KR101453636B1 - 폴리올레핀 제조 방법 - Google Patents

폴리올레핀 제조 방법 Download PDF

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Publication number
KR101453636B1
KR101453636B1 KR1020127023078A KR20127023078A KR101453636B1 KR 101453636 B1 KR101453636 B1 KR 101453636B1 KR 1020127023078 A KR1020127023078 A KR 1020127023078A KR 20127023078 A KR20127023078 A KR 20127023078A KR 101453636 B1 KR101453636 B1 KR 101453636B1
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catalyst
reactor
loop reactor
slurry
pump
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Korean (ko)
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KR20130008022A (ko
Inventor
에릭 담
루이 푸아르쥬
제롬 베떼
알바로 페르난데즈
오렐리앙 방？므
르노 오르앵
다니엘 시로
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토탈 리서치 앤드 테크놀로지 펠루이
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Priority claimed from EP10152827A external-priority patent/EP2354167A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y10T428/1393—Multilayer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397—Single layer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
KR1020127023078A 2010-02-05 2011-02-03 폴리올레핀 제조 방법 Active KR101453636B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10152827.1 2010-02-05
EP10152827A EP2354167A1 (en) 2010-02-05 2010-02-05 Bimodal polyethylene for blow-moulding applications.
EP10171373 2010-07-30
EP10171373.3 2010-07-30
PCT/EP2011/051524 WO2011095532A1 (en) 2010-02-05 2011-02-03 Process for preparing polyolefin

Publications (2)

Publication Number Publication Date
KR20130008022A KR20130008022A (ko) 2013-01-21
KR101453636B1 true KR101453636B1 (ko) 2014-10-22

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ID=43799736

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KR1020127023078A Active KR101453636B1 (ko) 2010-02-05 2011-02-03 폴리올레핀 제조 방법
KR1020127020499A Active KR101430847B1 (ko) 2010-02-05 2011-02-07 취입-성형 적용물용 바이모달 폴리에틸렌

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KR1020127020499A Active KR101430847B1 (ko) 2010-02-05 2011-02-07 취입-성형 적용물용 바이모달 폴리에틸렌

Country Status (14)

Country Link
US (6) US8642710B2 (enExample)
EP (2) EP2531533B2 (enExample)
KR (2) KR101453636B1 (enExample)
CN (2) CN102803307B (enExample)
BR (2) BR112012019015B1 (enExample)
DK (1) DK2531532T3 (enExample)
EA (2) EA025606B1 (enExample)
ES (1) ES2593977T3 (enExample)
FI (1) FI2531533T4 (enExample)
HU (1) HUE056588T2 (enExample)
IN (1) IN2012DN05905A (enExample)
MX (2) MX2012008436A (enExample)
PL (1) PL2531532T3 (enExample)
WO (2) WO2011095532A1 (enExample)

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US9670342B2 (en) 2013-08-12 2017-06-06 Total Research & Technology Feluy Polyethylene for injection stretch blow molding applications
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US9073029B2 (en) 2013-09-25 2015-07-07 Chevron Phillips Chemical Company Lp System and method for deterring fouling in a polymerization reactor
US9169337B2 (en) * 2014-03-12 2015-10-27 Chevron Phillips Chemical Company Lp Polymers with improved ESCR for blow molding applications
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BR112021019432A2 (pt) * 2019-04-30 2021-11-30 Dow Global Technologies Llc Copolímero de poli(etileno-co-1-alqueno), métodos para fazer o copolímero de poli(etileno-co-1-alqueno) e para fazer um artigo fabricado, formulação, artigo, fabricado, e, uso do artigo fabricado
KR102723897B1 (ko) * 2019-06-04 2024-11-01 보레알리스 아게 폴리올레핀의 생산 방법 및 폴리올레핀 생산을 위한 다단계 반응기 어셈블리
KR102203007B1 (ko) * 2019-06-05 2021-01-14 대림산업 주식회사 다단계 연속 중합 방법을 이용한 멀티모달 폴리올레핀 제조방법
CN112745408B (zh) * 2019-10-29 2022-10-21 中国石油化工股份有限公司 用于挤出吹塑小中空制品的双峰聚乙烯树脂及其制备方法和应用
USD938128S1 (en) 2020-01-06 2021-12-07 Geo Plastics Nestable drum
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US8829124B2 (en) 2014-09-09
US20140288258A1 (en) 2014-09-25
DK2531532T3 (en) 2016-10-24
US8911872B2 (en) 2014-12-16
IN2012DN05905A (enExample) 2015-09-18
FI2531533T4 (fi) 2025-06-10
CN102844333B (zh) 2015-04-08
BR112012019015B1 (pt) 2020-01-14
BR112012019487B1 (pt) 2020-05-26
CN102803307B (zh) 2014-07-30
CN102844333A (zh) 2012-12-26
EP2531532B1 (en) 2016-07-06
HUE056588T2 (hu) 2022-02-28
US9126179B2 (en) 2015-09-08
US20130030132A1 (en) 2013-01-31
MX2012008436A (es) 2012-12-10
US20140050873A1 (en) 2014-02-20
EP2531533A1 (en) 2012-12-12
PL2531532T3 (pl) 2017-01-31
EA025606B1 (ru) 2017-01-30
EA201290735A1 (ru) 2013-05-30
KR20120117014A (ko) 2012-10-23
KR101430847B1 (ko) 2014-08-18
ES2593977T3 (es) 2016-12-14
US20140334984A1 (en) 2014-11-13
BR112012019487A2 (pt) 2016-04-19
MX2012008833A (es) 2012-09-28
EP2531533B1 (en) 2021-08-25
BR112012019015A2 (pt) 2016-09-13
MX341120B (es) 2016-08-09
US20130202834A1 (en) 2013-08-08
EA022576B1 (ru) 2016-01-29
KR20130008022A (ko) 2013-01-21
EP2531533B2 (en) 2025-03-26
US8642710B2 (en) 2014-02-04
EP2531532A1 (en) 2012-12-12
US8609792B2 (en) 2013-12-17
WO2011095629A1 (en) 2011-08-11
US8802210B2 (en) 2014-08-12
US20140088272A1 (en) 2014-03-27
CN102803307A (zh) 2012-11-28
WO2011095532A1 (en) 2011-08-11
EA201270704A1 (ru) 2013-01-30

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