CN1026409C - 烃的制备方法 - Google Patents
烃的制备方法 Download PDFInfo
- Publication number
- CN1026409C CN1026409C CN90102735A CN90102735A CN1026409C CN 1026409 C CN1026409 C CN 1026409C CN 90102735 A CN90102735 A CN 90102735A CN 90102735 A CN90102735 A CN 90102735A CN 1026409 C CN1026409 C CN 1026409C
- Authority
- CN
- China
- Prior art keywords
- catalyzer
- hydrogen
- carbon monoxide
- weight part
- surface area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 22
- 239000003054 catalyst Substances 0.000 claims abstract description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 19
- 239000010941 cobalt Substances 0.000 claims abstract description 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010936 titanium Substances 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 235000013495 cobalt Nutrition 0.000 description 18
- 230000009183 running Effects 0.000 description 12
- 238000009835 boiling Methods 0.000 description 10
- 238000007598 dipping method Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 239000000969 carrier Substances 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- -1 n-propyl alcohols Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0455—Reaction conditions
- C07C1/046—Numerical values of parameters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/85—Chromium, molybdenum or tungsten
- C07C2523/86—Chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898911075A GB8911075D0 (en) | 1989-05-15 | 1989-05-15 | Process for the preparation of hydrocarbons |
| GB8911075.3 | 1989-05-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1047275A CN1047275A (zh) | 1990-11-28 |
| CN1026409C true CN1026409C (zh) | 1994-11-02 |
Family
ID=10656729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN90102735A Expired - Fee Related CN1026409C (zh) | 1989-05-15 | 1990-05-11 | 烃的制备方法 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US5037856A (enExample) |
| EP (1) | EP0398420B1 (enExample) |
| JP (1) | JPH0321694A (enExample) |
| CN (1) | CN1026409C (enExample) |
| AT (1) | ATE109760T1 (enExample) |
| AU (1) | AU620246B2 (enExample) |
| BR (1) | BR9002209A (enExample) |
| CA (1) | CA2016619A1 (enExample) |
| DE (1) | DE69011405T2 (enExample) |
| DK (1) | DK0398420T3 (enExample) |
| EG (1) | EG19591A (enExample) |
| ES (1) | ES2058753T3 (enExample) |
| GB (1) | GB8911075D0 (enExample) |
| IN (1) | IN176736B (enExample) |
| NO (1) | NO902103L (enExample) |
| NZ (1) | NZ233652A (enExample) |
| OA (1) | OA09210A (enExample) |
| RU (1) | RU1833355C (enExample) |
| TR (1) | TR25279A (enExample) |
| ZA (1) | ZA903610B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9108657D0 (en) * | 1991-04-23 | 1991-06-12 | Shell Int Research | Process for the preparation of hydrocarbons |
| CN1044979C (zh) * | 1993-02-17 | 1999-09-08 | 中国科学院大连化学物理研究所 | 一种煤气耐硫甲烷化铬基氧化物催化剂及其制备 |
| FR2745820B1 (fr) * | 1996-03-08 | 1998-04-17 | Inst Francais Du Petrole | Conversion du gaz de synthese en hydrocarbures en presence d'une phase liquide |
| FR2747054B1 (fr) * | 1996-04-09 | 1998-05-22 | Inst Francais Du Petrole | Procede de conversion du gaz de synthese en presence d'un catalyseur a base de cobalt et de titane |
| GC0000360A (en) | 2000-05-04 | 2007-03-31 | Shell Int Research | A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst |
| AU8582301A (en) | 2000-07-14 | 2002-01-30 | Shell Int Research | A catalyst support, a supported group viii metal catalyst and a precursor thereof, processes for their preparation, and use of the supported group viii metal catalyst |
| EP1303351B1 (en) | 2000-07-24 | 2004-03-03 | Shell Internationale Researchmaatschappij B.V. | A shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst |
| DE10157177A1 (de) * | 2001-11-22 | 2003-06-18 | Kataleuna Gmbh Catalysts | Katalysator zur Hydrierung von substituierten Phenolen und Verfahren zu dessen Herstellung |
| MY134279A (en) * | 2002-06-05 | 2007-11-30 | Shell Int Research | Process for the production of hydrocarbons from gaseous hydrocarbonaceous feed |
| GB0214383D0 (en) | 2002-06-21 | 2002-07-31 | Isis Innovation | Catalyst |
| AU2005308788B2 (en) | 2004-11-29 | 2009-04-30 | Shell Internationale Research Maatschappij B.V. | Catalytic process for the conversion of Co (II)hydroxide in Co (III)oxidehydroxide |
| CN101283077B (zh) * | 2005-08-22 | 2012-05-02 | 国际壳牌研究有限公司 | 柴油和操作柴油发动机的方法 |
| EP1782885B1 (en) | 2005-11-07 | 2012-04-04 | Research Institute of Petroleum Industry (RIPI) | Carbon nanotubes supported cobalt catalyst for converting synthesis gas into hydrocarbons |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| RU2407731C2 (ru) * | 2009-01-20 | 2010-12-27 | Общество с ограниченной ответственностью "Аромагаз" | Способ получения ароматических углеводородов из синтез-газа |
| US9358526B2 (en) | 2013-11-19 | 2016-06-07 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| US9180436B1 (en) | 2013-11-19 | 2015-11-10 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| MY193473A (en) | 2014-12-19 | 2022-10-14 | Shell Int Research | Method for preparing a catalyst |
| MY203255A (en) | 2015-12-21 | 2024-06-20 | Shell Int Research | Method for preparing a catalyst |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4522939A (en) * | 1983-05-31 | 1985-06-11 | Shell Oil Company | Preparation of catalyst for producing middle distillates from syngas |
| IN164465B (enExample) * | 1984-07-06 | 1989-03-18 | Shell Int Research | |
| IN166813B (enExample) * | 1985-01-18 | 1990-07-21 | Shell Int Research |
-
1989
- 1989-05-15 GB GB898911075A patent/GB8911075D0/en active Pending
-
1990
- 1990-05-08 DK DK90201167.5T patent/DK0398420T3/da active
- 1990-05-08 DE DE69011405T patent/DE69011405T2/de not_active Expired - Fee Related
- 1990-05-08 ES ES90201167T patent/ES2058753T3/es not_active Expired - Lifetime
- 1990-05-08 US US07/520,428 patent/US5037856A/en not_active Expired - Lifetime
- 1990-05-08 AT AT90201167T patent/ATE109760T1/de not_active IP Right Cessation
- 1990-05-08 EP EP90201167A patent/EP0398420B1/en not_active Expired - Lifetime
- 1990-05-11 RU SU904830117A patent/RU1833355C/ru active
- 1990-05-11 BR BR909002209A patent/BR9002209A/pt not_active Application Discontinuation
- 1990-05-11 JP JP2120166A patent/JPH0321694A/ja active Pending
- 1990-05-11 TR TR90/0467A patent/TR25279A/xx unknown
- 1990-05-11 NZ NZ233652A patent/NZ233652A/en unknown
- 1990-05-11 CN CN90102735A patent/CN1026409C/zh not_active Expired - Fee Related
- 1990-05-11 ZA ZA903610A patent/ZA903610B/xx unknown
- 1990-05-11 IN IN359MA1990 patent/IN176736B/en unknown
- 1990-05-11 OA OA59789A patent/OA09210A/xx unknown
- 1990-05-11 CA CA002016619A patent/CA2016619A1/en not_active Abandoned
- 1990-05-11 NO NO90902103A patent/NO902103L/no unknown
- 1990-05-11 AU AU54964/90A patent/AU620246B2/en not_active Ceased
- 1990-05-13 EG EG27990A patent/EG19591A/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| EG19591A (en) | 1996-02-29 |
| DE69011405D1 (de) | 1994-09-15 |
| RU1833355C (ru) | 1993-08-07 |
| GB8911075D0 (en) | 1989-06-28 |
| AU5496490A (en) | 1990-11-15 |
| AU620246B2 (en) | 1992-02-13 |
| NO902103L (no) | 1990-11-16 |
| TR25279A (tr) | 1993-01-01 |
| OA09210A (en) | 1992-06-30 |
| NZ233652A (en) | 1992-01-29 |
| US5037856A (en) | 1991-08-06 |
| NO902103D0 (no) | 1990-05-11 |
| ES2058753T3 (es) | 1994-11-01 |
| ZA903610B (en) | 1991-02-27 |
| JPH0321694A (ja) | 1991-01-30 |
| EP0398420B1 (en) | 1994-08-10 |
| EP0398420A3 (en) | 1991-05-29 |
| CA2016619A1 (en) | 1990-11-15 |
| CN1047275A (zh) | 1990-11-28 |
| DE69011405T2 (de) | 1994-12-15 |
| BR9002209A (pt) | 1991-08-13 |
| IN176736B (enExample) | 1996-08-31 |
| DK0398420T3 (da) | 1994-10-03 |
| ATE109760T1 (de) | 1994-08-15 |
| EP0398420A2 (en) | 1990-11-22 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |