BR112013018574A2 - método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila - Google Patents

método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila

Info

Publication number
BR112013018574A2
BR112013018574A2 BR112013018574A BR112013018574A BR112013018574A2 BR 112013018574 A2 BR112013018574 A2 BR 112013018574A2 BR 112013018574 A BR112013018574 A BR 112013018574A BR 112013018574 A BR112013018574 A BR 112013018574A BR 112013018574 A2 BR112013018574 A2 BR 112013018574A2
Authority
BR
Brazil
Prior art keywords
silyl
functionalized polyolefins
producing
silyl functionalized
monomer incorporation
Prior art date
Application number
BR112013018574A
Other languages
English (en)
Inventor
François De Buyl
Gary Burns
Peng-Fei Fu
Tobin J Marks
Valerie Smits
Original Assignee
Dow Corning
Univ Northwestern
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning, Univ Northwestern filed Critical Dow Corning
Publication of BR112013018574A2 publication Critical patent/BR112013018574A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
    • C08J2343/04—Homopolymers or copolymers of monomers containing silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila a presente invenção refere-se a métodos para a produção de um poliolefina funcionalizada por silila com incorporação de monômero de silila. o método inclui reagir uma olefina contendo silício com uma <244>-olefina, na presença de uma quantidade catalítica de um catalisador de grupo iv durante tempo suficiente para a produção de uma poliolefina funcionalizada por silila.
BR112013018574A 2011-01-19 2012-01-17 método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila BR112013018574A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161434228P 2011-01-19 2011-01-19
PCT/US2012/021558 WO2012099882A2 (en) 2011-01-19 2012-01-17 Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation

Publications (1)

Publication Number Publication Date
BR112013018574A2 true BR112013018574A2 (pt) 2016-09-27

Family

ID=45582035

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013018574A BR112013018574A2 (pt) 2011-01-19 2012-01-17 método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila

Country Status (7)

Country Link
US (1) US9388265B2 (pt)
EP (1) EP2665756B1 (pt)
JP (1) JP2014508198A (pt)
KR (1) KR101828586B1 (pt)
CN (1) CN103443143B (pt)
BR (1) BR112013018574A2 (pt)
WO (1) WO2012099882A2 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6697009B2 (ja) 2015-06-19 2020-05-20 ダウ シリコーンズ コーポレーション アクリロイルオキシシランの調製プロセス
CN105777950B (zh) * 2016-03-29 2018-06-22 沈阳化工大学 一种溶液法硅烷接枝改性三元乙丙橡胶的制备方法
EP3255759A1 (en) * 2016-06-10 2017-12-13 Goodrich Control Systems Stator assembly
CN107973870A (zh) * 2016-10-25 2018-05-01 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法
JP7256169B2 (ja) 2017-07-25 2023-04-11 ダウ シリコーンズ コーポレーション ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法
US10620999B2 (en) * 2017-11-08 2020-04-14 Western Digital Technologies, Inc Task scheduling through an operating system agnostic system abstraction layer from a top of the rack switch in a hyper converged infrastructure
CN108329415B (zh) * 2018-02-07 2020-10-27 中国科学技术大学 一种硅功能化聚烯烃及其制备方法
CA3093558A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof
EP3768792B1 (en) 2018-03-19 2023-09-20 Dow Silicones Corporation Hot melt adhesive composition containing a polyolefin - polydiorganosiloxane copolymer and methods for the preparation and use thereof
KR20200133349A (ko) 2018-03-19 2020-11-27 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 - 폴리디오르가노실록산 블록 공중합체 및 이의 합성을 위한 히드로실릴화 반응 방법
JP7067229B2 (ja) * 2018-04-17 2022-05-16 信越化学工業株式会社 反応性ケイ素含有基を有するポリマーおよびその製造方法
CN112334515B (zh) 2018-07-17 2022-08-09 美国陶氏有机硅公司 聚硅氧烷树脂-聚烯烃共聚物及其制备和使用方法
CN114514302A (zh) * 2019-10-14 2022-05-17 3M创新有限公司 包含未聚合的环状烯烃、催化剂和粘合增进剂聚合物的方法、制品和粘合剂组合物
WO2021262774A1 (en) 2020-06-24 2021-12-30 Dow Global Technologies Llc Olefin/siloxane interpolymers and olefin/cyclic silane interpolymers

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240768A (en) 1961-06-09 1966-03-15 Exxon Research Engineering Co Copolymers of alpha olefin and reactive omega alkenyl silanes
US3179612A (en) 1962-02-02 1965-04-20 Dow Corning alpha, beta-unsaturated carboxylicester-substituted organosilicon compounds
US3225018A (en) 1961-12-15 1965-12-21 Union Carbide Corp Heat curing of ethylene/vinylsilane copolymers
US3258477A (en) 1963-07-19 1966-06-28 Dow Corning Acryloxyalkylsilanes and compositions thereof
GB1415194A (en) * 1972-03-23 1975-11-26 Dow Corning Ltd Preparation of copolymers containing silicon
US4413066A (en) 1978-07-05 1983-11-01 Mitsubishi Petrochemical Company, Ltd. Crosslinkable polyethylene resin compositions
JPS5695940A (en) 1979-12-28 1981-08-03 Mitsubishi Petrochem Co Ltd Ethylene polymer composition
JPS57207632A (en) 1981-06-16 1982-12-20 Mitsubishi Petrochem Co Ltd Crosslinkable polyethylene resin composition
US4946977A (en) 1987-09-25 1990-08-07 Huels Troisdorf Ag Method for the preparation of organosilanes containing methacryloxy or acryloxy groups
CA1312166C (en) 1987-12-16 1992-12-29 Mitsui Chemicals, Incorporated Polyolefin resin composition
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP3024685B2 (ja) * 1989-11-28 2000-03-21 三井化学株式会社 α―オレフィン―アルケニルシラン共重合体およびその製造方法
EP0549646B1 (en) 1990-09-19 1997-06-18 Minnesota Mining And Manufacturing Company Moisture-curable polyolefin pressure-sensitive adhesives
US5763556A (en) * 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US5905150A (en) 1997-08-27 1999-05-18 General Electric Company Process for preparing organosilanes
US6624254B1 (en) 1999-01-21 2003-09-23 The Dow Chemical Company Silane functionalized olefin interpolymer derivatives
PL188756B1 (pl) 1999-05-23 2005-04-29 Univ Adama Mickiewicza Sposób otrzymywania winylosiloksanowych kompleksów niklu(O)
KR100656109B1 (ko) 1999-07-29 2006-12-12 다우 글로벌 테크놀로지스 인크. 개선된 실란 관능화 올레핀 인터폴리머 및 이의 유도체
DE10159859C1 (de) 2001-12-06 2003-01-16 Fraunhofer Ges Forschung Verfahren zur Herstellung von Styryl-funktionalisierten Silanen
US6838539B2 (en) 2002-02-12 2005-01-04 Bridgestone Corporation Cureable silane functionalized sealant composition and manufacture of same
DE10308579B3 (de) 2003-02-27 2004-06-24 Wacker-Chemie Gmbh Verfahren zur Stabilisierung ungesättigter Organosiliziumverbindungen
US6936671B2 (en) * 2003-10-08 2005-08-30 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
JP2005314246A (ja) 2004-04-27 2005-11-10 Dow Corning Toray Co Ltd エステル官能性基含有オルガノアルコキシシランの製造方法
US7531588B2 (en) 2004-07-30 2009-05-12 Momentive Performance Materials Inc. Silane compositions, processes for their preparation and rubber compositions containing same
EP1849816B1 (en) 2006-04-26 2008-06-25 Borealis Technology Oy Crosslinkable polyolefin composition comprising high molecular weight silanol condensation catalyst
JP4735550B2 (ja) 2007-01-19 2011-07-27 株式会社デンソー スペクトル拡散通信システムの受信機におけるコード相関処理方法
JP2009120810A (ja) 2007-10-25 2009-06-04 Nara Institute Of Science & Technology メタロセン系重合触媒およびこれを用いたα−オレフィン−アルケニルシラン共重合体の製造方法
GB0812185D0 (en) 2008-07-03 2008-08-13 Dow Corning Polymers modified by silanes
GB0812186D0 (en) 2008-07-03 2008-08-13 Dow Corning Modified polyolefins
JP5331900B2 (ja) 2008-12-23 2013-10-30 ダウ グローバル テクノロジーズ エルエルシー エチレン−ビニルシランコポリマーの湿分硬化用触媒系

Also Published As

Publication number Publication date
US20140011900A1 (en) 2014-01-09
CN103443143B (zh) 2017-08-04
US9388265B2 (en) 2016-07-12
WO2012099882A2 (en) 2012-07-26
EP2665756B1 (en) 2022-03-30
WO2012099882A3 (en) 2012-09-13
KR101828586B1 (ko) 2018-02-13
EP2665756A2 (en) 2013-11-27
KR20140018231A (ko) 2014-02-12
CN103443143A (zh) 2013-12-11
JP2014508198A (ja) 2014-04-03

Similar Documents

Publication Publication Date Title
BR112013018574A2 (pt) método para produção de poliolefinas funcionalizadas por silila e poliolefinas funcionalizadas por silila com incorporação de monômero de silila
MX2014000716A (es) Metodos para la sintesis de acidos nucleicos funcionalizados.
BRPI0918697A8 (pt) Processo para melhorar as propriedades de um procatalisador e composição de procatalisador
BR112013009078A2 (pt) produção de alquenos por conversão enzimática combinada de ácidos 3-hidroxialcanoicos
BRPI1013355A2 (pt) processo para a produção de copolímeros de acetato de vinila-etileno por meio de polimerização em emulsão
MX356337B (es) Anticuerpos contra csf-1r humano y sus usos.
EA201590172A1 (ru) ИММУНОКОНЪЮГАТЫ, СОДЕРЖАЩИЕ АНТИТЕЛА К CD79b
EA201291029A1 (ru) Высокотекучий длинноцепочечный разветвленный полипропилен
BR112014024493A2 (pt) método para a produção enzimática de isoprenol usando mevalonato como substrato
MX2014005897A (es) Asociacion de productos de polimeros hidrofobicos amino funcionales con polimeros hidrofilicos que contienen grupos acido, metodos de preparacion y aplicaciones para emplear los mismos.
BR112012017051A2 (pt) método para diminuir a imunogenicidade
FR2978961B1 (fr) Procede pour une production d&#39;hydrogene a partir de biogaz
MA37384A1 (fr) Nouveaux dérivés de thiénopyrimidine, leurs procédés de préparation et leurs utilisations thérapeutiques.
BR112013006473A2 (pt) processo de uma etapa, um recipiente para preparar um copolímero gradiente e multibloco
BRPI0720610A8 (pt) Processo de produção de uma poliolefina, poliolefina e 1-hexeno para ser usado como matéria-prima na produção de polietileno linear de baixa densidade
SG11201403338UA (en) Catalyst for the synthesis of alkyl mercaptans and process for producing it
BR112014009499A2 (pt) métodos para produzir autigênicos de rocha mineral para alterar a hidrologia da rocha
FR2994432B1 (fr) Procede d&#39;obtention d&#39;une composition riche en luteine produite par des microalgues
FR2987356B1 (fr) Formation de nanoparticules d&#39;antimoniures a partir du trihydrure d&#39;antimoine comme source d&#39;antimoine.
EA201590436A1 (ru) Получение симметричных и несимметричных дисульфидов реакционной дистилляцией их смеси
EA201201613A1 (ru) Способ получения перфторолефинов путем пиролиза перфторуглеродов в присутствии водорода
TN2014000329A1 (en) Method for preparing compound by novel michael addition reaction using water or various acids as additive
BR112014007818A2 (pt) co-cultura sintrófica de micro-organismos anaeróbicos para a produção de n-butanol a partir de gás de síntese
BR102012001153A8 (pt) processo para a produção de alquilfosfatos
FR2978450B1 (fr) Procede de combustion en boucle chimique utilisant la pyrolusite comme masse oxydo-reductrice

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]