KR101860813B1 - 리튬 혼합 금속 산화물의 제조 방법 및 캐소드 재료로서의 이의 용도 - Google Patents

리튬 혼합 금속 산화물의 제조 방법 및 캐소드 재료로서의 이의 용도 Download PDF

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KR101860813B1
KR101860813B1 KR1020137001978A KR20137001978A KR101860813B1 KR 101860813 B1 KR101860813 B1 KR 101860813B1 KR 1020137001978 A KR1020137001978 A KR 1020137001978A KR 20137001978 A KR20137001978 A KR 20137001978A KR 101860813 B1 KR101860813 B1 KR 101860813B1
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lithium
mixture
heat treatment
oxygen
lithium salt
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KR20130096224A (ko
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시몬 슈뤠들
할무트 히브스트
죠단 케이트 램퍼트
마크 슈웨터
이반 페트로빅
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바스프 에스이
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020137001978A 2010-06-25 2011-06-24 리튬 혼합 금속 산화물의 제조 방법 및 캐소드 재료로서의 이의 용도 Active KR101860813B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US35844010P 2010-06-25 2010-06-25
US61/358,440 2010-06-25
PCT/IB2011/052784 WO2011161652A1 (de) 2010-06-25 2011-06-24 Verfahren zur herstellung von lithium-mischmetalloxiden und ihre verwendung als kathodenmaterial

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KR20130096224A KR20130096224A (ko) 2013-08-29
KR101860813B1 true KR101860813B1 (ko) 2018-07-02

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US (1) US8980475B2 (https=)
EP (1) EP2586085B1 (https=)
JP (1) JP5809260B2 (https=)
KR (1) KR101860813B1 (https=)
CN (1) CN102959770B (https=)
ES (1) ES3010294T3 (https=)
HU (1) HUE070413T2 (https=)
PL (1) PL2586085T3 (https=)
TW (1) TW201204637A (https=)
WO (1) WO2011161652A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120177921A1 (en) 2011-01-10 2012-07-12 Basf Se Process for preparing transition metal carbonates
US9630842B2 (en) 2011-01-10 2017-04-25 Basf Se Process for preparing transition metal hydroxides
JP5808316B2 (ja) * 2011-01-21 2015-11-10 Jx日鉱日石金属株式会社 リチウムイオン電池用正極活物質の製造方法
US8992794B2 (en) * 2011-06-24 2015-03-31 Basf Corporation Process for synthesis of a layered oxide cathode composition
CN108139159A (zh) 2015-10-14 2018-06-08 巴斯夫欧洲公司 含有复合纤维陶瓷的热渗透管
US20180316004A1 (en) * 2016-06-09 2018-11-01 Hitachi Metals, Ltd. Method for producing cathode active material used for lithium secondary battery
PL3281915T3 (pl) 2016-08-10 2019-09-30 Umicore Prekursory materiałów katody zawierających tlenek metalu przejściowego litu do baterii wielokrotnego ładowania
KR102539250B1 (ko) * 2017-07-14 2023-06-01 바스프 에스이 전극 활물질의 제조 방법
JP7254830B2 (ja) 2018-03-26 2023-04-10 ビーエーエスエフ ソシエタス・ヨーロピア 混合金属酸化物の製造方法
US20220131129A1 (en) * 2019-02-26 2022-04-28 Linde Gmbh Method and apparatus for producing ternary cathode material
US11121354B2 (en) * 2019-06-28 2021-09-14 eJoule, Inc. System with power jet modules and method thereof
TWI778405B (zh) * 2019-08-27 2022-09-21 德商贏創運營有限公司 塗覆有熱解製造的含鋯氧化物之混合鋰過渡金屬氧化物
CN116438683A (zh) * 2020-11-17 2023-07-14 住友化学株式会社 锂金属复合氧化物的制造方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4980080A (en) 1988-06-09 1990-12-25 Societe Anonyme Dite: Saft Process of making a cathode material for a secondary battery including a lithium anode and application of said material
JPH02233989A (ja) * 1989-03-08 1990-09-17 Ngk Insulators Ltd トンネル式加熱炉
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
JPH07142093A (ja) 1993-11-22 1995-06-02 Yuasa Corp リチウム二次電池
JPH0822826A (ja) 1994-07-05 1996-01-23 Matsushita Electric Ind Co Ltd 非水電解液二次電池の正極活物質の合成法
EP0720247B1 (en) 1994-12-16 1998-05-27 Matsushita Electric Industrial Co., Ltd. Manufacturing processes of positive active materials for lithium secondary batteries and lithium secondary batteries comprising the same
JPH09156931A (ja) * 1995-12-06 1997-06-17 Nikki Kagaku Kk ニッケル酸リチウムの製造方法
JP4120014B2 (ja) * 1996-08-16 2008-07-16 堺化学工業株式会社 粒子状組成物の製造方法
US5993998A (en) 1996-12-20 1999-11-30 Japan Storage Battery Co., Ltd. Positive active material for lithium battery, lithium battery having the same and method for producing the same
JPH11111290A (ja) * 1997-10-06 1999-04-23 Mitsui Mining & Smelting Co Ltd リチウム二次電池用正極材料及びその製造方法
DE19849343A1 (de) 1997-10-30 1999-06-02 Samsung Display Devices Co Ltd Lithiumcompositoxid, dessen Herstellung und sekundäre Lithiumionzelle mit Lithiumcompositoxid als aktives Material der positiven Elektrode
EP1135334B1 (en) * 1998-11-20 2002-10-09 Fmc Corporation Multiple doped lithium manganese oxide compounds and methods of preparing same
JP3446639B2 (ja) * 1998-12-10 2003-09-16 松下電器産業株式会社 リチウム二次電池用正極活物質の製造方法およびリチウム二次電池
JP2001102054A (ja) * 1999-09-30 2001-04-13 Mitsui Chemicals Inc リチウム２次電池用正極活物質の製造方法及びそれを正極に用いた電池
US6680143B2 (en) 2000-06-22 2004-01-20 The University Of Chicago Lithium metal oxide electrodes for lithium cells and batteries
US6677082B2 (en) 2000-06-22 2004-01-13 The University Of Chicago Lithium metal oxide electrodes for lithium cells and batteries
US6878490B2 (en) * 2001-08-20 2005-04-12 Fmc Corporation Positive electrode active materials for secondary batteries and methods of preparing same
JP4774661B2 (ja) * 2001-09-25 2011-09-14 三菱化学株式会社 リチウム遷移金属複合酸化物、リチウム二次電池用正極材料、リチウム二次電池用正極及びリチウム二次電池、並びにリチウム遷移金属複合酸化物の製造方法
JP2004281163A (ja) 2003-03-14 2004-10-07 Seimi Chem Co Ltd 正極活物質粉末用の焼成容器，正極活物質粉末およびリチウムイオン二次電池
US7314682B2 (en) 2003-04-24 2008-01-01 Uchicago Argonne, Llc Lithium metal oxide electrodes for lithium batteries
JP2005196992A (ja) 2003-12-26 2005-07-21 Hitachi Ltd リチウム二次電池用正極材料及び電池
ATE523906T1 (de) * 2004-04-27 2011-09-15 Mitsubishi Chem Corp Schicht-lithium-nickel-mangan-kobalt- verbundoxidpulver für das material einer positivelektrode einer lithium-sekundärbatterie, herstellungsprozess dafür, positive elektrode einer lithium-sekundärbatterie daraus und lithium-sekundärbatterie
JP2006127923A (ja) 2004-10-29 2006-05-18 Shin Kobe Electric Mach Co Ltd リチウム二次電池用の正極活物質及びリチウム二次電池
FR2879822B1 (fr) * 2004-12-21 2009-05-22 Commissariat Energie Atomique Materiau d'electrode positive optimise pour accumulateurs au lithium, procede pour sa realisation, electrode, accumulateur et batterie mettant en oeuvre ce materiau
JP2007317585A (ja) 2006-05-29 2007-12-06 Hitachi Vehicle Energy Ltd リチウム二次電池用正極活物質及びこれを用いたリチウム二次電池
JP5231171B2 (ja) * 2008-10-30 2013-07-10 パナソニック株式会社 非水電解質二次電池用正極活物質およびその製造方法

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EP2586085A4 (de) 2015-10-14
JP5809260B2 (ja) 2015-11-10
KR20130096224A (ko) 2013-08-29
EP2586085B1 (de) 2024-11-13
EP2586085A1 (de) 2013-05-01
TW201204637A (en) 2012-02-01
CN102959770A (zh) 2013-03-06
CN102959770B (zh) 2016-01-13
US8980475B2 (en) 2015-03-17
PL2586085T3 (pl) 2025-04-14
ES3010294T3 (en) 2025-04-02
WO2011161652A1 (de) 2011-12-29
JP2013530917A (ja) 2013-08-01
HUE070413T2 (hu) 2025-06-28
US20110315938A1 (en) 2011-12-29

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