CN111050740A - Composition for caring hair - Google Patents
Composition for caring hair Download PDFInfo
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- CN111050740A CN111050740A CN201880055541.0A CN201880055541A CN111050740A CN 111050740 A CN111050740 A CN 111050740A CN 201880055541 A CN201880055541 A CN 201880055541A CN 111050740 A CN111050740 A CN 111050740A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
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Abstract
The present invention relates to a composition for caring hair, which comprises a cationic surfactant, a sugar-based surfactant, and an amino acid surfactant, and has the effects of improving entanglement of hair, increasing elasticity, and improving fluffy feeling, thereby being widely applicable to products of various formulations.
Description
Technical Field
The application requires application numbers of 10-2017 and 0122260 applied on 9, month and 22 of 2017; and korean patent application No. 10-2018-0106345, filed on 6.9.2018, which is hereby incorporated by reference in its entirety.
The present invention relates to a composition for caring for hair, which improves entanglement of hair, exhibits an effect of improving elasticity and a voluminous feeling, and more particularly to a composition for caring for hair comprising a cationic surfactant, a sugar-based surfactant and an amino acid surfactant.
Background
Generally, human hair is composed of three layers, a cuticle layer (cuticle layer), a cortex layer (cortix) and a medulla layer (medulla). The cuticle layer, which is present as the outermost layer, surrounds the cortex to serve a protective function, and the intact cuticle layer of healthy hair has a smooth surface to serve the functions of refracting light and reducing friction between the hairs.
Hair is easily affected by external environment, and specifically, it is damaged by cold and dry wind, indoor heating, excessive combing, stress, malnutrition, insufficient sleep, and the like. In addition, recently, modern people view hair as a fashion, and accordingly, frequent hair treatment such as hair coloring, perming, and bleaching, excessive use of hair cosmetic products, or use of hair dryers for a long time are increasing, and thus hair is frequently damaged.
When hair is damaged by various physical, chemical or environmental factors, the cuticle layer on the hair surface is damaged, and thus water, protein and lipid in the hair are eluted, so that the hair becomes rough, loses luster, and has increased friction, and the hair is easily tangled, broken, or split ends are generated. In addition, the loss of elasticity causes problems such as collapse of hair, loss of volume, and thinning of hair, and in severe cases, hair breakage and traction alopecia occur.
Accordingly, consumer demand and preference for Conditioning (Conditioning) products capable of maintaining the health of hair is increasing, and research on such products is continuously ongoing.
Existing conditioning products contain cationic surfactants and silicon to improve hair condition. However, even if the condition of hair is improved by conditioning the hair surface, the absorption and smearing of hair are reduced due to the characteristics of the formulation which concentrates on the hair surface, and there is a problem that proper hair conditioning cannot be achieved and there is a limit in imparting elasticity and a bulky feeling to hair, and the hair is collapsed.
In korean patent No. 10-1351473, a novel ammonium salt compound was developed and added together with a cationic surfactant in order to improve overall massage feeling during use, touch feeling during rinsing, soft feeling in a wet state, and soft feeling in a dry state. However, the effect is not expected, and there is no description about the effect of improving the elasticity and the bulky feeling of the hair.
[ Prior art documents ]
[ patent document ]
Korean granted patent No. 10-1351473.
Disclosure of Invention
Technical problem
Based on this, the present inventors have conducted a multi-angle study to solve the above problems, and as a result, verified that when a composition for caring for hair comprises a cationic surfactant, a sugar-based surfactant and an amino acid surfactant, not only is an excellent hair conditioning effect achieved by improving entanglement of hair, but also an excellent effect of improving elasticity and a voluminous feeling is achieved.
Accordingly, an object of the present invention is to provide a composition for caring for hair, which has the effect of improving the condition, elasticity and voluminous feeling of hair.
Technical scheme
In order to achieve the above object, the present invention provides a composition for caring for hair, comprising a cationic surfactant, a sugar-based surfactant, and an amino acid surfactant.
Advantageous effects
The composition for caring for hair of the present invention provides an improvement in the condition of hair by improving entanglement of hair and an improvement in the elasticity and the voluminous feeling.
Drawings
Fig. 1 is a graph showing the results of measuring the elastic force of the hair according to experimental example 1 of the present invention.
Fig. 2 is a graph showing a result of a sense amount of hair voluming according to experimental example 2 of the present invention.
Fig. 3 is a graph showing the results of measuring the entanglement level of the hair according to experimental example 3 of the present invention.
Detailed Description
Hereinafter, the present invention will be described in detail.
The present invention provides a composition for caring for hair, comprising a cationic surfactant, a sugar-based surfactant, and an amino acid surfactant.
Generally, a composition for caring for hair uses a cationic surfactant, unlike a hair cleanser mainly using an anionic surfactant. Since damaged hair exhibits anionic property due to loss of fatty acid on the surface of hair, unlike normal hair, damaged hair can be treated by forming ionic bonds with the inside of hair using the cationic surfactant to fill damaged portions of hair.
However, if only the cationic surfactant is used, there is a problem in that even if the effect of the hair is achieved, the effect of improving the elasticity and the volume feeling of the hair cannot be exhibited.
In contrast, the present invention provides a composition for hair care which not only has a hair conditioning effect but also can exhibit an effect of improving the elasticity and the voluminous feeling.
Specifically, the composition for caring for hair of the present invention comprises a cationic surfactant, a sugar-based surfactant, and an amino acid surfactant.
The cationic surfactant fills damaged parts of hair by forming ionic bonds with damaged hair exhibiting anions, thereby playing a role in caring for damaged hair.
The cationic surfactant is tertiary ammonium or quaternary ammonium salt, and specifically, may include a compound selected from stearamidopropyl dimethyl amine (stearamidopropyl dimethyl amine), behenyl trimethyl ammonium chloride (benzalkonium chloride), behenyl trimethyl ammonium methyl sulfate (benzalkonium chloride), behenyl trimethyl ammonium chloride (cetyltrimethyl ammonium chloride), stearyl trimethyl ammonium chloride (stearamidopropyl dimethyl ammonium chloride), distearyl dimethyl ammonium chloride (distearyl dimethyl ammonium chloride), dicetyldimethyl ammonium chloride (cetyltrimethyl ammonium chloride), cocoamidopropyl dimethyl ammonium chloride (cetyltrimethyl ammonium chloride), stearamidopropyl dimethyl ammonium chloride (stearamidopropyl dimethyl amine), stearamidopropyl dimethyl ammonium chloride (palmityl propyl dimethyl amine), behenyl dimethyl ammonium chloride (behenyl propyl dimethyl amine), behenyl dimethyl ammonium chloride (palmitoyl propyl dimethyl amide), behenyl dimethyl ammonium chloride (behenyl propyl dimethyl amide), behenyl dimethyl amide (palmitoyl propyl dimethyl amide), behenyl propyl dimethyl ammonium chloride (behenamide (isopropyl amide), behenyl dimethyl amide (palmitoyl propyl dimethyl amide (isopropyl dimethyl amide), behenyl dimethyl amide (isopropyl dimethyl amide (palmitoyl propyl amide (isopropyl amide), behenyl dimethyl amide (behenyl propyl amide (isopropyl amide (palmitoyl dimethyl amide), behenamide (isopropyl amide (behenamide (isopropyl amide), behenamide (isopropyl amide), behenyl trimethyl ammonium chloride (behenamide), behenamide (isopropyl amide), behenyl trimethyl ammonium chloride (isopropyl amide), or cetyl amide (isopropyl amide), or isopropyl amide (isopropyl amide), or cetyl trimethyl ammonium chloride (isopropyl amide), or isopropyl amide (isopropyl amide) or isopropyl amide (isopropyl amide), or isopropyl amide (isopropyl amide), or One or more substances, preferably, may include one or more substances selected from stearamidopropyl dimethyl amine (stearamidopropyl dimethyl amine), behenyl trimethyl ammonium chloride (behenyl trimethyl ammonium chloride), behenyl trimethyl ammonium methyl sulfate (behenyl trimethyl ammonium methyl sulfate), and dipalmitoyloxyethyl hydroxyethyl methyl ammonium methyl sulfate (dipalmitoyl hydroxyethyl methyl ammonium methyl sulfate).
Further, the content of the cationic surfactant is 1 to 10% by weight, preferably 1 to 5% by weight, based on the total weight of the composition for caring for hair.
As described above, if the content of the cationic surfactant is 1 to 10% by weight, the conditioning effect of the hair can be improved, and in particular, the entanglement of the hair is improved and the surface of the hair is uniformly treated to reduce the friction on the surface of the hair, so that the suppleness feeling of the hair can be improved.
In the present invention, "conditioning effect" refers to repair of damaged hair or prevention of damage of healthy hair, and specifically refers to imparting softness, moisturization, smoothness, etc. to hair to maintain the healthy state of hair.
The sugar-based surfactant serves to increase the elasticity and the fluffy feeling of hair and improve the entanglement of hair by coating the surface of hair with sugar, thereby increasing the suppleness feeling.
The sugar-based surfactant may include one or more selected from octyl/decyl glucoside (caprylyl/caprylyl glucoside), lauryl glucoside (lauryl glucoside), isostearyl glucoside (isostearyl glucoside), ethyl glucoside (ethyl glucoside), coco-glucoside (coco-glucoside), octyl glucoside (caprylyl glucoside), myristyl glucoside (myristyl glucoside), ascorbyl glucoside (ascorbyl glucoside), cetearyl glucoside (cetearyl glucoside), decyl glucoside (decylglucoside) and glycerol glucoside (glycerol glucoside), and preferably, may include one or more selected from octyl/decyl glucoside (caprylyl/caprylyl glucoside) and cetearyl glucoside (cetearyl glucoside).
Furthermore, the sugar-based surfactant is contained in an amount of 0.5 to 5% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition for caring for hair.
As described above, if the sugar-based surfactant is contained in an amount of 0.5 to 5 wt%, the surface of the hair is coated with sugar, thereby increasing the elasticity and the bulky feeling of the hair, improving entanglement, and thus achieving the effect of softening the hair. However, if the content of the sugar-based surfactant exceeds 5% by weight, the surface of the hair is excessively coated with sugar, so that the hair becomes hard, and thus the effects of improving the elasticity, the bulky feeling, and the tangling of the hair cannot be obtained.
The amino acid surfactant serves as an anionic surfactant, which forms a cation/anion complex structure with the cationic surfactant to soften the surface of hair and improve entanglement between hair strands, thereby achieving an effect of improving the fluffy feeling of hair.
The amino acid surfactant may include one or more selected from sodium stearyl glutamate (sodium stearyl glutamate), sodium cocoyl glutamate (sodium cocoyl glutamate), sodium lauryl glutamate (sodium lauryl glutamate), sodium myristyl glutamate (sodium myristyl glutamate), disodium cocoyl glutamate (sodium cocoyl glutamate), disodium lauryl glutamate (sodium lauryl glutamate), disodium stearyl glutamate (sodium stearyl glutamate), and disodium caprylyl glutamate (sodium caprylyl glutamate), and preferably, may include one or more selected from sodium stearyl glutamate (sodium stearyl glutamate) and sodium cocoyl glutamate (sodium cocoyl glutamate).
Furthermore, the amino acid surfactant is present in an amount of 0.1 to 1 wt%, preferably 0.1 to 0.5 wt%, based on the total weight of the composition for caring for hair.
As described above, when the content of the amino acid surfactant is 0.1 to 1% by weight, the effect of improving the entanglement of hair to improve the soft feeling and the bulky feeling can be obtained. Further, if the content of the amino acid surfactant exceeds 1 wt%, the risk of formulation stability increases, which is not preferable.
In the present invention, the cationic surfactant may be included at 1 to 10 wt%, the sugar-based surfactant may be included at 0.5 to 5 wt%, and the amino acid surfactant may be included at 0.1 to 1 wt%, based on the total weight of the composition for caring for hair, and preferably, the cationic surfactant may be included at 1 to 5 wt%, the sugar-based surfactant may be included at 0.5 to 3 wt%, and the amino acid surfactant may be included at 0.1 to 0.5 wt%.
However, when exceeding the above range, the composition for hair care has poor formulation stability, which may result in difficulty in formulation.
In the present invention, the sugar-based surfactant and the amino acid surfactant are preferably mixed at a weight ratio of 10: 1 to 1: 1, and more preferably at a weight ratio of 5: 1 to 2: 1.
If the sugar-based surfactant and the amino acid surfactant are mixed in a weight ratio of 10: 1 to 1: 1, absorption and spreadability of the composition for caring for hair in the whole hair are enhanced, so that the suppleness, elasticity and fluffiness of hair can be improved due to the improvement of hair tangle; when the ratio of 5: 1 to 2: the above effect can be maximized when the weight ratio of 1 is mixed.
In addition, the composition for caring for hair of the present invention may further comprise a cationic polymer. By including the cationic polymer, a sustained conditioning effect on hair can be obtained, and the effect of improving the bulky feeling can be further increased.
The cationic polymer may include one or more selected from the group consisting of polyquaternium-10 (polyquaternium-10), polyquaternium-11 (polyquaternium-11), polyquaternium-37 (polyquaternium-37), polyquaternium-51 (polyquaternium-51), and polyquaternium-55 (polyquaternium-55), and preferably, may include polyquaternium-55 (polyquaternium-55). The polyquaternium-55 (polyquaternium-55) has a structure in which the length of the hydrophobic chain is long, thereby supporting the surface of hair and firmly wrapping the hair, and is most preferable.
Furthermore, the cationic polymer is present in an amount of 0.01 to 5 wt%, preferably 0.05 to 1 wt%, based on the total weight of the composition for caring for hair.
As described above, the content of the cationic polymer is preferably 0.01 to 5% by weight because the hair conditioning effect and the voluminous feeling enhancing effect can be obtained.
In addition to the above ingredients, the composition for caring for hair according to the present invention may further include an ingredient for strengthening hair. The hair-strengthening ingredient may be, for example, one or more substances selected from extracts of natural products derived from animals, plants, minerals, etc., amino acids, peptides, proteins, high molecular compounds, silicon compounds, fatty alcohols, fatty acids, waxes, and ester compounds, as a substance acting on the outside of hair to increase the thickness of hair or fill damaged parts.
In addition, the composition for caring for hair of the present invention may include any conventional ingredient known to those skilled in the art for maintaining basic physical properties and qualities, in addition to the above-mentioned ingredients, for example, may further include a foaming agent, a detergent, a pearlizing agent, a preservative, a thickener, a viscosity modifier, a pH modifier, a chelating agent, an oil, a perfume, etc., and may include deionized water, an organic solvent, etc., as a solvent.
As the foaming agent and the cleaning agent, an anionic surfactant, an amphoteric (zwitter) ionic surfactant, or an amphoteric surfactant, a nonionic surfactant, or a combination thereof may be included.
As the anionic surfactant, a surfactant selected from alkyl sulfates, alkyl sulfonates, alkyl carboxylates, alkyl ether sulfates, alkyl isethionates, alkyl taurates, alkyl sulfosuccinates, alkyl sulfoacetates, alkyl phosphates, anionic amino acid derivatives, anionic polypeptide derivatives, anionic derivatives of alkyl polyglucosides, fatty acid soaps, and mixtures thereof may be used, and among the alkyl sulfates, Ammonium Lauryl Sulfate (ALS), Ammonium Lauryl Sulfate (ALES), Sodium Lauryl Sulfate (SLS), and Sodium Lauryl Sulfate (SLES) may be used.
The zwitterionic or amphoteric surfactant may use (C8-C20) alkyl betaine, N- (C8-C20) alkyl amido betaine and its derivatives, glycine derivatives, sulfobetaine and its derivatives, (C8-C20) alkyl polyaminocarboxylate, (C8-C20) alkyl amphoacetate, sodium lauroamphoacetate and mixtures thereof, but is not limited thereto. Preferably, it is selected from the group consisting of amine oxides, cocoamphocarboxyglycinates, cocamidopropyl betaines and mixtures thereof.
The nonionic surfactant can be selected from block copolymers of poly (ethylene oxide) and poly (propylene oxide), alkyl esters and polyalkyl esters of poly (ethylene oxide), Oxyalkylated alcohols (oxyalkylenated alcohol), alkyl ethers and polyalkyl ethers of poly (ethylene oxide), alkyl esters and polyalkyl esters of polyoxyethylated sorbitan, alkyl ethers and polyalkyl ethers of polyoxyethylated sorbitan, alkyl glycosides and polyalkylglycosides or alkylpolyglycosides and polyglycosides, alkyl esters and polyalkyl esters of sucrose, alkyl esters and polyalkyl esters of polyoxyethylated glycerol, alkyl ethers and polyalkyl ethers of polyoxyethylated glycerol, gemini surfactants, alkyl alcohols, and mixtures thereof.
As the pearling agent, ethylene glycol distearate, ethylene glycol monostearate, fatty acid, or the like can be used.
The preservative comprises a mixture of methylparaben (methyl p-hydroxybenzoate), methylparaben (methylparaben), butylparaben, ethylparaben, propylparaben, benzyl alcohol, phenoxyethanol, phenoxyisopropanol, phenylpropanol, methylchloroisothiazolinone, and methylisothiazolinone.
The thickener or viscosity modifier comprises fatty alcohol, fatty acid, hydroxypropyl methylcellulose, hydroxymethyl cellulose, sodium chloride, ammonium chloride, propylene glycol, and hexylene glycol.
The pH adjusting agent includes acetic acid, lactic acid, adipic acid, aminoethylpropanediol, aminomethylpropanediol, aminomethylpropanol, aminopropanediol, ascorbic acid, Azelaic acid (Azelaic acid), benzoic acid, butyldiethanolamine, butylethanolamine, citric acid, dibutylethanolamine, diethanolamine, diisopropylamine, diisopropanolamine, dimethylisopropanolamine, diethylethanolamine, Galacturonic acid (Galacturonic acid), Glycolic acid (Glycolic acid), isopropanolamine, isopropylamine, malic acid, Malonic acid (Malonic acid), and Methylethanolamine (Methylethanolamine).
The organic solvent includes n-butanol, t-butanol, Benzyl alcohol, phenethyl alcohol, hexanol, isopropanol, methanol, oleyl alcohol, propanol, cyclohexanedimethanol, phenoxyethanol, butoxyethanol, deoxyethanol, methoxyethanol, methoxydiglycol, butanediol, propylene Glycol, pentanediol, hexanediol, benzyldiol (Benzyl Glycol), diethylene Glycol, dipropylene Glycol, 1, 2-butanediol, 1, 4-butanediol, 2, 3-butanediol, 1, 3-propanediol, 1, 5-pentanediol, isoprene Glycol, ethylhexanediol, 1, 2-hexanediol, 1,2, 6-hexanetriol, 1, 10-decanediol, 3-methoxybutanol, methoxyisopropanol, methoxymethylbutanol, ethylene carbonate, propylene carbonate, and mixtures thereof.
The humectant of the component that may be further contained is not particularly limited, and glycerin, polyhydric alcohol, propylene glycol, 1, 3-butylene glycol, dipropylene glycol, sorbitol, and the like may be used, and the colorant may be a component commonly used in scalp and hair preparations, and is not particularly limited.
The composition for caring for hair according to the present invention comprising the above-mentioned composition can improve entanglement of hair to improve the suppleness feeling of hair, can improve the elasticity and the volume feeling of hair, and preferably, can improve the elasticity and the volume feeling of hair by using the cationic surfactant, the sugar-based surfactant, and the amino acid surfactant.
Therefore, the composition for caring for hair of the present invention can be used for improving entanglement of hair, enhancing elasticity of hair or enhancing fluffy feeling of hair, and more preferably, can be used for enhancing elasticity of hair or enhancing fluffy feeling of hair.
The composition for Hair care of the present invention can be applied to all formulations applicable to Hair such as Hair conditioner (Hair rinse), Hair conditioner (Hair conditioner), Hair cream (Hair cream), Hair cream (Hair position), scalp care film, Hair tonic (Hair tonic), Hair spray (Hair mist), Hair tonic, Hair treatment cream (Hair treatment), ampoule, Hair conditioner (Hair serum), Hair mousse, Hair wax, Hair spray, Hair styling gel, or scalp conditioner (Hair treatment). In this case, the method for preparing the dosage form is not particularly limited, and a general method known in the art can be used without limitation.
[ examples ] A method for producing a compound
[ examples 1 to 11 and comparative examples 1 to 6 ] preparation of composition for caring hairRinse-off type compositions for conditioning hair of cream were prepared according to the compositions and contents of tables 1 and 2 below.
[ TABLE 1 ]
(unit: wt%)
[ TABLE 2 ]
(unit: wt%)
[ Experimental example 1 ] measurement of Hair elasticity
The composition prepared as above was treated on hair, and then the elasticity of hair was measured to evaluate the elasticity effect of the composition for hair care prepared in said examples 1 to 9 and comparative examples 1 to 6.
The hair used at this time was a hair strand (tress) (manufactured by Phoenix Korea company) which was washed with a base shampoo having no conditioning function, rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3g of the compositions for hair care of examples 1 to 9 and comparative examples 1 to 6, respectively.
Hair elasticity was measured using a multifunctional hair measuring instrument MTT175 (manufactured by DiaStron corporation) on hair to which the composition for hair care of examples 1 to 9 and comparative examples 1 to 6 were applied.
Specifically, hair tresses coated with the compositions for caring hair of examples 1 to 9 and comparative examples 1 to 6 were fixed in a dome shape having a height of 1.5 cm. Then, the initial force was set to 0.001N by the push-pull piston and pressurization was performed with a force increased by 0.001N per second. At this time, the force is applied in the vertical direction from the apex of the arch, and the pressure on the measuring member equipped with the push-pull piston is measured while pressurizing. This was repeated 30 times after measuring the force at the arch collapse of the hair. In this case, the hair elastic force is a force supported by the hair when the center point is pressed after the hair is bent into a dome shape, and a larger supported force means a larger elastic force of the hair. The results obtained at this time are shown in fig. 1.
From the results of fig. 1, it was confirmed that the elasticity of the hair treated by the compositions for hair care of examples 1 to 5, which contained the cationic surfactant, the sugar-based surfactant and the amino acid surfactant in the preferred content ranges according to the present invention and included the weight ratio of the sugar-based surfactant to the amino acid surfactant in the preferred weight ratio ranges, was increased as compared to the untreated hair and the hair treated by the compositions for hair care of comparative examples 1 to 6.
Further, a method is utilized that: hair treated with the composition for hair care of example 6 comprising sugar-based surfactant and amino acid surfactant in a weight ratio of 1 also showed excellent elasticity by using a surfactant having a ratio of more than 10: the hair treated with the composition for hair care of example 8 comprising sugar-based surfactant and amino acid surfactant in a weight ratio of 1 showed excellent elasticity due to the increase of sugar-based surfactant.
The method comprises the following steps of 1: 1, example 7 comprising a sugar-based surfactant and an amino acid surfactant in a weight ratio of less than 1: 1 weight ratio of the hair treated with the composition for caring hair of example 9 comprising sugar-based surfactant and amino acid surfactant, the effect of increasing hair elasticity due to the decrease in the content of sugar-based surfactant was very small.
In contrast, the hair treated with the compositions for caring hair of comparative examples 1 and 4, which do not contain a sugar-based surfactant and an amino acid surfactant, and comparative examples 2 and 5, which do not contain a sugar-based surfactant and contain only an amino acid surfactant, had an elastic force similar to that of untreated hair, and the hair treated with the compositions for caring hair of comparative examples 3 and 6, which contain a sugar-based surfactant but do not contain an amino acid surfactant, had an increased elastic force compared to untreated hair, but had a lower effect of improving the elastic force than those of examples 1 to 6 and 8.
It can be seen that the composition for caring for hair of the present invention has an effect of improving hair elasticity.
[ Experimental example 2 ] measurement of Hair fluffiness
The compositions prepared as above were treated to the hair and then measured for the voluminous feeling of the hair to evaluate the effect of the elasticity of the compositions for hair care prepared in said examples 1 to 9 and comparative examples 1 to 6.
The hair used at this time was a hair strand (tress) (manufactured by Phoenix Korea company) which was washed with a base shampoo having no conditioning function, rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3g of the compositions for hair care of examples 1 to 9 and comparative examples 1 to 6, respectively.
The voluminous feeling of the hair applied with the compositions for hair care of examples 1 to 9 and comparative examples 1 to 6 was measured by measuring the resistance when the hair strand passes through a prescribed diameter using a multifunctional hair measuring instrument MTT175 (manufactured by DiaStron corporation) machine, and the results thereof are shown in fig. 2.
From the results of fig. 2, it was confirmed that the hair treated by the compositions for hair care of examples 1 to 5, which contain the cationic surfactant, the sugar-based surfactant and the amino acid surfactant at the preferred contents according to the present invention and include the sugar-based surfactant and the amino acid surfactant at the preferred weight ratio ranges, had an increased feeling of volume as compared to the untreated hair and the hair treated by the compositions for hair care of comparative examples 1 to 6.
Further, a method is utilized that: hair treated with the composition for hair care of example 6 containing the sugar-based surfactant and the amino acid surfactant at a weight ratio of 1 also showed excellent results in a voluminous feel, and the hair treated with the composition for hair care of example 6 was treated with a surfactant having a weight ratio of more than 10: the hair treated with the composition for hair care of example 8 comprising the sugar-based surfactant and the amino acid surfactant at a weight ratio of 1 failed to exhibit the effect of sufficiently improving the voluminous feeling due to the decrease in the amino acid surfactant, but exhibited the effect superior to those of comparative examples 1 to 6.
The method comprises the following steps of 1: 1, example 7 comprising a sugar-based surfactant and an amino acid surfactant in a weight ratio of less than 1: hair treated with the composition for hair care of example 9 containing a sugar-based surfactant and an amino acid surfactant at a weight ratio of 1 exhibited an effect of increasing a hair volume feeling due to an increase in the content of the amino acid surfactant.
In contrast, the hair treated with the compositions for caring hair of comparative examples 1 and 4, which did not contain sugar-based surfactant and amino acid surfactant, had a reduced volume feeling as compared with untreated hair. Further, the hair treated with the compositions for caring hair of comparative examples 2 and 5, which contained no sugar-based surfactant but contained only amino acid surfactant, had a slightly increased voluminous feeling as compared with untreated hair, but did not exhibit the effects equivalent to examples 1 to 9. The hair treated with the composition for hair care of comparative example 3, which did not contain the amino acid surfactant but contained only the sugar-based surfactant, exhibited a similar voluminous feeling to the untreated hair. The hair treated with the composition for hair care of comparative example 6 having the same composition as comparative example 3 but containing a sugar-based surfactant in an amount higher than that of comparative example 3 had a reduced voluminous feeling as compared with the untreated hair.
It can be seen that the composition for caring for hair of the present invention has an effect of improving the hair volume feeling.
[ Experimental example 3 ] measurement of Hair tangle
The combing resistance of the hair was measured after the above-prepared composition was treated on the hair to evaluate the entanglement-improving effect of the compositions for hair care prepared in said examples 1 to 9 and comparative examples 1 to 6.
The higher the combing resistance of the hair, the higher the entanglement of the hair is meant.
The hair used at this time was a hair strand (tress) (manufactured by Phoenix Korea company) which was washed with a base shampoo having no conditioning function, rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3g of the composition for hair care of examples 1 to 9 and comparative examples 1 to 6.
The degree of entanglement of the hair applied with the compositions for hair care of examples 1 to 9 and comparative examples 1 to 6 was measured by measuring the force to which the hair tresses were subjected at the time of combing using a multifunctional hair measuring instrument MTT175 (manufactured by DiaStron corporation) machine, and the results thereof are shown in fig. 3.
From the results of fig. 3, it was confirmed that the hair treated by using the composition for hair care of examples 1 to 5, which contains the cationic surfactant, the sugar-based surfactant and the amino acid surfactant in the preferred content ranges according to the present invention and contains the sugar-based surfactant and the amino acid surfactant in weight ratios within the preferred weight ratio ranges, was less in combing resistance and thus was less tangled, as compared to the untreated hair (104.75gmf) and the hair treated by using the composition for hair care of comparative examples 1 to 6.
Further, a method is utilized that: 1, example 6 comprising a sugar-based surfactant and an amino acid surfactant in a weight ratio of more than 10: 1 weight ratio of hair treated with the composition for hair care of example 8 comprising sugar-based surfactant and amino acid surfactant, the degree of hair tangling measured due to the increase of sugar-based surfactant was slightly higher, but showed results lower than those of comparative examples 1 to 6.
The method comprises the following steps of 1: 1 and example 7 comprising a sugar-based surfactant and an amino acid surfactant in a weight ratio of less than 1: hair treated with the composition for hair care of example 9 comprising a sugar-based surfactant and an amino acid surfactant in a weight ratio of 1 showed an excellent effect in hair tangle improvement due to an increase in the content of the amino acid surfactant.
As can be seen, the composition for caring for hair of the present invention has the effect of improving hair tangle to enhance the soft feeling of hair.
From the results of the experimental examples 1 to 3, it was confirmed that the composition for hair care of the present invention comprising the sugar-based surfactant and the amino acid surfactant exhibited the effects of increasing the elasticity, increasing the bulky feeling, and improving the tangling.
In particular, it is found that the composition for hair care containing the cationic surfactant, the sugar-based surfactant and the amino acid surfactant in the preferable content ranges and the weight ratio of the sugar-based surfactant to the amino acid surfactant in the preferable weight ratio range according to the present invention exhibits excellent effects in 3 effects of increasing the elasticity, increasing the bulky feeling and improving the entanglement.
Further, the composition for hair care of example 3 is most excellent in the effects of increasing the elasticity, increasing the voluminous feeling, and improving the hair tangle, and thus it is understood that the above-described effects are most excellent when behenyltrimethylammonium chloride is used as the cationic surfactant, octyl/decyl glucoside is used as the sugar-based surfactant, sodium stearyl glutamate is used as the amino acid surfactant, and polyquaternium-55 is used as the cationic polymer.
Therefore, the present invention can overcome the existing problem of hair collapse due to poor elasticity and fluffy feeling, and the composition for hair care of the present invention can be widely applied to products of various formulations.
[ dosage forms example 1 ] Hair tonics
According to the composition and content shown in table 3 below, a conditioner was prepared according to a usual method.
[ TABLE 3 ]
Formulation example 2 Hair cream
According to the composition and content of table 4 below, hair cream was prepared according to a usual method.
[ TABLE 4 ]
Formulation example 3 Hair conditioner essence (hair)
serum)
The hair care essence was prepared according to the general method according to the composition and content of table 5 below.
[ TABLE 5 ]
Formulation example 4 Hair conditioner essence (hair)
essence)
The hair care essence was prepared according to the usual method according to the composition and content of table 6 below.
[ TABLE 6 ]
Formulation example 5 Hair cream (hair)
cream)
According to the composition and content of table 7 below, a hair cream was prepared according to a usual method.
[ TABLE 7 ]
Formulation example 6 styling Agents
The molding agent was prepared according to the usual method with the composition and content shown in Table 8 below.
[ TABLE 8 ]
| Composition (I) | Content (unit: wt%) |
| Cationic surfactant | 2 |
| Sugar-based surfactant | 2 |
| Amino acid surfactants | 0.5 |
| Microcrystalline wax | 5 |
| VP/VA copolymer | 5 |
| Glycerol | 15 |
| Perfume | 0.5 |
| Pigment | 0.1 |
| Purified water | Balance of |
Claims (12)
1. A composition for treating hair comprising a cationic surfactant, a sugar-based surfactant and an amino acid surfactant.
2. A composition for the care of hair according to claim 1, characterized in that said cationic surfactant comprises one or more substances selected from stearamidopropyl dimethylamine, behenyl trimethyl ammonium chloride, behenyl trimethyl ammonium methyl sulfate, behenyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, cocamidopropyl dimethylamine, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, oleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, palmitamidopropyl trimethyl ammonium chloride, ricinoleic acid amidopropyl dimethylamine and dipalmitoyloxyethyl hydroxyethyl methyl ammonium methyl sulfate.
3. Composition for the care of the hair according to claim 1, characterized in that said sugar-based surfactant comprises one or more substances selected from octyl/decyl glucoside, lauryl glucoside, isostearyl glucoside, ethyl glucoside, coco-glucoside, octyl glucoside, myristyl glucoside, ascorbyl glucoside, cetearyl glucoside, decyl glucoside and glycerol glucoside.
4. A composition for the care of hair according to claim 1, characterized in that said amino acid surfactant comprises one or more substances selected from sodium stearoyl glutamate, sodium cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, disodium cocoyl glutamate, disodium lauroyl glutamate, disodium stearoyl glutamate and disodium caprylyl glutamate.
5. The composition for hair care according to claim 1, characterized in that the cationic surfactant is contained in an amount of 1 to 10% by weight, the sugar-based surfactant is contained in an amount of 0.5 to 5% by weight, and the amino acid surfactant is contained in an amount of 0.1 to 1% by weight, based on the total weight of the composition for hair care.
6. Composition for the care of the hair according to claim 1, characterized in that the weight ratio of said sugar-based surfactant to said amino acid surfactant is 10: 1 to 1: 1.
7. the composition for treating hair according to claim 1, further comprising a cationic polymer.
8. The composition for treating hair according to claim 7, wherein the cationic polymer comprises one or more materials selected from the group consisting of polyquaternium-10, polyquaternium-11, polyquaternium-37, polyquaternium-51, and polyquaternium-55.
9. The composition for treating hair according to claim 7, wherein the cationic polymer is contained in an amount of 0.01 to 5% by weight, based on the total weight of the composition for treating hair.
10. Composition for the care of hair according to claim 1, characterized in that it is used to improve the entanglement of the hair, to increase the elasticity or to increase the voluminous feel.
11. Composition for the care of hair according to claim 10, characterized in that it is used to increase the elasticity or to increase the voluminous feel.
12. The composition for treating hair according to claim 1, wherein the composition is in the form of a hair conditioner, hair rinse, hair cream, scalp conditioner, hair tonic, hair spray, hair tonic, hair cream, ampoule, hair conditioner, hair mousse, hair wax, spray hair gel, styling gel, or scalp conditioner.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20170122260 | 2017-09-22 | ||
| KR10-2017-0122260 | 2017-09-22 | ||
| KR1020180106345A KR20190034084A (en) | 2017-09-22 | 2018-09-06 | Composition For Hair Care |
| KR10-2018-0106345 | 2018-09-06 | ||
| PCT/KR2018/010965 WO2019059608A1 (en) | 2017-09-22 | 2018-09-18 | Hair care composition |
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| CN111050740A true CN111050740A (en) | 2020-04-21 |
| CN111050740B CN111050740B (en) | 2023-06-06 |
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| CN201880055541.0A Active CN111050740B (en) | 2017-09-22 | 2018-09-18 | Composition for caring hair |
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|---|---|
| KR (1) | KR20190034084A (en) |
| CN (1) | CN111050740B (en) |
| TW (1) | TW201919571A (en) |
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| CN111957228A (en) * | 2020-08-11 | 2020-11-20 | 广州碧涛化妆品有限公司 | Emulsifying device and preparation method of pomade |
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| KR102326035B1 (en) * | 2020-03-05 | 2021-11-15 | 엑스카즈믹 주식회사 | Composition for improving condition of hair and preventing hair loss |
| KR102301510B1 (en) * | 2021-04-29 | 2021-09-13 | 주식회사 리치바이오 | hair treatment composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050031570A1 (en) * | 2003-08-08 | 2005-02-10 | Kpss-Kao Professional Salon Services Gmbh | Cosmetic composition for hair |
| CN102895151A (en) * | 2012-10-22 | 2013-01-30 | 广州立白企业集团有限公司 | Sulfate-free hair cleanser and preparation method thereof |
| CN103826600A (en) * | 2011-04-01 | 2014-05-28 | 考格尼斯知识产权管理有限责任公司 | Hair care agent |
| CN104203202A (en) * | 2012-04-03 | 2014-12-10 | 巴斯夫欧洲公司 | Hair cosmetic composition which comprises a plant lecithin |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101351473B1 (en) | 2007-05-17 | 2014-01-14 | 주식회사 엘지생활건강 | Hair conditioner composition having improved sm00thness and slippery feel on dry hair |
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2018
- 2018-09-06 KR KR1020180106345A patent/KR20190034084A/en not_active IP Right Cessation
- 2018-09-18 CN CN201880055541.0A patent/CN111050740B/en active Active
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050031570A1 (en) * | 2003-08-08 | 2005-02-10 | Kpss-Kao Professional Salon Services Gmbh | Cosmetic composition for hair |
| CN103826600A (en) * | 2011-04-01 | 2014-05-28 | 考格尼斯知识产权管理有限责任公司 | Hair care agent |
| CN104203202A (en) * | 2012-04-03 | 2014-12-10 | 巴斯夫欧洲公司 | Hair cosmetic composition which comprises a plant lecithin |
| CN102895151A (en) * | 2012-10-22 | 2013-01-30 | 广州立白企业集团有限公司 | Sulfate-free hair cleanser and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111957228A (en) * | 2020-08-11 | 2020-11-20 | 广州碧涛化妆品有限公司 | Emulsifying device and preparation method of pomade |
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| Publication number | Publication date |
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| CN111050740B (en) | 2023-06-06 |
| KR20190034084A (en) | 2019-04-01 |
| TW201919571A (en) | 2019-06-01 |
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