EP2688924A4 - Vinyl terminated higher olefin polymers and methods to produce thereof - Google Patents

Vinyl terminated higher olefin polymers and methods to produce thereof

Info

Publication number
EP2688924A4
EP2688924A4 EP12764747.7A EP12764747A EP2688924A4 EP 2688924 A4 EP2688924 A4 EP 2688924A4 EP 12764747 A EP12764747 A EP 12764747A EP 2688924 A4 EP2688924 A4 EP 2688924A4
Authority
EP
European Patent Office
Prior art keywords
produce
methods
olefin polymers
vinyl terminated
higher olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP12764747.7A
Other languages
German (de)
French (fr)
Other versions
EP2688924A2 (en
Inventor
Matthew W Holtcamp
Charles J Ruff
Donna J Crowther
John R Hagadorn
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,288 external-priority patent/US8426659B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP12764747.7A priority Critical patent/EP2688924A4/en
Publication of EP2688924A2 publication Critical patent/EP2688924A2/en
Publication of EP2688924A4 publication Critical patent/EP2688924A4/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP12764747.7A 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof Ceased EP2688924A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12764747.7A EP2688924A4 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,288 US8426659B2 (en) 2011-03-25 2011-03-25 Vinyl terminated higher olefin polymers and methods to produce thereof
EP11167033 2011-05-23
EP12764747.7A EP2688924A4 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof
PCT/US2012/027690 WO2012134721A2 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof

Publications (2)

Publication Number Publication Date
EP2688924A2 EP2688924A2 (en) 2014-01-29
EP2688924A4 true EP2688924A4 (en) 2015-02-25

Family

ID=46932228

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12764747.7A Ceased EP2688924A4 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof

Country Status (5)

Country Link
EP (1) EP2688924A4 (en)
JP (1) JP5826913B2 (en)
CN (1) CN103443139B (en)
TW (1) TWI460193B (en)
WO (1) WO2012134721A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104968693B (en) * 2013-01-30 2017-10-17 埃克森美孚化学专利公司 Macromonomer containing ethenyl blocking as comonomer polyethylene and ethylene copolymers
KR101757370B1 (en) 2015-06-01 2017-07-12 주식회사 엘지화학 1-Octene composition
WO2017097571A1 (en) * 2015-12-09 2017-06-15 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains
CN109790240A (en) * 2016-10-05 2019-05-21 埃克森美孚化学专利公司 Steric hindrance metallocene, synthesis and purposes
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
CN111344316B (en) * 2017-11-13 2023-02-03 埃克森美孚化学专利公司 Polyethylene compositions and articles made therefrom
CN113015755B (en) * 2018-09-17 2023-09-08 埃克森美孚化学专利公司 Metallocene dimer selective catalyst and process for preparing poly alpha-olefin dimer
WO2021086926A1 (en) * 2019-10-28 2021-05-06 Exxonmobil Chemical Patents Inc. Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith
CA3196746A1 (en) * 2020-09-30 2022-04-07 Borealis Ag Ethylene-octene copolymers with improved property profile
WO2023190212A1 (en) * 2022-03-30 2023-10-05 三井化学株式会社 Method for producing olefin polymer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004031250A1 (en) * 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers

Family Cites Families (28)

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EP0268214B1 (en) 1986-11-13 1991-08-21 Idemitsu Kosan Company Limited Process for producing propylene oligomers
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
EP0426637B2 (en) 1989-10-30 2001-09-26 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
JP3115595B2 (en) 1990-07-24 2000-12-11 三井化学株式会社 Polymerization catalyst for α-olefin and method for producing poly-α-olefin using the same
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
DE69326463T2 (en) 1992-07-01 2000-05-04 Exxon Chemical Patents Inc OLEFIN POLYMERIZATION CATALYSTS BASED ON TRANSITIONAL METALS
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
JPH10501288A (en) * 1994-06-09 1998-02-03 エクソン ケミカル パテンツ インコーポレイテッド Dilution polymerization method of non-ethylene α-olefin homopolymer and copolymer using metallocene catalyst system
DE69600892T2 (en) 1995-02-21 1999-04-01 Mitsubishi Chem Corp Catalysts for olefin polymerization and process for producing olefin polymers obtained therewith
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
ES2277381T5 (en) * 1997-02-07 2014-02-06 Exxonmobil Chemical Patents Inc. Preparation of vinyl containing macromers
IL132189A (en) 1997-04-03 2003-10-31 Univ Colorado State Res Found Polyhalogenated monoheteroborane anion compositions
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60318616T2 (en) * 2002-12-04 2009-01-08 Basell Polyolefine Gmbh PROCESS FOR PREPARING 1-BUTENE POLYMERS
CA2579879C (en) * 2004-09-10 2011-04-12 Mitsui Chemicals, Inc. Ethylene/.alpha.- olefin copolymer for use as viscosity modifier
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
WO2009155471A2 (en) 2008-06-20 2009-12-23 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
WO2004031250A1 (en) * 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
See also references of WO2012134721A2 *
XU G ET AL: "ETHYLENE COPOLYMERIZATION WITH 1-OCTENE USING A 2-METHYLBENZÚE 3/4 INDENYL-BASED ANSA-MONOCYCLOPENTADIENYLAMIDO COMPLEX AND METHYLALUMINOXANES CATALYST", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 31, no. 15, 28 July 1998 (1998-07-28), pages 4724 - 4729, XP000769970, ISSN: 0024-9297, DOI: 10.1021/MA980498D *
ZHIXIAN LIU ET AL: "Kinetics of Initiation, Propagation, and Termination for the [ rac -(C 2 H 4 (1-indenyl) 2 )ZrMe][MeB(C 6 F 5 ) 3 ]-Catalyzed Polymerization of 1-Hexene", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 123, no. 45, 1 November 2001 (2001-11-01), pages 11193 - 11207, XP055125935, ISSN: 0002-7863, DOI: 10.1021/ja016072n *

Also Published As

Publication number Publication date
TWI460193B (en) 2014-11-11
JP2014511912A (en) 2014-05-19
WO2012134721A3 (en) 2012-11-29
TW201300431A (en) 2013-01-01
CN103443139A (en) 2013-12-11
CN103443139B (en) 2016-10-12
JP5826913B2 (en) 2015-12-02
WO2012134721A2 (en) 2012-10-04
EP2688924A2 (en) 2014-01-29

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