CN103443199B - 通过开环易位聚合得到的烯烃三嵌段聚合物 - Google Patents

通过开环易位聚合得到的烯烃三嵌段聚合物 Download PDF

Info

Publication number
CN103443199B
CN103443199B CN201280014779.1A CN201280014779A CN103443199B CN 103443199 B CN103443199 B CN 103443199B CN 201280014779 A CN201280014779 A CN 201280014779A CN 103443199 B CN103443199 B CN 103443199B
Authority
CN
China
Prior art keywords
preferred
mol
many block
alkyl
block polyolefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280014779.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN103443199A (zh
Inventor
I·C·斯图尔特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,432 external-priority patent/US8669330B2/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN103443199A publication Critical patent/CN103443199A/zh
Application granted granted Critical
Publication of CN103443199B publication Critical patent/CN103443199B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C08G2261/126—Copolymers block
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3323—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other monocyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201280014779.1A 2011-03-25 2012-03-05 通过开环易位聚合得到的烯烃三嵌段聚合物 Expired - Fee Related CN103443199B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/072,432 US8669330B2 (en) 2011-03-25 2011-03-25 Olefin triblock polymers via ring-opening metathesis polymerization
US13/072,432 2011-03-25
EP11167037 2011-05-23
EP11167037.8 2011-05-23
PCT/US2012/027670 WO2012134713A2 (en) 2011-03-25 2012-03-05 Olefin triblock polymers via ring-opening metathesis polymerization

Publications (2)

Publication Number Publication Date
CN103443199A CN103443199A (zh) 2013-12-11
CN103443199B true CN103443199B (zh) 2016-04-06

Family

ID=46932221

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280014779.1A Expired - Fee Related CN103443199B (zh) 2011-03-25 2012-03-05 通过开环易位聚合得到的烯烃三嵌段聚合物

Country Status (3)

Country Link
EP (1) EP2688954A4 (de)
CN (1) CN103443199B (de)
WO (1) WO2012134713A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110170077B (zh) * 2019-03-26 2021-09-28 南京理工大学 一种聚离子型生物润滑剂及其制备方法
CN111777647A (zh) * 2020-07-31 2020-10-16 山东京博中聚新材料有限公司 一种共轭二烯烃聚合物中碳-碳双键的连续氢化生产装置和方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101180346A (zh) * 2005-03-22 2008-05-14 日本瑞翁株式会社 热塑性树脂，其制造方法和成形材料

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6660809B1 (en) * 1997-02-07 2003-12-09 Exxonmobil Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers
WO2000055218A1 (en) * 1999-03-18 2000-09-21 California Institute Of Technology Novel aba triblock and diblock copolymers and methods of preparing the same
GB0428172D0 (en) * 2004-12-23 2005-01-26 Ici Plc Olefin metathesis polymerisation
JP5666902B2 (ja) * 2007-05-23 2015-02-12 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 反応性基を有するイソタクチックポリスチレン
US8283419B2 (en) * 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101180346A (zh) * 2005-03-22 2008-05-14 日本瑞翁株式会社 热塑性树脂，其制造方法和成形材料

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ABA Triblock Copolymers with a Ring-Opening Metathesis Polymerization/Macromolecular Chain-Transfer Agent Approach;Karen A.Switek et al.;《Journal of Polymer Science:Part A:Polymer Chemistry》;20070201;第45卷(第3期);第362-364页 *
Direct Synthesis of Soluble, End-Functionalized Polyenes and Polyacetylene Block Copolymers;Oren A. Scherman et al.;《Journal of the American Chemical Society》;20030716;第125卷(第8期);第8519页右栏，第8520页左栏 *
Polydispersity-Induced Stabilization of a Disordered Bicontinuous Morphology in ABA Triblock Copolymers;Joan M. Widin et al.;《Mocromolecules》;20101012;第43卷(第19期);第7913页右栏，表1 *

Also Published As

Publication number Publication date
WO2012134713A2 (en) 2012-10-04
WO2012134713A3 (en) 2013-01-31
CN103443199A (zh) 2013-12-11
WO2012134713A8 (en) 2013-04-25
EP2688954A2 (de) 2014-01-29
EP2688954A4 (de) 2014-10-01

Similar Documents

Publication Publication Date Title
CN104428324B (zh) 负载型Salan催化剂
US8669330B2 (en) Olefin triblock polymers via ring-opening metathesis polymerization
CN102066436B (zh) 通过复分解反应进行的烯烃官能化
CN104379679B (zh) 使用改性的Salan催化剂化合物制备的聚α烯烃
CN103443139B (zh) 乙烯基封端的高级烯烃聚合物及其生产方法
CN105377906A (zh) 取代的茂金属催化剂
CN102112499B (zh) 催化剂体系和用于烯烃聚合的方法
CN105814015A (zh) 环戊二烯基取代的Salan催化剂
CN104379680A (zh) 具有长链支化的乙烯基封端的聚烯烃
US8940839B2 (en) Diblock copolymers prepared by cross metathesis
CN107922527A (zh) 用于聚烯烃反应的具有悬垂烯烃的铝烷基
CN103443133B (zh) 来自甲硅烷基化乙烯基封端的大分子单体的嵌段共聚物
CN103443137A (zh) 支化的乙烯基封端的聚合物及其制造方法
CN102482373A (zh) 催化剂体系、烯烃聚合方法和由其制备的聚合物组合物
CN103443132A (zh) 用于生产乙烯基封端的丙烯和乙烯/丙烯大分子单体的增强的催化剂性能
CN105358588A (zh) 使用取代茂金属催化剂的方法和由其得到的产品
CN104428326A (zh) 乙烯基封端聚合物及其制造方法
CN103502281A (zh) 新型催化剂和使用其生产乙烯基封端的聚合物的方法
CN102245650A (zh) 长链支化全同立构聚丙烯的制备
CN107847920A (zh) 包含‑Si‑Si‑桥基的取代的双茚基茂金属催化剂化合物
CN102300889B (zh) 降冰片烯共聚物及其制造方法
CN103443199B (zh) 通过开环易位聚合得到的烯烃三嵌段聚合物
CN103443136B (zh) 通过烯烃易位制备的两亲性嵌段聚合物
CN103987755B (zh) 通过开环交叉复分解的乙烯基封端聚合物的官能化
CN103502282B (zh) 胺官能化的聚烯烃及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160406

Termination date: 20210305