CN102741208B - 使用沸石催化剂生产乙酸和二甲醚的方法 - Google Patents

使用沸石催化剂生产乙酸和二甲醚的方法 Download PDF

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Publication number
CN102741208B
CN102741208B CN201080050510.XA CN201080050510A CN102741208B CN 102741208 B CN102741208 B CN 102741208B CN 201080050510 A CN201080050510 A CN 201080050510A CN 102741208 B CN102741208 B CN 102741208B
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China
Prior art keywords
zeolite
acetic acid
dimethyl ether
methanol
range
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CN201080050510.XA
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English (en)
Chinese (zh)
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CN102741208A (zh
Inventor
B·J·丹尼尔
D·J·劳
J·G·森利
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Ineos Acetyls UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080050510.XA 2009-09-03 2010-08-31 使用沸石催化剂生产乙酸和二甲醚的方法 Active CN102741208B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09252123.6 2009-09-03
EP09252123A EP2292578A1 (en) 2009-09-03 2009-09-03 Process for producing acetic acid and dimethyl ether using a zeolite catalyst
PCT/GB2010/001648 WO2011027105A1 (en) 2009-09-03 2010-08-31 Process for producing acetic acid and dimethyl ether using a zeolite catalyst

Publications (2)

Publication Number Publication Date
CN102741208A CN102741208A (zh) 2012-10-17
CN102741208B true CN102741208B (zh) 2015-05-20

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Family Applications (1)

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CN201080050510.XA Active CN102741208B (zh) 2009-09-03 2010-08-31 使用沸石催化剂生产乙酸和二甲醚的方法

Country Status (14)

Country Link
US (1) US9212117B2 (enExample)
EP (2) EP2292578A1 (enExample)
JP (1) JP5750106B2 (enExample)
KR (1) KR20120046764A (enExample)
CN (1) CN102741208B (enExample)
BR (1) BR112012004952A2 (enExample)
CA (1) CA2772092C (enExample)
IN (1) IN2012DN01991A (enExample)
MY (1) MY159303A (enExample)
RU (1) RU2559058C2 (enExample)
SG (1) SG178926A1 (enExample)
TW (1) TWI482754B (enExample)
UA (1) UA106993C2 (enExample)
WO (1) WO2011027105A1 (enExample)

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* Cited by examiner, † Cited by third party
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US9365483B2 (en) 2012-02-23 2016-06-14 Bp Chemicals Limited Process for the production of acetic acid and dimethyl ether
MY167587A (en) * 2012-02-23 2018-09-20 Bp Chem Int Ltd Catalyst and process for the production of acetic acid and dimethyl ether
US9242920B2 (en) 2012-12-21 2016-01-26 Bp Chemicals Limited Integrated process for making acetic acid
UA116126C2 (uk) * 2013-02-15 2018-02-12 Бп Кемікалз Лімітед Способи дегідратації-гідролізу й каталізатори для цього
TW201538471A (zh) * 2014-02-13 2015-10-16 Bp Chem Int Ltd 脫水－水解之製程及用於該製程之催化劑
JP2017521379A (ja) 2014-06-20 2017-08-03 ビーピー ケミカルズ リミテッドＢｐ Ｃｈｅｍｉｃａｌｓ Ｌｉｍｉｔｅｄ 酢酸およびジメチルエーテルの併産用プロセス
WO2015193188A1 (en) * 2014-06-20 2015-12-23 Bp Chemicals Limited Process for the co-production of acetic acid and dimethyl ether
UA120931C2 (uk) 2014-06-20 2020-03-10 Бп Кемікалз Лімітед Спосіб очистки сумішей метилацетату
RU2704319C2 (ru) * 2014-06-20 2019-10-28 Бп Кемикэлз Лимитед Улучшенные каталитические характеристики в способах получения уксусной кислоты
EP3131867A1 (en) * 2014-06-20 2017-02-22 BP Chemicals Limited Process for the co-production of acetic acid and dimethyl ether
KR20170022984A (ko) * 2014-06-20 2017-03-02 비피 케미칼즈 리미티드 일산화탄소, 수소 및 메틸 아세테이트의 기체성 혼합물로부터 디메틸 에테르를 제조하는 공정
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037766A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037760A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
EP3672928A4 (en) 2017-08-24 2021-05-12 Bp P.L.C. PROCESS
WO2019037769A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
CN108586247B (zh) * 2018-07-02 2020-09-22 中国科学院山西煤炭化学研究所 一种二甲醚羰基化制备乙酸甲酯的方法
WO2020168548A1 (en) 2019-02-22 2020-08-27 Bp P.L.C. Process
US12084409B2 (en) 2019-02-22 2024-09-10 Bp P.L.C. Process for dehydrating methanol to dimethyl ether

Citations (1)

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US6521783B1 (en) * 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates

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US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
DE3606169A1 (de) * 1986-02-26 1987-08-27 Basf Ag Verfahren zur herstellung von essigsaeure, methylacetat und/oder dimethylether
US5235102A (en) 1990-11-20 1993-08-10 Amoco Corporation Catalytic distillation using rigid, cellular monoliths as catalyst-packing material
US5684213A (en) 1996-03-25 1997-11-04 Chemical Research & Licensing Company Method for the preparation of dialkyl ethers
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
JP2003128599A (ja) * 2001-10-16 2003-05-08 Teijin Ltd テレフタル酸の製造方法
JP4309627B2 (ja) 2002-09-06 2009-08-05 東洋エンジニアリング株式会社 ジメチルエーテルの製造方法
DE10255648B4 (de) * 2002-11-28 2005-01-27 Wacker-Chemie Gmbh Verfahren und Vorrichtung zur hydrolytischen Gewinnung einer Carbonsäure und Alkohol aus dem entsprechenden Carbonsäureester
KR100454091B1 (ko) * 2002-12-11 2004-10-26 한국화학연구원 미정제 메탄올로부터 디메틸에테르의 제조방법
KR100501922B1 (ko) 2003-02-19 2005-07-18 에스케이 주식회사 메탄올로부터 디메틸에테르의 제조방법
CN1224596C (zh) 2003-04-29 2005-10-26 中国石油化工股份有限公司 酯类的水解方法
KR100629939B1 (ko) 2004-10-15 2006-09-28 에스케이 주식회사 단열반응기에서 미정제 메탄올로부터 디메틸에테르의제조방법
JP2008029988A (ja) * 2006-07-31 2008-02-14 Sumitomo Chemical Co Ltd ジメチルエーテル製造用触媒とその製造方法およびこれを用いたジメチルエーテルの製造方法
FR2909666B1 (fr) * 2006-12-08 2009-03-06 Centre Nat Rech Scient Deshydratation du methanol en dimethyl ether employant des catalyseurs a base d'une zeolithe supportee sur du carbure de silicium
CN101600678B (zh) * 2006-12-15 2012-08-15 加州大学评议会 脂肪醇和/或其反应性衍生物羰基化的方法
CN101204669B (zh) * 2006-12-22 2010-04-21 中国石油化工股份有限公司 一种甲醇脱水制备二甲醚催化剂
CN101274878B (zh) * 2007-03-30 2011-07-20 中国石油化工股份有限公司 一种甲醇多段气相脱水生产二甲醚的流化催化方法
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KR100966706B1 (ko) * 2008-06-18 2010-06-29 아주대학교산학협력단 메탄올로부터 디메틸에테르를 제조하는 방법
EP2251314A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation process

Patent Citations (1)

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US6521783B1 (en) * 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates

Also Published As

Publication number Publication date
TWI482754B (zh) 2015-05-01
RU2559058C2 (ru) 2015-08-10
BR112012004952A2 (pt) 2019-09-24
RU2012112638A (ru) 2013-10-10
WO2011027105A1 (en) 2011-03-10
JP2013503840A (ja) 2013-02-04
EP2292578A1 (en) 2011-03-09
CA2772092C (en) 2017-01-10
IN2012DN01991A (enExample) 2015-07-24
CN102741208A (zh) 2012-10-17
JP5750106B2 (ja) 2015-07-15
SG178926A1 (en) 2012-04-27
MY159303A (en) 2016-12-30
US20120165570A1 (en) 2012-06-28
UA106993C2 (uk) 2014-11-10
TW201113250A (en) 2011-04-16
CA2772092A1 (en) 2011-03-10
KR20120046764A (ko) 2012-05-10
US9212117B2 (en) 2015-12-15
EP2473466A1 (en) 2012-07-11

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Effective date of registration: 20210915

Address after: England Hampshire

Patentee after: Ineos acetyl UK Ltd.

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Patentee before: BP Chemicals Ltd.

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