JP2018076268A - Cleansing agent composition, and cleansing method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cleansing agent composition that has a good texture and good foaming during rinsing, and a cleansing method.SOLUTION: A cleansing agent composition contains a component (A): linear or branched polyglycerol-modified silicone.SELECTED DRAWING: None

Description

  The present disclosure relates to a cleaning composition and a cleaning method.

  The hair cleansing composition is used to wash away dirt on the hair and scalp. As a component of the hair cleansing composition, for example, any one of an anionic surfactant, a nonionic surfactant, and an amphoteric surfactant is used alone, or two or more thereof are used in combination. In addition, in order to improve the feel at the time of rinsing, a cationic surfactant and a cationic polymer are blended with the above-described hair cleaning composition to form a complex. Furthermore, a shampoo composition containing a polyether-modified silicone or the like is also known (see, for example, Patent Document 1).

JP 58-74798 A

  However, the conventional techniques as described above have not yet been sufficiently satisfied with regard to squeaking, hardness, and smoothness during rinsing. In addition, by blending the polyether-modified silicone and the like as described above, creaking and hardness at the time of rinsing, smoothness can be improved to some extent, but it causes another problem of inhibiting foaming, There is a problem that it is difficult to improve various characteristics in a balanced manner.

  In one aspect of the present disclosure, it is desirable to provide a cleaning composition excellent in feel and foaming during rinsing and a cleaning method.

  One aspect of the present disclosure is a cleaning composition, which contains a linear or branched polyglycerin-modified silicone as the component (A). According to the thus-configured cleaning composition, since it contains the component (A), it becomes a cleaning composition excellent in feel and foaming during rinsing.

  Another embodiment of the present disclosure is a cleaning method for cleaning gray hair using the cleaning composition of the present disclosure. According to such a cleaning method, since the gray hair is washed using the cleaning composition as described above, the feeling and foaming during rinsing are excellent, and the feeling during rinsing is good even for gray hair. can do.

  For example, elderly people and the like change the hair quality and the touch when the gray hair increases. In the case of gray hair, there is a problem that the conventional cleaning composition is not sufficiently satisfactory with respect to the feel during rinsing. On the other hand, if it is the cleaning composition of this indication, the feel at the time of the rinse with respect to gray hair can be made favorable by mix | blending the component as mentioned above.

Hereinafter, the cleaning composition of the present disclosure will be described in more detail.
(1) Details of cleaning composition [component (A)]
The cleaning composition of the present disclosure includes linear or branched polyglycerin-modified silicone as the component (A). In the present disclosure, the polyglycerin-modified silicone is a compound having a structure in which a polyglycerin chain is introduced into a silicone chain. As the polyglycerin-modified silicone, either a linear polyglycerin-modified silicone having a linear silicone chain or a branched polyglycerin-modified silicone having a branched silicone chain may be used. May be. However, the alkyl co-modified polyglycerin-modified silicone is hardly soluble in water and it is difficult to obtain a transparent composition. Therefore, for example, when it is desired to configure as a transparent shampoo, it is preferable to use a non-alkyl co-modified type.

  The polymerization number of the polyglycerin chain is usually 2 or more, preferably 3 or more, and usually 5 or less, preferably 4 or less. Specific examples of the polyglycerin-modified silicone include polyglyceryl-3 disiloxane dimethicone, polyglyceryl-3 polydimethylsiloxyethyl dimethicone, and the like.

  As such a polyglycerin-modified silicone, a commercially available product can be used. For example, “KF-6100” manufactured by Shin-Etsu Chemical Co., Ltd. can be used as polyglyceryl-3disiloxane dimethicone. As polyglyceryl-3 polydimethylsiloxyethyl dimethicone, “KF-6104” manufactured by Shin-Etsu Chemical Co., Ltd. or the like can be used.

  Although the compounding quantity of a component (A) should just be prepared suitably, it is 0.01 mass%-5 mass% in the mass ratio which occupies in the whole cleaning composition, for example, Preferably it is 0.05 mass%-3 mass. %, More preferably 0.1% by mass to 1% by mass. By making the blending amount of the component (A) 0.01% by mass or more, the feeling at the time of rinsing becomes good. The feeling at the time of rinsing can be improved by making the blending amount of the component (A) 0.05% by mass or more, and the blending amount of the component (A) is 0.1% by mass or more. Therefore, it can be further improved. Moreover, by making the compounding quantity of a component (A) into 5 mass% or less, it can suppress that it becomes overconditioning (namely, excessive adsorption | suction and accumulation | storage of a component), and, thereby, for example, hair is hardened. Can be suppressed. The effect of suppressing overconditioning is further improved by setting the amount of component (A) to 3% by mass or less, and further improved by setting the amount of component (A) to 1% by mass or less.

  By blending component (A), unlike the case of blending polyether-modified silicone or the like, it is possible to improve the squeeze, hardness, and smoothness during rinsing without excessively inhibiting foaming.

[Component (B)]
The cleaning composition of the present disclosure may contain an amino acid-based anionic surfactant as the component (B). In the cleaning composition of the present disclosure, examples of the amino acid-based anionic surfactant include N-acylamino acid type surfactants. The N-acyl amino acid type surfactant is a salt of an amino acid having a saturated or unsaturated acyl group, and a salt of an analog of the same amino acid. Examples of the amino acid include glutamic acid, glycine, aspartic acid, alanine, phenylalanine, leucine, isoleucine, methionine, proline, tryptophan, valine, serine, N-methylglycine (sarcosine), and N-methylalanine. . Examples of the amino acid analog include 2-aminoethanesulfonic acid (taurine) and N-methyltaurine. Further, the acidic amino acid and its analogs may be any of D-form, L-form, and DL-form.

  Examples of the counter ion of the anionic group include sodium, potassium, magnesium, monoethanolamine, and triethanolamine. Specific examples of the N-acyl amino acid type surfactant include, for example, triethanolamine cocoyl glutamate, sodium lauroylmethyl-β-alanine, sodium lauroyl aspartate, sodium lauroylmethyl taurate, sodium stearoyl glutamate, sodium myristoyl glutamate, and palmitoyl Mention may be made of sodium proline. Among these amino acid-based anionic surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination. Of these, an amino acid salt having an acyl group is preferred from the viewpoint of good feeling during rinsing.

  Although the compounding quantity of a component (B) should just be prepared suitably, for example, 1 mass%-20 mass% in the mass ratio which occupies in the whole cleaning composition, Preferably 3 mass%-15 mass%, More preferably Is preferably adjusted to 5 mass% to 10 mass%. By setting the blending amount of the component (B) to 1% by mass or more, foaming during use can be improved. Foaming at the time of use becomes better when the blending amount of the component (B) is 3% by mass or more, and better when the blending amount of the component (B) is 5% by mass or more. Moreover, the feeling at the time of a rinse becomes favorable by the compounding quantity of a component (B) being 20 mass% or less. The feeling at the time of rinsing becomes better by setting the blending amount of the component (B) to 15% by mass or less, and further improved by setting the blending amount of the component (B) to 10% by mass or less.

[Component (C)]
Moreover, the cleaning composition of this indication may contain the amphoteric surfactant as a component (C). In the cleaning composition of the present disclosure, examples of the amphoteric surfactant include cocamidopropyl betaine, lauramidopropyl betaine, coco betaine, lauryl betaine, isostearamid propyl betaine, hydroxyalkyl (C12-C14) hydroxyethyl sarcosine. And sodium cocoamphoacetate, sodium lauroamphoacetate, sodium cocoamphopropionate, and the like.

  Although the compounding quantity of a component (C) should just be prepared suitably, it is 1 mass%-20 mass% in the mass ratio which occupies in the whole cleaning composition, for example, Preferably it is 3 mass%-15 mass%, More preferably Is preferably adjusted to 5 mass% to 10 mass%. By setting the blending amount of the component (C) to 1% by mass or more, foaming during use can be improved. Moreover, it can suppress that a viscosity falls by the compounding quantity of a component (C) being 1 mass% or more. When it is desired to improve the effect of suppressing foaming and viscosity reduction during use, the blending amount of component (C) may be 3% by mass or more. When the effect of suppressing viscosity decrease is to be further improved, component (C ) May be 5% by mass or more. Moreover, the feeling at the time of a rinse becomes favorable by the compounding quantity of a component (C) being 20 mass% or less. The feeling at the time of rinsing becomes better by setting the blending amount of the component (C) to 15% by mass or less, and further improved by setting the blending amount of the component (A) to 10% by mass or less.

[Total amount of component (B) and component (C)]
Both the component (B) and the component (C) described above serve as foaming components. Therefore, about the component (B) and the component (C), it is preferable to consider the compounding amount which totaled both. Specifically, the total amount of component (B) and component (C) is, for example, 1% by mass to 25% by mass, preferably 5% by mass to 20% by mass, based on the mass ratio in the entire cleaning composition. More preferably, it may be adjusted to 10% by mass to 18% by mass. Thus, foaming at the time of use becomes favorable by adjusting the total compounding quantity of a component (B) and a component (C).

[Component (D)]
Moreover, the cleaning composition of this indication may contain the nonionic surfactant as a component (D). In the cleaning composition of the present disclosure, as the nonionic surfactant, (D1) a nonionic surfactant that is liquid at room temperature and (D2) a nonionic surfactant that is solid at room temperature can be used. it can. Either a nonionic surfactant that is liquid at room temperature or a nonionic surfactant that is solid at room temperature may be added, or both may be added. In addition, the room temperature as used in this indication means 25 degreeC.

  (D1) Nonionic surfactants that are liquid at room temperature include, for example, coconut oil fatty acid polyethylene glycol-7 glyceryl, cocamide DEA, cocamide methyl MEA, decyl glucoside, lauryl glucoside, (lauryl / myristyl) glycol hydroxypropyl ether, isostearic acid PEG-20 sorbitan, polyglyceryl-10 laurate, BG laurate, PEG-20 sorbitan cocoate, polysorbate 40, polysorbate 60, polysorbate 80, laureth-2, laureth-4, laureth-9, (C12-14) palace-7, (C12-14) Palace-9, (C12-14) Palace-12, etc. can be employed.

  (D2) Nonionic surfactants that are solid at room temperature include, for example, ceteareth-60 myristyl glycol, cocamide MEA, PEG-3 lauramide, PEG-150 distearate, PEG-80 sorbitan laurate, crocus myristate, tris PEG-120 methyl glucose isostearate, PEG-120 methyl glucose dioleate, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, ceteth-10, ceteth-15, ceteth- 20, ceteth-25, ceteth-30, ceteth-40, steareth-20, etc. can be employed.

  Although the compounding quantity of a component (D) should just be prepared suitably, for example, it is good to be prepared by 0.1 mass%-15 mass% in the mass ratio which occupies in the whole cleaning composition. However, with regard to component (D), the blending amount is also adjusted depending on whether (D1) a nonionic surfactant that is liquid at room temperature or (D2) a nonionic surfactant that is solid at room temperature. Specifically, in the case of the component (D1), the blending amount is 0.1% by mass to 10% by mass, preferably 0.5% by mass to 7% by mass, based on the mass ratio in the entire cleaning composition. More preferably, it may be adjusted to 1% by mass to 5% by mass. By making the blending amount of the component (D1) 0.1% by mass or more, the feeling at the time of rinsing becomes good. The feeling at the time of rinsing becomes better when the blending amount of the component (D1) is 0.5% by mass or more, and even better when the blending amount of the component (D1) is 1% by mass or more. Become. Moreover, it can suppress becoming overconditioning by the compounding quantity of a component (D1) being 10 mass% or less. The effect of suppressing overconditioning is further improved by setting the amount of component (D1) to 7% by mass or less, and further improved by setting the amount of component (D1) to 5% by mass or less. .

  On the other hand, in the case of a component (D2), it is good to adjust the compounding quantity to 0.5 mass%-6 mass% by the mass ratio which occupies in the whole cleaning composition. In this case, by setting the blending amount of the component (D2) to 0.5% by mass or more, the foam quality can be improved, and the viscosity of the base can be increased. Moreover, the feeling at the time of a rinse becomes favorable by the compounding quantity of a component (D2) being 6 mass% or less.

  Further, in the cleaning composition of the present disclosure, when an anionic surfactant is contained, the feel during rinsing is better when the blending amount of the sulfuric anionic surfactant is suppressed. This is preferable. More specifically, the cleaning composition of the present disclosure contains an anionic surfactant, and the proportion of the sulfuric anionic surfactant in the entire anionic surfactant is 50% by mass. It may be prepared as follows. In addition, in the cleaning composition of this indication, when the above-mentioned component (B) is contained, the above-mentioned component (B) is also contained in the whole anionic surfactant here.

  Examples of sulfuric anionic surfactants include alkyl sulfates such as sodium lauryl sulfate and triethanolamine lauryl sulfate, and alkyl ether sulfates such as sodium POE lauryl ether sulfate. When the sulfuric anionic surfactant is suppressed to 50% by mass or less in the total blending amount of all the anionic surfactants blended in the cleaning composition, the feel during rinsing is improved. The feel at the time of rinsing becomes better when the sulfuric anionic surfactant is 25% by mass or less, and even better if no sulfuric anionic surfactant is added.

[Other ingredients]
In addition, the cleaning composition of this indication may contain other components in the range which does not impair the effect as a cleaning composition other than the main components as mentioned above. For example, guar hydroxypropyltrimonium chloride and polyquaternium-10 may be blended to improve the softness of hair. Thereby, a soft feeling can be improved, for example with respect to the hair from which the elasticity has disappeared with aging.

  For example, a ume fruit extract may be blended in order to increase the elasticity of the hair. For example, a pomegranate flower extract may be blended in order to suppress hair undulation. Furthermore, in order to reduce the burden on the scalp associated with shampooing, a sapin strawberry triphorius fruit extract may be blended. Thereby, the burden on the scalp is reduced and the hair can be gently washed.

  In addition to these, each component that is generally contained in the cleaning composition and does not impair the action of the above-described components and the effect of the present invention may be contained. Examples of such components include oily components, solvents, surfactants other than those described above, polymer compounds, acid dyes, hair coloring materials, sugars, preservatives, chelating agents, stabilizers, herbal extracts, vitamins, fragrances, Mention may be made of antioxidants, UV absorbers, pH adjusters, and inorganic salts. These components may be contained alone as one specific example, or may be contained in combination of two or more.

  Examples of the oil component include fats and oils, waxes, higher alcohols, hydrocarbons, higher fatty acids, alkyl glyceryl ethers, esters, and silicones. Specific examples of fats and oils include, for example, olive oil, camellia oil, shea fat, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil, Mention may be made of avocado oil, macadamia nut oil, castor oil, palm oil and evening primrose oil. Specific examples of the wax include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.

  Specific examples of higher alcohols include, for example, cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol. , Decyltetradecanol, and lanolin alcohol.

  Specific examples of the hydrocarbon include paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, and petroleum jelly. Specific examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, and lanolin fatty acid. Specific examples of alkyl glyceryl ethers include, for example, batyl alcohol, chimyl alcohol, seraalkyl alcohol, and isostearyl glyceryl ether.

  Specific examples of esters include, for example, diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl stearate, stearyl stearate, myristyl myristate, isotridecyl myristate, 2-ethyl palmitate Hexyl, octyldodecyl ricinoleate, cholesteryl / lanosteryl consisting of fatty acids having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, Cetyl caprate, glyceryl tricaprylate, diisostearyl malate, dioctyl succinate, diethoxyethyl succinate, and 2-ethylhexyl Mention may be made of phosphate cetyl.

  Specific examples of silicones include, for example, dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane (dimethiconol), and an average polymerization degree of 650 to 10,000. Highly polymerized silicone, polyether modified silicone (eg (PEG / PPG / butylene / dimethicone) copolymer), amino modified silicone, betaine modified silicone, alkyl modified silicone, alkoxy modified silicone, mercapto modified silicone, carboxy modified silicone, and fluorine Mention may be made of modified silicones. Among the specific examples of these oily components, only one kind may be contained alone, or two or more kinds may be contained in combination.

  Examples of the solvent include water and organic solvents. Examples of the organic solvent include ethanol, isopropanol, benzyl alcohol, benzyloxyethanol, glycol, and glycerin. Examples of glycols include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, and 1,3-butylene glycol. Examples of glycerin include glycerin, diglycerin, and polyglycerin. Among the specific examples of these solvents, only one kind may be contained alone, or two or more kinds may be contained in combination.

  As the surfactant, a surfactant different from that defined as the components (B), (C), and (D) may be blended. Such a surfactant can be blended as a solubilizer that solubilizes each component, in addition to being blended as a cleaning component. Moreover, it can mix | blend in order to adjust the viscosity of a composition or to improve viscosity stability. Examples of surfactants different from those defined as the above components (B), (C), and (D) include anionic surfactants other than amino acids, cationic surfactants, and the like.

  Examples of anionic surfactants other than amino acids include ether carboxyl, sulfonic acid, and phosphoric acid anionic surfactants. Specifically, for example, dodecylbenzenesulfonic acid triethanolamine, sodium tetradecenesulfonate, alkyl (carbon number 6 to 24) ether carboxylic acid, hydroxyalkyl (carbon number 6 to 24) ether carboxylic acid, polyoxyalkylenation Alkyl (carbon number 6-24) ether carboxylic acid, polyoxyalkylenated alkyl (carbon number 6-24) aryl ether carboxylic acid, polyoxyalkylenated alkyl (carbon number 6-24) amide ether carboxylic acid, and Alkali metal salts (for example, sodium salts, potassium salts, etc.), organic amine salts (for example, monoethanolamine salts, diethanolamine salts, triethanolamine salts, monoisopropanolamine salts, etc.), POE lauryl ether phosphoric acid and its salts Raising It is possible.

  Examples of the cationic surfactant include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, ethyl lanolin sulfate. Examples include fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methacryloyloxyethyltrimethylammonium chloride, and behenyltrimethylammonium methylsulfate.

  Examples of the polymer compound include nonionic polymers, anionic polymers, cationic polymers, and amphoteric polymers. Nonionic polymers include, for example, hydroxyethylcellulose, hydroxypropylmethylcellulose, hydroxypropylcellulose, methylcellulose, dextrin, galactan, pullulan, highly polymerized polyethylene glycol, polyvinyl alcohol, etc., homo- and copolymers of vinylpyrrolidone, especially polyvinylpyrrolidone alone, vinyl Examples thereof include a copolymer of pyrrolidone and vinyl acetate, or a trade name “rubiscol” (manufactured by BASF), a terpolymer of vinyl pyrrolidone, vinyl acetate and vinyl propionate. Moreover, for example, various acrylic acid and methacrylic acid ester, acrylamide and a copolymer of methacrylamide, for example, polyacrylamide having a molecular weight of 100,000 or more, dimethylhydantoin formaldehyde resin and the like can be mentioned.

  Anionic polymers can include, for example, xanthan gum, carrageenan, sodium alginate, gum arabic, pectin, and carboxyvinyl polymer. Cationic polymers include, for example, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, O- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydroxyethylcellulose chloride, hydroxy Cationized cellulose such as ethylcellulose dimethyl diallylammonium chloride; Cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guagum chloride; Cationized dextran such as dextran chloride hydroxypropyltrimethylammonium ether Cationized polysaccharides obtained by cationizing polysaccharides such as cellulose derivatives, natural gums, starches, and dextrans; N- [2-hydroxy-3- (trimethylammonio) propyl] hydrochloride chloride Collagen, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed silk chloride, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed keratin chloride, N- [2- chloride] Hydroxy-3- (trimethylammonio) propyl] hydrolyzed conchiolin, N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrolyzed keratin chloride, N- [2-hydroxy-3- (stearyldimethyl) chloride Ammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrochloride silk, N- [2-hydroxy-3- (stearyldimethylammonio) propyl chloride] hydrochloride Degraded conchiolin, N- [2-hydroxy-3- (lauryl chloride) chloride Methylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (lauryldimethylammonio) propyl chloride] Hydrolyzed silk, N- [2-hydroxy-3- (lauryldimethylammonio) propyl chloride] hydrolyzed conchiolin, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed soybean protein White, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed collagen chloride, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed silk, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) chloride (Lopyl) hydrolyzed keratin, cationized hydrolyzed protein obtained by cationizing hydrolyzed protein such as N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed conchiolin, Dimethyldiallylammonium chloride / acrylamide copolymer, β-methacryloxyethyltrimethylammonium / acrylamide copolymer, vinylpyrrolidone / N, N-dimethylaminoethylmethacrylic acid copolymer diethyl sulfate, β-methacryloxyethyltrimethylammonium / Cationized vinyl or acrylic polymer such as acrylamide copolymer, polydimethylmethylenepiperidinium chloride; N, N-dimethylaminoethyl diethyl sulfate, N, N-dimethylacrylamide, dimethacrylic acid Examples thereof include polyglycol polyamine condensates such as polyethylene glycol; dimethyl adipionate-aminohydroxypropyl diethyltriamine copolymer; aminoethylaminopropyl / methyl polysiloxane copolymer.

  Examples of the amphoteric polymer include N-methacryloylethyl N, N-dimethylammonium α-N-methylcarboxybetaine / butyl methacrylate copolymer (commercial name: Yucaformer AM-75; manufactured by Mitsubishi Chemical Corporation), hydroxypropyl acrylate, Butylaminoethyl methacrylate / acrylic acid octylamide copolymer (commercial name; Amphomer 28-4910; manufactured by National Starch), dimethyldiallylammonium chloride / acrylic acid copolymer (commercial name; Marcote 280, 295; Ondeo Narco) Co., Ltd.), dimethyldiallylammonium chloride / acrylamide / acrylic acid terpolymer (commercial name; Marquat Plus 3330, 3331; manufactured by Ondeo Narco), acrylic acid / methyl acrylate / methacrylamidopropyltrimethyla Moniumu copolymer (trade name; Merquat 2001; manufactured by Ondeo Nalco Co.) and the like. Among the specific examples of these polymer compounds, only one kind may be contained alone, or two or more kinds may be contained in combination.

  Examples of the sugar include sorbitol, maltose, glycosyl trehalose, and N-acetylglucosamine. Examples of preservatives include paraoxybenzoic acid ester, paraben, methyl paraben and sodium benzoate. Examples of chelating agents include edetic acid (ethylenediaminetetraacetic acid (EDTA)) and salts thereof, diethylenetriaminepentaacetic acid and salts thereof, and hydroxyethanediphosphonic acid (ethidronic acid, HEDP) and salts thereof.

  Examples of the stabilizer include phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, and tannic acid. Examples of the antioxidant include ascorbic acid and sulfite. Examples of inorganic salts include sodium chloride and sodium carbonate.

  The cleaning composition of the present disclosure is, for example, in the form of a shampoo product using water as a solvent or a dispersion medium. In this case, when a transparent shampoo is desired, the transparency of the cleaning composition is maintained by using a linear or branched polyglycerin-modified silicone other than the alkyl co-modified type as the component (A). be able to. With regard to the transparency of the cleaning composition, even when the cleaning composition is opaque or low in transparency, it can be in the form of a shampoo product. However, in the case of a cleaning composition with low transparency or low transparency, in order to make the turbidity of the cleaning composition inconspicuous, a countermeasure such as adding a pearlizing agent such as ethylene glycol distearate or triethylene glycol distearate, etc. Is required. In this respect, if it is configured as a transparent shampoo, it can be made into a product having a good appearance without blending a pearling agent.

  The dosage form of the cleaning composition is not particularly limited, and may be, for example, an aqueous solution, a dispersion, an emulsion, a gel, a foam (foam), or a cream. For example, when making the dosage form of the cleaning composition into a foam, an aerosol container may be used, or a non-aerosol container may be used. Examples of the non-aerosol container include a pump former container and a squeeze foamer container.

  The cleaning composition of the present disclosure may be applied to hair wet with water or hot water, or may be applied to dry hair, but is preferably applied to wet hair. The method for applying the cleaning composition to the hair is not particularly limited, and a known method can be appropriately used. Examples of the application method include application by hand comb, application by spraying, and application using a comb or a brush. The cleaning composition is used in a cleaning process in which foaming is performed in accordance with a conventional method and then rinsed with water or hot water. However, the use of the cleaning composition of the present disclosure is not particularly limited, and can be used as a cleaning agent for the body (body soap), a facial cleanser, a hand soap, etc. in addition to the above-described hair cleaning.

(2) Experimental Example Next, the embodiment of the present invention will be described more specifically with reference to some examples and comparative examples.

  Cleaning compositions containing the components shown in Table 1 and Table 2 below were prepared. Each numerical value corresponding to each component shown in Table 1 and Table 2 indicates the blending amount of each component, and the unit is mass%. In Tables 1 and 2, the symbols “A”, “B”, “C”, “D1”, and “D2” added to the left side of each component indicate the components (A ), (B), (C), (D1), and (D2). The symbol “not A” appended to the left side of each component indicates that the component appended with the symbol is a component for comparison with the component (A), and the symbol “not B” is the symbol Indicates that the component marked with is a component for comparison with the component (B).

  As an experimental procedure, 20 high-damaged hair women that were repeatedly subjected to hair dyeing or decoloring treatment multiple times were used as subjects, and appropriate amounts of each hair cleaning composition shown in Tables 1 and 2 were applied to each subject's hair. This was applied and subjected to a hair washing treatment according to a conventional method. Thereafter, the hair was washed away with water. Each cleaning composition was evaluated for “foaming” and “feel during rinsing” by the following methods.

[Bubbling]
Among the 20 subjects, the number of subjects evaluated as having good foaming (excellent foaming property) is 16 or more is “excellent: AA”, and the case of 11 to 15 is “good: A”. The case of 6 to 10 people was evaluated as “normal: B”, and the case of 5 or less people was evaluated as “bad: C” in four stages.

[Rinse feel]
Among the 20 subjects, the number of subjects evaluated that the fingering during rinsing is good is 16 or more, “Excellent: AA”, and 11-15, “Good: A”, 6 A case of 10 people was evaluated as “Normal: B”, and a case of 6 people or less was evaluated as “Bad: C” in 4 grades.

  As a comprehensive evaluation, the evaluation result for at least one of the above two evaluation items is “AA” or “A” and there is no evaluation item whose evaluation result is “C”. Anything other than passing was rejected. As shown in Table 1 and Table 2, in each of Examples 1 to 21, the evaluation results of “foaming” and “feel during rinsing” were “AA”, “A”, or “B”. .

  On the other hand, Comparative Example 1 is an example in which the component (A) referred to in the present disclosure is not included. However, in Comparative Example 1, the evaluation result of “feel during rinsing” was “C”. Moreover, the comparative example 2 is an example which mix | blended polyethyleneglycol-11 methyl ether dimethicone instead of the component (A). However, in Comparative Example 2, the evaluation result of “foaming” was “C”. The comparative example 3 is an example which mix | blended dimethicone instead of the component (A). However, in Comparative Example 3, the evaluation result of “foaming” was “C”. In the case of Comparative Example 3, the cleaning composition was turbid, and the transparency of the cleaning composition was reduced. Therefore, in the case of the comparative example 3, if it is as it is, the commercial property as a cleaning composition will become low. Therefore, in order to compensate for this, for example, it is necessary to further add a component that becomes an opaque pearl shampoo. In other words, when preparing a transparent shampoo composition, it turned out that it cannot respond | correspond with prescription like the comparative example 3. FIG.

  Example 2 is an example in which an amino acid-based anionic surfactant different from that in Example 1 is employed as the component (B). In both Examples 1 and 2, the evaluation results of “foaming” and “feel during rinsing” were “AA”. Example 3 is an example in which an amphoteric surfactant different from that in Example 1 was employed as the component (C). In both Examples 1 and 3, the evaluation results of “foaming” and “feel during rinsing” were “AA”.

  In Example 1, as component (D) in the present disclosure, both (D1) a nonionic surfactant that is liquid at normal temperature and (D2) a nonionic surfactant that is solid at normal temperature are blended. On the other hand, Example 4 is an example in which the component (D) referred to in the present disclosure is not included. However, in the case of Example 4, the evaluation results of “bubble generation” and “feel during rinsing” were “A”. In Example 5, the component (D) contains (D2) a nonionic surfactant that is solid at room temperature, but (D1) does not contain a nonionic surfactant that is liquid at room temperature. It is. However, in the case of Example 5, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “A”. Example 6 is an example in which (D1) a nonionic surfactant that is liquid at room temperature is included as the component (D), but (D2) a nonionic surfactant that is solid at room temperature is not included. . However, in the case of Example 6, the evaluation result of “foaming” was “A”, and the evaluation result of “feel during rinsing” was “AA”.

  Examples 7-10 are the examples which changed the compounding quantity of the component (A) from Example 1. FIG. Even in Examples 7 to 10, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “AA” or “A”. Although both Examples 7 and 8 were good evaluation results, Example 7 was more preferable when both were compared. Although both Examples 9 and 10 were good evaluation results, Example 10 was more preferable when both were compared.

  Examples 11 and 12 are examples in which the blending amount of the component (B) was changed from that in Example 1. Even in Example 11, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “A”. In the case of Example 12, the evaluation result of “foaming” was “A”, and the evaluation result of “feel during rinsing” was “AA”. Examples 13 and 14 are examples in which the blending amount of the component (C) was changed from that in Example 1. Even in Example 13, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “A”. In the case of Example 14, the evaluation result of “foaming” was “A”, and the evaluation result of “feel during rinsing” was “AA”.

  Examples 15-17 are the examples which changed the compounding quantity of the component (D2) with Example 1. FIG. In the case of Example 15, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “AA”. In the case of Example 16, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “A”. In the case of Example 17, the evaluation result of “foaming” was “A”, and the evaluation result of “feel during rinsing” was “AA”. Examples 18-20 are the examples which changed the compounding quantity with respect to Example 1 about some of components (A)-(D). In each of Examples 18 to 20, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “AA”.

  Example 21 is an example in which the component (B) referred to in the present disclosure is not included. In the case of Example 21, the evaluation result of “foaming” was “B”, and the evaluation result of “feel during rinsing” was “AA”. Therefore, although Example 21 is also passed as comprehensive evaluation, it turns out that it is more preferable to mix | blend a component (B) in order to improve foaming further. Example 22 is an example in which a sulfuric acid-based anionic surfactant was blended in place of the component (B) in the present disclosure (that is, an amino acid-based anionic surfactant). In the case of Example 22, the evaluation result of “foaming” was “AA”, and the evaluation result of “feel during rinsing” was “B”. Therefore, although Example 22 is also passed as comprehensive evaluation, it turns out that the feeling at the time of a rinse becomes favorable when the component (B) is mix | blended.

  In Example 22, the total amount of the component (B) exemplified in Examples 1 and 2 is replaced with a sulfuric acid-based anionic surfactant. However, the component (B) and the sulfuric anionic surfactant can be used in combination. As an intermediate formulation between Example 1 and Example 22, for example, the blending amount of the component (B) is 3.75% by mass, and the blending amount of the sulfuric anionic surfactant is 3.75% by mass. In other words, the sulfuric anionic surfactant is 50% by mass in the total amount of the anionic surfactant. In this case, the feeling at the time of rinsing is improved as compared with Example 22 and approaches Example 1.

  In order to further improve the feel during rinsing as compared with the above intermediate formulation, the blending amount of component (B) is 5.625% by mass, and the blending amount of sulfuric anionic surfactant is 1.875% by mass. (In other words, in the total amount of the anionic surfactant, the sulfuric anionic surfactant is 25% by mass). In this case, the feel during rinsing is further improved over the intermediate formulation described above, approaching Example 1.

  That is, in the total blending amount of all the anionic surfactants blended in the cleaning composition, when the sulfuric anionic surfactant is suppressed to 50% by mass or less, the feel during rinsing is good. Thus, when the sulfuric anionic surfactant is adjusted to 25% by mass or less, the feel during rinsing becomes better, and when no sulfuric anionic surfactant is blended (that is, Example 1). , 2), the feeling during rinsing is further improved.

  Example 23 is an example in which the component (C) referred to in the present disclosure is not included. In the case of Example 23, the evaluation result of “foaming” was “B”, and the evaluation result of “feel during rinsing” was “AA”. Therefore, although Example 23 is also passed as comprehensive evaluation, it turns out that it is more preferable to mix | blend a component (C) in order to improve foaming further.

  Furthermore, in the case of the cleaning composition of Example 1, the “feel during rinsing” was good for both black hair and gray hair. However, in the case of the cleaning composition of Comparative Example 2, there was a tendency that the “feel during rinsing” was not good particularly in the case of gray hair. Comparative Example 2 is different from Example 1 in that polyethylene glycol-11 methyl ether dimethicone is blended instead of component (A) and component (B) is not blended. Accordingly, the cleaning composition of Example 19 was also tested. As a result, the cleaning composition of Example 19 had good “feel during rinsing” for both black hair and gray hair. Therefore, from these results, it is considered that the component (A) is important for improving the “feel during rinsing” for gray hair. Further, it is considered that both “foaming” and “feel during rinsing” can be improved by blending component (B) in addition to component (A).

(3) Formulation example Next, the cleaning composition of the present disclosure is exemplified in the following Table 3, Table 4, and Table 5 in which other components are further added.

  The cleaning composition containing each component shown in Table 3 was excellent in the feel and foaming at the time of rinsing, and particularly excellent in the feeling at the time of rinsing for gray hair.

  The cleaning composition containing each component shown in Table 4 was excellent in the feel and foaming at the time of rinsing, and particularly excellent in the feeling at the time of rinsing for gray hair.

The cleaning composition containing each component shown in Table 5 was excellent in feel and foaming at the time of rinsing, and particularly excellent in touch when rinsing gray hair.
(4) Other Embodiments While the cleaning composition has been described with reference to exemplary embodiments, the above-described embodiments are merely exemplified as one aspect of the present disclosure. In other words, the present disclosure is not limited to the exemplary embodiments described above, and can be implemented in various forms without departing from the technical idea of the present disclosure.

  For example, in each column of “(2) Experimental Example” and “(3) Formulation Example”, some specific substances are exemplified as specific examples of the components (A) to (D). Other substances may be used as long as they are the substances mentioned in “Details of Cleaning Composition”.

Claims (8)

A cleaning composition containing a linear or branched polyglycerin-modified silicone as component (A). The cleaning composition according to claim 1,
As an ingredient (B), an amino acid anionic surfactant is contained,
A cleaning composition containing an amphoteric surfactant as component (C). The cleaning composition according to claim 1 or 2,
A cleaning composition containing a nonionic surfactant as component (D). The cleaning composition according to claim 3,
A cleaning composition containing (D1) a nonionic surfactant that is liquid at room temperature as the component (D). The cleaning composition according to claim 3 or 4, wherein
A cleaning composition containing 0.5% to 6% by mass of (D2) a nonionic surfactant that is solid at room temperature as a component (D) in a mass ratio of the entire cleaning composition. A cleaning composition according to any one of claims 1 to 5, wherein
A cleaning composition comprising an anionic surfactant and a ratio of a sulfuric anionic surfactant occupying in the entire anionic surfactant to 50% by mass or less. A cleaning composition according to any one of claims 1 to 6,
A cleaning composition for gray hair. The washing | cleaning method which wash | cleans gray hair using the cleaning composition as described in any one of Claim 1- Claim 7.