CN102895151A - Sulfate-free hair cleanser and preparation method thereof - Google Patents
Sulfate-free hair cleanser and preparation method thereof Download PDFInfo
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- CN102895151A CN102895151A CN2012104042714A CN201210404271A CN102895151A CN 102895151 A CN102895151 A CN 102895151A CN 2012104042714 A CN2012104042714 A CN 2012104042714A CN 201210404271 A CN201210404271 A CN 201210404271A CN 102895151 A CN102895151 A CN 102895151A
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Abstract
The invention discloses a sulfate-free hair cleanser and a preparation method thereof. The sulfate-free hair cleanser comprises the following concrete formulation components in percentage by weight: 1-40% of anionic surfactant, 0.1-25% of nonionic surfactant, 0.1-15% of ampholytic surfactant, 0.1-5% of cationic conditioner, 0-2% of cocamidopropyl MEA (Mono Ethanol Amine), 0-2% of cetyl alcohol, 0-1% of EDTA (Ethylene Diamine Tetraacetic Acid)-disodium, 0-3% of anti-dandruff agent, 0-5% of pearling agent, 0.1-3% of conditioning component, 0-5% of polydimethylsiloxane, 0.1-2.0% of essence, 0.01-1% of preservative, 0.01-1% of pH adjusting agent, 0.01-1% of viscosity adjusting agent and 0.01% of natural extract. The invention relates to the technical field of daily chemical industry. The hair cleanser has the characteristics of more mildness to scalp, less irritation and capability of more caring the scalp in the hair washing process.
Description
Technical field
The present invention relates to a kind of hair detergent, belong to daily use chemicals cleaning product technical field, particularly relate to hair cleanser of a kind of not containing sulfate and preparation method thereof.
Background technology
Along with the raising of people's living standard, consumer is not only more and more higher to the effect requirement of shampoo, and is also more and more higher to low irritant, the health requirement of shampoo.The shampoo system overwhelming majority that sell existing market mainly plays decontamination and foaming effect take lauryl alcohol ether sulfate (ammonium) and lauryl sulfate (ammonium) as main surfactant.
This class surfactant of prior art (contains a large amount of SO
4 2-) in the hair washing process, easily scalp is produced relatively large stimulation.Use for a long time, easily cause hair damage, be unfavorable at last health.
Summary of the invention
The object of the present invention is to provide a kind of hair cleanser of not containing sulfate, simple and convenient and anti-corrosive properties of its production and application and having good stability, gentleer to scalp in the use procedure, zest is still less.
Another object of the present invention is to provide a kind of preparation method of hair cleanser of above-mentioned not containing sulfate.
The object of the invention to solve the technical problems realizes by the following technical solutions.The hair cleanser of a kind of not containing sulfate that proposes according to the present invention comprises each raw material components of following weight percentage ratio:
Anion surfactant 1-40%
Non-ionic surface active agent 0.1-25%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0-2%
EDTA-two Na 0-1%
Pearling agent 0-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0-5%
Anti-dandruff dose of 0-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
In addition, a kind of hair cleanser of not containing sulfate comprises each raw material components of following weight percentage ratio:
Anion surfactant 1-30%
Non-ionic surface active agent 0.1-20%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-two Na 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-5%
Anti-dandruff dose of 0.1-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
Moreover a kind of hair cleanser of not containing sulfate comprises each raw material components of following weight percentage ratio:
Anion surfactant 1-25%
Non-ionic surface active agent 0.1-15%
Amphoteric surfactant 0.1-10%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-two Na 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-4%
Anti-dandruff dose of 0.1-1%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
Described amino acid type surfactant is any one or the two or more mixture in sodium lauroyl glutamate, lauroyl Kaglutam, sodium lauroyl sarcosine, potassium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, myristoyl-N-methylaminoacetic acid potassium, cocos nucifera oil acyl Glycine sodium, the cocos nucifera oil acyl glycine potassium.
Described non-ionic surface active agent is any one or the two or more mixture in coconut oleoyl amine MEA, coconut oil diethanol amide, Cortex cocois radicis oils and fats single ethanol amide, the alkyl polyglucoside.
Described amphoteric surfactant is any one or the two or more mixture in lauroyl both sexes base list acetic acid disodium, lauroyl both sexes base list acetic acid list sodium, cocamido propyl betaine, the cocoamido propyl hydroxy sulfobetaine.
Described cation opsonizing agent is the mixing of guar gum hydroxypropyl-trimethyl ammonium chloride, Polyquaternium-10,12-22 alkyl ammomium chloride, quaternary ammonium salt-91 and PPG-3 benzylic ether myristinate, any one or two or more mixture in the quaternary ammonium salt-52.
Described pearling agent is glycol distearate or ethylene glycol monostearate or both mixing.
Described conditioning nursing composition is any one or the two or more mixture in hydrolyzed wheat protein, hydrogenated polydecene, guar gum hydroxypropyl-trimethyl ammonium chloride, keratin, pantolactone, D-panthenol, the vitamin E;
Described pH adjusting agent is citric acid or sodium citrate or both mixing;
Viscosity modifier is sodium chloride;
Described anti-dandruff dose is climbazole or Zinc Pyrithione or both mixing;
Described antiseptic be Methylisothiazolinone (with) in the mixing of methylchloroisothiazandnone, phenoxyethanol, sodium salicylate, sodium benzoate one or more.
In addition, the present invention also provides a kind of preparation method of hair cleanser of above-mentioned not containing sulfate, may further comprise the steps:
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs rotating speed 500 ~ 600, stir 5min, after dissolving fully or being uniformly dispersed, the material of beaker B is poured among the beaker A, continue to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate respectively pH value and viscosity with pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
By technique scheme, the advantage that the present invention has is:
Of the present invention without sulfate hair cleanser (shampoo), owing to do not contain traditional lauryl alcohol ether sulfate (ammonium) and lauryl sulfate (ammonium), choose gentleer amphoteric surfactant and alkyl androstanediol, thus have scalp gentleer, zest still less etc. characteristics.The present invention compares with existing hair washing product, has gentleer to scalp and zest is less, can more take good care of the remarkable results such as scalp in the hair washing process.
The specific embodiment
Below by specifically better enforcement ratio and effect experiment example the present invention is done further in detail statement, but the present invention is not limited in following embodiment.
Embodiment 1
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight:
Lauroyl dimethyl hydroxyethyl sodium sulfonate 5%
Cocos nucifera oil acyl both sexes base disodium beclomethasone 9%
Cocamido propyl betaine 15%
Alpha-olefin sodium sulfonate 4%
Coco-Glucoside 3%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Quaternary ammonium salt-91(and) PPG-3 benzylic ether myristinate 0.4%
Acrylic acid/Methacrylamide oxypropyl trimethyl ammonium chloride/acrylamide copolymer 0.2%
Quaternary ammonium salt-52(and) lauryl alcohol-16 0.5%
Polydimethylsiloxane 2%
Hydrolyzed wheat protein 0.5%
Methylisothiazolinone (with) chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Embodiment 2
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight:
Sodium N-lauroyl sarcosinate 9%
Cocos nucifera oil acyl both sexes base disodium beclomethasone 9%
Cocamido propyl betaine 8%
Alpha-olefin sodium sulfonate 4%
Coco-Glucoside 3%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.4%
Acrylic acid/Methacrylamide oxypropyl trimethyl ammonium chloride/acrylamide copolymer 0.2%
Quaternary ammonium salt-52(and) lauryl alcohol-16 0.5%
Polydimethylsiloxane 2%
Zinc Pyrithione 1.5%
Methylisothiazolinone (with) chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
Radix Sophorae Flavescentis 0.3%
The Radix Stemonae 0.3%
Hundred moss skins 0.3%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Embodiment 3
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight:
Sodium lauroyl glutamate 15%
Cocamido propyl betaine 15%
Coco-Glucoside 8%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Quaternary ammonium salt-10 0.4%
Acrylic acid/Methacrylamide oxypropyl trimethyl ammonium chloride/acrylamide copolymer 0.2%
Quaternary ammonium salt-52 and lauryl alcohol-16 0.5%
Polydimethylsiloxane 2%
Methylisothiazolinone and chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
Fructus Gleditsiae Abnormalis extract 0.5%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Embodiment 4
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight:
Lauroyl glutamate potassium 10%
Cocamido propyl betaine 15%
Coco-Glucoside 8%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Hydrolyzed wheat protein 0.5%
Cashmere lipoprotein 0.3%
Methylisothiazolinone and chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
Radix Ginseng extract 0.2%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Embodiment 5
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Lauroyl dimethyl hydroxyethyl sodium sulfonate 5%
Lauroyl glutamate potassium 10%
Cocamido propyl betaine 15%
Coco-Glucoside 8%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Zinc Pyrithione 2%
Hydrolyzed wheat protein 0.5%
Cashmere lipoprotein 0.3%
Methylisothiazolinone (with) chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
Radix Ginseng extract 0.2%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Embodiment 6
Described not containing sulfate hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Lauroyl dimethyl hydroxyethyl sodium sulfonate 5%
Cocos nucifera oil acyl both sexes base disodium beclomethasone 9%
Alpha-olefin sodium sulfonate 4%
Coco-Glucoside 3%
Coconut oleoyl amine MEA 1%
Ethylene glycol bisthioglycolate sodium stearate 1.8%
EDTA-2Na 0.05%
Spermol 0.4%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Climbazole 0.4%
Quaternary ammonium salt-52 and lauryl alcohol-16 0.5%
Polydimethylsiloxane 2%
Methylisothiazolinone and chlormethylisothiazo,ine ketone 0.05%
Essence 1%
Citric acid 0.4%
Sodium chloride 0.5%
Radix Polygoni Multiflori extract 0.3%
The surplus pure water;
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed is controlled at 500 ~ 600(rotating speed unit: 17 rev/mins, as follows), the anion surfactant of ormal weight in the adding prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added in the beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, rotating speed control 200 ~ 300; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water water that then adds ormal weight stirs, and rotating speed 500 ~ 600 stirs 5min, after dissolving fully or being uniformly dispersed.The material of beaker B is poured among the beaker A, continued to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in the A beaker, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH value and viscosity pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
Effect experiment example (stability test)
In order to detect not containing sulfate hair cleanser stability, to be placed on respectively under the condition of different temperatures without the sulfate hair cleanser, observe the cosmetic variation situation of sample, the sample that regularly is opposite to room temperature carries out viscosity, pH value is measured, and observes the variation of two indexs.The result shows: significant change do not occur in the sample appearance color, without floccule or precipitation, without lamination, has good stability.
Table 1 is containing sulfate hair cleanser stability test not
The result is as shown in table 1 to be: significant change do not occur in the sample appearance color, without floccule or precipitation, without lamination, has good stability.
Table 2 effect experimental example (anti-corrosive properties test)
The antiseptic property of containing sulfate hair cleanser is not detected such as above-mentioned table 2, its result shows: inoculated fungi and antibacterial in containing sulfate hair cleanser not, micro organism quantity in the test sample after 2 days, 6 days, 13 days, 20 days, 27 days respectively, the result shows: micro organism quantity all is lower than 10 in the sample, and its anti-corrosive properties are good.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, so every technical solution of the present invention content that do not break away from,, all still belong in the scope of technical solution of the present invention any simple modification, equivalent variations and modification that above embodiment does according to technical spirit of the present invention.
Claims (10)
1. hair cleanser of containing sulfate not is characterized in that: each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-40%
Non-ionic surface active agent 0.1-25%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0-2%
EDTA-two Na 0-1%
Pearling agent 0-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0-5%
Anti-dandruff dose of 0-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
2. the hair cleanser of not containing sulfate according to claim 1 is characterized in that: each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-30%
Non-ionic surface active agent 0.1-20%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-two Na 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-5%
Anti-dandruff dose of 0.1-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
3. the hair cleanser of not containing sulfate according to claim 2 is characterized in that: each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-25%
Non-ionic surface active agent 0.1-15%
Amphoteric surfactant 0.1-10%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-two Na 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-4%
Anti-dandruff dose of 0.1-1%
Essence 0.1-2.0%
Antiseptic 0.01-1%
PH adjusting agent 0.01-1%,
Viscosity modifier 0.01-1%
Natural extract 0.01%
Water surplus;
Described anion surfactant is any one or the two or more mixture in lauroyl dimethyl hydroxyethyl sodium sulfonate, amino acid type surfactant, the alpha-olefin sodium sulfonate.
4. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that: described amino acid type surfactant is any one or the two or more mixture in sodium lauroyl glutamate, lauroyl Kaglutam, sodium lauroyl sarcosine, potassium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, myristoyl-N-methylaminoacetic acid potassium, cocos nucifera oil acyl Glycine sodium, the cocos nucifera oil acyl glycine potassium.
5. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that: described non-ionic surface active agent is any one or the two or more mixture in coconut oil diethanol amide, Cortex cocois radicis oils and fats single ethanol amide, the alkyl polyglucoside.
6. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that: described amphoteric surfactant is any one or the two or more mixture in lauroyl both sexes base list acetic acid disodium, lauroyl both sexes base list acetic acid list sodium, cocamido propyl betaine, the cocoamido propyl hydroxy sulfobetaine.
7. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that: described cation opsonizing agent is the mixing of guar gum hydroxypropyl-trimethyl ammonium chloride, Polyquaternium-10,12-22 alkyl ammomium chloride, quaternary ammonium salt-91 and PPG-3 benzylic ether myristinate, any one or two or more mixture in the quaternary ammonium salt-52.
8. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that: described pearling agent is glycol distearate or ethylene glycol monostearate or both mixing.
9. the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that:
Described conditioning nursing composition is any one or the two or more mixture in hydrolyzed wheat protein, hydrogenated polydecene, guar gum hydroxypropyl-trimethyl ammonium chloride, keratin, pantolactone, D-panthenol, the vitamin E;
Described pH adjusting agent is citric acid or sodium citrate or both mixing;
Viscosity modifier is sodium chloride;
Described anti-dandruff dose is climbazole or Zinc Pyrithione or both mixing;
Described antiseptic be Methylisothiazolinone (with) in the mixing of methylchloroisothiazandnone, phenoxyethanol, sodium salicylate, sodium benzoate one or more.
10. the preparation method of the hair cleanser of each described not containing sulfate according to claim 1-3 is characterized in that may further comprise the steps:
1) accurately take by weighing in the prescription ormal weight distilled water and add among the beaker A, open heating by electric cooker to 70 ~ 75 ℃ after, turn on agitator, mixing speed are controlled at 500 ~ 600 rev/mins, add the anion surfactant of ormal weight in the prescription, insulation is at 70 ℃-75 ℃;
2) then non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol of ormal weight added among the beaker A successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later on, 200 ~ 300 rev/mins of rotating speed controls; Dissolve rear insulation 10 minutes fully to all materials, begin to cool to 55 ℃ ~ 60 ℃ and add amphoteric surfactantes, add and keep behind the above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃ ~ 50 ℃ after stirring 5min;
3) take by weighing among the cationic surfactant beaker B of formula ratio, the pure water that then adds ormal weight stirs 500 ~ 600 rev/mins of rotating speeds, stir 5min, after dissolving fully or being uniformly dispersed, the material of beaker B is poured among the beaker A, continue to stir, be cooled to 45 ℃ ~ 40 ℃;
4) take by weighing the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence of the amount of prescription regulation in beaker A, rotating speed 500 ~ 600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate respectively pH value and viscosity with pH adjusting agent and viscosity modifier, add antiseptic after reaching predetermined pH value and viscosity, stirred 5 minutes, be cooled to 45 ℃ ~ 40 ℃, stop to stir discharging.
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| CN201210404271.4A CN102895151B (en) | 2012-10-22 | 2012-10-22 | Sulfate-free hair cleanser and preparation method thereof |
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| CN201210404271.4A CN102895151B (en) | 2012-10-22 | 2012-10-22 | Sulfate-free hair cleanser and preparation method thereof |
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