CN102885740B - Hair cleanser containing no dioxane residue and preparation method of hair cleanser - Google Patents
Hair cleanser containing no dioxane residue and preparation method of hair cleanser Download PDFInfo
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- CN102885740B CN102885740B CN201210404185.3A CN201210404185A CN102885740B CN 102885740 B CN102885740 B CN 102885740B CN 201210404185 A CN201210404185 A CN 201210404185A CN 102885740 B CN102885740 B CN 102885740B
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Abstract
The invention discloses a hair cleanser containing no dioxane residue and a preparation method of the hair cleanser. The hair cleanser comprises the following components by weight percent: 1-40% of ionic surfactant, 0.1-25% of nonionic surfactant, 0.1-15% of amphoteric surfactant, 0.1-5% of cationic conditioning agent, 0-2% of cetyl alcohol, 0-1% of EDTA-2Na, 0-5% of pearlescent agent, 0.1-3% of conditioning and caring ingredients, 0-5% of polydimethylsiloxane, 0.1-2.0% of essence, 0-3% of anti-dandruff agent, 0.01-1% of preservative, 0.01-1% of pH adjusting agent, 0.01-1% of viscosity adjusting agent and 0.01-5% of natural extract. Epoxy ethane is not included in the raw materials used in the formula of the hair cleanser disclosed by the invention, so no dioxane is contained in the formula, milder effect and lower irritation of the hair cleanser is mild and slightly irritates the scalp. Compared with the hair cleanser in the prior art, the hair cleanser disclosed by the invention can avoid residual dioxane in the hair cleanser, and simultaneously, the formula is mild and slightly irritates the scalp.
Description
Technical field
The present invention relates to a kind of hair cleanser, belong to daily chemical product technical field, particularly relate to a kind of hair cleanser that does not contain dioxanes residue and preparation method thereof.
Background technology
Dioxanes is the by-product of shampoo and bath gel product main surfactant used, the surfactant of use ethyleneoxide addition explained hereafter all contains the dioxanes of different content, and the shampoo that sell most markets and bath gel product contain dioxanes.
Although in America and Europe, Association of South-east Asian Nations, Japan, existing cosmetics management is not all made stipulations to cosmetic material by-product dioxanes, dioxanes potential risks or objective reality.Dioxanes, and may cause damage to liver, kidney and nervous system by zest to skin, eye and respiratory system, during acute poisoning, may cause death.
Therefore, how developing a kind of shampoo that does not contain dioxanes residue, make it can avoid above-mentioned potential hazard, is the primary technical barriers that solve of current one of ordinary skill in the art.
Summary of the invention
The object of the present invention is to provide a kind of newly not containing the hair cleanser of dioxanes residue, make its production and application simple and convenient, and anti-corrosive properties and having good stability, gentleer to scalp in use procedure, zest is still less.
The object of the invention to solve the technical problems realizes by the following technical solutions.A kind of hair cleanser that does not contain dioxanes residue proposing according to the present invention, each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-40%;
Non-ionic surface active agent 0.1-25%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0-2%
EDTA-bis-Na(disodiumedetates) 0-1%
Pearling agent 0-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0-5%
Anti-dandruff dose of 0-3%
PH adjusting agent 0.01-3%
Viscosity modifier 0.01-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
Natural extract 0.01-5%
Water surplus;
Described anion surfactant is alkyl sodium sulfate, alkylsurfuric acid ammonium, alkylsurfuric acid triethanolamine, amino acid type surfactant.
In addition, a kind of hair cleanser that does not contain dioxanes residue, each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-30%
Non-ionic surface active agent 0.1-20%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-disodium 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-5%
Anti-dandruff dose of 0.1-3%
PH adjusting agent 0.01-3%
Viscosity modifier 0.01-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
Natural extract 0.01-3%
Water surplus;
Described anion surfactant is alkyl sodium sulfate, alkylsurfuric acid ammonium, alkylsurfuric acid triethanolamine, amino acid type surfactant.
Moreover, a kind of hair cleanser that does not contain dioxanes residue, each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-25%
Non-ionic surface active agent 0.1-15%
Amphoteric surfactant 0.1-10%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-disodium 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-4%
Anti-dandruff dose of 0.1-1%
PH adjusting agent 0.01-3%
Viscosity modifier 0.01-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
Natural extract 0.01-1%
Water surplus;
Described anion surfactant is alkyl sodium sulfate, alkylsurfuric acid ammonium, alkylsurfuric acid triethanolamine, amino acid type surfactant.
The hair cleanser that does not contain dioxanes residue of the present invention, any one in described amino acid type surfactant sodium lauroyl glutamate, lauroyl Kaglutam, sodium lauroyl sarcosine, potassium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, myristoyl-N-methylaminoacetic acid potassium, cocos nucifera oil acyl Glycine sodium, cocos nucifera oil acyl glycine potassium or two or more mixture;
Described non-ionic surface active agent is any one or the two or more mixture in coconut oleoyl amine MEA, coconut oil diethanol amide, Oleum Cocois single ethanol amide, alkyl polyglucoside;
Described amphoteric surfactant is any one or the two or more mixture in lauroyl both sexes base list acetic acid disodium, lauroyl both sexes base list acetic acid list sodium, cocamido propyl betaine, cocoamido propyl hydroxy sulfobetaine;
Described cation opsonizing agent is any one or the two or more mixture in guar gum hydroxypropyl-trimethyl ammonium chloride, Polyquaternium-10,12-22 alkyl ammomium chloride;
Described pearling agent is glycol distearate or ethylene glycol monostearate or both mixing;
Described conditioning nursing composition is any one or the two or more mixture in hydrolyzed wheat protein, hydrogenated polydecene, guar gum hydroxypropyl-trimethyl ammonium chloride, keratin, pantolactone, D-panthenol, vitamin E;
Described pH adjusting agent is citric acid, sodium citrate or both mixing;
Described viscosity modifier is sodium chloride;
Described anti-dandruff dose is climbazole, Zinc Pyrithione or both mixing;
Described antiseptic be Methylisothiazolinone and methylchloroisothiazandnone mixing, phenoxyethanol, sodium salicylate, sodium benzoate one or more;
Described natural extract is one or more in Radix Ginseng extract, Radix Polygoni Multiflori extract, Fructus Gleditsiae Abnormalis extract, Rhizoma Zingiberis Recens extract, Radix Sophorae Flavescentis extract, Fructus cnidii extract, Cortex Dictamni extract, Radix Stemonae extract.
In addition, the present invention also provides the above-mentioned preparation method that does not contain the hair cleanser of dioxanes residue, comprises the following steps:
1) accurately take ormal weight distilled water in formula and add in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600 revs/min, adds the anion surfactant of ormal weight in formula, and insulation is at 70 ℃-75 ℃;
2) non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol that take formula ratio add in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, and rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed; The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
By technique scheme, the advantage that the present invention has is:
In composition of raw materials of the present invention, adopt dodecyltriethanolamine sulfate salt as main surfactant, this surfactant does not relate to oxirane in synthetic, thereby there is no the residual quantity risk of potential dioxanes; Meanwhile, this raw material as mild as a dove, is mainly used in baby's shower product of having one's hair wash abroad.By the shampoo of this preparation of raw material, the risk that both can avoid dioxanes to bring, there is again, the still less remarkable result such as zest gentleer to scalp.
The specific embodiment
By concrete preferred embodiment and effect experimental example, the present invention is expressed in further detail below, but the present invention is not limited in following embodiment.
embodiment 1
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Dodecyltriethanolamine sulfate 25%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Sophorae Flavescentis extract 0.3%
Fructus cnidii extract 0.5%
Cortex Dictamni extract 0.2%
Radix Stemonae extract 0.3%
Water surplus;
1) accurately take distilled water 30g and add in beaker A, open behind heating by electric cooker to 70～75 ℃ turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), add dodecyltriethanolamine sulfate 25g, insulation is at 70 ℃-75 ℃.
2) then coconut oleoyl amine MEA1g, glycol distearate 1.8g, EDETATE SODIUM 0.1g, spermol 0.5g are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Extremely all materials dissolve completely, keep temperature and rotating speed constant, after stirring 5min, are cooled to 60 ℃～65 ℃.
3) take guar gum hydroxypropyl-trimethyl ammonium chloride 0.6g to beaker B, then add water 15g to stir, rotating speed 1350～1400, stirs 5min.Then the material of beaker B is poured in beaker A, continued to stir.
4) cool after 40～45 ℃, add successively polydimethylsiloxane? 2.21g, lauroyl both sexes base list acetic acid disodium 10g, ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1g, Methylisothiazolinone (with) methylchloroisothiazandnone 0.1g, essence 0.6g stir, rotating speed 300～400.Adjust pH to plant with viscosity conformance with standard and require discharging.
embodiment 2
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkylsurfuric acid triethanolamine 15%
Alkyl sodium sulfate 10%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Fructus Gleditsiae Abnormalis extract 0.3%
Water surplus;
1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
embodiment 3
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkylsurfuric acid triethanolamine 15%
Alkylsurfuric acid ammonium 10%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Ginseng extract 0.3%
Water surplus;
1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
embodiment 4
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkylsurfuric acid triethanolamine 25%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Polygoni Multiflori extract 1%;
Water surplus;
1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
embodiment 5
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkylsurfuric acid triethanolamine 5%
Alkylsurfuric acid ammonium 10%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Zinc Pyrithione 2%
Water surplus;
1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
embodiment 6
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkylsurfuric acid ammonium 8%
Alkyl polyglucoside 5%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Polygoni Multiflori extract 1%;
Water surplus; 1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
embodiment 7
Described not containing dioxanes hair cleanser, its effective ingredient includes the raw material of following percentage by weight and makes:
Alkyl sodium sulfate 8%
Cocoyl glycine potassium 5%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Sodium salicylate 0.3%
Sodium benzoate 0.5%;
Water surplus; 1) accurately taking ormal weight distilled water in formula adds in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600(rotating speed unit: 17 revs/min, as follows), the anion surfactant that adds ormal weight in formula, insulation is at 70 ℃-75 ℃;
2) then the non-ionic surface active agent of ormal weight, pearling agent, EDETATE SODIUM, spermol are added in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed.The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
It is below effect experimental example of the present invention.
effect experimental example 1(stability test)
In order to detect not containing dioxanes shampoo stability, will containing dioxanes shampoo, not be placed on respectively under room temperature, low temperature-15 ° C, 40 ° of C environment of high temperature, observe the cosmetic variation situation of sample; The sample that is regularly opposite to room temperature carries out viscosity, pH value is measured, and observes the variation of two indexs.
Result shows: be placed in the sample under varying environment, significant change does not occur appearance color, without floccule or precipitation, without lamination, has good stability.
the test of effect experimental example 2(anti-corrosive properties)
To do not carry out preservation challenge tests in 28 days of CTFA recommendation containing dioxanes shampoo.
Result shows: in sample, the quantity of antibacterial and fungus is all lower than 10, and its antiseptic power is excellent.
dioxanes residual quantity test in effect experimental example 3(shampoo)
Use gas chromatogram tandem mass spectrometry to detect not containing dioxanes residual quantity in dioxanes shampoo.
Result shows: of the present invention not containing dioxanes shampoo, in its formula, do not contain dioxanes residual quantity.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, therefore every, do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the modification above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. not containing a hair cleanser for dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-30%
Non-ionic surface active agent 0.1-20%
Amphoteric surfactant 0.1-15%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-disodium 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-5%
Anti-dandruff dose of 0.1-3%
PH adjusting agent 0.01-3%
Viscosity modifier 0.01-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
Natural extract 0.01-3%
Water surplus;
Described anion surfactant is the above mixture of any one or two kinds in alkyl sodium sulfate, alkylsurfuric acid ammonium, alkylsurfuric acid triethanolamine, amino acid type surfactant;
Described amino acid type surfactant is any one or the two or more mixture in sodium lauroyl glutamate, lauroyl Kaglutam, sodium lauroyl sarcosine, potassium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, myristoyl-N-methylaminoacetic acid potassium, cocos nucifera oil acyl Glycine sodium, cocos nucifera oil acyl glycine potassium;
Described non-ionic surface active agent is any one or the mixture of two kinds in coconut oil diethanol amide, Oleum Cocois single ethanol amide;
Described amphoteric surfactant is any one or the two or more mixture in lauroyl both sexes base list acetic acid disodium, lauroyl both sexes base list acetic acid list sodium, cocamido propyl betaine, cocoamido propyl hydroxy sulfobetaine;
Described cation opsonizing agent is any one or the two or more mixture in guar gum hydroxypropyl-trimethyl ammonium chloride, Polyquaternium-10,12-22 alkyl ammomium chloride;
Described pearling agent is glycol distearate or ethylene glycol monostearate or both mixing;
Described conditioning nursing composition is any one or the two or more mixture in hydrolyzed wheat protein, hydrogenated polydecene, guar gum hydroxypropyl-trimethyl ammonium chloride, keratin, pantolactone, D-panthenol, vitamin E;
Described pH adjusting agent is citric acid or sodium citrate or both mixing;
Described viscosity modifier is sodium chloride;
Described anti-dandruff dose is climbazole or Zinc Pyrithione or both mixing;
Described antiseptic is any one or the two or more mixture in the mixing, phenoxyethanol, sodium salicylate, sodium benzoate of Methylisothiazolinone and methylchloroisothiazandnone;
Described natural extract is any one or the two or more mixture in Radix Ginseng extract, Radix Polygoni Multiflori extract, Fructus Gleditsiae Abnormalis extract, Rhizoma Zingiberis Recens extract, Radix Sophorae Flavescentis extract, Fructus cnidii extract, Cortex Dictamni extract, Radix Stemonae extract.
2. according to claim 1 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Anion surfactant 1-25%
Non-ionic surface active agent 0.1-15%
Amphoteric surfactant 0.1-10%
Cation opsonizing agent 0.1-5%
Spermol 0.1-2%
EDTA-disodium 0.01-1%
Pearling agent 0.1-5%
Conditioning nursing composition 0.1-3%
Polydimethylsiloxane 0.1-4%
Anti-dandruff dose of 0.1-1%
PH adjusting agent 0.01-3%
Viscosity modifier 0.01-3%
Essence 0.1-2.0%
Antiseptic 0.01-1%
Natural extract 0.01-1%
Water surplus;
Described anion surfactant is the above mixture of any one or two kinds in alkyl sodium sulfate, alkylsurfuric acid ammonium, alkylsurfuric acid triethanolamine, amino acid type surfactant;
Described amino acid type surfactant is any one or the two or more mixture in sodium lauroyl glutamate, lauroyl Kaglutam, sodium lauroyl sarcosine, potassium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, myristoyl-N-methylaminoacetic acid potassium, cocos nucifera oil acyl Glycine sodium, cocos nucifera oil acyl glycine potassium;
Described non-ionic surface active agent is any one or the mixture of two kinds in coconut oil diethanol amide, Oleum Cocois single ethanol amide;
Described amphoteric surfactant is any one or the two or more mixture in lauroyl both sexes base list acetic acid disodium, lauroyl both sexes base list acetic acid list sodium, cocamido propyl betaine, cocoamido propyl hydroxy sulfobetaine;
Described cation opsonizing agent is any one or the two or more mixture in guar gum hydroxypropyl-trimethyl ammonium chloride, Polyquaternium-10,12-22 alkyl ammomium chloride;
Described pearling agent is glycol distearate or ethylene glycol monostearate or both mixing;
Described conditioning nursing composition is any one or the two or more mixture in hydrolyzed wheat protein, hydrogenated polydecene, guar gum hydroxypropyl-trimethyl ammonium chloride, keratin, pantolactone, D-panthenol, vitamin E;
Described pH adjusting agent is citric acid or sodium citrate or both mixing;
Described viscosity modifier is sodium chloride;
Described anti-dandruff dose is climbazole or Zinc Pyrithione or both mixing;
Described antiseptic is any one or the two or more mixture in the mixing, phenoxyethanol, sodium salicylate, sodium benzoate of Methylisothiazolinone and methylchloroisothiazandnone;
Described natural extract is any one or the two or more mixture in Radix Ginseng extract, Radix Polygoni Multiflori extract, Fructus Gleditsiae Abnormalis extract, Rhizoma Zingiberis Recens extract, Radix Sophorae Flavescentis extract, Fructus cnidii extract, Cortex Dictamni extract, Radix Stemonae extract.
3. according to claim 1 and 2 not containing the preparation method of the hair cleanser of dioxanes residue, it is characterized in that comprising the following steps:
1) accurately take ormal weight distilled water in formula and add in beaker A, open behind heating by electric cooker to 70～75 ℃, turn on agitator, mixing speed is controlled at 500～600 revs/min, adds the anion surfactant of ormal weight in formula, and insulation is at 70 ℃-75 ℃;
2) non-ionic surface active agent, pearling agent, EDETATE SODIUM, the spermol that take formula ratio add in beaker successively, add above-mentioned raw materials and continue 73 ℃ of-75 ℃ of insulated and stirred later, and rotating speed controls 200～300; Dissolve rear insulation 10 minutes completely to all materials, start to cool to 55 ℃～60 ℃ and add amphoteric surfactant, add keep after above-mentioned raw materials temperature and rotating speed constant, be cooled to 55 ℃～50 ℃ after stirring 5min;
3) take in the cationic surfactant beaker B of formula ratio, then add the pure water of ormal weight to stir, rotating speed 500～600, stirs 5min, after dissolving completely or being uniformly dispersed; The material of beaker B is poured in beaker A, continued to stir, be cooled to 45 ℃～40 ℃;
4) the conditioning nursing composition, polydimethylsiloxane, anti-dandruff dose, essence that take the amount of formula regulation are in A beaker, rotating speed 500～600, stir 5min, after stirring, sample thief test pH value and viscosity, regulate pH adjusting agent and viscosity modifier for pH value and viscosity, after reaching predetermined pH value and viscosity, add antiseptic, stir 5 minutes, be cooled to 45 ℃～40 ℃, stop stirring discharging.
4. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Dodecyltriethanolamine sulfate 25%
Coconut oleoyl amine MEA 1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Sophorae Flavescentis extract 0.3%
Fructus cnidii extract 0.5%
Cortex Dictamni extract 0.2%
Radix Stemonae extract 0.3%
Water surplus.
5. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkylsurfuric acid triethanolamine 15%
Alkyl sodium sulfate 10%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Fructus Gleditsiae Abnormalis extract 0.3%
Water surplus.
6. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkylsurfuric acid triethanolamine 15%
Alkylsurfuric acid ammonium 10%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Guar gum hydroxypropyl-trimethyl ammonium chloride 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Ginseng extract 0.3%
Water surplus.
7. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkylsurfuric acid triethanolamine 25%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Polygoni Multiflori extract 1%;
Water surplus.
8. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkylsurfuric acid triethanolamine 5%
Alkylsurfuric acid ammonium 10%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Cocoyl CAB 5%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Zinc Pyrithione 2%
Water surplus.
9. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkylsurfuric acid ammonium 8%
Alkyl polyglucoside 5%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Methylisothiazolinone (with) methylchloroisothiazandnone 0.1%
Radix Polygoni Multiflori extract 1%;
Water surplus.
10. according to claim 1 and 2 not containing the hair cleanser of dioxanes residue, it is characterized in that: each raw material components that comprises following weight percentage ratio:
Alkyl sodium sulfate 8%
Cocoyl glycine potassium 5%
Coconut oleoyl amine MEA1.0%
Lauroyl both sexes base list acetic acid disodium 10%
Spermol 0.5%
EDTA-2Na?0.1%
Glycol distearate 2%
Ricinoleic acid amide oxypropyl trimethyl ammonium chloride 1%
Polyquaternium-10 0.5%
Polydimethylsiloxane 2%
Sodium chloride 0.6%
Citric acid 0.3%
Essence 1%
Sodium salicylate 0.3%
Sodium benzoate 0.5%;
Water surplus.
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| CN201210404185.3A CN102885740B (en) | 2012-10-22 | 2012-10-22 | Hair cleanser containing no dioxane residue and preparation method of hair cleanser |
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| CN102885740B true CN102885740B (en) | 2014-09-17 |
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| CN103251541B (en) * | 2013-05-30 | 2016-01-13 | 云南七丹药业股份有限公司 | A kind of shampoo containing arasaponin and preparation method thereof |
| CN103356408A (en) * | 2013-08-06 | 2013-10-23 | 珀莱雅化妆品股份有限公司 | Conditioning shampoo composition free of sulfates and dioxan |
| CN104473823A (en) * | 2014-12-03 | 2015-04-01 | 刘三猫 | Traditional Chinese medicine healthcare hair shampoo |
| CN105496883A (en) * | 2015-12-25 | 2016-04-20 | 名臣健康用品股份有限公司 | Application of cinnamomum burmanii fruit extract to personal care product |
| CA3008325A1 (en) * | 2015-12-29 | 2017-07-06 | Colgate-Palmolive Company | Cleansing composition |
| CN107789235A (en) * | 2016-08-30 | 2018-03-13 | 广州诣可贸易有限公司 | Foam-like hot spring Essence prescription is used in a kind of scalp conditioning |
| CN106389154A (en) * | 2016-10-25 | 2017-02-15 | 澳宝化妆品（惠州）有限公司 | Multi-effect balanced shampoo and preparation method thereof |
| CN106726707A (en) * | 2017-01-24 | 2017-05-31 | 郭正伟 | One kind hair washing water and preparation method thereof |
| CN107157876A (en) * | 2017-05-16 | 2017-09-15 | 广州市柏亚化妆品有限公司 | A kind of shampoo for being used to improve hair color and luster and newborn hair |
| CN108653027A (en) * | 2018-07-03 | 2018-10-16 | 广州仲思生物科技有限公司 | A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica |
| CN108771645B (en) * | 2018-08-21 | 2021-02-09 | 广东博然堂生物科技有限公司 | Quinoa shampoo and preparation method thereof |
| CN109370807A (en) * | 2018-12-28 | 2019-02-22 | 昆山聚贝机械设计有限公司 | Environment-friendly type oil painting brush cleaning solution and preparation method thereof |
| CN109837142B (en) * | 2019-04-10 | 2021-01-26 | 广州洁生日化有限公司 | Solid detergents without ethoxylates |
| CN113081889A (en) * | 2021-04-14 | 2021-07-09 | 广东珍宝健康日用品科技有限公司 | Three-stage washing and protecting integrated composition |
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| CN1475199A (en) * | 2003-07-10 | 2004-02-18 | 凌沛学 | Hair dressing cosmetics containing actire carbon, transparent acid, heparin |
| CN1545404A (en) * | 2000-09-14 | 2004-11-10 | Shampoo compositions with cationic polymers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1545404A (en) * | 2000-09-14 | 2004-11-10 | Shampoo compositions with cationic polymers | |
| CN1475199A (en) * | 2003-07-10 | 2004-02-18 | 凌沛学 | Hair dressing cosmetics containing actire carbon, transparent acid, heparin |
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