CN102803307B - 制备聚烯烃的方法 - Google Patents

制备聚烯烃的方法 Download PDF

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Publication number
CN102803307B
CN102803307B CN201180009020.XA CN201180009020A CN102803307B CN 102803307 B CN102803307 B CN 102803307B CN 201180009020 A CN201180009020 A CN 201180009020A CN 102803307 B CN102803307 B CN 102803307B
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reactor
loop reactor
catalyst
catalyzer
pump
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CN201180009020.XA
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Chinese (zh)
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CN102803307A (zh
Inventor
E.达梅
L.弗亚戈
J.贝特
A.福南德兹
A.范托米
R.奥雷恩斯
D.西劳克斯
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Total Petrochemicals Research Feluy SA
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Total Petrochemicals Research Feluy SA
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Priority claimed from EP10152827A external-priority patent/EP2354167A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y10T428/1393—Multilayer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397—Single layer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
CN201180009020.XA 2010-02-05 2011-02-03 制备聚烯烃的方法 Active CN102803307B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10152827.1 2010-02-05
EP10152827A EP2354167A1 (en) 2010-02-05 2010-02-05 Bimodal polyethylene for blow-moulding applications.
EP10171373 2010-07-30
EP10171373.3 2010-07-30
PCT/EP2011/051524 WO2011095532A1 (en) 2010-02-05 2011-02-03 Process for preparing polyolefin

Publications (2)

Publication Number Publication Date
CN102803307A CN102803307A (zh) 2012-11-28
CN102803307B true CN102803307B (zh) 2014-07-30

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CN201180009020.XA Active CN102803307B (zh) 2010-02-05 2011-02-03 制备聚烯烃的方法
CN201180009019.7A Active CN102844333B (zh) 2010-02-05 2011-02-07 用于吹塑应用的双峰聚乙烯

Family Applications After (1)

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CN201180009019.7A Active CN102844333B (zh) 2010-02-05 2011-02-07 用于吹塑应用的双峰聚乙烯

Country Status (14)

Country Link
US (6) US8642710B2 (enExample)
EP (2) EP2531533B2 (enExample)
KR (2) KR101453636B1 (enExample)
CN (2) CN102803307B (enExample)
BR (2) BR112012019015B1 (enExample)
DK (1) DK2531532T3 (enExample)
EA (2) EA025606B1 (enExample)
ES (1) ES2593977T3 (enExample)
FI (1) FI2531533T4 (enExample)
HU (1) HUE056588T2 (enExample)
IN (1) IN2012DN05905A (enExample)
MX (2) MX2012008436A (enExample)
PL (1) PL2531532T3 (enExample)
WO (2) WO2011095532A1 (enExample)

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KR102203007B1 (ko) * 2019-06-05 2021-01-14 대림산업 주식회사 다단계 연속 중합 방법을 이용한 멀티모달 폴리올레핀 제조방법
CN112745408B (zh) * 2019-10-29 2022-10-21 中国石油化工股份有限公司 用于挤出吹塑小中空制品的双峰聚乙烯树脂及其制备方法和应用
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US8829124B2 (en) 2014-09-09
US20140288258A1 (en) 2014-09-25
DK2531532T3 (en) 2016-10-24
US8911872B2 (en) 2014-12-16
IN2012DN05905A (enExample) 2015-09-18
FI2531533T4 (fi) 2025-06-10
CN102844333B (zh) 2015-04-08
BR112012019015B1 (pt) 2020-01-14
BR112012019487B1 (pt) 2020-05-26
CN102844333A (zh) 2012-12-26
EP2531532B1 (en) 2016-07-06
HUE056588T2 (hu) 2022-02-28
US9126179B2 (en) 2015-09-08
US20130030132A1 (en) 2013-01-31
MX2012008436A (es) 2012-12-10
US20140050873A1 (en) 2014-02-20
EP2531533A1 (en) 2012-12-12
PL2531532T3 (pl) 2017-01-31
EA025606B1 (ru) 2017-01-30
EA201290735A1 (ru) 2013-05-30
KR20120117014A (ko) 2012-10-23
KR101430847B1 (ko) 2014-08-18
ES2593977T3 (es) 2016-12-14
US20140334984A1 (en) 2014-11-13
BR112012019487A2 (pt) 2016-04-19
MX2012008833A (es) 2012-09-28
EP2531533B1 (en) 2021-08-25
BR112012019015A2 (pt) 2016-09-13
MX341120B (es) 2016-08-09
US20130202834A1 (en) 2013-08-08
EA022576B1 (ru) 2016-01-29
KR20130008022A (ko) 2013-01-21
EP2531533B2 (en) 2025-03-26
US8642710B2 (en) 2014-02-04
EP2531532A1 (en) 2012-12-12
KR101453636B1 (ko) 2014-10-22
US8609792B2 (en) 2013-12-17
WO2011095629A1 (en) 2011-08-11
US8802210B2 (en) 2014-08-12
US20140088272A1 (en) 2014-03-27
CN102803307A (zh) 2012-11-28
WO2011095532A1 (en) 2011-08-11
EA201270704A1 (ru) 2013-01-30

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