CN103242471A - 一种非离子聚丙烯酰胺乳液的制备方法及制得的乳液 - Google Patents
一种非离子聚丙烯酰胺乳液的制备方法及制得的乳液 Download PDFInfo
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- CN103242471A CN103242471A CN2013101290223A CN201310129022A CN103242471A CN 103242471 A CN103242471 A CN 103242471A CN 2013101290223 A CN2013101290223 A CN 2013101290223A CN 201310129022 A CN201310129022 A CN 201310129022A CN 103242471 A CN103242471 A CN 103242471A
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- 229920002401 polyacrylamide Polymers 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title abstract description 9
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 238000004945 emulsification Methods 0.000 claims abstract description 9
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- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000003381 stabilizer Substances 0.000 claims abstract description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 3
- -1 polyoxyethylene Polymers 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 238000004821 distillation Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 8
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 4
- 229920002521 macromolecule Polymers 0.000 claims description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- 239000003352 sequestering agent Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 claims description 3
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- KWYJDIUEHHCHCZ-UHFFFAOYSA-N 3-[2-[bis(2-carboxyethyl)amino]ethyl-(2-carboxyethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CCC(O)=O)CCN(CCC(O)=O)CCC(O)=O KWYJDIUEHHCHCZ-UHFFFAOYSA-N 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 229920004890 Triton X-100 Polymers 0.000 claims description 2
- 239000013504 Triton X-100 Substances 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- FYIBPWZEZWVDQB-UHFFFAOYSA-N dicyclohexyl carbonate Chemical class C1CCCCC1OC(=O)OC1CCCCC1 FYIBPWZEZWVDQB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- ODCCJTMPMUFERV-UHFFFAOYSA-N ditert-butyl carbonate Chemical compound CC(C)(C)OC(=O)OC(C)(C)C ODCCJTMPMUFERV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 claims description 2
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- 229920000223 polyglycerol Polymers 0.000 claims description 2
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- 229910052708 sodium Inorganic materials 0.000 claims description 2
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- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 claims description 2
- 239000001593 sorbitan monooleate Substances 0.000 claims description 2
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 abstract description 4
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106988714A (zh) * | 2017-04-10 | 2017-07-28 | 中国石油化工股份有限公司 | 一种超稠油降黏方法 |
CN108003856A (zh) * | 2017-12-01 | 2018-05-08 | 北京恒聚化工集团有限责任公司 | 一种珠状微球调剖堵水剂及其制备方法 |
CN108129586A (zh) * | 2017-12-01 | 2018-06-08 | 北京恒聚化工集团有限责任公司 | 一种高效防粘剂及其制备方法 |
CN109748992A (zh) * | 2017-11-03 | 2019-05-14 | 中国石油化工股份有限公司 | 具有选择性堵水功能的聚合物及其制备方法和应用 |
CN113355079A (zh) * | 2021-08-09 | 2021-09-07 | 山东诺尔生物科技有限公司 | 一种压裂液用稠化剂悬浮乳液及其制备方法 |
US11359135B2 (en) | 2019-08-07 | 2022-06-14 | Ecolab Usa Inc. | Inversion agents for water-in-oil lattices and methods of use |
US11708485B2 (en) | 2019-08-07 | 2023-07-25 | Ecolab Usa Inc. | High molecular weight polymer with low insoluble gel content |
Citations (3)
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US4025712A (en) * | 1975-03-24 | 1977-05-24 | Nalco Chemical Company | Method for enhancing the solubility of dried latex polymer |
CN101143742A (zh) * | 2006-09-15 | 2008-03-19 | 中国石油化工股份有限公司 | 聚丙烯酰胺絮凝剂的反相乳液合成方法 |
CN101235111A (zh) * | 2007-01-29 | 2008-08-06 | 中南大学 | 高固含、低油水比水溶性聚合物反相微乳液制备技术 |
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2013
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US4025712A (en) * | 1975-03-24 | 1977-05-24 | Nalco Chemical Company | Method for enhancing the solubility of dried latex polymer |
CN101143742A (zh) * | 2006-09-15 | 2008-03-19 | 中国石油化工股份有限公司 | 聚丙烯酰胺絮凝剂的反相乳液合成方法 |
CN101235111A (zh) * | 2007-01-29 | 2008-08-06 | 中南大学 | 高固含、低油水比水溶性聚合物反相微乳液制备技术 |
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包德隆等: "《染整工艺学 (第一册)》", 31 July 1993, 纺织工业出版社, article "高分子化合物的基础知识", pages: 4 * |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106988714A (zh) * | 2017-04-10 | 2017-07-28 | 中国石油化工股份有限公司 | 一种超稠油降黏方法 |
CN109748992A (zh) * | 2017-11-03 | 2019-05-14 | 中国石油化工股份有限公司 | 具有选择性堵水功能的聚合物及其制备方法和应用 |
CN108003856A (zh) * | 2017-12-01 | 2018-05-08 | 北京恒聚化工集团有限责任公司 | 一种珠状微球调剖堵水剂及其制备方法 |
CN108129586A (zh) * | 2017-12-01 | 2018-06-08 | 北京恒聚化工集团有限责任公司 | 一种高效防粘剂及其制备方法 |
US11359135B2 (en) | 2019-08-07 | 2022-06-14 | Ecolab Usa Inc. | Inversion agents for water-in-oil lattices and methods of use |
US11708485B2 (en) | 2019-08-07 | 2023-07-25 | Ecolab Usa Inc. | High molecular weight polymer with low insoluble gel content |
CN113355079A (zh) * | 2021-08-09 | 2021-09-07 | 山东诺尔生物科技有限公司 | 一种压裂液用稠化剂悬浮乳液及其制备方法 |
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Inventor after: Yang Kaiji Inventor after: Guo Wenli Inventor after: Xu Qinglin Inventor after: Hui Zhaosen Inventor before: Yang Kaiji Inventor before: Guo Wenli Inventor before: Xu Qinglin |
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Free format text: CORRECT: INVENTOR; FROM: YANG KAIJI GUO WENLI XU QINGLIN TO: YANG KAIJI GUO WENLI XU QINGLIN HUI ZHAOSEN |
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Effective date of registration: 20150817 Address after: 101109 Beijing city Tongzhou District Huoxian Industrial Development Zone Patentee after: Beijing Hengju Chemical Group Co., Ltd. Patentee after: Henan permanent dimerization work limited liability company Address before: 101109 Beijing city Tongzhou District Huoxian Industrial Development Zone Patentee before: Beijing Hengju Chemical Group Co., Ltd. |
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Denomination of invention: Method for preparing non-ionic polyacrylamide emulsion and prepared emulsion Effective date of registration: 20181226 Granted publication date: 20150429 Pledgee: Industrial and Commercial Bank of China Limited Lankao Branch Pledgor: Beijing Hengju Chemical Group Co., Ltd.|Henan permanent dimerization work limited liability company Registration number: 2018990001267 |
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Date of cancellation: 20200508 Granted publication date: 20150429 Pledgee: Industrial and Commercial Bank of China Limited Lankao Branch Pledgor: Beijing Hengju Chemical Group Corp.|HENAN HENGJU CHEMICAL Co.,Ltd. Registration number: 2018990001267 |
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