ZA903610B - Process for the preparation of hydrocarbons - Google Patents

Process for the preparation of hydrocarbons

Info

Publication number
ZA903610B
ZA903610B ZA903610A ZA903610A ZA903610B ZA 903610 B ZA903610 B ZA 903610B ZA 903610 A ZA903610 A ZA 903610A ZA 903610 A ZA903610 A ZA 903610A ZA 903610 B ZA903610 B ZA 903610B
Authority
ZA
South Africa
Prior art keywords
parts
weight
hydrogen
carbon monoxide
hydrocarbons
Prior art date
Application number
ZA903610A
Inventor
Martin Franciscus Maria Post
Franciscus Maria Post Martin
Willibrord Adelbert Van Erp
Adelbert Van Erp Willibrord
Original Assignee
Shell Res Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Res Ltd filed Critical Shell Res Ltd
Publication of ZA903610B publication Critical patent/ZA903610B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0455Reaction conditions
    • C07C1/046Numerical values of parameters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • C07C1/0435Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/75Cobalt
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • C07C2523/86Chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention relates to a process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen, comprising the steps of: a) selecting a catalyst comprising: i) 3-80 parts by weight cobalt per 100 parts by weight of porous carrier; ii) 0.1-100 parts by weight of at least one metal selected from zirconium, titanium and chromium, per 100 parts by weight of porous carrier; and iii) an external surface area (Se) Se </= 70 cm<2>/ml; b) activating the catalyst; and c) contacting the activated catalyst in a fixed bed form with a mixture of carbon monoxide and hydrogen having a hydrogen/carbon monoxide feed ratio (F) F </= 1.9 under such conditions that Se/F >/= 12.5, and to hydrocarbons obtained therewith.
ZA903610A 1989-05-15 1990-05-11 Process for the preparation of hydrocarbons ZA903610B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB898911075A GB8911075D0 (en) 1989-05-15 1989-05-15 Process for the preparation of hydrocarbons

Publications (1)

Publication Number Publication Date
ZA903610B true ZA903610B (en) 1991-02-27

Family

ID=10656729

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA903610A ZA903610B (en) 1989-05-15 1990-05-11 Process for the preparation of hydrocarbons

Country Status (20)

Country Link
US (1) US5037856A (en)
EP (1) EP0398420B1 (en)
JP (1) JPH0321694A (en)
CN (1) CN1026409C (en)
AT (1) ATE109760T1 (en)
AU (1) AU620246B2 (en)
BR (1) BR9002209A (en)
CA (1) CA2016619A1 (en)
DE (1) DE69011405T2 (en)
DK (1) DK0398420T3 (en)
EG (1) EG19591A (en)
ES (1) ES2058753T3 (en)
GB (1) GB8911075D0 (en)
IN (1) IN176736B (en)
NO (1) NO902103L (en)
NZ (1) NZ233652A (en)
OA (1) OA09210A (en)
RU (1) RU1833355C (en)
TR (1) TR25279A (en)
ZA (1) ZA903610B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9108657D0 (en) * 1991-04-23 1991-06-12 Shell Int Research Process for the preparation of hydrocarbons
CN1044979C (en) * 1993-02-17 1999-09-08 中国科学院大连化学物理研究所 Non-molybdenum oxide catalyzer resisting methanation of sulfur and its processing
FR2745820B1 (en) * 1996-03-08 1998-04-17 Inst Francais Du Petrole CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS IN THE PRESENCE OF A LIQUID PHASE
FR2747054B1 (en) * 1996-04-09 1998-05-22 Inst Francais Du Petrole PROCESS FOR THE CONVERSION OF SYNTHESIS GAS IN THE PRESENCE OF A CATALYST BASED ON COBALT AND TITANIUM
GC0000360A (en) 2000-05-04 2007-03-31 Shell Int Research A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst
ATE342129T1 (en) 2000-07-14 2006-11-15 Shell Int Research METHOD FOR THE PRODUCTION OF A COBALT SUPPORTED CATALYST AND ITS PRECURSOR AND THE USE OF THE SUPPORTED CATALYST
US7087191B2 (en) 2000-07-24 2006-08-08 Shell Oil Company Shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst
DE10157177A1 (en) * 2001-11-22 2003-06-18 Kataleuna Gmbh Catalysts Catalyst for hydrogenation of substituted phenol compounds, e.g. terpenyl-guaiacol and -catechol to terpenyl alcohols, contains cobalt and manganese, chromium or iron on an alumina, silica or titanium dioxide support
GB0214383D0 (en) 2002-06-21 2002-07-31 Isis Innovation Catalyst
CN101080365A (en) 2004-11-29 2007-11-28 国际壳牌研究有限公司 Catalytic process for the conversion of co (II)hydroxide in co (III)oxidehydroxide
JP5619356B2 (en) * 2005-08-22 2014-11-05 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイShell Internationale Research Maatschappij Beslotenvennootshap Operation method of diesel fuel and diesel engine
EP1782885B1 (en) 2005-11-07 2012-04-04 Research Institute of Petroleum Industry (RIPI) Carbon nanotubes supported cobalt catalyst for converting synthesis gas into hydrocarbons
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US9180436B1 (en) 2013-11-19 2015-11-10 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
RU2710375C2 (en) 2014-12-19 2019-12-26 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method of catalyst preparation
CN108430629B (en) 2015-12-21 2021-11-12 国际壳牌研究有限公司 Hydrogenation catalyst and process for its preparation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4522939A (en) * 1983-05-31 1985-06-11 Shell Oil Company Preparation of catalyst for producing middle distillates from syngas
IN164465B (en) * 1984-07-06 1989-03-18 Shell Int Research
IN166813B (en) * 1985-01-18 1990-07-21 Shell Int Research

Also Published As

Publication number Publication date
ES2058753T3 (en) 1994-11-01
EP0398420A2 (en) 1990-11-22
CA2016619A1 (en) 1990-11-15
US5037856A (en) 1991-08-06
DE69011405D1 (en) 1994-09-15
EP0398420B1 (en) 1994-08-10
CN1047275A (en) 1990-11-28
NO902103L (en) 1990-11-16
IN176736B (en) 1996-08-31
AU620246B2 (en) 1992-02-13
NO902103D0 (en) 1990-05-11
DE69011405T2 (en) 1994-12-15
DK0398420T3 (en) 1994-10-03
CN1026409C (en) 1994-11-02
EP0398420A3 (en) 1991-05-29
TR25279A (en) 1993-01-01
OA09210A (en) 1992-06-30
AU5496490A (en) 1990-11-15
EG19591A (en) 1996-02-29
RU1833355C (en) 1993-08-07
BR9002209A (en) 1991-08-13
NZ233652A (en) 1992-01-29
JPH0321694A (en) 1991-01-30
ATE109760T1 (en) 1994-08-15
GB8911075D0 (en) 1989-06-28

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