CN103108994B - 氨的合成方法 - Google Patents

氨的合成方法 Download PDF

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Publication number
CN103108994B
CN103108994B CN201180035396.8A CN201180035396A CN103108994B CN 103108994 B CN103108994 B CN 103108994B CN 201180035396 A CN201180035396 A CN 201180035396A CN 103108994 B CN103108994 B CN 103108994B
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CN
China
Prior art keywords
ammonia
anode
cathodic area
positive column
synthetic method
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Expired - Fee Related
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CN201180035396.8A
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English (en)
Chinese (zh)
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CN103108994A (zh
Inventor
日数谷进
森匠磨
荒木贞夫
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Kanadevia Corp
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Hitachi Zosen Corp
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C01C1/0411—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Analytical Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Catalysts (AREA)
CN201180035396.8A 2010-07-21 2011-06-03 氨的合成方法 Expired - Fee Related CN103108994B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010163537A JP5604204B2 (ja) 2010-07-21 2010-07-21 アンモニアの合成方法
JP2010-163537 2010-07-21
PCT/JP2011/062790 WO2012011324A1 (ja) 2010-07-21 2011-06-03 アンモニアの合成方法

Publications (2)

Publication Number Publication Date
CN103108994A CN103108994A (zh) 2013-05-15
CN103108994B true CN103108994B (zh) 2016-01-20

Family

ID=45496753

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180035396.8A Expired - Fee Related CN103108994B (zh) 2010-07-21 2011-06-03 氨的合成方法

Country Status (5)

Country Link
US (1) US8801915B2 (enExample)
JP (1) JP5604204B2 (enExample)
CN (1) CN103108994B (enExample)
AU (1) AU2011280799B2 (enExample)
WO (1) WO2012011324A1 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015120118A (ja) * 2013-12-24 2015-07-02 株式会社デンソー アンモニア合成触媒
JP6366287B2 (ja) * 2014-02-06 2018-08-01 国立大学法人北海道大学 アンモニア発生装置及びアンモニア発生方法
US20160160312A1 (en) * 2014-12-04 2016-06-09 Air Products And Chemicals, Inc. Hydrometallurgical System and Process Using an Ion Transport Membrane
CN104630811B (zh) * 2015-02-13 2017-03-08 王海斌 一种电解制氨装置
GB2544485B (en) * 2015-11-16 2018-09-19 Siemens Ag Electrochemical cell comprising a steam inlet and a solid oxide layer
GB2545444B (en) * 2015-12-16 2018-05-30 Siemens Ag An electrochemical cell with a steam inlet and a solid catalyst structure
JPWO2017149718A1 (ja) 2016-03-03 2018-12-27 日揮株式会社 アンモニアの製造方法
CN106082270B (zh) * 2016-06-08 2018-02-06 南京科技职业学院 一种光催化合成氨的方法
CN106480469A (zh) * 2016-07-14 2017-03-08 张国权 小型制氨机的制造方法
CN107686120B (zh) * 2016-08-05 2020-04-21 华中师范大学 一种聚集太阳能催化合成氨的方法及其催化剂
PE20200524A1 (es) * 2017-07-25 2020-03-09 Haldor Topsoe As Metodo para la preparacion de gas de sintesis de amoniaco
CN108754534B (zh) * 2018-05-25 2020-06-26 山东师范大学 一种电催化合成氨的铁基非贵金属催化剂及制备方法
CN108993546B (zh) * 2018-07-12 2021-03-02 福州大学 高效光催化水裂解产氢和醇氧化的异质结光催化剂
CN108977841B (zh) * 2018-08-30 2021-07-23 中国科学院长春应用化学研究所 一种氮气和二氧化碳气体同步电化学还原合成尿素的方法
US11885029B2 (en) 2019-02-12 2024-01-30 Georgia Tech Research Corporation Systems and methods for forming nitrogen-based compounds
GB201904004D0 (en) 2019-03-22 2019-05-08 Oxford Univ Innovation Photocatalyst
JP7613692B2 (ja) * 2019-09-05 2025-01-15 国立大学法人 東京大学 アンモニアの製造方法及び製造装置
CN111394740B (zh) * 2020-03-11 2021-07-27 南京航空航天大学 一种提高电催化氮还原合成氨反应效率的方法
CN114622223B (zh) * 2020-12-14 2023-08-25 中国科学院大连化学物理研究所 一种电催化脱硝合成氨的方法
CN112939023A (zh) * 2021-03-31 2021-06-11 西安热工研究院有限公司 一种火电厂制氨储能及脱硝的系统及其方法
CN113387371B (zh) * 2021-05-28 2023-08-22 西安交通大学 一种基于燃料电池形式设计的光电催化合成氨反应器
CN114672823B (zh) * 2022-05-16 2025-02-14 西安交通大学 基于高-低频声波组合的光电催化合成氨反应器及方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4167461A (en) * 1978-07-10 1979-09-11 Allied Chemical Corporation Photoenhanced reduction process
JP2001072985A (ja) * 1999-09-02 2001-03-21 Katsuyoshi Hoshino 酸化チタンと導電性ポリマーの複合材料を用いた空中窒素の固定化方法
JP2003200057A (ja) * 2002-01-11 2003-07-15 Japan Science & Technology Corp 可視光応答性を持つ酸化チタン／導電性ポリマー複合材料からなる高効率な空中窒素固定複合化光触媒材料
JP2010030870A (ja) * 2008-07-30 2010-02-12 Laser Gijutsu Sogo Kenkyusho バイオマスエネルギー変換装置

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005272856A (ja) 2004-03-22 2005-10-06 Kenichi Machida アンモニア合成装置、アンモニア合成方法および燃焼装置を含むシステム
WO2008116254A1 (en) * 2007-03-23 2008-10-02 Robin Brimblecombe Water oxidation catalyst
JP5127385B2 (ja) * 2007-09-28 2013-01-23 学校法人同志社 アンモニア電解合成装置
US20100133110A1 (en) * 2008-10-08 2010-06-03 Massachusetts Institute Of Technology Catalytic materials, photoanodes, and photoelectrochemical cells for water electrolysis and other, electrochemical techniques
US8236146B2 (en) * 2008-10-30 2012-08-07 Panasonic Corporation Photoelectrochemical cell and energy system using the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4167461A (en) * 1978-07-10 1979-09-11 Allied Chemical Corporation Photoenhanced reduction process
JP2001072985A (ja) * 1999-09-02 2001-03-21 Katsuyoshi Hoshino 酸化チタンと導電性ポリマーの複合材料を用いた空中窒素の固定化方法
JP2003200057A (ja) * 2002-01-11 2003-07-15 Japan Science & Technology Corp 可視光応答性を持つ酸化チタン／導電性ポリマー複合材料からなる高効率な空中窒素固定複合化光触媒材料
JP2010030870A (ja) * 2008-07-30 2010-02-12 Laser Gijutsu Sogo Kenkyusho バイオマスエネルギー変換装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ELECTROCHEMICAL AND PHOTOELECTROCHEMICAL REDUCTION OF MOLECULAR NITROGEN TO AMMONIA;S. GRAYER et al.;《J. Electroanal. Chem.》;19840725;第170卷;第363页第1段、第364页最后一段至第365页第2段、表1 *

Also Published As

Publication number Publication date
JP5604204B2 (ja) 2014-10-08
WO2012011324A1 (ja) 2012-01-26
US20130112568A1 (en) 2013-05-09
CN103108994A (zh) 2013-05-15
AU2011280799A1 (en) 2013-01-31
AU2011280799B2 (en) 2015-02-26
JP2012025985A (ja) 2012-02-09
US8801915B2 (en) 2014-08-12

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