CN103356408A - Conditioning shampoo composition free of sulfates and dioxan - Google Patents
Conditioning shampoo composition free of sulfates and dioxan Download PDFInfo
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- CN103356408A CN103356408A CN201310339096XA CN201310339096A CN103356408A CN 103356408 A CN103356408 A CN 103356408A CN 201310339096X A CN201310339096X A CN 201310339096XA CN 201310339096 A CN201310339096 A CN 201310339096A CN 103356408 A CN103356408 A CN 103356408A
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Abstract
The invention relates to a conditioning shampoo composition free of sulfates and dioxan. The conditioning shampoo composition is characterized in that the conditioning shampoo composition comprises 4.5%-15% of an amino acid type anionic surfactant and a thickening composition; the amino acid type anionic surfactant is one of a cocoyl alaninate, a lauroyl glutamate, a cocoyl glycinate, a lauroyl sarcosinate, a methyl cocoyl taurate or a mixture thereof; the above mentioned salts are potassium salts or sodium salts or triethanolamine salts; the thickening composition comprises 0.2-4.0% of glyceryl cocoate, 0.05%-1.00% of trihydroxystearin, 0.05-1.50% of polyhydroxystearic acid and 0.2-3.0% of an acrylic (acrylate) copolymer; and the above percentages are both weight percentages. The conditioning shampoo composition is advantageous in that the conditioning shampoo composition has a viscosity range of 3000-30000 cps and is shown as long flowing deformation; the conditioning shampoo composition can be poured out easily from a container; the conditioning shampoo composition is liable to spread on hair; foams of the conditioning shampoo composition are uniform and comfortable; the conditioning shampoo composition is free of the sulfates and the dioxan, and the conditioning shampoo composition has beneficial effects of safety and little irritation.
Description
Technical field
Class cosmetics technical field, the particularly conditioning shampoo composition of a kind of not containing sulfate and dioxanes the present invention relates to have one's hair wash.
Background technology
Clean hair, has simultaneously the conditioner shampoo of necessarily washing rear conditioning performance, this series products is main flow in the market, it is the main composition that cleans, foams that these products adopt anion surfactant such as sodium laureth sulfate (ammonium) and sodium lauryl sulfate more, because this class surfactant washing power and foam are all good, and with low cost, therefore obtained at present a large amount of application.Yet the anion surfactant of this sulfate structure exists degreasing power excessively strong, and to the shortcoming such as the stimulation of scalp and hair is larger, some rear scalp can occur washing than more sensitive people itches, the phenomenon that hair is too dried.If through the boiling hot hair of overstain, use the strong shampoo of this type of degreasing power, hair dyes the color of scalding acquisition and can lose very soon.
On the other hand, as a kind of material that may be carcinogenic, dioxanes is also paid special attention to by consumer.All be to bring in the raw material in the most situation of dioxanes in the shampoo, although content is not high, from the consumer angle, this remains potential risk, and consumer wishes to use the conditioner shampoo product that does not contain dioxanes.But dioxanes is the by-product of ethyleneoxide addition reaction, and the raw material that contains ethylene oxide group all contains the dioxanes that quantity does not wait, and therefore, if will stop dioxanes, best bet is exactly not add the raw material that contains ethylene oxide group in prescription.
If conditioner shampoo is take the amino acid pattern anion surfactant as main, because its not containing sulfate and ethylene oxide group, product can possess following advantage, do not contain dioxanes, mildness is good, and cleaning force is moderate, for responsive hair quality and responsive scalp better nursing role is arranged.But adopt the system of amino acid pattern anion surfactant to have a hard problem, namely be very difficult to thickening.In existing thickening raw material, the thickening agent of macromolecule type is responsive to salt, efficient is not high, and is economical not, and use sense bad, if in take the amino acid pattern anion surfactant as main conditioner shampoo, only use the thickening agent of macromolecule type, when reaching the minimal viscosity 3000cps that conditioner shampoo wishes, product just presents the glue that is not easy to open, if pursue the higher conditioner shampoo of viscosity, gluey situation can be more serious, uses sense greatly to descend; If the hydrophilic PEGlike coating type of composite other thickening agent then contains the ethylene oxide group of some, can not avoid the dioxanes risk, and easily present jelly state in winter and be not easy to extrude from container.
Therefore wish to obtain a performance gentle, modest viscosity is used and is felt, and the conditioner shampoo of containing sulfate and dioxanes is not a present technical difficult problem that need to solve.
Summary of the invention
The technical problem to be solved in the present invention is, the conditioner shampoo of a kind of not containing sulfate and dioxanes is provided, and it has the performance gentleness, and viscosity at room temperature is controlled at 3000cps – 30000cps, easily opens, and uses the good characteristics of sense.
For solving the problems of the technologies described above, the technical solution used in the present invention is: the conditioning shampoo composition of a kind of not containing sulfate and dioxanes, it is characterized in that: the amino acid pattern anion surfactant and the thickening composition that comprise 4.5%-15%, described amino acid pattern anion surfactant is cocoyl alanine salt, lauroyl glutamate, cocos nucifera oil acyl glycinate, Hamposyl L salt, one of methyl cocoyl taurate or their mixture, salt wherein are potassium salt or sodium salt or triethanolamine salt; Acrylic acid (ester) analog copolymer of the poly-hydroxy stearic acid of the glyceryl cocoate that described thickening composition is 0.2%-4.0%, the trihydroxy stearin of 0.05%-1.00%, 0.05-1.50% and 0.2-3.0%, described percentage ratio is mass percent.
The content of described amino acid pattern anion surfactant is 4.5%-15%.
Acrylic acid (ester) analog copolymer of the poly-hydroxy stearic acid of the glyceryl cocoate that described thickening composition is 0.5%-2.0%, the trihydroxy stearin of 0.05%-0.75%, 0.05-1.00% and 0.6-2.0%.
Further, the present invention can also comprise that mass percent is the zwitterionic surfactant of 0.3%-5%, and described zwitterionic surfactant is a kind of in myristamide CAB, lauroylamidopropyl betaine, cocamido propyl betaine, the cocos nucifera oil acyl both sexes guanidine-acetic acid sodium or their mixture.
The present invention can also comprise that mass percent is the non-ionic surface active agent of 0.3%-5%, and described non-ionic surface active agent is a kind of in coconut oleoyl amine MEA, palmitamide MEA, Coco-Glucoside, the C8-20 alkyl androstanediol or their mixture.
Glyceryl cocoate in the thickening composition has rich fat effect, can moisten hair, also has simultaneously certain collaborative thickening effect; Glyceryl cocoate, trihydroxy stearin, poly-hydroxy stearic acid carry out composite, mixed dissolution in 70 ℃ of aqueous solutions, and the mixed liquor that obtains can form the sheet crystallization when room temperature is separated out, be applied in to have preferably thick stabilization effect in the surfactant system; Acrylic acid (ester) copolymer is as traditional thickening agent, can bring preferably rheological characteristic and viscosity according to the macromolecule space structure, when these four kinds of materials use separately, viscosity and rheological characteristic are all undesirable, four carry out composite according to special ratios, then cooperate with the amino acid pattern anion surfactant of appropriate amount, then can bring suitable viscosity and suitable rheological characteristic.Product viscosity can not present the glue of not opening reaching 3000cps when above, and (5-10 ℃) product can not form yet and freeze shape under low temperature environment, can not affect the outflow of product.
Glyceryl cocoate has the Lipo GMC of U.S. LIPO company production etc. in the market, and its INCI english name is GLYCERYL COCOATE, CAS No. 61789-05-7; Poly-hydroxy stearic acid, existing market have the Dispersun DSP-OL 300 of INNOSPEC company production or the HS-6C of Japan day clear company, CAS No. 58128-22-6; The THIXCIN R that trihydroxy stearin, existing market have ELEMENTIS company to produce, CAS No. 139-44-6; Acrylic acid (ester) analog copolymer then has the Carbopol Aqua SF-1 Polymer of Lubrizol company etc., CAS No. 25035-69-2.
The used amino acid pattern anion surfactant of the present invention is amino acid derivativges; comprise cocoyl alanine salt, lauroyl glutamate, cocos nucifera oil acyl glycinate, Hamposyl L salt, the methyl cocoyl taurate, salt wherein comprises potassium salt; sodium salt, triethanolamine salt.Above-mentioned amino acid pattern anion surfactant can be selected a use, also can mix use.Amino acid pattern anion surfactant addition is the 4.5%-15% of total composition among the present invention, preferred 6%-15%.Such ratio can be brought more suitable cleaning force and foam, and character is gentle, and the cost of final products is not high yet.
The present invention can also comprise other conventional cosmetics additives that does not contain ethylene oxide group, such as: cation opsonizing agent Polyquaternium-10 and guar hydroxypropyltrimonium chloride, pearling agent, pH adjusting agent, hair nutrition composition, antioxidant, anti-dandruff dose, essence etc.
The percentage composition of related material is mass percent among the present invention.
The present invention selects an amount of glyceryl cocoate, poly-hydroxy stearic acid, trihydroxy stearin and acrylic acid (ester) analog copolymer to carry out composite, then cooperate with the amino acid pattern anion surfactant, so that the conditioning shampoo composition range of viscosities is at 3000-30000cps, present long rheology, be easy to from container pour out, be easy to sprawl at hair, uniform in foaming is comfortable, and not containing sulfate and dioxanes, have safety, bland beneficial effect.
The specific embodiment
Embodiment 1:
The conditioning shampoo composition of a kind of not containing sulfate and dioxanes comprises following component:
1.5% cocos nucifera oil acyl alanine TEA salt (aminoacid anion surfactant)
1.0% lauroyl Kaglutam (aminoacid anion surfactant)
1.0% sodium lauroyl sarcosine (aminoacid anion surfactant)
1.0% sodium methyl cocoyl taurate (aminoacid anion surfactant)
0.1% lauroylamidopropyl betaine (zwitterionic surfactant)
0.2% cocamido propyl betaine (zwitterionic surfactant)
0.2% coconut oleoyl amine MEA (non-ionic surface active agent)
0.1% palmitamide MEA (non-ionic surface active agent)
1.6% glycol distearate (pearling agent)
0.2% glyceryl cocoate (thickening agent)
0.2% acrylic acid (ester) analog copolymer (thickening agent)
0.05% poly-hydroxy stearic acid (thickening agent)
0.05% trihydroxy stearin (thickening agent)
1.0% Polyquaternium-10 (cation opsonizing agent)
0.1% guar hydroxypropyltrimonium chloride (cation opsonizing agent)
0.2% triethanolamine (pH adjusting agent)
0.2% cetearyl alcohol (hair conditioner)
0.1% citric acid (pH buffer agent)
0.2% sodium citrate (pH buffer agent)
1.5% sodium chloride (thickening agent)
0.08% antiseptic (antiseptic)
0.1% hair nutrition composition (nutritional labeling)
0.8% essence (aromatic)
Surplus is water.The listed percentage ratio of the present embodiment is mass percent.
The present invention prepares by following technique:
With the cation opsonizing agent Polyquaternium-10, guar hydroxypropyltrimonium chloride is dispersed in a small amount of water in advance first, forms the cation opsonizing agent solution for standby;
In the emulsifying pot of water adding with heat exchange remaining in the prescription; add cocos nucifera oil acyl alanine TEA salt; the lauroyl Kaglutam; sodium lauroyl sarcosine; sodium methyl cocoyl taurate; after being uniformly dispersed; add glyceryl cocoate; be heated to 70 ℃ to 80 ℃; add again acrylic acid (ester) analog copolymer after the dissolving fully; after stirring; add poly-hydroxy stearic acid; the trihydroxy stearin; glycol distearate; cetearyl alcohol; coconut oleoyl amine MEA; palmitamide MEA; lauroylamidopropyl betaine; cocamido propyl betaine; triethanolamine; make fully and disperse; add scattered cationic conditioning agent solution; after disperseing fully; be cooled to 30 ℃ to approximately 40 ℃, add antiseptic under the stirring condition; the hair nutrition composition; essence is behind the mix homogeneously; add again sodium chloride; citric acid; other compositions such as sodium citrate; fully stir, obtain uniform mixture, take the dish out of the pot.
Containing mass percent in this product is 0.2% glyceryl cocoate, 0.05% poly-hydroxy stearic acid, 0.05% trihydroxy stearin and 0.2% acrylic acid (ester) analog copolymer.This product contains aminoacid anion surfactant 4.5%, contains non-ionic surface active agent 0.3%, contains zwitterionic surfactant 0.3%.
The viscosity of this product is 3000cps under 25 ℃ of room temperature, uses the test of Brookfield viscometer, and test condition is: TB pin, 6rpm.
Embodiment 2:
The conditioning shampoo composition of a kind of not containing sulfate and dioxanes comprises following component:
2.5% cocos nucifera oil acyl alanine TEA salt (aminoacid anion surfactant)
1.5% lauroyl glutamic acid TEA salt (aminoacid anion surfactant)
1.0% cocos nucifera oil acyl Glycine sodium (aminoacid anion surfactant)
2.0% potassium lauroyl sarcosine (aminoacid anion surfactant)
1.0% methyl cocoyl taurine potassium (aminoacid anion surfactant)
1.0% cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (zwitterionic surfactant)
1.2% cocamido propyl betaine (zwitterionic surfactant)
0.88% coconut oleoyl amine MEA (non-ionic surface active agent)
2.5% ethylene glycol stearate (pearling agent)
4.0% glyceryl cocoate (thickening agent)
3.0% acrylic acid (ester) analog copolymer (thickening agent)
1.5% poly-hydroxy stearic acid (thickening agent)
1.0% trihydroxy stearin (thickening agent)
0.8% Polyquaternium-10 (cation opsonizing agent)
0.2% guar hydroxypropyltrimonium chloride (cation opsonizing agent)
0.2% triethanolamine (pH adjusting agent)
0.25% spermol (hair conditioner)
0.10% stearyl alcohol (hair conditioner)
0.1% citric acid (pH buffer agent)
0.2% sodium citrate (pH buffer agent)
1.5% sodium chloride (thickening agent)
0.08% antiseptic (antiseptic)
0.8% essence (aromatic)
Surplus is water.The listed percentage ratio of the present embodiment is mass percent.
The present invention prepares by following technique:
With the cation opsonizing agent Polyquaternium-10, guar hydroxypropyltrimonium chloride is dispersed in a small amount of water in advance first, forms the cation opsonizing agent solution for standby;
In the emulsifying pot of water adding with heat exchange remaining in the prescription; add cocos nucifera oil acyl alanine TEA salt; lauroyl glutamic acid TEA salt; cocos nucifera oil acyl Glycine sodium; potassium lauroyl sarcosine; methyl cocoyl taurine potassium; after being uniformly dispersed; add glyceryl cocoate and be heated to 70 ℃ to 80 ℃; add again acrylic acid (ester) analog copolymer after the dissolving fully; after stirring; add ethylene glycol stearate; poly-hydroxy stearic acid; the trihydroxy stearin; spermol; coconut oleoyl amine MEA; cocos nucifera oil acyl both sexes guanidine-acetic acid sodium; cocamido propyl betaine; triethanolamine; make fully and disperse; add scattered cationic conditioning agent solution; after disperseing fully; be cooled to 30 ℃ to approximately 40 ℃; add antiseptic under the stirring condition; essence; behind the mix homogeneously, add again sodium chloride; citric acid; other compositions such as sodium citrate fully stir; obtain uniform mixture, take the dish out of the pot.
Contain mass percent in this product and be 4% glyceryl cocoate, 1.0% trihydroxy stearin, 1.5% poly-hydroxy stearic acid and 3% acrylic acid (ester) analog copolymer.This product contains aminoacid anion surfactant 8.0%, contains non-ionic surface active agent 0.88%, contains zwitterionic surfactant 2.2%.
The viscosity of this product is 30000cps under 25 ℃ of room temperature.Use the test of Brookfield viscometer, test condition is: TB pin, 6rpm.
Embodiment 3:
The conditioning shampoo composition of a kind of not containing sulfate and dioxanes comprises following component:
3.5% cocos nucifera oil acyl alanine potassium (aminoacid anion surfactant)
1.5% lauroyl glutamic acid TEA salt (aminoacid anion surfactant)
2.0% sodium lauroyl sarcosine (aminoacid anion surfactant)
3.0% methyl cocoyl taurine potassium (aminoacid anion surfactant)
1.0% lauroylamidopropyl betaine (zwitterionic surfactant)
1.0% cocamido propyl betaine (zwitterionic surfactant)
1.0% cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (zwitterionic surfactant)
2.0% Coco-Glucoside (non-ionic surface active agent)
0.5% C8 alkyl androstanediol (non-ionic surface active agent)
0.7% coconut oleoyl amine MEA (non-ionic surface active agent)
1.5% glycol distearate (pearling agent)
0.5% glyceryl cocoate (thickening agent)
2.0% acrylic acid (ester) analog copolymer (thickening agent)
1.00% poly-hydroxy stearic acid (thickening agent)
0.75% trihydroxy stearin (thickening agent)
0.5% Polyquaternium-10 (cation opsonizing agent)
0.1% guar hydroxypropyltrimonium chloride (cation opsonizing agent)
0.2% triethanolamine (pH adjusting agent)
0.3% stearyl alcohol (hair conditioner)
0.1% citric acid (pH buffer agent)
0.1% sodium citrate (pH buffer agent)
0.1% sodium hydroxide (pH adjusting agent)
1.5% sodium chloride (thickening agent)
0.08% antiseptic (antiseptic)
0.8% essence (aromatic)
Surplus is water.The listed percentage ratio of the present embodiment is mass percent.
The present invention prepares by following technique:
First cation opsonizing agent polyquaternary ammonium salt 10, guar hydroxypropyltrimonium chloride are dispersed in a small amount of water in advance, form the cation opsonizing agent solution for standby;
In the emulsifying pot of water adding with heat exchange remaining in the prescription; add cocos nucifera oil acyl alanine potassium; lauroyl glutamic acid TEA salt; sodium lauroyl sarcosine; methyl cocoyl taurine potassium; after being uniformly dispersed; add glyceryl cocoate; be heated to 70 ℃ to 80 ℃; add again acrylic acid (ester) analog copolymer after the dissolving fully; after stirring; add glycol distearate; poly-hydroxy stearic acid; the trihydroxy stearin; stearyl alcohol; coconut oleoyl amine MEA; lauroylamidopropyl betaine; cocamido propyl betaine; cocos nucifera oil acyl both sexes guanidine-acetic acid sodium; the cocoyl glucoside; triethanolamine; make fully and disperse; add scattered cationic conditioning agent solution; after disperseing fully; be cooled to 30 ℃ to approximately 40 ℃; add antiseptic under the stirring condition; essence behind the mix homogeneously, adds sodium chloride again; citric acid; sodium citrate; other compositions such as sodium hydroxide; obtain uniform mixture, take the dish out of the pot.
Contain mass percent in this product and be 0.5% glyceryl cocoate and 2% acrylic acid (ester) analog copolymer, 0.75% trihydroxy stearin, 1.0% poly-hydroxy stearic acid.This product contains aminoacid anion surfactant 10.0%, contains non-ionic surface active agent 3.2%, contains zwitterionic surfactant 3%.
The viscosity of this product is 15000cps under 25 ℃ of room temperature.Use the test of Brookfield viscometer, test condition is: TB pin, 6rpm.
Embodiment 4:
The conditioning shampoo composition of a kind of not containing sulfate and dioxanes comprises following component:
4.5% cocos nucifera oil acyl alanine TEA salt (aminoacid anion surfactant)
1.5% lauroyl glutamic acid TEA salt (aminoacid anion surfactant)
2.5% cocos nucifera oil acyl glycine potassium (aminoacid anion surfactant)
3.5% sodium methyl cocoyl taurate (aminoacid anion surfactant)
1.5% cocamido propyl betaine (zwitterionic surfactant)
1.0% cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (zwitterionic surfactant)
1.3% myristamide CAB (zwitterionic surfactant)
2.5% decyl glucoside (non-ionic surface active agent)
1.0% C12-20 alkyl androstanediol (non-ionic surface active agent)
1.0% coconut oleoyl amine MEA (non-ionic surface active agent)
1.8% ethylene glycol stearate (pearling agent)
2.0% glyceryl cocoate (thickening agent)
1.0% poly-hydroxy stearic acid (thickening agent)
0.5% trihydroxy stearin (thickening agent)
0.6% acrylic acid (ester) analog copolymer (thickening agent)
0.3% Polyquaternium-10 (cation opsonizing agent)
0.1% guar hydroxypropyltrimonium chloride (cation opsonizing agent)
0.2% triethanolamine (pH adjusting agent)
0.35% cetearyl alcohol (hair conditioner)
0.1% citric acid (pH buffer agent)
0.1% sodium citrate (pH buffer agent)
0.1% potassium hydroxide (pH adjusting agent)
1.5% sodium chloride (thickening agent)
0.08% antiseptic (antiseptic)
0.8% essence (aromatic)
Surplus is water.The listed percentage ratio of the present embodiment is mass percent.
The present invention prepares by following technique:
First cation opsonizing agent polyquaternary ammonium salt 10, guar hydroxypropyltrimonium chloride are dispersed in a small amount of water in advance, form the cation opsonizing agent solution for standby;
In the emulsifying pot of water adding with heat exchange remaining in the prescription; add cocos nucifera oil acyl alanine TEA salt; lauroyl glutamic acid TEA salt; cocos nucifera oil acyl glycine potassium; sodium methyl cocoyl taurate; after being uniformly dispersed; add glyceryl cocoate; be heated to 70 ℃ to 80 ℃; add again acrylic acid (ester) analog copolymer after the dissolving fully; after stirring; add ethylene glycol stearate; poly-hydroxy stearic acid; the trihydroxy stearin; cetearyl alcohol; coconut oleoyl amine MEA; cocamido propyl betaine; cocos nucifera oil acyl both sexes guanidine-acetic acid sodium; the myristamide CAB; decyl glucoside; the C12-20 alkyl androstanediol; triethanolamine; make fully and disperse; add scattered cationic conditioning agent solution; after disperseing fully; be cooled to 30 ℃ to approximately 40 ℃; add antiseptic under the stirring condition; essence behind the mix homogeneously, adds sodium chloride again; citric acid; sodium citrate; other compositions such as potassium hydroxide; obtain uniform mixture, take the dish out of the pot.
Contain mass percent in this product and be 2% glyceryl cocoate and 0.6% acrylic acid (ester) analog copolymer, 0.5% trihydroxy stearin, 1.0% poly-hydroxy stearic acid.This product contains aminoacid anion surfactant 11.0%, contains non-ionic surface active agent 4.5%, contains zwitterionic surfactant 3.8%.
The viscosity of this product is 15000cps under 25 ℃ of room temperature.Use the test of Brookfield viscometer, test condition is: TB pin, 6rpm.
Embodiment 5:
The conditioning shampoo composition of a kind of not containing sulfate and dioxanes comprises following component:
5.5% lauroyl glutamic acid TEA salt (aminoacid anion surfactant)
3.0% cocos nucifera oil acyl glycine potassium (aminoacid anion surfactant)
3.0% sodium lauroyl sarcosine (aminoacid anion surfactant)
1.5% sodium methyl cocoyl taurate (aminoacid anion surfactant)
2.0 % sodium lauroyl glutamate (aminoacid anion surfactant)
1.5% lauroylamidopropyl betaine (zwitterionic surfactant)
1.5% cocamido propyl betaine (zwitterionic surfactant)
1.0% cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (zwitterionic surfactant)
1.0% myristamide CAB (zwitterionic surfactant)
5.0% coconut oleoyl amine MEA (non-ionic surface active agent)
2.0% glycol distearate (pearling agent)
1.3% glyceryl cocoate (thickening agent)
1.6% acrylic acid (ester) analog copolymer (thickening agent)
0.05% poly-hydroxy stearic acid (thickening agent)
0.75% trihydroxy stearin (thickening agent)
0.1% guar hydroxypropyltrimonium chloride (cation opsonizing agent)
0.2% triethanolamine (pH adjusting agent)
0.4% cetearyl alcohol (hair conditioner)
0.1% citric acid (pH buffer agent)
0.2% sodium citrate (pH buffer agent)
2.0% sodium chloride (thickening agent)
0.08% antiseptic (antiseptic)
0.8% essence (aromatic)
Surplus is water.The listed percentage ratio of the present embodiment is mass percent.
The present invention prepares by following technique:
First the cation opsonizing agent guar hydroxypropyltrimonium chloride is carried out pretreatment, be dispersed in advance in a small amount of water, form the cation opsonizing agent solution for standby;
In the emulsifying pot of water adding with heat exchange remaining in the prescription; add lauroyl glutamic acid TEA salt; cocos nucifera oil acyl glycine potassium; sodium lauroyl sarcosine; sodium methyl cocoyl taurate; sodium lauroyl glutamate; after being uniformly dispersed; add glyceryl cocoate; be heated to 70 ℃ to 80 ℃; add again acrylic acid (ester) analog copolymer after the dissolving fully; after stirring; add glycol distearate; poly-hydroxy stearic acid; the trihydroxy stearin; cetearyl alcohol; coconut oleoyl amine MEA; lauroylamidopropyl betaine; cocamido propyl betaine; cocos nucifera oil acyl both sexes guanidine-acetic acid sodium; the myristamide CAB; triethanolamine; make fully and disperse; add scattered cationic conditioning agent solution; after disperseing fully; be cooled to 30 ℃ to approximately 40 ℃; add antiseptic under the stirring condition; essence behind the mix homogeneously, adds sodium chloride again; citric acid; other compositions such as sodium citrate; obtain uniform mixture, take the dish out of the pot.
Contain mass percent in this product and be 1.3% glyceryl cocoate and 1.6% acrylic acid (ester) analog copolymer, 0.75% trihydroxy stearin, 0.05% poly-hydroxy stearic acid.This product contains aminoacid anion surfactant 15.0%, contains non-ionic surface active agent 5%, contains zwitterionic surfactant 5%.
The viscosity of this product is 12000cps under 25 ℃ of room temperature.Use the test of Brookfield viscometer, test condition is: TB pin, 6rpm.
Claims (3)
1. conditioning shampoo composition of containing sulfate and dioxanes not, it is characterized in that: the amino acid pattern anion surfactant and the thickening composition that comprise 4.5%-15%, described amino acid pattern anion surfactant is cocoyl alanine salt, lauroyl glutamate, cocos nucifera oil acyl glycinate, Hamposyl L salt, one of methyl cocoyl taurate or their mixture, salt wherein are potassium salt or sodium salt or triethanolamine salt; Acrylic acid (ester) analog copolymer of the poly-hydroxy stearic acid of the glyceryl cocoate that described thickening composition is 0.2%-4.0%, the trihydroxy stearin of 0.05%-1.00%, 0.05-1.50% and 0.2-3.0%, described percentage ratio is mass percent.
2. the conditioning shampoo composition of not containing sulfate according to claim 1 and dioxanes, it is characterized in that: the content of described amino acid pattern anion surfactant is 4.5%-15%.
3. the conditioning shampoo composition of not containing sulfate according to claim 1 and dioxanes is characterized in that: acrylic acid (ester) analog copolymer of the poly-hydroxy stearic acid of the glyceryl cocoate that described thickening composition is 0.5%-2.0%, the trihydroxy stearin of 0.05%-0.75%, 0.05-1.00% and 0.6-2.0%.
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