유 소구체 탄소분말 및 그 제조방법
JP3850427B2 (ja) 2005-03-22 2006-11-29 株式会社物産ナノテク研究所 炭素繊維結合体およびこれを用いた複合材料
US8003257B2 (en) 2005-07-04 2011-08-23 Showa Denko K.K. Method for producing anode for lithium secondary battery and anode composition, and lithium secondary battery
US20070009799A1 (en) 2005-07-07 2007-01-11 Eveready Battery Company, Inc. Electrochemical cell having a partially oxidized conductor
US7658901B2 (en) 2005-10-14 2010-02-09 The Trustees Of Princeton University Thermally exfoliated graphite oxide
US7914844B2 (en) 2005-11-18 2011-03-29 Northwestern University Stable dispersions of polymer-coated graphitic nanoplatelets
EP1952467B9 (en) 2005-11-21 2012-03-14 Nanosys, Inc. Nanowire structures comprising carbon
KR20140083054A (ko) 2006-06-02 2014-07-03 미쓰비시 가가꾸 가부시키가이샤 비수계 전해액 및 비수계 전해액 전지
JP2008218125A (ja) 2007-03-02 2008-09-18 Matsushita Electric Ind Co Ltd リチウムイオン二次電池用負極およびリチウムイオン二次電池
JP4240157B2 (ja) 2007-03-05 2009-03-18 東洋インキ製造株式会社 電池用組成物
US8715610B2 (en) 2007-10-19 2014-05-06 University Of Wollongong Process for the preparation of graphene
KR100923304B1 (ko) 2007-10-29 2009-10-23 삼성전자주식회사 그라펜 시트 및 그의 제조방법
US7745047B2 (en) * 2007-11-05 2010-06-29 Nanotek Instruments, Inc. Nano graphene platelet-base composite anode compositions for lithium ion batteries
JP5377946B2 (ja) 2007-12-25 2013-12-25 花王株式会社 リチウム電池正極用複合材料
US8426064B2 (en) 2007-12-25 2013-04-23 Kao Corporation Composite material for positive electrode of lithium battery
WO2009085015A1 (en) 2008-01-03 2009-07-09 National University Of Singapore Functionalised graphene oxide
WO2009127901A1 (en) 2008-04-14 2009-10-22 High Power Lithium S.A. Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries
WO2009134707A2 (en) * 2008-04-27 2009-11-05 Board Of Regents, The University Of Texas System Ultracapacitors and methods of making and using
US8936874B2 (en) 2008-06-04 2015-01-20 Nanotek Instruments, Inc. Conductive nanocomposite-based electrodes for lithium batteries
US8450014B2 (en) 2008-07-28 2013-05-28 Battelle Memorial Institute Lithium ion batteries with titania/graphene anodes
US8257867B2 (en) 2008-07-28 2012-09-04 Battelle Memorial Institute Nanocomposite of graphene and metal oxide materials
TW201012749A (en) 2008-08-19 2010-04-01 Univ Rice William M Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom
US8114375B2 (en) 2008-09-03 2012-02-14 Nanotek Instruments, Inc. Process for producing dispersible nano graphene platelets from oxidized graphite
US8580432B2 (en) 2008-12-04 2013-11-12 Nanotek Instruments, Inc. Nano graphene reinforced nanocomposite particles for lithium battery electrodes
US9093693B2 (en) 2009-01-13 2015-07-28 Samsung Electronics Co., Ltd. Process for producing nano graphene reinforced composite particles for lithium battery electrodes
WO2010096665A1 (en) 2009-02-19 2010-08-26 William Marsh Rice University Dissolution of graphite, graphite oxide and graphene nanoribbons in superacid solutions and manipulation thereof
JP2010239122A (ja) * 2009-03-09 2010-10-21 Semiconductor Energy Lab Co Ltd 蓄電デバイス
EP2237346B1 (en) 2009-04-01 2017-08-09 The Swatch Group Research and Development Ltd. Electrically conductive nanocomposite material comprising sacrificial nanoparticles and open porous nanocomposites produced thereof
JP5650418B2 (ja) * 2009-03-12 2015-01-07 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 犠牲ナノ粒子を含む電気伝導性ナノ複合材料およびそれから生成される開放多孔質ナノ複合材
EP2228854B1 (en) 2009-03-12 2014-03-05 Belenos Clean Power Holding AG Nitride and carbide anode materials
US8317984B2 (en) 2009-04-16 2012-11-27 Northrop Grumman Systems Corporation Graphene oxide deoxygenation
US20140370380A9 (en) 2009-05-07 2014-12-18 Yi Cui Core-shell high capacity nanowires for battery electrodes
US20100291438A1 (en) 2009-05-15 2010-11-18 PDC Energy, LLC Electrode material, lithium-ion battery and method thereof
CA2762430A1 (en) 2009-05-22 2011-02-10 William Marsh Rice University Highly oxidized graphene oxide and methods for production thereof
EP3865454A3 (en) 2009-05-26 2021-11-24 Belenos Clean Power Holding AG Stable dispersions of single and multiple graphene layers in solution
CN101562248B (zh) 2009-06-03 2011-05-11 龚思源 一种石墨烯复合的锂离子电池正极材料磷酸铁锂及其制备方法
SG10201403233XA (en) 2009-06-15 2014-10-30 Univ Rice William M Graphene nanoribbons prepared from carbon nanotubes via alkali metal exposure
WO2010147859A1 (en) 2009-06-15 2010-12-23 William Marsh Rice University Nanomaterial-containing signaling compositions for assay of flowing liquid streams and geological formations and methods for use thereof
JP5456392B2 (ja) 2009-07-09 2014-03-26 国立大学法人三重大学 リチウムイオン二次電池用の負極材料及びリチウムイオン二次電池
US8835046B2 (en) 2009-08-10 2014-09-16 Battelle Memorial Institute Self assembled multi-layer nanocomposite of graphene and metal oxide materials
US9017867B2 (en) * 2009-08-10 2015-04-28 Battelle Memorial Institute Self assembled multi-layer nanocomposite of graphene and metal oxide materials
JP2011048992A (ja) 2009-08-26 2011-03-10 Sekisui Chem Co Ltd 炭素材料、電極材料及びリチウムイオン二次電池負極材料
WO2011041663A2 (en) * 2009-10-02 2011-04-07 Board Of Regents, The University Of Texas System Exfoliation of graphite oxide in propylene carbonate and thermal reduction of resulting graphene oxide platelets
US8778538B2 (en) 2009-11-06 2014-07-15 Northwestern University Electrode material comprising graphene-composite materials in a graphite network
JP5001995B2 (ja) * 2009-11-11 2012-08-15 トヨタ自動車株式会社 リチウム二次電池用正極およびその製造方法
JP5471351B2 (ja) 2009-11-20 2014-04-16 富士電機株式会社 グラフェン薄膜の製膜方法
US9431649B2 (en) 2009-11-23 2016-08-30 Uchicago Argonne, Llc Coated electroactive materials
US8993177B2 (en) 2009-12-04 2015-03-31 Envia Systems, Inc. Lithium ion battery with high voltage electrolytes and additives
CN101752561B (zh) * 2009-12-11 2012-08-22 宁波艾能锂电材料科技股份有限公司 石墨烯改性磷酸铁锂正极活性材料及其制备方法以及锂离子二次电池
US8652687B2 (en) * 2009-12-24 2014-02-18 Nanotek Instruments, Inc. Conductive graphene polymer binder for electrochemical cell electrodes
WO2011116369A2 (en) * 2010-03-19 2011-09-22 Board Of Regents, The University Of Texas System Electrophoretic deposition and reduction of graphene oxide to make graphene film coatings and electrode structures
KR101809771B1 (ko) 2010-05-14 2017-12-15 바스프 에스이 그래핀에 의한 금속 및 금속 산화물의 캡슐화 방법 및 상기 물질의 용도
US9437344B2 (en) * 2010-07-22 2016-09-06 Nanotek Instruments, Inc. Graphite or carbon particulates for the lithium ion battery anode
CN103053055B (zh) 2010-08-19 2016-10-12 株式会社半导体能源研究所 电气设备
US8691441B2 (en) 2010-09-07 2014-04-08 Nanotek Instruments, Inc. Graphene-enhanced cathode materials for lithium batteries
KR101861212B1 (ko) * 2010-09-09 2018-06-29 캘리포니아 인스티튜트 오브 테크놀로지 전기화학적 에너지 저장 시스템 및 방법
US9558860B2 (en) * 2010-09-10 2017-01-31 Samsung Electronics Co., Ltd. Graphene-enhanced anode particulates for lithium ion batteries
US20120088151A1 (en) 2010-10-08 2012-04-12 Semiconductor Energy Laboratory Co., Ltd. Positive-electrode active material and power storage device
CN103140967B (zh) 2010-10-08 2016-08-31 株式会社半导体能源研究所 储能装置用正极活性材料的制造方法及储能装置
EP2698854B1 (en) 2010-10-22 2017-02-22 Belenos Clean Power Holding AG Method of an electrode (anode and cathode) performance enhancement by composite formation with graphene oxide
CN102174702A (zh) * 2011-01-11 2011-09-07 湖南大学 一种金属纳米粒子-石墨烯复合物的制备方法
JP2012224526A (ja) * 2011-04-21 2012-11-15 Hiroshima Univ グラフェンの製造方法
TWI582041B (zh) 2011-06-03 2017-05-11 半導體能源研究所股份有限公司 單層和多層石墨烯，彼之製法，含彼之物件，以及含彼之電器裝置
KR20190139340A (ko) 2011-06-03 2019-12-17 가부시키가이샤 한도오따이 에네루기 켄큐쇼 정극, 리튬 이온 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전자 기기
CN105600776B (zh) 2011-08-18 2018-03-30 株式会社半导体能源研究所 形成石墨烯及氧化石墨烯盐的方法、以及氧化石墨烯盐
JP5961496B2 (ja) 2011-09-16 2016-08-02 株式会社半導体エネルギー研究所 蓄電装置
KR102120603B1 (ko) * 2011-09-30 2020-06-08 가부시키가이샤 한도오따이 에네루기 켄큐쇼 그래핀 및 축전 장치, 및 이들의 제작 방법
US20130084384A1 (en) 2011-10-04 2013-04-04 Semiconductor Energy Laboratory Co., Ltd. Manufacturing method of secondary particles and manufacturing method of electrode of power storage device
JP6077347B2 (ja) 2012-04-10 2017-02-08 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110183180A1 (en) * 2010-01-25 2011-07-28 Zhenning Yu Flexible asymmetric electrochemical cells using nano graphene platelet as an electrode material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Electrochemical reduction of graphene oxide in organic solvents;Yutaka Harima等;《Electrochimica Acta》;20110404;第56卷;第5363-5368页 *

Also Published As

Publication number Publication date
US20200052299A1 (en) 2020-02-13
JP2013163636A (ja) 2013-08-22
JP5356622B2 (ja) 2013-12-04
JP2013082606A (ja) 2013-05-09
JP2023026498A (ja) 2023-02-24
JP6797995B2 (ja) 2020-12-09
JP2018107137A (ja) 2018-07-05
US10461332B2 (en) 2019-10-29
KR102120603B1 (ko) 2020-06-08
TWI792027B (zh) 2023-02-11
KR102304204B1 (ko) 2021-09-17
CN108101050B (zh) 2022-04-01
TWI705602B (zh) 2020-09-21
US20230307639A1 (en) 2023-09-28
KR20190139332A (ko) 2019-12-17
KR102514830B1 (ko) 2023-03-30
KR20190116537A (ko) 2019-10-14
JP6157820B2 (ja) 2017-07-05
KR20230047202A (ko) 2023-04-06
KR20210118222A (ko) 2021-09-29
JP2020017542A (ja) 2020-01-30
JP2013149624A (ja) 2013-08-01
JP7573013B2 (ja) 2024-10-24
JP2017017035A (ja) 2017-01-19
KR20200093709A (ko) 2020-08-05
JP6937873B2 (ja) 2021-09-22
CN103858259A (zh) 2014-06-11
KR20240123422A (ko) 2024-08-13
JP2021143123A (ja) 2021-09-24
TWI608649B (zh) 2017-12-11
KR102693192B1 (ko) 2024-08-09
JP2024111066A (ja) 2024-08-16
KR102376305B1 (ko) 2022-03-18
TW201820685A (zh) 2018-06-01
TWI623131B (zh) 2018-05-01
US20130266869A1 (en) 2013-10-10
US20230073850A1 (en) 2023-03-09
TW201640720A (zh) 2016-11-16
TW202017232A (zh) 2020-05-01
JP6892489B2 (ja) 2021-06-23
US20240266538A1 (en) 2024-08-08
KR20140072868A (ko) 2014-06-13
US11735731B2 (en) 2023-08-22
WO2013047630A1 (en) 2013-04-04
US20200350585A1 (en) 2020-11-05
KR102029506B1 (ko) 2019-10-07
TW202505791A (zh) 2025-02-01
TW202044649A (zh) 2020-12-01
TW201937788A (zh) 2019-09-16
JP2020177919A (ja) 2020-10-29
TW202343854A (zh) 2023-11-01
TWI669847B (zh) 2019-08-21
JP6291543B2 (ja) 2018-03-14
JP2020013799A (ja) 2020-01-23
US8883351B2 (en) 2014-11-11
TW201324930A (zh) 2013-06-16
US12463217B2 (en) 2025-11-04
KR20220040501A (ko) 2022-03-30
JP2020170722A (ja) 2020-10-15
CN108101050A (zh) 2018-06-01
JP7198870B2 (ja) 2023-01-04
US20150064565A1 (en) 2015-03-05
US20260038831A1 (en) 2026-02-05
US11990621B2 (en) 2024-05-21

Similar Documents

Publication Publication Date Title
CN103858259B (zh) 石墨烯及蓄电装置、及它们的制造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180306