CN102816003A - Nano carbon sulfate radical organic fertilizer and preparation method thereof - Google Patents

Nano carbon sulfate radical organic fertilizer and preparation method thereof Download PDF

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CN102816003A
CN102816003A CN2012103252607A CN201210325260A CN102816003A CN 102816003 A CN102816003 A CN 102816003A CN 2012103252607 A CN2012103252607 A CN 2012103252607A CN 201210325260 A CN201210325260 A CN 201210325260A CN 102816003 A CN102816003 A CN 102816003A
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organic fertilizer
sulfate radical
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CN102816003B (en
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张志明
陈谏知
甘朝生
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Abstract

The invention relates to a nano carbon sulfate radical organic fertilizer. The nano carbon sulfate radical organic fertilizer comprises a sulfate radical organic fertilizer and nanocarbon, and the sulfate radical organic fertilizer is subjected to antibiotic bacteria fermentation and contains sulfate and an organic fertilizer. A preparation method of the nano carbon sulfate radical organic fertilizer is simple, and the nano carbon sulfate radical organic fertilizer can be widely applied to treating plant diseases and has a good effect on clearing cadmium pollution in soil.

Description

A kind of nano-sized carbon sulfate radical organic fertilizer and preparation method thereof
Technical field
The present invention relates to the organic fertilizer in the agricultural, particularly a kind of efficiently, can purify the organic fertilizer of Cadmium Pollution in Soils.
Background technology
Since the reform and opening-up, China's agriculture prodn has obtained significant progress, yet the long-term application chemical fertilizer has brought serious negative issues such as Soil structure destruction, water pollution, utilization rate of fertilizer decline and quality of agricultural product reduction.Current, China's food safety situation is still severe, and the pollution of agricultural-food source ranks first.Soil is the supplier of nutrient, and soil is again that the guarantor of nutrient holds agent, is that other material is irreplaceable; Regulate soil, improve the soil, bring up soil, recover soil vitality, demonstrate the natural true qualities of soil; Be food safety, the only way of human civilization and scientific development.And in the agricultural production process, the use of fertilizer is absolutely necessary again, so all the time, people are carrying out the research improvement of fertilizer, and expectation can obtain soil and crop harm very little even harmless, but the fertilizer that can in agriculture prodn, play a significant role.If using of a kind of fertilizer can also be improved the soil assurance provides nutrition source and guarantees plant growth for crop when, it will be with a wide range of applications.
Summary of the invention
The objective of the invention is to, provide a kind of efficiently, nano-sized carbon sulfate radical organic fertilizer of important application and preparation method thereof is being arranged aspect the Cadmium Pollution in Soils purifying, for achieving the goal, the present invention adopts following technical scheme:
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, the sulfate radical organic fertilizer also ferments via antibiotic bacteria.
Aforesaid sulfate radical organic fertilizer comprises vitriol and organic fertilizer.
Preferably, in the aforesaid sulfate radical organic fertilizer, vitriol includes a kind of in the following material or any several kinds: vitriolate of tartar, ammonium sulfate, calcium sulfate, sal epsom, zinc sulfate and copper sulfate.
In above-mentioned arbitrary technical scheme preferably; In the sulfate radical organic fertilizer; Include vitriolate of tartar, ammonium sulfate, calcium sulfate, sal epsom, zinc sulfate and copper sulfate, the per-cent that its mass content accounts for the sulfate radical organic fertilizer is: vitriolate of tartar 5%-25%, ammonium sulfate 15%-30%, calcium sulfate 10%-20%, sal epsom 2%-10%, zinc sulfate 0.2%-0.5%, copper sulfate 0.05%-0.1%.
Aforesaid antibiotic bacteria can be Mycophyta, ray fungi or bacterium class.
Preferably, antibiotic bacteria is wood mould type of fungi, thin yellow actinomycetes, vinelandii, thiobacterium, phosphor bacterium or potassium bacterium in above-mentioned arbitrary technical scheme.
Preferably, the size of nano carbon particle diameter is 5-70nm in above-mentioned arbitrary technical scheme.
Aforesaid organic fertilizer is: compost, make compost, barnyard manure, natural pond fertilizer or green manure.
Compost is as stated: tangerine stalk, fallen leaves, green grass, plant and animal residues and/or human and animal excreta.
Barnyard manure is as stated: fecaluria of livestock and poultry such as pig, ox, horse, sheep, chicken, duck, goose and the fertilizer that stalk bedding and padding stack retting is processed.
Natural pond fertilizer is as stated: in the methane-generating pit of sealing, the organism decomposition produces the by product behind the biogas, comprises methane liquid and residue.
Green manure is as stated: utilize cultivation or wild green plants body to make fertilizer.Like the mung bean of pulse family, broad bean, Melilotus suaveolens Ledeb., sesbania, clover, sweet potato etc.Nonleguminous green manure has rye grass, infertile field radish, little certain herbaceous plants with big flowers, Herba azollae imbricatae, Herba Eichhorniae, water peanut etc.
For selecting for use of organic fertilizer: organic fertilizer is of a great variety, but all is that plant and animal residues forms soil ulmin or animal excrement through microbiological degradation, and wherein water-soluble portion is an xanthohumic acid; Can be directly by plant absorbing, alkaline hydrolysis partly can not dissolve part and claim humin partly by plant absorbing for humic acid; Being the integral part of soil granular, so organic matter is the fertility basis of soil, is slow-release fertilizer; The structure of matter is similar, suits measures to local conditions to select for use material.
Preferably, a kind of nano-sized carbon sulfate radical organic fertilizer, material that it comprises and mass percent thereof are: sulfate radical organic fertilizer: 10-20%, nano-sized carbon: 0.1-0.7%.
Aforesaid nano-sized carbon sulfate radical organic fertilizer, its preparation method may further comprise the steps:
(1) vitriol is mixed with organic fertilizer, wherein the mass content percentage ratio of vitriol is: 0.05-86% obtains the sulfate radical organic fertilizer;
(2) antibiotic bacteria (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3% with substratum; All the other are agar) ferment and produced bacterial classification in 60-70 hour; Wherein, the temperature of fermentation is 38 ℃-42 ℃, and the pH value should be controlled 6.0-8.0;
(3) antibiotic bacteria that obtains is inoculated in the sulfate radical organic fertilizer, the mass content percentage ratio of bacterial classification is: 0.05%-0.5%, and ferment then formed in 8-10 days, obtained the sulfate radical organic fertilizer of antibiotic bacteria fermentation;
The sulfate radical organic fertilizer of the antibiotic bacteria fermentation that (4) obtains mixes with organic fertilizer, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for the 10-20% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with organic fertilizer, and wherein nano-sized carbon accounts for the 0.1%-0.7% of nano-sized carbon sulfate radical organic fertilizer quality total amount, and all the other are organic fertilizer;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Preferably, aforesaid antibiotic bacteria can be Mycophyta, ray fungi or bacterium class.
More preferably, antibiotic bacteria is wood mould type of fungi, thin yellow actinomycetes, vinelandii, thiobacterium, phosphor bacterium or potassium bacterium.
In above-mentioned arbitrary technical scheme preferably, the application of nano-sized carbon sulfate radical organic fertilizer in suppressing phytopathogen.
Preferably, nano-sized carbon sulfate radical organic fertilizer is in the late application of sending out in the rust of treatment banana in above-mentioned arbitrary technical scheme.
Preferably, nano-sized carbon sulfate radical organic fertilizer is in the application of treatment in the canker of apple fruit in above-mentioned arbitrary technical scheme.
Preferably, nano-sized carbon sulfate radical organic fertilizer is in the application of treatment in the sweet potato black rot in above-mentioned arbitrary technical scheme.
Preferably, nano-sized carbon sulfate radical organic fertilizer is in the application of treatment in the sclerotinia rot of colza in above-mentioned arbitrary technical scheme.
In above-mentioned arbitrary technical scheme preferably, the application of nano-sized carbon sulfate radical organic fertilizer in treatment genseng root rot.
Preferably, nano-sized carbon sulfate radical organic fertilizer is in the application of treatment in the Achlya spp in above-mentioned arbitrary technical scheme.
In above-mentioned arbitrary technical scheme preferably, the application of nano-sized carbon sulfate radical organic fertilizer in mashed kind of treatment cotton.
In above-mentioned arbitrary technical scheme preferably, the application of nano-sized carbon sulfate radical organic fertilizer in lodging resistance in rice.
In above-mentioned arbitrary technical scheme preferably, the application of nano-sized carbon sulfate radical organic fertilizer in purifying Cadmium Pollution in Soils.
Preferably, nano-sized carbon sulfate radical organic fertilizer is applied to Cruciferae rape or fern flowers in above-mentioned arbitrary technical scheme.
Nano-sized carbon sulfate radical organic fertilizer of the present invention, nano-sized carbon wherein combines with various microbiotic, and under the situation of equal consumption, the perviousness of drug effect and adsorptivity increase, and drug effect strengthens.Nano-sized carbon is an isolator; But become behind the chance water " superconductor ", thus " superconduction " fertilizer claimed, after nano-sized carbon sulfate radical organic fertilizer gets into soil; It can make the resistance of soil colloid, solution reduce greatly; Become conduction fertilizer, be lower than common fertilizer 30%~50%, therefore the effect of obvious joint fertile 30%~50% is arranged through measuring its EC value.It can transfer macronutrient in the soil (nitrogen, phosphorus, potassium), middle amount nutritive element (calcium, magnesium, sulphur and silicon) and trace element (iron, manganese, copper, zinc, molybdenum, boron etc.), and snap-out release comes out from soil colloid.The exceptional function of nano-sized carbon is to transfer negatively charged ion nutrients such as phosphorus in the soil, silicon, sulphur, molybdenum, so can make lodging resistance in rice, improves effects such as soybean oil content.Nano-sized carbon has very strong absorbent function; Can be described as " bio-pump ", use nano-sized carbon sulfate radical organic fertilizer of the present invention, ability enhancing crop root system absorbs the ability of nutrient and moisture; Increase is to the absorption of soil inorganic nutritive element; Show the increase of plant mitochondria cell and the increase of chloroplast(id) cell, therefore can promote crop root flourishing, increase nutrition absorption and growth fast.
In organic fertilizer, add vitriol; Organic content is increased greatly, when making a large amount of cadmiums like this in getting into plant materials, be concentrated in the root and the stem of rape; Purify the cadmium pollution of soil with biological organic sulfur-containing fertilizer; Can promote the absorption of plant to cadmium on the one hand, can concentrate on the plant root deposition on the other hand, cadmium is sulfide-cadmium precipitation (S 2-+ Cd 2+→ CdS), extract roots of plants and can from soil, remove cadmium, thus reach the purpose that purifies cadmium pollution in the soil.
The dose of nano-sized carbon sulfate radical organic fertilizer is a conventional fertilizer application amount 50%~70%, can save under the situation of fertilizer 30% ~ 50%, and field crop can increase production 10%~20%; Vegetable crop can increase production 20%~40%; Woods fruit crop can increase production 15%~30%.When its as as base manure or to topdress be that during use, its preferable sowing amount is every mu of 100-200 kilogram.
Embodiment
Embodiment 1
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via thin yellow actinomycete fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with organic fertilizer; Organic fertilizer is the stalk fertilizer through spontaneous fermentation; Wherein the mass content percentage ratio of vitriol is 32.25% (vitriolate of tartar 5%, ammonium sulfate 15%, calcium sulfate 10%, sal epsom 2%, zinc sulfate 0.2%, copper sulfate 0.05%), obtains the sulfate radical organic fertilizer;
(2) thin yellow actinomycetes (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3% with substratum; All the other are agar) ferment and produced bacterial classification in 60 hours; Wherein, the temperature of fermentation is 38 ℃, and the pH value should be controlled 6.0-8.0;
The thin yellow actinomycetes that (3) will obtain are inoculated in the sulfate radical organic fertilizer, and the mass content percentage ratio of bacterial classification is: 0.05%, and ferment then formed in 8 days, obtained the sulfate radical organic fertilizer of thin yellow actinomycete fermentation;
The sulfate radical organic fertilizer of the thin yellow actinomycete fermentation that (4) obtains mixes with organic fertilizer, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 10% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with organic fertilizer, and wherein nano-sized carbon accounts for 0.1% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 2
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via the vinelandii fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with compost, wherein the mass content percentage ratio of vitriol is 49.36% (vitriolate of tartar 10%, ammonium sulfate 20%, calcium sulfate 15%, sal epsom 4%, zinc sulfate 0.3%, copper sulfate 0.06%), obtains the sulfate radical organic fertilizer;
(2) vinelandii were produced bacterial classification in 65 hours with substratum (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3%, all the other are agar) fermentation, and wherein, the temperature of fermentation is 40 ℃, and the pH value is controlled at 6.5;
(3) vinelandii that obtain are inoculated in the sulfate radical organic fertilizer, the mass content percentage ratio of bacterial classification is: 0.1%, and ferment then formed in 9 days, obtained the sulfate radical organic fertilizer of vinelandii fermentation;
The sulfate radical organic fertilizer of the vinelandii fermentation that (4) obtains mixes with compost, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 12% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with compost, and wherein nano-sized carbon accounts for 0.2% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 3
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via the thiobacterium fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with making compost, wherein the mass content percentage ratio of vitriol is 64.47% (vitriolate of tartar 15%, ammonium sulfate 25%, calcium sulfate 18%, sal epsom 6%, zinc sulfate 0.4%, copper sulfate 0.07%), obtains the sulfate radical organic fertilizer;
(2) thiobacterium was produced bacterial classification in 70 hours with substratum (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3%, all the other are agar) fermentation, and wherein, the temperature of fermentation is 41 ℃, and the pH value should control 7.0;
(3) thiobacterium that obtains is inoculated in the sulfate radical organic fertilizer, the mass content percentage ratio of bacterial classification is: 0.2%, and ferment then formed in 10 days, obtained the sulfate radical organic fertilizer of thiobacterium fermentation;
The sulfate radical organic fertilizer of the thiobacterium that (4) obtains fermentation mixes with making compost, and wherein the sulfate radical organic fertilizer that ferments of antibiotic bacteria accounts for 14% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with making compost, and wherein nano-sized carbon accounts for 0.3% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 4
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via the phosphor bacterium fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with barnyard manure, wherein the mass content percentage ratio of vitriol is 75.58% (vitriolate of tartar 20%, ammonium sulfate 27%, calcium sulfate 19%, sal epsom 8%, zinc sulfate 0.5%, copper sulfate 0.08%), obtains the sulfate radical organic fertilizer;
(2) phosphor bacterium was produced bacterial classification in 60 hours with substratum (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3%, all the other are agar) fermentation, and wherein, the temperature of fermentation is 42 ℃, and the pH value should control 7.5;
(3) phosphor bacterium that obtains is inoculated in the sulfate radical organic fertilizer, the mass content percentage ratio of bacterial classification is: 0.35%, and ferment then formed in 10 days, obtained the sulfate radical organic fertilizer of phosphor bacterium fermentation;
The sulfate radical organic fertilizer of the phosphor bacterium fermentation that (4) obtains mixes with barnyard manure, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 16% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with barnyard manure, and wherein nano-sized carbon accounts for 0.4% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 5
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, the sulfate radical organic fertilizer is also via the potassium fermentation using bacteria, and its preparation method is:
(1) vitriol and natural pond fertilizer are mixed, wherein the mass content percentage ratio of vitriol is 83.34% (vitriolate of tartar 25%, ammonium sulfate 29%, calcium sulfate 20%, sal epsom 9%, zinc sulfate 0.25%, copper sulfate 0.09%), obtains the sulfate radical organic fertilizer;
(2) the potassium bacterium was produced bacterial classification in 70 hours with substratum (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3%, all the other are agar) fermentation, and wherein, the temperature of fermentation is 38 ℃, and the pH value should control 8.0;
(3) with the potassium microbionation that obtains in the sulfate radical organic fertilizer, the mass content percentage ratio of bacterial classification is: 0.4%, ferment then formed in 10 days, obtained the sulfate radical organic fertilizer of potassium fermentation using bacteria;
The sulfate radical organic fertilizer of the potassium fermentation using bacteria that (4) obtains mixes with the natural pond is fertile, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 18% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with the natural pond is fertile, and wherein nano-sized carbon accounts for 0.5% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 6
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via thin yellow actinomycete fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with green manure, wherein the mass content percentage ratio of vitriol is 85.6% (vitriolate of tartar 25%, ammonium sulfate 30%, calcium sulfate 20%, sal epsom 10%, zinc sulfate 0.5%, copper sulfate 0.1%), obtains the sulfate radical organic fertilizer;
(2) thin yellow actinomycetes (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3% with substratum; All the other are agar) ferment and produced bacterial classification in 65 hours; Wherein, the temperature of fermentation is 38 ℃, and the pH value should control 7.5;
The thin yellow actinomycetes that (3) will obtain are inoculated in the sulfate radical organic fertilizer, and the mass content percentage ratio of bacterial classification is: 0. 5%, and ferment then formed in 9 days, obtained the sulfate radical organic fertilizer of thin yellow actinomycete fermentation;
The sulfate radical organic fertilizer of the thin yellow actinomycete fermentation that (4) obtains mixes with green manure, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 20% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with green manure, and wherein nano-sized carbon accounts for 0.7% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
Embodiment 7
A kind of nano-sized carbon sulfate radical organic fertilizer, it includes sulfate radical organic fertilizer and nano-sized carbon, and wherein, also via thin yellow actinomycete fermentation, its preparation method is the sulfate radical organic fertilizer:
(1) vitriol is mixed with barnyard manure (usefulness is pig manure here); Wherein the mass content percentage ratio of vitriol is 46.51% (vitriolate of tartar 12%, ammonium sulfate 17%, calcium sulfate 14%, sal epsom 3%, zinc sulfate 0.45%, copper sulfate 0.06%), obtains the sulfate radical organic fertilizer;
(2) thin yellow actinomycetes (mass percent is respectively: soyabean cake cake powder 2%, glucose 2%, lime carbonate 0.4%, sodium-chlor 0.3% with substratum; All the other are agar) ferment and produced bacterial classification in 60 hours; Wherein, the temperature of fermentation is 38 ℃, and the pH value should control 7.5;
The thin yellow actinomycetes that (3) will obtain are inoculated in the sulfate radical organic fertilizer, and the mass content percentage ratio of bacterial classification is: 0. 5%, and ferment then formed in 9 days, obtained the sulfate radical organic fertilizer of thin yellow actinomycete fermentation;
The sulfate radical organic fertilizer of the thin yellow actinomycete fermentation that (4) obtains mixes with barnyard manure, and wherein the sulfate radical organic fertilizer of antibiotic bacteria fermentation accounts for 20% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(5) nano-sized carbon is mixed with green manure, and wherein nano-sized carbon accounts for 0.7% of nano-sized carbon sulfate radical organic fertilizer quality total amount;
(6) the fertilizer uniform mixing that step (4) and step (5) is obtained gets final product.
The sulfate radical nano-sized carbon organic fertilizer that obtains is applied in 50,000 hectares the rape flower experimental plot, and cadmium content exceeds standard in the experimental plot, uses this fertilizer after for some time, and through detecting, cadmium element mainly is enriched in the plant rhizome leaf.After 7 years, the soil cadmium content in this experimental plot just reaches normal range, reduces to 0.3mg/kg, and executes general fertilizers plantation rape flower according to normal circumstances, needs could the cadmium in the soil be purified in 300 years.
Need to prove, comprise the arbitrary combination between the each part mentioned above according to the category of nano-sized carbon sulfate radical organic fertilizer of the present invention and preparation method thereof.
More than combine specific embodiment of the present invention to describe in detail, but be not to be limitation of the present invention.Every foundation technical spirit of the present invention all still belongs to the scope of technical scheme of the present invention to any simple modification that above embodiment did.

Claims (10)

1. nano-sized carbon sulfate radical organic fertilizer, it is characterized in that: include sulfate radical organic fertilizer and nano-sized carbon, wherein, the sulfate radical organic fertilizer also ferments via antibiotic bacteria.
2. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 1 is characterized in that: described sulfate radical organic fertilizer includes vitriol and organic fertilizer.
3. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 2 is characterized in that: vitriol includes a kind of in the following material or any several kinds: vitriolate of tartar, ammonium sulfate, calcium sulfate, sal epsom, zinc sulfate and copper sulfate.
4. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 3; It is characterized in that: in the sulfate radical organic fertilizer; Include vitriolate of tartar, ammonium sulfate, calcium sulfate, sal epsom, zinc sulfate and copper sulfate, the per-cent that its mass content accounts for the sulfate radical organic fertilizer is: vitriolate of tartar 5%-25%, ammonium sulfate 15%-30%, calcium sulfate 10%-20%, sal epsom 2%-10%, zinc sulfate 0.2%-0.5%, copper sulfate 0.05%-0.1%.
5. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 1 is characterized in that: described antibiotic bacteria is Mycophyta, ray fungi or bacterium class.
6. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 1 is characterized in that: antibiotic bacteria is wood mould type of fungi, thin yellow actinomycetes, vinelandii, thiobacterium, phosphor bacterium or potassium bacterium.
7. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 1 is characterized in that: the size of nano carbon particle diameter is 5-70nm.
8. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 2, it is characterized in that: described organic fertilizer is: compost, make compost, barnyard manure, natural pond fertilizer or green manure.
9. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 8 is characterized in that: said compost is tangerine stalk, fallen leaves, green grass, plant and animal residues and/or human and animal excreta.
10. nano-sized carbon sulfate radical organic fertilizer as claimed in claim 8 is characterized in that: said barnyard manure is fecaluria of livestock and poultry such as pig, ox, horse, sheep, chicken, duck, goose and the fertilizer that stalk bedding and padding stack retting is processed.
CN201210325260.7A 2012-08-15 2012-09-06 Nano carbon sulfate radical organic fertilizer and preparation method thereof Active CN102816003B (en)

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CN103524237A (en) * 2013-10-15 2014-01-22 广西宁明百事康生物工程有限公司 Special nano-carbon fertilizer for sugarcane and preparation method thereof
CN103739396A (en) * 2014-01-08 2014-04-23 广西宁明百事康生物工程有限公司 Nano-carbon fertilizer special for paddy rice
CN106518505A (en) * 2015-09-11 2017-03-22 深圳市中兴恒熙环保有限公司 Micro-nano carbon fertilizer prepared from domestic garbage and preparation method thereof
CN105111027A (en) * 2015-10-15 2015-12-02 刘学增 Formula and preparation process of nanocarbon type organic fertilizers
CN105565936A (en) * 2016-02-27 2016-05-11 黑龙江省农垦科学院农畜产品综合利用研究所 Special bulk blended fertilizer added with biological preparation for nano rice
CN107417378A (en) * 2017-06-23 2017-12-01 合肥市风达农业有限责任公司 A kind of Special fertilizer for paddy rice and preparation method thereof
CN107593353A (en) * 2017-10-13 2018-01-19 赵华勤 A kind of implantation methods for improving mung bean active component content
CN107593353B (en) * 2017-10-13 2018-11-23 赵华勤 A kind of implantation methods improving mung bean active component content

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