CN102884030B - 制备六氟-2-丁烯的方法 - Google Patents

制备六氟-2-丁烯的方法 Download PDF

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Publication number
CN102884030B
CN102884030B CN201180016420.3A CN201180016420A CN102884030B CN 102884030 B CN102884030 B CN 102884030B CN 201180016420 A CN201180016420 A CN 201180016420A CN 102884030 B CN102884030 B CN 102884030B
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hexafluoro
metal
catalyst
reaction
reactor
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CN102884030A (zh
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童雪松
H·王
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Honeywell International Inc
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Honeywell International Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/278—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/358—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201180016420.3A 2010-03-26 2011-03-15 制备六氟-2-丁烯的方法 Active CN102884030B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US31787910P 2010-03-26 2010-03-26
US61/317,879 2010-03-26
US61/317879 2010-03-26
US13/045,926 2011-03-11
US13/045926 2011-03-11
US13/045,926 US8461401B2 (en) 2010-03-26 2011-03-11 Method for making hexafluoro-2-butene
PCT/US2011/028476 WO2011119370A2 (en) 2010-03-26 2011-03-15 Method for making hexafluoro-2-butene

Publications (2)

Publication Number Publication Date
CN102884030A CN102884030A (zh) 2013-01-16
CN102884030B true CN102884030B (zh) 2015-11-25

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CN201180016420.3A Active CN102884030B (zh) 2010-03-26 2011-03-15 制备六氟-2-丁烯的方法

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US (1) US8461401B2 (https=)
EP (1) EP2552873B1 (https=)
JP (3) JP5913279B2 (https=)
CN (1) CN102884030B (https=)
ES (1) ES2654159T3 (https=)
MX (1) MX2012011055A (https=)
WO (1) WO2011119370A2 (https=)

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US12421182B2 (en) 2020-01-23 2025-09-23 The Chemours Company Fc, Llc Synthesis of (e)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene

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CN103228757B (zh) 2010-11-25 2016-02-17 阿克马法国公司 氯三氟丙烯和六氟丁烯的组合物
FR2968009B1 (fr) 2010-11-25 2012-11-16 Arkema France Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene
FR2968310B1 (fr) 2010-12-03 2012-12-07 Arkema France Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene
FR2977256B1 (fr) * 2011-07-01 2013-06-21 Arkema France Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene
CN103917507A (zh) * 2011-10-24 2014-07-09 纳幕尔杜邦公司 制备氢单氯氟丁烷和氢单氯氟戊烷化合物的催化方法
JP5790438B2 (ja) 2011-11-21 2015-10-07 セントラル硝子株式会社 トランス−１−クロロ−３，３，３−トリフルオロプロペンの製造方法
FR2989084B1 (fr) 2012-04-04 2015-04-10 Arkema France Compositions a base de 2,3,3,4,4,4-hexafluorobut-1-ene
FR2989374A1 (fr) * 2012-04-11 2013-10-18 Arkema France Procede de preparation d'un compose olefinique sous forme d'un isomere specifique.
US9234123B2 (en) * 2013-03-21 2016-01-12 Hsi Fire & Safety Group, Llc Compositions for totally non-flammable aerosol dusters
WO2015142981A1 (en) * 2014-03-21 2015-09-24 E I Du Pont De Nemours And Company Processes for the production of z 1,1,1,4,4,4 hexafluoro 2-butene
US9353030B2 (en) * 2014-07-25 2016-05-31 Honeywell International Inc. One-step process for hexafluoro-2-butene
CN104447186B (zh) * 2014-11-20 2016-08-17 西安近代化学研究所 一种2,4,4-三氯-1,1,1-三氟丁烷的制备方法
CN104370690B (zh) * 2014-11-20 2016-08-17 西安近代化学研究所 一种反式-1,1,1,4,4,4-六氟-2-丁烯的合成方法
CN104529695B (zh) * 2015-01-26 2016-06-22 杭州芳环科技有限公司 一种制备1,1,1,4,4,4-六氟-2-丁烯的方法
MX2018001489A (es) * 2015-08-07 2018-04-24 Chemours Co Fc Llc Isomerizacion catalitica de z-1,1,14,4,4,-hexafluoro-2-buteno a e-1,1,1,4,4,4-hexafluoro-2-buteno.
US20170210869A1 (en) * 2016-01-22 2017-07-27 The Chemours Company Fc, Llc Foaming of polyisocyanate/active hydrogen-containing compound reaction product
ES2891525T3 (es) * 2016-07-27 2022-01-28 Chemours Co Fc Llc Proceso de producción de olefinas halogenadas
CN111094503B (zh) 2017-09-11 2022-04-01 科慕埃弗西有限公司 包含氟化氢和含氟烃的共沸组合物
KR102700055B1 (ko) 2017-09-11 2024-08-29 더 케무어스 컴퍼니 에프씨, 엘엘씨 (e)-1,1,1,4,4,4-헥사플루오로부트-2-엔을 제조하는 액체상 공정
CN107759440B (zh) * 2017-11-07 2020-07-03 中国民航大学 一种将含氟烯烃双键上的氟置换成氢的方法
JP2021505590A (ja) * 2017-12-04 2021-02-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー １，１，３−トリクロロ−４，４，４−トリフルオロブタ−１−エン及び（ｅ）−１，１，１，４，４，４−ヘキサフルオロブタ−２−エンを調製するためのプロセス及び中間体
CN109678650A (zh) * 2018-12-25 2019-04-26 西安近代化学研究所 一种1,1,1,3-四氯-4,4,4-三氟丁烷的制备方法
CN110590496A (zh) * 2019-09-24 2019-12-20 浙江三美化工股份有限公司 一种气相连续合成顺式-1,1,1,4,4,4-六氟-2-丁烯的方法
JP7697960B2 (ja) 2020-03-04 2025-06-24 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー （ｚ）－１，１，１，４，４，４－ヘキサフルオロ－２－ブテン及び中間体を生成するためのプロセス
CN112159301B (zh) * 2020-09-29 2022-12-13 西安近代化学研究所 一种2-氯-1,1,1,4,4,4-六氟-2-丁烯的合成方法
IL302119A (en) * 2020-10-15 2023-06-01 Resonac Corp STORAGE METHOD FOR FLUORO-2-BUTENE
US20230373887A1 (en) * 2020-10-15 2023-11-23 Resonac Corporation Method for storing fluorobutene
KR102924126B1 (ko) * 2020-10-15 2026-02-06 가부시끼가이샤 레조낙 플루오로-2-부텐의 보관 방법
JPWO2022080272A1 (https=) * 2020-10-15 2022-04-21
US20230373889A1 (en) * 2020-10-15 2023-11-23 Resonac Corporation Method for storing fluoro-2-butene
KR102924118B1 (ko) * 2020-10-15 2026-02-09 가부시끼가이샤 레조낙 플루오로부텐의 보관 방법
EP4235702A4 (en) * 2020-10-22 2024-07-24 Agc Inc. ELECTRICAL EQUIPMENT
CN114716297B (zh) * 2021-01-06 2023-10-27 浙江省化工研究院有限公司 一种e-1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN114292158B (zh) * 2021-12-01 2024-01-02 西安近代化学研究所 一种制备顺式-1,1,1,4,4,4-六氟-2-丁烯的方法
KR102788759B1 (ko) 2022-05-13 2025-04-01 (주)후성 1,1,1,4,4,4-헥사플루오로-2-부텐의 제조방법
CN116037117B (zh) * 2023-03-31 2023-07-25 北京宇极科技发展有限公司 引发剂、氟化催化剂和e-1,3,3,3-四氟丙烯与z-1,3,3,3-四氟丙烯的制备方法
CN116037120B (zh) * 2023-03-31 2023-07-14 北京宇极科技发展有限公司 1,1,1,4,4,4-六氟-2-丁烯的正反异构体的制备方法

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US5463150A (en) * 1993-02-19 1995-10-31 Bayer Aktiengesellschaft Process for preparing hexafluorobutene
US5516951A (en) * 1992-11-20 1996-05-14 Daikin Industries Ltd. Process for preparing 1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,4,4,4-hexafluorobutane
US5608128A (en) * 1993-01-29 1997-03-04 Daikin Industries, Ltd. Production methods of 1,1,1,4,4,4-hexsfluoro-2-butene compounds and 1,1,1,4,4,4,-hexafluorobutane
CN101500973A (zh) * 2005-01-19 2009-08-05 大湖化学公司 卤化碳制备方法，卤化碳分离方法和卤化碳制备系统
CN101578252A (zh) * 2006-09-05 2009-11-11 纳幕尔杜邦公司 1,2,3,3,3-五氟丙烯生产方法

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US5463150A (en) * 1993-02-19 1995-10-31 Bayer Aktiengesellschaft Process for preparing hexafluorobutene
CN101500973A (zh) * 2005-01-19 2009-08-05 大湖化学公司 卤化碳制备方法，卤化碳分离方法和卤化碳制备系统
CN101578252A (zh) * 2006-09-05 2009-11-11 纳幕尔杜邦公司 1,2,3,3,3-五氟丙烯生产方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12421182B2 (en) 2020-01-23 2025-09-23 The Chemours Company Fc, Llc Synthesis of (e)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene

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Publication number Publication date
MX2012011055A (es) 2013-01-28
JP2013523637A (ja) 2013-06-17
JP5913279B2 (ja) 2016-04-27
JP6088618B2 (ja) 2017-03-01
CN102884030A (zh) 2013-01-16
EP2552873A4 (en) 2014-09-10
ES2654159T3 (es) 2018-02-12
JP2016034970A (ja) 2016-03-17
WO2011119370A3 (en) 2011-12-22
EP2552873B1 (en) 2017-10-18
WO2011119370A2 (en) 2011-09-29
EP2552873A2 (en) 2013-02-06
US20110237844A1 (en) 2011-09-29
JP2017125023A (ja) 2017-07-20
US8461401B2 (en) 2013-06-11

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