CN103788280B - 质子传导材料 - Google Patents

质子传导材料 Download PDF

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Publication number
CN103788280B
CN103788280B CN201410012608.6A CN201410012608A CN103788280B CN 103788280 B CN103788280 B CN 103788280B CN 201410012608 A CN201410012608 A CN 201410012608A CN 103788280 B CN103788280 B CN 103788280B
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polymer
group
acid
metal
following formula
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CN103788280A (zh
Inventor
史蒂文·J·哈姆罗克
马克·S·沙伯格
尼拉吉·沙拉玛
约翰·E·阿布卢
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3834—Aromatic acids (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4021—Esters of aromatic acids (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inert Electrodes (AREA)
CN201410012608.6A 2008-04-24 2009-04-24 质子传导材料 Active CN103788280B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4764308P 2008-04-24 2008-04-24
US61/047,643 2008-04-24
CN200980122800.8A CN102066468B (zh) 2008-04-24 2009-04-24 质子传导材料

Related Parent Applications (1)

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Publications (2)

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CN103788280A CN103788280A (zh) 2014-05-14
CN103788280B true CN103788280B (zh) 2016-08-17

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Country Status (5)

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US (4) US20090269644A1 (enExample)
EP (3) EP2276728B1 (enExample)
JP (2) JP2011523398A (enExample)
CN (2) CN103788280B (enExample)
WO (1) WO2009132241A2 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090269644A1 (en) 2008-04-24 2009-10-29 3M Innovative Properties Company Proton conducting materials
CN104016891B (zh) 2010-04-16 2016-08-17 3M创新有限公司 质子传导材料
WO2012096653A1 (en) * 2011-01-11 2012-07-19 Utc Power Corporation Proton exchange material and method therefor
EP2684239B1 (en) 2011-03-11 2025-01-01 Audi AG Unitized electrode assembly with high equivalent weight ionomer
CN104640926B (zh) 2012-04-23 2016-09-21 奥迪股份公司 将颗粒分散在全氟化聚合物离聚物中的方法
KR101925670B1 (ko) 2012-12-21 2018-12-05 아우디 아게 전해질 막, 분산액 및 그를 위한 방법
JP6185079B2 (ja) * 2012-12-21 2017-08-23 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 電解質材料の製造方法
JP2016507611A (ja) 2012-12-21 2016-03-10 トヨタ自動車株式会社 プロトン交換材料およびその製造方法
WO2014129971A1 (en) * 2013-02-25 2014-08-28 National University Of Singapore Polyamide single-ion conducting composite polymer electrolyte
CA2904489C (en) * 2013-03-18 2017-02-14 Nippon Soda Co., Ltd. Method for producing disulfonylamine alkali metal salt
CN104425788B (zh) 2013-08-28 2017-05-03 比亚迪股份有限公司 一种锂离子电池隔膜及其制备方法和含有该隔膜的锂离子电池
EP3252034B1 (en) * 2015-01-26 2019-06-12 LG Chem, Ltd. Compound comprising aromatic ring, polymer comprising same, and polyelectrolyte membrane using same
EP3252035B1 (en) * 2015-01-27 2020-03-04 LG Chem, Ltd. Compound comprising aromatic ring, and polyelectrolyte membrane using same
CN108467407B (zh) * 2018-04-09 2020-06-09 山东大学 一种增强二维层状稀土有机膦酸盐质子传导能力的方法
US11165068B2 (en) 2018-08-08 2021-11-02 Ryo Tamaki Manufacturing of electrolytic membrane with cationic or anionic ion conducting capability comprising crosslinked inorganic-organic hybrid electrolyte in a porous support and articles comprising the same
CN114614058B (zh) * 2020-12-04 2024-05-07 中国石油化工股份有限公司 一种薄层复合质子交换膜及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5919583A (en) * 1995-03-20 1999-07-06 E. I. Du Pont De Nemours And Company Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same
CN1301191A (zh) * 1998-05-22 2001-06-27 美国3M公司 交联的离子导电膜
WO2003035611A1 (en) * 2001-10-25 2003-05-01 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
WO2004106349A1 (en) * 2003-05-27 2004-12-09 E.I. Dupont De Nemours And Company Fuel cell membrane containing zirconium phosphate

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE791289A (nl) 1971-11-24 1973-05-14 Agfa Gevaert Nv Werkwijze voor het bereiden van fotografische zilverzoutemulsies
DE2741669A1 (de) * 1977-09-16 1979-03-22 Bayer Ag Semipermeable membranen aus acrylnitrilcopolymerisaten
US5246901A (en) * 1988-05-23 1993-09-21 Catalytica, Inc. Polysulfonic acids
FR2637284B1 (fr) * 1988-10-05 1991-07-05 Elf Aquitaine Methode de synthese de sulfonylimidures
US5256821A (en) 1988-10-05 1993-10-26 Societe Nationale Elf Aquitaine Method of synthesis of sulphonylimides
US5256493A (en) * 1990-04-26 1993-10-26 Szita Jeno G Sulfonimide catalysts for coatings
US5463005A (en) * 1992-01-03 1995-10-31 Gas Research Institute Copolymers of tetrafluoroethylene and perfluorinated sulfonyl monomers and membranes made therefrom
US5317001A (en) * 1992-12-23 1994-05-31 Eastman Kodak Company Thermal dye transfer receiving element with aqueous dispersible polyester dye image-receiving layer
JP3159569B2 (ja) * 1993-07-09 2001-04-23 富士写真フイルム株式会社 感光性組成物及び画像形成方法
JP3117369B2 (ja) 1994-09-12 2000-12-11 セントラル硝子株式会社 スルホンイミドの製造方法
DE69608793T2 (de) * 1995-03-20 2001-02-01 E.I. Du Pont De Nemours And Co., Wilmington Anorganische füllstoffe enthaltende membranen für brennstoffzellen
WO1999038842A1 (fr) 1998-01-30 1999-08-05 Hydro-Quebec Derives bis-sulfonyles polymerisables et leur utilisation dans la preparation de membranes echangeuses d'ions
US6063522A (en) 1998-03-24 2000-05-16 3M Innovative Properties Company Electrolytes containing mixed fluorochemical/hydrocarbon imide and methide salts
JP3835786B2 (ja) * 1998-11-13 2006-10-18 富士写真フイルム株式会社 ポジ型レジスト液
US6420082B1 (en) 1998-11-13 2002-07-16 Fuji Photo Film Co., Ltd. Positive resist fluid and positive resist composition
JP4799776B2 (ja) 2000-08-22 2011-10-26 富士フイルム株式会社 電解質組成物及びそれを用いた電気化学電池
US6660445B2 (en) * 2000-10-13 2003-12-09 Fuji Photo Film Co., Ltd. Photosensitive composition comprising a vinyl copolymer and an o-naphthoquinone diazide compound
US20040122256A1 (en) * 2001-02-01 2004-06-24 Masanori Ikeda Perfluorvinyl ether monomer having sulfonamide group
JP3630306B2 (ja) * 2001-02-23 2005-03-16 株式会社豊田中央研究所 多官能化電解質及びこれを用いた電気化学デバイス並びに多官能化電解質の製造方法
US20020160272A1 (en) 2001-02-23 2002-10-31 Kabushiki Kaisha Toyota Chuo Process for producing a modified electrolyte and the modified electrolyte
JP3969077B2 (ja) 2001-04-04 2007-08-29 住友化学株式会社 高分子電解質及びその製造方法
US20030013817A1 (en) * 2001-06-26 2003-01-16 Kelly Lu High temperature ionic polymers and membranes made therefrom
JP2003098657A (ja) * 2001-09-21 2003-04-04 Fuji Photo Film Co Ltd ポジ型印刷版用原版
US6863838B2 (en) * 2001-10-25 2005-03-08 3M Innovative Properties Company Zwitterionic imides
ITPG20020015A1 (it) 2002-03-22 2003-09-22 Giulio Alberti Un metodo innovativo per la preparazione di membrane nanopolimeriche a conduzione protonica per usi in celle a combustibile o in reattori ca
JP4106983B2 (ja) * 2002-03-25 2008-06-25 住友化学株式会社 芳香族系高分子、その製造方法およびその用途
KR100968398B1 (ko) * 2002-06-28 2010-07-07 스미또모 가가꾸 가부시끼가이샤 고분자 적층막, 그 제조 방법 및 그 용도
TW200416257A (en) * 2002-10-15 2004-09-01 Sumitomo Chemical Co Block copolymer and application thereof
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US20040225153A1 (en) * 2003-02-13 2004-11-11 The Penn State Research Foundation Synthesis of polyphosphazenes with sulfonimide side groups
JP2004331799A (ja) * 2003-05-07 2004-11-25 Yokohama Tlo Co Ltd 新規重合体
JP2005029624A (ja) * 2003-07-08 2005-02-03 Sumitomo Bakelite Co Ltd エポキシ樹脂組成物及び半導体装置
WO2005029624A1 (ja) 2003-09-17 2005-03-31 Asahi Kasei Kabushiki Kaisha 固体高分子型燃料電池用膜‐電極接合体
US7285349B2 (en) 2003-10-30 2007-10-23 3M Innovative Properties Company Polymer electrolyte membrane and method of making
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7259208B2 (en) 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7576165B2 (en) * 2004-01-27 2009-08-18 Georgia Institute Of Technology Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes
US7517604B2 (en) 2005-09-19 2009-04-14 3M Innovative Properties Company Fuel cell electrolyte membrane with acidic polymer
JP2007089017A (ja) * 2005-09-26 2007-04-05 Pioneer Electronic Corp 通信端末、データ送信方法、データ受信方法、データ送信プログラム、データ受信プログラムおよび記録媒体
JP5156399B2 (ja) 2006-02-03 2013-03-06 ダイキン工業株式会社 −ｓｏ３ｈ基含有フルオロポリマー製造方法及び−ｓｏ３ｈ基含有フルオロポリマー
JPWO2007125845A1 (ja) * 2006-04-28 2009-09-10 国立大学法人横浜国立大学 スルホンイミド型モノマー及びその重合体
CN101919100B (zh) 2007-11-09 2014-10-01 3M创新有限公司 包含杂多酸的聚合物电解质
US8137828B2 (en) 2007-12-27 2012-03-20 3M Innovative Properties Company Durable fuel cell membrane electrode assembly with combined additives
US20090269644A1 (en) 2008-04-24 2009-10-29 3M Innovative Properties Company Proton conducting materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5919583A (en) * 1995-03-20 1999-07-06 E. I. Du Pont De Nemours And Company Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same
CN1301191A (zh) * 1998-05-22 2001-06-27 美国3M公司 交联的离子导电膜
WO2003035611A1 (en) * 2001-10-25 2003-05-01 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
WO2004106349A1 (en) * 2003-05-27 2004-12-09 E.I. Dupont De Nemours And Company Fuel cell membrane containing zirconium phosphate

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