CN102741208B - 使用沸石催化剂生产乙酸和二甲醚的方法 - Google Patents

使用沸石催化剂生产乙酸和二甲醚的方法 Download PDF

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Publication number
CN102741208B
CN102741208B CN201080050510.XA CN201080050510A CN102741208B CN 102741208 B CN102741208 B CN 102741208B CN 201080050510 A CN201080050510 A CN 201080050510A CN 102741208 B CN102741208 B CN 102741208B
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Prior art keywords
zeolite
acetic acid
dimethyl ether
methanol
range
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Chinese (zh)
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CN102741208A (zh
Inventor
B·J·丹尼尔
D·J·劳
J·G·森利
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Ineos Acetyls UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080050510.XA 2009-09-03 2010-08-31 使用沸石催化剂生产乙酸和二甲醚的方法 Active CN102741208B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09252123.6 2009-09-03
EP09252123A EP2292578A1 (en) 2009-09-03 2009-09-03 Process for producing acetic acid and dimethyl ether using a zeolite catalyst
PCT/GB2010/001648 WO2011027105A1 (en) 2009-09-03 2010-08-31 Process for producing acetic acid and dimethyl ether using a zeolite catalyst

Publications (2)

Publication Number Publication Date
CN102741208A CN102741208A (zh) 2012-10-17
CN102741208B true CN102741208B (zh) 2015-05-20

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Family Applications (1)

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CN201080050510.XA Active CN102741208B (zh) 2009-09-03 2010-08-31 使用沸石催化剂生产乙酸和二甲醚的方法

Country Status (14)

Country Link
US (1) US9212117B2 (https=)
EP (2) EP2292578A1 (https=)
JP (1) JP5750106B2 (https=)
KR (1) KR20120046764A (https=)
CN (1) CN102741208B (https=)
BR (1) BR112012004952A2 (https=)
CA (1) CA2772092C (https=)
IN (1) IN2012DN01991A (https=)
MY (1) MY159303A (https=)
RU (1) RU2559058C2 (https=)
SG (1) SG178926A1 (https=)
TW (1) TWI482754B (https=)
UA (1) UA106993C2 (https=)
WO (1) WO2011027105A1 (https=)

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* Cited by examiner, † Cited by third party
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EP2817282A1 (en) * 2012-02-23 2014-12-31 BP Chemicals Limited Catalyst and process for the production of acetic acid and dimetyhl ether
US9365483B2 (en) 2012-02-23 2016-06-14 Bp Chemicals Limited Process for the production of acetic acid and dimethyl ether
US9242920B2 (en) 2012-12-21 2016-01-26 Bp Chemicals Limited Integrated process for making acetic acid
SG11201506356WA (en) * 2013-02-15 2015-09-29 Bp Chem Int Ltd Dehydration-hydrolysis processes and catalysts therefor
TW201538471A (zh) * 2014-02-13 2015-10-16 Bp Chem Int Ltd 脫水－水解之製程及用於該製程之催化劑
JP2017519745A (ja) * 2014-06-20 2017-07-20 ビーピー ケミカルズ リミテッドＢｐ Ｃｈｅｍｉｃａｌｓ Ｌｉｍｉｔｅｄ 酢酸の製造方法における改善された触媒性能
WO2015193183A1 (en) * 2014-06-20 2015-12-23 Bp Chemicals Limited Process for the co-production of acetic acid and dimethyl ether
EP3131871A1 (en) * 2014-06-20 2017-02-22 BP Chemicals Limited Process for the co-production of acetic acid and dimethyl ether
CN106660920B (zh) * 2014-06-20 2020-07-14 英国石油化学品有限公司 用于联合生产乙酸和二甲醚的方法
CN106795074A (zh) * 2014-06-20 2017-05-31 英国石油化学品有限公司 从一氧化碳、氢气和乙酸甲酯的气体混合物生产二甲醚的方法
CA2950361A1 (en) * 2014-06-20 2015-12-23 Bp Chemicals Limited Process for purifying methyl acetate mixtures
US11236032B2 (en) 2017-08-24 2022-02-01 Bp P.L.C. Process for dehydrating methanol to dimethyl ether
CN111344272B (zh) 2017-08-24 2023-06-23 英国石油有限公司 甲醇脱水的方法
US11427524B2 (en) 2017-08-24 2022-08-30 Bp P.L.C. Process for dehydrating methanol to dimethyl ether product
WO2019037769A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
CN108586247B (zh) * 2018-07-02 2020-09-22 中国科学院山西煤炭化学研究所 一种二甲醚羰基化制备乙酸甲酯的方法
US12084410B2 (en) 2019-02-22 2024-09-10 BP P.L.C. and BP (CHINA) Holdings LTD Process for dehydrating methanol to dimethyl ether
EP3927681B1 (en) 2019-02-22 2024-04-03 Bp P.L.C. Process for dehydrating methanol to dimethylether
CN115677478A (zh) * 2022-11-07 2023-02-03 上海燮宸新材料科技有限公司 一种乙醛酸的制备方法

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US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
DE3606169A1 (de) * 1986-02-26 1987-08-27 Basf Ag Verfahren zur herstellung von essigsaeure, methylacetat und/oder dimethylether
US5235102A (en) 1990-11-20 1993-08-10 Amoco Corporation Catalytic distillation using rigid, cellular monoliths as catalyst-packing material
US5684213A (en) 1996-03-25 1997-11-04 Chemical Research & Licensing Company Method for the preparation of dialkyl ethers
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
JP2003128599A (ja) * 2001-10-16 2003-05-08 Teijin Ltd テレフタル酸の製造方法
JP4309627B2 (ja) 2002-09-06 2009-08-05 東洋エンジニアリング株式会社 ジメチルエーテルの製造方法
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KR100501922B1 (ko) 2003-02-19 2005-07-18 에스케이 주식회사 메탄올로부터 디메틸에테르의 제조방법
CN1224596C (zh) 2003-04-29 2005-10-26 中国石油化工股份有限公司 酯类的水解方法
KR100629939B1 (ko) 2004-10-15 2006-09-28 에스케이 주식회사 단열반응기에서 미정제 메탄올로부터 디메틸에테르의제조방법
JP2008029988A (ja) * 2006-07-31 2008-02-14 Sumitomo Chemical Co Ltd ジメチルエーテル製造用触媒とその製造方法およびこれを用いたジメチルエーテルの製造方法
FR2909666B1 (fr) * 2006-12-08 2009-03-06 Centre Nat Rech Scient Deshydratation du methanol en dimethyl ether employant des catalyseurs a base d'une zeolithe supportee sur du carbure de silicium
UA95663C2 (uk) * 2006-12-15 2011-08-25 Зе Регентс Оф Зе Юніверситі Оф Каліфорнія Спосіб одержання с1-с3-аліфатичної карбонової кислоти й/або відповідного складного ефіру шляхом карбонілювання
CN101204669B (zh) * 2006-12-22 2010-04-21 中国石油化工股份有限公司 一种甲醇脱水制备二甲醚催化剂
CN101274878B (zh) * 2007-03-30 2011-07-20 中国石油化工股份有限公司 一种甲醇多段气相脱水生产二甲醚的流化催化方法
EP2072492A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
KR100966706B1 (ko) * 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
EP2251314A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation process

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
US6521783B1 (en) * 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates

Also Published As

Publication number Publication date
CA2772092C (en) 2017-01-10
SG178926A1 (en) 2012-04-27
US9212117B2 (en) 2015-12-15
WO2011027105A1 (en) 2011-03-10
BR112012004952A2 (pt) 2019-09-24
JP5750106B2 (ja) 2015-07-15
RU2012112638A (ru) 2013-10-10
CA2772092A1 (en) 2011-03-10
IN2012DN01991A (https=) 2015-07-24
RU2559058C2 (ru) 2015-08-10
TWI482754B (zh) 2015-05-01
JP2013503840A (ja) 2013-02-04
CN102741208A (zh) 2012-10-17
EP2473466A1 (en) 2012-07-11
US20120165570A1 (en) 2012-06-28
MY159303A (en) 2016-12-30
EP2292578A1 (en) 2011-03-09
TW201113250A (en) 2011-04-16
UA106993C2 (uk) 2014-11-10
KR20120046764A (ko) 2012-05-10

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Effective date of registration: 20210915

Address after: England Hampshire

Patentee after: Ineos acetyl UK Ltd.

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Patentee before: BP Chemicals Ltd.

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