WO2012134713A3 - Olefin triblock polymers via ring-opening metathesis polymerization - Google Patents

Olefin triblock polymers via ring-opening metathesis polymerization Download PDF

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Publication number
WO2012134713A3
WO2012134713A3 PCT/US2012/027670 US2012027670W WO2012134713A3 WO 2012134713 A3 WO2012134713 A3 WO 2012134713A3 US 2012027670 W US2012027670 W US 2012027670W WO 2012134713 A3 WO2012134713 A3 WO 2012134713A3
Authority
WO
WIPO (PCT)
Prior art keywords
opening metathesis
metathesis polymerization
via ring
polymers via
triblock polymers
Prior art date
Application number
PCT/US2012/027670
Other languages
French (fr)
Other versions
WO2012134713A8 (en
WO2012134713A2 (en
Inventor
Ian C. STEWART
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,432 external-priority patent/US8669330B2/en
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to CN201280014779.1A priority Critical patent/CN103443199B/en
Priority to EP12764275.9A priority patent/EP2688954A4/en
Publication of WO2012134713A2 publication Critical patent/WO2012134713A2/en
Publication of WO2012134713A3 publication Critical patent/WO2012134713A3/en
Publication of WO2012134713A8 publication Critical patent/WO2012134713A8/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C08G2261/126—Copolymers block
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3323—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other monocyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-(-C=C-Z-)n-C=C-PO* (I) or PO-(-C-C-Z-)n-C-C-PO* (la) wherein Z is the portion of a cyclic monomer having at least one internal double bond that remains after a ring-opening metathesis reaction; PO and PO* are each independently polyolefins; and n is 1 to 10,000; and a process to produce such comprising contacting an alkene metathesis catalyst with a dimer of vinyl terminated polyolefins, and a cyclic hydrocarbyl monomer comprising at least one internal double bond.
PCT/US2012/027670 2011-03-25 2012-03-05 Olefin triblock polymers via ring-opening metathesis polymerization WO2012134713A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201280014779.1A CN103443199B (en) 2011-03-25 2012-03-05 The alkene triblock polymer obtained by ring-opening metathesis polymerization
EP12764275.9A EP2688954A4 (en) 2011-03-25 2012-03-05 Olefin triblock polymers via ring-opening metathesis polymerization

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,432 US8669330B2 (en) 2011-03-25 2011-03-25 Olefin triblock polymers via ring-opening metathesis polymerization
US13/072,432 2011-03-25
EP11167037 2011-05-23
EP11167037.8 2011-05-23

Publications (3)

Publication Number Publication Date
WO2012134713A2 WO2012134713A2 (en) 2012-10-04
WO2012134713A3 true WO2012134713A3 (en) 2013-01-31
WO2012134713A8 WO2012134713A8 (en) 2013-04-25

Family

ID=46932221

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/027670 WO2012134713A2 (en) 2011-03-25 2012-03-05 Olefin triblock polymers via ring-opening metathesis polymerization

Country Status (3)

Country Link
EP (1) EP2688954A4 (en)
CN (1) CN103443199B (en)
WO (1) WO2012134713A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110170077B (en) * 2019-03-26 2021-09-28 南京理工大学 Polyion type biological lubricant and preparation method thereof
CN111777647A (en) * 2020-07-31 2020-10-16 山东京博中聚新材料有限公司 Continuous hydrogenation production device and method for carbon-carbon double bonds in conjugated diene polymer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6410666B1 (en) * 1999-03-18 2002-06-25 California Institute Of Technology ABA triblock and diblock copolymers and methods of preparing the same
US6750307B2 (en) * 1997-02-07 2004-06-15 Exxon Mobil Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers
US20080234451A1 (en) * 2004-12-23 2008-09-25 Imperial Chemical Industries Plc Olefin Metathesis Polymerisation
US20090318647A1 (en) * 2008-06-20 2009-12-24 Hagadorn John R Olefin Functionalization By Metathesis Reaction

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1862491A4 (en) * 2005-03-22 2009-12-30 Zeon Corp Thermoplastic resin, method for producing same and molding material
JP5666902B2 (en) * 2007-05-23 2015-02-12 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Isotactic polystyrene with reactive groups

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6750307B2 (en) * 1997-02-07 2004-06-15 Exxon Mobil Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers
US6410666B1 (en) * 1999-03-18 2002-06-25 California Institute Of Technology ABA triblock and diblock copolymers and methods of preparing the same
US20080234451A1 (en) * 2004-12-23 2008-09-25 Imperial Chemical Industries Plc Olefin Metathesis Polymerisation
US20090318647A1 (en) * 2008-06-20 2009-12-24 Hagadorn John R Olefin Functionalization By Metathesis Reaction

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2688954A4 *

Also Published As

Publication number Publication date
CN103443199B (en) 2016-04-06
CN103443199A (en) 2013-12-11
EP2688954A4 (en) 2014-10-01
WO2012134713A8 (en) 2013-04-25
WO2012134713A2 (en) 2012-10-04
EP2688954A2 (en) 2014-01-29

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