CN102959770B - 制备锂-混合金属氧化物的方法及其作为阴极材料的用途 - Google Patents

制备锂-混合金属氧化物的方法及其作为阴极材料的用途 Download PDF

Info

Publication number
CN102959770B
CN102959770B CN201180030258.0A CN201180030258A CN102959770B CN 102959770 B CN102959770 B CN 102959770B CN 201180030258 A CN201180030258 A CN 201180030258A CN 102959770 B CN102959770 B CN 102959770B
Authority
CN
China
Prior art keywords
lithium
mixture
heat treatment
cobalt
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180030258.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN102959770A (zh
Inventor
S·施勒德勒
H·希布施特
J·K·拉姆派尔特
M·施韦特
I·佩特罗维克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102959770A publication Critical patent/CN102959770A/zh
Application granted granted Critical
Publication of CN102959770B publication Critical patent/CN102959770B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201180030258.0A 2010-06-25 2011-06-24 制备锂-混合金属氧化物的方法及其作为阴极材料的用途 Active CN102959770B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US35844010P 2010-06-25 2010-06-25
US61/358,440 2010-06-25
PCT/IB2011/052784 WO2011161652A1 (de) 2010-06-25 2011-06-24 Verfahren zur herstellung von lithium-mischmetalloxiden und ihre verwendung als kathodenmaterial

Publications (2)

Publication Number Publication Date
CN102959770A CN102959770A (zh) 2013-03-06
CN102959770B true CN102959770B (zh) 2016-01-13

Family

ID=45351664

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180030258.0A Active CN102959770B (zh) 2010-06-25 2011-06-24 制备锂-混合金属氧化物的方法及其作为阴极材料的用途

Country Status (10)

Country Link
US (1) US8980475B2 (https=)
EP (1) EP2586085B1 (https=)
JP (1) JP5809260B2 (https=)
KR (1) KR101860813B1 (https=)
CN (1) CN102959770B (https=)
ES (1) ES3010294T3 (https=)
HU (1) HUE070413T2 (https=)
PL (1) PL2586085T3 (https=)
TW (1) TW201204637A (https=)
WO (1) WO2011161652A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120177921A1 (en) 2011-01-10 2012-07-12 Basf Se Process for preparing transition metal carbonates
US9630842B2 (en) 2011-01-10 2017-04-25 Basf Se Process for preparing transition metal hydroxides
KR20120099411A (ko) * 2011-01-21 2012-09-10 제이엑스 닛코 닛세키 킨조쿠 가부시키가이샤 리튬 이온 전지용 정극 활물질의 제조 방법 및 리튬 이온 전지용 정극 활물질
US8992794B2 (en) * 2011-06-24 2015-03-31 Basf Corporation Process for synthesis of a layered oxide cathode composition
JP6945526B2 (ja) 2015-10-14 2021-10-06 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ 繊維強化セラミックスマトリックス複合材料を含有する熱透過性チューブ
CN107851794B (zh) * 2016-06-09 2020-09-22 日立金属株式会社 锂二次电池用正极活性物质的制造方法
PL3281915T3 (pl) 2016-08-10 2019-09-30 Umicore Prekursory materiałów katody zawierających tlenek metalu przejściowego litu do baterii wielokrotnego ładowania
KR102539250B1 (ko) * 2017-07-14 2023-06-01 바스프 에스이 전극 활물질의 제조 방법
US11502296B2 (en) 2018-03-26 2022-11-15 Basf Se Process for making a mixed metal oxide
AU2019431304B2 (en) * 2019-02-26 2025-03-13 Linde Gmbh Method and apparatus for producing ternary cathode material
US11121354B2 (en) * 2019-06-28 2021-09-14 eJoule, Inc. System with power jet modules and method thereof
TWI778405B (zh) * 2019-08-27 2022-09-21 德商贏創運營有限公司 塗覆有熱解製造的含鋯氧化物之混合鋰過渡金屬氧化物
US20240010518A1 (en) * 2020-11-17 2024-01-11 Sumitomo Chemical Company, Limited Method for producing lithium metal composite oxide

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4980080A (en) 1988-06-09 1990-12-25 Societe Anonyme Dite: Saft Process of making a cathode material for a secondary battery including a lithium anode and application of said material
JPH02233989A (ja) * 1989-03-08 1990-09-17 Ngk Insulators Ltd トンネル式加熱炉
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
JPH07142093A (ja) 1993-11-22 1995-06-02 Yuasa Corp リチウム二次電池
JPH0822826A (ja) 1994-07-05 1996-01-23 Matsushita Electric Ind Co Ltd 非水電解液二次電池の正極活物質の合成法
EP0720247B1 (en) 1994-12-16 1998-05-27 Matsushita Electric Industrial Co., Ltd. Manufacturing processes of positive active materials for lithium secondary batteries and lithium secondary batteries comprising the same
JPH09156931A (ja) * 1995-12-06 1997-06-17 Nikki Kagaku Kk ニッケル酸リチウムの製造方法
JP4120014B2 (ja) * 1996-08-16 2008-07-16 堺化学工業株式会社 粒子状組成物の製造方法
EP0849817A3 (en) 1996-12-20 1999-03-24 Japan Storage Battery Company Limited Positive active material for lithium battery having the same, and method for producing the same
JPH11111290A (ja) * 1997-10-06 1999-04-23 Mitsui Mining & Smelting Co Ltd リチウム二次電池用正極材料及びその製造方法
DE19849343A1 (de) 1997-10-30 1999-06-02 Samsung Display Devices Co Ltd Lithiumcompositoxid, dessen Herstellung und sekundäre Lithiumionzelle mit Lithiumcompositoxid als aktives Material der positiven Elektrode
CN1170773C (zh) * 1998-11-20 2004-10-13 Fmc公司 含多种掺杂剂的含锂、锰和氧的化合物及其制备方法
JP3446639B2 (ja) * 1998-12-10 2003-09-16 松下電器産業株式会社 リチウム二次電池用正極活物質の製造方法およびリチウム二次電池
JP2001102054A (ja) * 1999-09-30 2001-04-13 Mitsui Chemicals Inc リチウム２次電池用正極活物質の製造方法及びそれを正極に用いた電池
US6677082B2 (en) 2000-06-22 2004-01-13 The University Of Chicago Lithium metal oxide electrodes for lithium cells and batteries
US6680143B2 (en) 2000-06-22 2004-01-20 The University Of Chicago Lithium metal oxide electrodes for lithium cells and batteries
US6878490B2 (en) * 2001-08-20 2005-04-12 Fmc Corporation Positive electrode active materials for secondary batteries and methods of preparing same
JP4774661B2 (ja) * 2001-09-25 2011-09-14 三菱化学株式会社 リチウム遷移金属複合酸化物、リチウム二次電池用正極材料、リチウム二次電池用正極及びリチウム二次電池、並びにリチウム遷移金属複合酸化物の製造方法
JP2004281163A (ja) 2003-03-14 2004-10-07 Seimi Chem Co Ltd 正極活物質粉末用の焼成容器，正極活物質粉末およびリチウムイオン二次電池
US7314682B2 (en) 2003-04-24 2008-01-01 Uchicago Argonne, Llc Lithium metal oxide electrodes for lithium batteries
JP2005196992A (ja) 2003-12-26 2005-07-21 Hitachi Ltd リチウム二次電池用正極材料及び電池
EP1742281B1 (en) * 2004-04-27 2011-09-07 Mitsubishi Chemical Corporation Layered lithium nickel manganese cobalt composite oxide powder for material of positive electrode of lithium secondary battery, process for producing the same, positive electrode of lithium secondary battery therefrom, and lithium secondary battery
JP2006127923A (ja) 2004-10-29 2006-05-18 Shin Kobe Electric Mach Co Ltd リチウム二次電池用の正極活物質及びリチウム二次電池
FR2879822B1 (fr) * 2004-12-21 2009-05-22 Commissariat Energie Atomique Materiau d'electrode positive optimise pour accumulateurs au lithium, procede pour sa realisation, electrode, accumulateur et batterie mettant en oeuvre ce materiau
JP2007317585A (ja) 2006-05-29 2007-12-06 Hitachi Vehicle Energy Ltd リチウム二次電池用正極活物質及びこれを用いたリチウム二次電池
JP5231171B2 (ja) * 2008-10-30 2013-07-10 パナソニック株式会社 非水電解質二次電池用正極活物質およびその製造方法

Also Published As

Publication number Publication date
ES3010294T3 (en) 2025-04-02
KR101860813B1 (ko) 2018-07-02
CN102959770A (zh) 2013-03-06
WO2011161652A1 (de) 2011-12-29
EP2586085A1 (de) 2013-05-01
TW201204637A (en) 2012-02-01
HUE070413T2 (hu) 2025-06-28
JP5809260B2 (ja) 2015-11-10
US8980475B2 (en) 2015-03-17
KR20130096224A (ko) 2013-08-29
EP2586085A4 (de) 2015-10-14
PL2586085T3 (pl) 2025-04-14
EP2586085B1 (de) 2024-11-13
US20110315938A1 (en) 2011-12-29
JP2013530917A (ja) 2013-08-01

Similar Documents

Publication Publication Date Title
CN102959770B (zh) 制备锂-混合金属氧化物的方法及其作为阴极材料的用途
TWI497807B (zh) Production method of positive electrode active material for lithium ion battery and positive electrode active material for lithium ion battery
JP6344007B2 (ja) 非水電解質二次電池用正極活物質の前駆体の製造方法、及び非水電解質二次電池用正極活物質の製造方法
JP4915488B1 (ja) ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池
JP3860542B2 (ja) リチウム２次電池の正極活物質及びその製造方法
JP6016329B2 (ja) リチウムイオン電池用正極活物質、リチウムイオン電池用正極及びリチウムイオン電池
JP5464348B2 (ja) 非水系電解質二次電池正極活物質用ニッケル−コバルト複合水酸化物およびその製造方法、ならびに該ニッケル−コバルト複合水酸化物を用いた非水系電解質二次電池正極活物質の製造方法
EP3007254A1 (en) Transition metal composite hydroxide particles, method for producing same, positive electrode active material for non-aqueous electrolyte secondary battery, method for producing same, and non-aqueous electrolyte secondary battery
US11862784B2 (en) Process for making a cathode active material for a lithium ion battery
CN110785381B (zh) 制备电极活性材料的方法
CN107810571B (zh) 用于高功率应用的纳米级孔结构阴极和材料合成方法
JP2015162322A (ja) 非水電解質二次電池用正極活物質の前駆体とその製造方法、及び非水電解質二次電池用正極活物質の製造方法
CN111261851A (zh) 一种锂离子电池三元正极材料及其制备方法
JP4826147B2 (ja) アルミニウム含有水酸化ニッケル粒子及びその製造方法
JP7338133B2 (ja) 非水系電解質二次電池用正極活物質前駆体、非水系電解質二次電池用正極活物質前駆体の製造方法、非水系電解質二次電池用正極活物質の製造方法
JP7273260B2 (ja) リチウムイオン二次電池用正極活物質とその製造方法およびリチウムイオン二次電池
JP5799849B2 (ja) ニッケルコバルト複合水酸化物及びその製造方法
JP6876600B2 (ja) 非水電解質二次電池用正極活物質の前駆体とその製造方法、及び非水電解質二次電池用正極活物質とその製造方法
JP7119302B2 (ja) 非水系電解質二次電池用正極活物質前駆体、非水系電解質二次電池用正極活物質前駆体の製造方法、非水系電解質二次電池用正極活物質の製造方法
JP2022504835A (ja) リチウム遷移金属複合酸化物およびその製造方法
JP2023060191A (ja) 水酸化リチウム水和物
JP2020017525A (ja) 非水電解質二次電池用正極活物質の前駆体とその製造方法、及び非水電解質二次電池用正極活物質とその製造方法
JP7412485B1 (ja) 金属複合水酸化物粒子及びリチウム二次電池用正極活物質の製造方法
JP7412486B1 (ja) 金属複合水酸化物及びリチウム二次電池用正極活物質の製造方法
JP5544798B2 (ja) マンガン酸リチウムの製造方法及びそれに用いる二酸化マンガン

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant