WO2012134721A3 - Vinyl terminated higher olefin polymers and methods to produce thereof - Google Patents

Vinyl terminated higher olefin polymers and methods to produce thereof Download PDF

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Publication number
WO2012134721A3
WO2012134721A3 PCT/US2012/027690 US2012027690W WO2012134721A3 WO 2012134721 A3 WO2012134721 A3 WO 2012134721A3 US 2012027690 W US2012027690 W US 2012027690W WO 2012134721 A3 WO2012134721 A3 WO 2012134721A3
Authority
WO
WIPO (PCT)
Prior art keywords
higher olefin
vinyl terminated
produce
methods
olefin polymers
Prior art date
Application number
PCT/US2012/027690
Other languages
French (fr)
Other versions
WO2012134721A2 (en
Inventor
Matthew W. Holtcamp
Charles J. Ruff
Donna J. Crowther
John R. Hagadorn
Patrick Brant
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,288 external-priority patent/US8426659B2/en
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to JP2014501094A priority Critical patent/JP5826913B2/en
Priority to CN201280015024.3A priority patent/CN103443139B/en
Priority to EP12764747.7A priority patent/EP2688924A4/en
Publication of WO2012134721A2 publication Critical patent/WO2012134721A2/en
Publication of WO2012134721A3 publication Critical patent/WO2012134721A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Abstract

This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
PCT/US2012/027690 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof WO2012134721A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2014501094A JP5826913B2 (en) 2011-03-25 2012-03-05 Vinyl-terminated higher olefin polymer and process for producing the same
CN201280015024.3A CN103443139B (en) 2011-03-25 2012-03-05 The higher olefin polymer of ethenyl blocking and production method thereof
EP12764747.7A EP2688924A4 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,288 2011-03-25
US13/072,288 US8426659B2 (en) 2011-03-25 2011-03-25 Vinyl terminated higher olefin polymers and methods to produce thereof
EP11167033 2011-05-23
EP111670337 2011-05-23

Publications (2)

Publication Number Publication Date
WO2012134721A2 WO2012134721A2 (en) 2012-10-04
WO2012134721A3 true WO2012134721A3 (en) 2012-11-29

Family

ID=46932228

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/027690 WO2012134721A2 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof

Country Status (5)

Country Link
EP (1) EP2688924A4 (en)
JP (1) JP5826913B2 (en)
CN (1) CN103443139B (en)
TW (1) TWI460193B (en)
WO (1) WO2012134721A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014120478A1 (en) * 2013-01-30 2014-08-07 Exxonmobil Chemical Patents Inc. Polyethylene copolymers with vinyl terminated macromonomers as comonomers
KR101757370B1 (en) 2015-06-01 2017-07-12 주식회사 엘지화학 1-Octene composition
WO2017097571A1 (en) * 2015-12-09 2017-06-15 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
SG11201901900SA (en) * 2016-10-05 2019-04-29 Exxonmobil Chemical Patents Inc Sterically hindered metallocenes, synthesis and use
EP3710499A1 (en) * 2017-11-13 2020-09-23 ExxonMobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
WO2020060692A2 (en) * 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimer and apparatus therefor
CN114845980A (en) * 2019-10-28 2022-08-02 埃克森美孚化学专利公司 Dimer-selective metallocene catalyst, non-aromatic hydrocarbon soluble activator and method for preparing poly alpha-olefin oligomer using the same
WO2022069411A1 (en) * 2020-09-30 2022-04-07 Borealis Ag Ethylene-octene copolymers with improved property profile
WO2023190212A1 (en) * 2022-03-30 2023-10-05 三井化学株式会社 Method for producing olefin polymer

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US20090318644A1 (en) * 2008-06-20 2009-12-24 Patrick Brant High Vinyl Terminated Propylene Based Oligomers

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3772331D1 (en) 1986-11-13 1991-09-26 Idemitsu Kosan Co METHOD FOR OLIGOMERIZING PROPEN.
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
DE69018376T3 (en) 1989-10-30 2002-05-16 Fina Technology Manufacture of metallocene catalysts for olefin polymerization.
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
WO1992001723A1 (en) 1990-07-24 1992-02-06 Mitsui Toatsu Chemicals, Incorporated CATALYST FOR α-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY-α-OLEFIN THEREWITH
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
DE69332811T2 (en) 1992-07-01 2004-01-29 Exxonmobil Chem Patents Inc Catalyst precursors based on Group 5 and 6 transition metals
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
DE69513822T2 (en) * 1994-06-09 2000-06-21 Infineum Usa Lp DILUTION PROCESS FOR THE POLYMERIZATION OF NON-ETHYLENE-ALPHA-OLEFIN HOMO- AND COPOLYMERS USING METALLOCEN-CATALYST SYSTEMS
EP0728773B1 (en) 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
JP2001511214A (en) * 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク Preparation of vinyl-containing macromers
US6130357A (en) 1997-04-03 2000-10-10 Colorado State University Research Foundation Polyhalogenated monoheteroborane anion compositions
JP4728643B2 (en) * 2002-10-02 2011-07-20 ダウ グローバル テクノロジーズ エルエルシー Liquid and gel-like low molecular weight ethylene polymers
WO2004050724A1 (en) * 2002-12-04 2004-06-17 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
JPWO2006028169A1 (en) * 2004-09-10 2008-05-08 三井化学株式会社 Viscosity modifier for lubricating oil, additive composition for lubricating oil, and lubricating oil composition
EP2288630B1 (en) 2008-06-20 2013-05-08 ExxonMobil Chemical Patents Inc. High vinyl terminated propylene based oligomers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US20090318644A1 (en) * 2008-06-20 2009-12-24 Patrick Brant High Vinyl Terminated Propylene Based Oligomers

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
LIU, Z. ET AL.: "Kinetics of Initiation, Propagation, and Termination for the [rac-(C2H4(1-indenyl)2)ZrMe][MeB(C6F5)3]-Catalyzed Polymerization of 1-Hexene.", J. AM. CHEM. SOC., vol. 123, 2001, pages 11193 - 11207, XP055125935 *
See also references of EP2688924A4 *
XU, G. ET AL.: "Ethylene Copolymerization with 1-Octene Using a 2-Methylbenz[e]indenyl-Based ansa-Monocyclopentadienylamido Complex and Methylaluminoxane Catalyst.", MACROMOLECULES, vol. 31, 1998, pages 4724 - 4729, XP000769970 *

Also Published As

Publication number Publication date
CN103443139A (en) 2013-12-11
EP2688924A2 (en) 2014-01-29
WO2012134721A2 (en) 2012-10-04
TWI460193B (en) 2014-11-11
CN103443139B (en) 2016-10-12
EP2688924A4 (en) 2015-02-25
JP5826913B2 (en) 2015-12-02
TW201300431A (en) 2013-01-01
JP2014511912A (en) 2014-05-19

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