CN103443143B - 产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法 - Google Patents

产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法 Download PDF

Info

Publication number
CN103443143B
CN103443143B CN201280005871.1A CN201280005871A CN103443143B CN 103443143 B CN103443143 B CN 103443143B CN 201280005871 A CN201280005871 A CN 201280005871A CN 103443143 B CN103443143 B CN 103443143B
Authority
CN
China
Prior art keywords
group
silyl
catalyst
olefin
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280005871.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN103443143A (zh
Inventor
加里·伯恩斯
F·德比耶
P-F·傅
图斌·J·马克斯
瓦莱丽·斯米茨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northwest University
Dow Silicones Corp
Original Assignee
NORTHWEST UNIVERSITY
Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NORTHWEST UNIVERSITY, Dow Corning Corp filed Critical NORTHWEST UNIVERSITY
Publication of CN103443143A publication Critical patent/CN103443143A/zh
Application granted granted Critical
Publication of CN103443143B publication Critical patent/CN103443143B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
    • C08J2343/04—Homopolymers or copolymers of monomers containing silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201280005871.1A 2011-01-19 2012-01-17 产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法 Active CN103443143B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161434228P 2011-01-19 2011-01-19
US61/434,228 2011-01-19
PCT/US2012/021558 WO2012099882A2 (en) 2011-01-19 2012-01-17 Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation

Publications (2)

Publication Number Publication Date
CN103443143A CN103443143A (zh) 2013-12-11
CN103443143B true CN103443143B (zh) 2017-08-04

Family

ID=45582035

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280005871.1A Active CN103443143B (zh) 2011-01-19 2012-01-17 产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法

Country Status (7)

Country Link
US (1) US9388265B2 (enExample)
EP (1) EP2665756B1 (enExample)
JP (1) JP2014508198A (enExample)
KR (1) KR101828586B1 (enExample)
CN (1) CN103443143B (enExample)
BR (1) BR112013018574A2 (enExample)
WO (1) WO2012099882A2 (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016205642A1 (en) 2015-06-19 2016-12-22 Dow Corning Corporation Process for preparing an acryloyloyloxysilane
CN105777950B (zh) * 2016-03-29 2018-06-22 沈阳化工大学 一种溶液法硅烷接枝改性三元乙丙橡胶的制备方法
EP3255759A1 (en) * 2016-06-10 2017-12-13 Goodrich Control Systems Stator assembly
CN107973870A (zh) * 2016-10-25 2018-05-01 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法
US11078335B2 (en) 2017-07-25 2021-08-03 Dow Silicones Corporation Method for preparing a graft copolymer with a polyolefin backbone and polyorganosiloxane pendant groups
US10620999B2 (en) * 2017-11-08 2020-04-14 Western Digital Technologies, Inc Task scheduling through an operating system agnostic system abstraction layer from a top of the rack switch in a hyper converged infrastructure
CN108329415B (zh) * 2018-02-07 2020-10-27 中国科学技术大学 一种硅功能化聚烯烃及其制备方法
WO2019182719A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof
JP7378411B2 (ja) 2018-03-19 2023-11-13 ダウ シリコーンズ コーポレーション ポリオレフィン－ポリジオルガノシロキサンブロックコポリマーおよびその合成のための加水分解反応方法
JP7378416B2 (ja) 2018-03-19 2023-11-13 ダウ シリコーンズ コーポレーション ポリオレフィン－ポリジオルガノシロキサンブロックコポリマーおよびその合成のための方法
JP2021518460A (ja) 2018-03-19 2021-08-02 ダウ シリコーンズ コーポレーション ポリオレフィン−ポリジオルガノシロキサンコポリマーを含有するホットメルト接着剤組成物ならびにその調製方法および使用方法
JP7067229B2 (ja) * 2018-04-17 2022-05-16 信越化学工業株式会社 反応性ケイ素含有基を有するポリマーおよびその製造方法
JP7334195B2 (ja) 2018-07-17 2023-08-28 ダウ シリコーンズ コーポレーション ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法
EP4045560A1 (en) 2019-10-14 2022-08-24 3M Innovative Properties Company Compositions comprising cyclic olefins and thermally conductive filler
US20220380628A1 (en) * 2019-10-14 2022-12-01 3M Innovative Properties Company Methods, Articles and Adhesive Composition Comprising Unpolymerized Cyclic Olefin, Catalyst, and Adhesion Promoter Polymer
WO2021119437A1 (en) 2019-12-13 2021-06-17 Dow Silicones Corporation Processes for synthesizing unsymmetrical disiloxanes
KR20220120600A (ko) 2019-12-20 2022-08-30 쓰리엠 이노베이티브 프로퍼티즈 캄파니 중합체 및 중합성 환형 올레핀을 포함하는 접착제 물품, 접착제 조성물 및 방법
CN116157457A (zh) * 2020-06-24 2023-05-23 陶氏环球技术有限责任公司 烯烃/硅烷互聚物的固化和官能化
US20230265222A1 (en) 2020-06-24 2023-08-24 Dow Global Technologies Llc Olefin/siloxane interpolymers and olefin/cyclic silane interpolymers

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240768A (en) * 1961-06-09 1966-03-15 Exxon Research Engineering Co Copolymers of alpha olefin and reactive omega alkenyl silanes
GB1415194A (en) * 1972-03-23 1975-11-26 Dow Corning Ltd Preparation of copolymers containing silicon
EP0321258A2 (en) * 1987-12-16 1989-06-21 MITSUI TOATSU CHEMICALS, Inc. Use of a copolymer alpha olefin alkenylsilane for bonding two layers or for coating an article
WO1992005226A1 (en) * 1990-09-19 1992-04-02 Minnesota Mining And Manufacturing Company Moisture-curable polyolefin pressure-sensitive adhesives
WO2005035600A1 (en) * 2003-10-08 2005-04-21 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
WO2010074920A1 (en) * 2008-12-23 2010-07-01 Dow Global Technologies Inc. Catalyst system for moisture cure of ethylene-vinylsilane copolymers

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3179612A (en) 1962-02-02 1965-04-20 Dow Corning alpha, beta-unsaturated carboxylicester-substituted organosilicon compounds
US3225018A (en) 1961-12-15 1965-12-21 Union Carbide Corp Heat curing of ethylene/vinylsilane copolymers
US3258477A (en) 1963-07-19 1966-06-28 Dow Corning Acryloxyalkylsilanes and compositions thereof
US4413066A (en) 1978-07-05 1983-11-01 Mitsubishi Petrochemical Company, Ltd. Crosslinkable polyethylene resin compositions
JPS5695940A (en) 1979-12-28 1981-08-03 Mitsubishi Petrochem Co Ltd Ethylene polymer composition
JPS57207632A (en) 1981-06-16 1982-12-20 Mitsubishi Petrochem Co Ltd Crosslinkable polyethylene resin composition
US4946977A (en) 1987-09-25 1990-08-07 Huels Troisdorf Ag Method for the preparation of organosilanes containing methacryloxy or acryloxy groups
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP3024685B2 (ja) * 1989-11-28 2000-03-21 三井化学株式会社 α―オレフィン―アルケニルシラン共重合体およびその製造方法
US5763556A (en) * 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US5905150A (en) 1997-08-27 1999-05-18 General Electric Company Process for preparing organosilanes
US6624254B1 (en) 1999-01-21 2003-09-23 The Dow Chemical Company Silane functionalized olefin interpolymer derivatives
PL188756B1 (pl) 1999-05-23 2005-04-29 Univ Adama Mickiewicza Sposób otrzymywania winylosiloksanowych kompleksów niklu(O)
KR100656109B1 (ko) * 1999-07-29 2006-12-12 다우 글로벌 테크놀로지스 인크. 개선된 실란 관능화 올레핀 인터폴리머 및 이의 유도체
DE10159859C1 (de) 2001-12-06 2003-01-16 Fraunhofer Ges Forschung Verfahren zur Herstellung von Styryl-funktionalisierten Silanen
US6838539B2 (en) * 2002-02-12 2005-01-04 Bridgestone Corporation Cureable silane functionalized sealant composition and manufacture of same
DE10308579B3 (de) 2003-02-27 2004-06-24 Wacker-Chemie Gmbh Verfahren zur Stabilisierung ungesättigter Organosiliziumverbindungen
JP2005314246A (ja) 2004-04-27 2005-11-10 Dow Corning Toray Co Ltd エステル官能性基含有オルガノアルコキシシランの製造方法
US7531588B2 (en) 2004-07-30 2009-05-12 Momentive Performance Materials Inc. Silane compositions, processes for their preparation and rubber compositions containing same
DE602006001583D1 (de) 2006-04-26 2008-08-07 Borealis Tech Oy Vernetzbare Polyolefinzusammensetzung enthaltend hochmolekuaren Silanolkondensationskatalysator
JP4735550B2 (ja) 2007-01-19 2011-07-27 株式会社デンソー スペクトル拡散通信システムの受信機におけるコード相関処理方法
JP2009120810A (ja) * 2007-10-25 2009-06-04 Nara Institute Of Science & Technology メタロセン系重合触媒およびこれを用いたα−オレフィン−アルケニルシラン共重合体の製造方法
GB0812185D0 (en) 2008-07-03 2008-08-13 Dow Corning Polymers modified by silanes
GB0812186D0 (en) 2008-07-03 2008-08-13 Dow Corning Modified polyolefins

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240768A (en) * 1961-06-09 1966-03-15 Exxon Research Engineering Co Copolymers of alpha olefin and reactive omega alkenyl silanes
GB1415194A (en) * 1972-03-23 1975-11-26 Dow Corning Ltd Preparation of copolymers containing silicon
EP0321258A2 (en) * 1987-12-16 1989-06-21 MITSUI TOATSU CHEMICALS, Inc. Use of a copolymer alpha olefin alkenylsilane for bonding two layers or for coating an article
WO1992005226A1 (en) * 1990-09-19 1992-04-02 Minnesota Mining And Manufacturing Company Moisture-curable polyolefin pressure-sensitive adhesives
WO2005035600A1 (en) * 2003-10-08 2005-04-21 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
WO2010074920A1 (en) * 2008-12-23 2010-07-01 Dow Global Technologies Inc. Catalyst system for moisture cure of ethylene-vinylsilane copolymers

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris( pentafluoropheny1)borane. A Synthetic, Structural, Solution Dynamic, and Polymerization;Yang Xinmin et al.;《Journal of the American Chemical Society》;19940901;第116卷;第10015-10031页 *
Constrained Geometry" Dialkyl Catalysts. Efficient Syntheses, C-H Bond Activation Chemistry,Monomer-Dimer Equilibration，and α-Olefin Polymerization Catalysis;Chen You-Xian et al.;《Organometallics》;19970701;第16卷;第3649-3657页 *
Ethene and Propene Copolymers Containing Silsesquioxane Side Groups;Akira Tsuchida et al.;《Macromolecules》;19970501;第30卷;第2818-2824页 *
Metallocene Polymerization Catalyst Ion-Pair Aggregation by Cryoscopy and Pulsed Field Gradient Spin-Echo NMR Diffusion Measurements;Nicholas G. Stahl et al.;《Journal of the American Chemical Society》;20031230;第125卷(第18期);第5256-5257页 *
NOE and PGSE NMR Spectroscopic Studies of Solution Structure and Aggregation in Metallocenium Ion-Pairs;Cristiano Zuccaccia et al.;《Journal of the American Chemical Society》;20041230;第126卷;第1448-1464页 *

Also Published As

Publication number Publication date
EP2665756A2 (en) 2013-11-27
BR112013018574A2 (pt) 2016-09-27
US20140011900A1 (en) 2014-01-09
EP2665756B1 (en) 2022-03-30
CN103443143A (zh) 2013-12-11
KR20140018231A (ko) 2014-02-12
WO2012099882A2 (en) 2012-07-26
KR101828586B1 (ko) 2018-02-13
US9388265B2 (en) 2016-07-12
JP2014508198A (ja) 2014-04-03
WO2012099882A3 (en) 2012-09-13

Similar Documents

Publication Publication Date Title
CN103443143B (zh) 产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法
FI112234B (fi) Katalyyttikoostumuksia ja menetelmä polyolefiinien valmistamiseksi
Galan-Fereres et al. Synthesis and olefin polymerization using supported and non-supported geometry constrained titanium complexes
CN105473601B (zh) 茂金属化合物、包含其的催化剂组合物及使用其制备烯烃聚合物的方法
CN105452268A (zh) 茂金属化合物、包含其的催化剂组合物以及使用其制备烯烃聚合物的方法
CN114401977B (zh) 过渡金属化合物和包含该化合物的催化剂组合物
CN104254547B (zh) 用于聚烯烃聚合的催化剂的制备方法和聚烯烃的制备方法
KR101958015B1 (ko) 에틸렌/알파-올레핀 공중합체
EP3312201B1 (en) Supported hybrid catalyst and method for preparing olefin polymer using the same
CN113631594B (zh) 杂化负载型茂金属催化剂以及使用其制备聚丙烯的方法
US10280238B2 (en) Transition metal compound, catalyst composition comprising same, and method for producing olefin polymer using same
JP2002538237A (ja) メタロセン化合物及びこれを利用したオレフィン重合
CN106795229B (zh) 金属茂-负载型催化剂以及使用该催化剂制备聚烯烃的方法
JP2003246820A (ja) プロピレン−アルケニルジアルキルアルミニウム共重合体
CN113039218A (zh) 用于丙烯聚合的负载催化剂及利用它的聚丙烯树脂制备方法
US12098158B2 (en) Transition metal compound, catalyst composition and method for preparing polypropylene using the same
CN106661072A (zh) 金属茂化合物、包含其的催化剂组合物以及使用其制备基于烯烃的聚合物的方法
WO2016186295A1 (ko) 혼성 담지 촉매계, 및 이를 이용한 폴리올레핀의 제조방법
KR20170075529A (ko) 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
JPH05502266A (ja) オイゲノールのシリル誘導体
WO2023124896A1 (zh) 硅烷类化合物、催化剂组合物及其制备方法和应用
CN113614124A (zh) 复合负载型茂金属催化剂以及使用其制备聚乙烯共聚物的方法
CN111433237B (zh) 丙烯无规共聚物
CN117222677A (zh) 1,3-二烯与乙烯的官能共聚物或者1,3-二烯、乙烯与α-单烯烃的官能共聚物
JPH11222505A (ja) 共重合体の製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: michigan

Co-patentee after: Northwest University

Patentee after: Dow organosilicon company

Address before: michigan

Co-patentee before: Northwest University

Patentee before: Dow Corning