CN103437158B - 一种碳纤维复合材料及其制备方法 - Google Patents
一种碳纤维复合材料及其制备方法 Download PDFInfo
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- CN103437158B CN103437158B CN201310414028.5A CN201310414028A CN103437158B CN 103437158 B CN103437158 B CN 103437158B CN 201310414028 A CN201310414028 A CN 201310414028A CN 103437158 B CN103437158 B CN 103437158B
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- carbon fiber
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- modified carbon
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- 239000002131 composite material Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000000835 fiber Substances 0.000 title abstract description 7
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 81
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 75
- 239000004917 carbon fiber Substances 0.000 claims abstract description 75
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 71
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 31
- -1 Graphene modified carbon fiber Chemical class 0.000 claims abstract description 23
- 239000004744 fabric Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- 239000000843 powder Substances 0.000 claims description 30
- 239000004840 adhesive resin Substances 0.000 claims description 28
- 229920006223 adhesive resin Polymers 0.000 claims description 28
- 238000000227 grinding Methods 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical group NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 5
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 abstract description 3
- 238000012986 modification Methods 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 description 15
- 229920000647 polyepoxide Polymers 0.000 description 15
- 238000005452 bending Methods 0.000 description 12
- 238000005303 weighing Methods 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000011344 liquid material Substances 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 2
- 229920000271 Kevlar® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000005007 epoxy-phenolic resin Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 239000004761 kevlar Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000004844 aliphatic epoxy resin Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000004845 glycidylamine epoxy resin Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
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- Reinforced Plastic Materials (AREA)
Abstract
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CN201310414028.5A CN103437158B (zh) | 2013-09-11 | 2013-09-11 | 一种碳纤维复合材料及其制备方法 |
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CN103437158B true CN103437158B (zh) | 2016-06-01 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108353862A (zh) * | 2018-02-10 | 2018-08-03 | 湖南狼图腾碳纤维科技有限公司 | 一种空心碳纤维浮标的制备方法 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104448239B (zh) * | 2014-10-11 | 2017-02-22 | 浙江大学 | 一种高强度环氧树脂复合材料及其制备方法 |
CN104558525B (zh) * | 2014-10-11 | 2017-01-11 | 浙江大学 | 一种高弯曲强度氧化纳米碳材料/碳纤维/环氧树脂复合材料及其制备方法 |
CN106159009A (zh) * | 2015-03-26 | 2016-11-23 | 汉能新材料科技有限公司 | 一种柔性封装复合膜及其制造方法 |
CN104882613B (zh) * | 2015-03-30 | 2017-11-03 | 中国科学院金属研究所 | 一种柔性高导电复合碳纤维布的制备方法 |
CN105644024A (zh) * | 2015-12-10 | 2016-06-08 | 湖北鸿宇复合碳纤维科技有限公司 | 一种抗震减灾建筑用的高强度碳纤维复合布及加工工艺 |
CN105462565B (zh) * | 2015-12-14 | 2018-09-21 | 德阳烯碳科技有限公司 | 一种石墨烯和碳纤维复合热界面材料的制备方法 |
CN106364023A (zh) * | 2016-08-29 | 2017-02-01 | 湖南省鑫源新材料股份有限公司 | 一种碳碳平板及其制备方法 |
CN107325326B (zh) * | 2017-06-28 | 2023-02-10 | 南京航空航天大学 | 一种碳纤维复合材料微反应器及其制备方法 |
CN109704767A (zh) * | 2019-02-27 | 2019-05-03 | 无锡市星达石化配件有限公司 | 一种氮化硼高温强化石墨烯复合法兰及其锻造方法 |
CN109769314A (zh) * | 2019-03-13 | 2019-05-17 | 中航复材(北京)科技有限公司 | 一种柔性碳复合材料电加热膜及其应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102046367A (zh) * | 2008-03-28 | 2011-05-04 | 赫克塞尔合成有限公司 | 改进的复合材料 |
CN102600734A (zh) * | 2012-03-27 | 2012-07-25 | 南京工业大学 | 增强型氧化石墨烯中空纤维复合膜及其制备方法 |
CN102795873A (zh) * | 2012-07-30 | 2012-11-28 | 哈尔滨工业大学 | 一种石墨烯/聚合物涂层界面改性碳/碳复合材料的方法 |
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JP2705319B2 (ja) * | 1991-01-28 | 1998-01-28 | 日本電気株式会社 | 炭素繊維強化複合材料の作製方法 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102046367A (zh) * | 2008-03-28 | 2011-05-04 | 赫克塞尔合成有限公司 | 改进的复合材料 |
CN102600734A (zh) * | 2012-03-27 | 2012-07-25 | 南京工业大学 | 增强型氧化石墨烯中空纤维复合膜及其制备方法 |
CN102795873A (zh) * | 2012-07-30 | 2012-11-28 | 哈尔滨工业大学 | 一种石墨烯/聚合物涂层界面改性碳/碳复合材料的方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108353862A (zh) * | 2018-02-10 | 2018-08-03 | 湖南狼图腾碳纤维科技有限公司 | 一种空心碳纤维浮标的制备方法 |
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Inventor after: Cai Yan Inventor after: Xu Huailiang Inventor after: Liu Qiongxin Inventor after: Ji Yan Inventor before: Cai Yan Inventor before: Liu Qiongxin Inventor before: Ji Yan |
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Denomination of invention: Carbon fiber composite, preparation method thereof and tank Effective date of registration: 20171228 Granted publication date: 20160601 Pledgee: Jiangsu Jiangnan Rural Commercial Bank Limited by Share Ltd Pledgor: The Sixth Element (Changzhou) Ltd. Registration number: 2017320000070 |
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Date of cancellation: 20180713 Granted publication date: 20160601 Pledgee: Jiangsu Jiangnan Rural Commercial Bank Limited by Share Ltd Pledgor: The Sixth Element (Changzhou) Ltd. Registration number: 2017320000070 |