CN103524885A - 一种新型的膨胀型阻燃剂 - Google Patents
一种新型的膨胀型阻燃剂 Download PDFInfo
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- CN103524885A CN103524885A CN201310556753.6A CN201310556753A CN103524885A CN 103524885 A CN103524885 A CN 103524885A CN 201310556753 A CN201310556753 A CN 201310556753A CN 103524885 A CN103524885 A CN 103524885A
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- fire retardant
- retardant
- phosphonitriles
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- poly
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 73
- -1 polypropylene Polymers 0.000 claims abstract description 14
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 8
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 9
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- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 102100039875 Histone H3-7 Human genes 0.000 claims description 2
- 101001035307 Homo sapiens Histone H3-7 Proteins 0.000 claims description 2
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- 239000000463 material Substances 0.000 abstract description 13
- 239000002253 acid Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 5
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- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000460 chlorine Substances 0.000 abstract description 2
- 229910052801 chlorine Inorganic materials 0.000 abstract description 2
- DZKXDEWNLDOXQH-UHFFFAOYSA-N 1,3,5,2,4,6-triazatriphosphinine Chemical compound N1=PN=PN=P1 DZKXDEWNLDOXQH-UHFFFAOYSA-N 0.000 abstract 3
- ANMAWDWFQHQPFX-UHFFFAOYSA-N 1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)NC(=O)NC1=O ANMAWDWFQHQPFX-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 11
- 229910052698 phosphorus Inorganic materials 0.000 description 11
- 239000011574 phosphorus Substances 0.000 description 11
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical compound OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
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- 238000011160 research Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000234314 Zingiber Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- BNBQRQQYDMDJAH-UHFFFAOYSA-N benzodioxan Chemical class C1=CC=C2OCCOC2=C1 BNBQRQQYDMDJAH-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- UBIJTWDKTYCPMQ-UHFFFAOYSA-N hexachlorophosphazene Chemical compound ClP1(Cl)=NP(Cl)(Cl)=NP(Cl)(Cl)=N1 UBIJTWDKTYCPMQ-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
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- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
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- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310556753.6A CN103524885B (zh) | 2013-11-11 | 2013-11-11 | 一种由聚氨基环三磷腈和三(2-羟乙基)异氰尿酸酯复配而成的膨胀型阻燃剂 |
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CN201310556753.6A CN103524885B (zh) | 2013-11-11 | 2013-11-11 | 一种由聚氨基环三磷腈和三(2-羟乙基)异氰尿酸酯复配而成的膨胀型阻燃剂 |
Publications (2)
Publication Number | Publication Date |
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CN103524885A true CN103524885A (zh) | 2014-01-22 |
CN103524885B CN103524885B (zh) | 2015-08-26 |
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CN201310556753.6A Active CN103524885B (zh) | 2013-11-11 | 2013-11-11 | 一种由聚氨基环三磷腈和三(2-羟乙基)异氰尿酸酯复配而成的膨胀型阻燃剂 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103951959A (zh) * | 2014-05-20 | 2014-07-30 | 上海电力学院 | 膨胀型阻燃增强pc/abs合金及其制备方法 |
CN104292826A (zh) * | 2014-09-28 | 2015-01-21 | 上海电力学院 | 一种导热塑料及其制备方法 |
CN104928978A (zh) * | 2015-04-02 | 2015-09-23 | 青岛科技大学 | 一种基于六氨基环三磷腈的阻燃纸的制备方法 |
CN107187122A (zh) * | 2017-04-27 | 2017-09-22 | 东营俊富净化科技有限公司 | 一种高效阻燃防护复合材料及其制备方法和应用 |
CN111825971A (zh) * | 2020-07-31 | 2020-10-27 | 鑫宝防水材料股份有限公司 | 一种阻燃隔热特种性能防水卷材及其制备方法 |
CN112724358A (zh) * | 2021-01-22 | 2021-04-30 | 四川大学 | 一种基于改性石墨烯的水性阻燃自修复聚氨酯的制备方法 |
CN113845725A (zh) * | 2021-10-19 | 2021-12-28 | 青岛塑科高分子科技有限公司 | 一种具有良好耐水性的阻燃聚丙烯材料及其制备方法 |
CN116535864A (zh) * | 2023-07-07 | 2023-08-04 | 山东迈特新材料科技有限公司 | 一种含聚氨基环三磷腈和赛克改性密胺树脂的膨胀型阻燃剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4405738A (en) * | 1982-03-05 | 1983-09-20 | Akzona Incorporated | Flame retardant additives and flame retardant polyester compositions |
CN102875947A (zh) * | 2012-09-20 | 2013-01-16 | 中国科学院上海应用物理研究所 | 核用电缆无卤阻燃护套料、电缆护套,制备方法和应用 |
CN102952325A (zh) * | 2012-09-20 | 2013-03-06 | 中国科学院上海应用物理研究所 | 无卤无红磷阻燃热收缩材料、热收缩管,制备方法和应用 |
-
2013
- 2013-11-11 CN CN201310556753.6A patent/CN103524885B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4405738A (en) * | 1982-03-05 | 1983-09-20 | Akzona Incorporated | Flame retardant additives and flame retardant polyester compositions |
CN102875947A (zh) * | 2012-09-20 | 2013-01-16 | 中国科学院上海应用物理研究所 | 核用电缆无卤阻燃护套料、电缆护套,制备方法和应用 |
CN102952325A (zh) * | 2012-09-20 | 2013-03-06 | 中国科学院上海应用物理研究所 | 无卤无红磷阻燃热收缩材料、热收缩管,制备方法和应用 |
Non-Patent Citations (2)
Title |
---|
朱红伟等: "聚氨基环磷腈的合成及其在PVA纤维中的应用", 《合成纤维工业》 * |
李永强等: "Ⅱ型聚磷酸铵和赛克对聚丙烯的协同阻燃作用", 《青岛科技大学学报(自然科学版)》 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103951959A (zh) * | 2014-05-20 | 2014-07-30 | 上海电力学院 | 膨胀型阻燃增强pc/abs合金及其制备方法 |
CN104292826A (zh) * | 2014-09-28 | 2015-01-21 | 上海电力学院 | 一种导热塑料及其制备方法 |
CN104928978A (zh) * | 2015-04-02 | 2015-09-23 | 青岛科技大学 | 一种基于六氨基环三磷腈的阻燃纸的制备方法 |
CN107187122A (zh) * | 2017-04-27 | 2017-09-22 | 东营俊富净化科技有限公司 | 一种高效阻燃防护复合材料及其制备方法和应用 |
CN111825971A (zh) * | 2020-07-31 | 2020-10-27 | 鑫宝防水材料股份有限公司 | 一种阻燃隔热特种性能防水卷材及其制备方法 |
CN112724358A (zh) * | 2021-01-22 | 2021-04-30 | 四川大学 | 一种基于改性石墨烯的水性阻燃自修复聚氨酯的制备方法 |
CN112724358B (zh) * | 2021-01-22 | 2021-11-26 | 四川大学 | 一种基于改性石墨烯的水性阻燃自修复聚氨酯的制备方法 |
CN113845725A (zh) * | 2021-10-19 | 2021-12-28 | 青岛塑科高分子科技有限公司 | 一种具有良好耐水性的阻燃聚丙烯材料及其制备方法 |
CN116535864A (zh) * | 2023-07-07 | 2023-08-04 | 山东迈特新材料科技有限公司 | 一种含聚氨基环三磷腈和赛克改性密胺树脂的膨胀型阻燃剂及其制备方法 |
CN116535864B (zh) * | 2023-07-07 | 2023-10-20 | 山东迈特新材料科技有限公司 | 一种含聚氨基环三磷腈和赛克改性密胺树脂的膨胀型阻燃剂及其制备方法 |
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