CN102574878A - 气相加氢甲酰化方法 - Google Patents

气相加氢甲酰化方法 Download PDF

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Publication number
CN102574878A
CN102574878A CN2010800468045A CN201080046804A CN102574878A CN 102574878 A CN102574878 A CN 102574878A CN 2010800468045 A CN2010800468045 A CN 2010800468045A CN 201080046804 A CN201080046804 A CN 201080046804A CN 102574878 A CN102574878 A CN 102574878A
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catalyst
ligand
group
hydroformylation
reaction
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R·W·韦格曼
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Dow Technology Investments LLC
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Dow Technology Investments LLC
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Priority to CN201710599890.6A priority Critical patent/CN107266298A/zh
Publication of CN102574878A publication Critical patent/CN102574878A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2010800468045A 2009-10-16 2010-10-06 气相加氢甲酰化方法 Pending CN102574878A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710599890.6A CN107266298A (zh) 2009-10-16 2010-10-06 气相加氢甲酰化方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US25245009P 2009-10-16 2009-10-16
US61/252,450 2009-10-16
PCT/US2010/051576 WO2011046781A1 (en) 2009-10-16 2010-10-06 Gas phase hydroformylation process

Related Child Applications (1)

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CN201710599890.6A Division CN107266298A (zh) 2009-10-16 2010-10-06 气相加氢甲酰化方法

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CN102574878A true CN102574878A (zh) 2012-07-11

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CN2010800468045A Pending CN102574878A (zh) 2009-10-16 2010-10-06 气相加氢甲酰化方法
CN201710599890.6A Pending CN107266298A (zh) 2009-10-16 2010-10-06 气相加氢甲酰化方法

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US (1) US8586800B2 (https=)
EP (1) EP2488539B2 (https=)
JP (1) JP5823967B2 (https=)
CN (2) CN102574878A (https=)
WO (1) WO2011046781A1 (https=)
ZA (1) ZA201202751B (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104475161A (zh) * 2014-12-03 2015-04-01 中国石油大学(北京) 铁磁性纳米颗粒固载铑络合物的氢甲酰化催化剂的制法
CN113181966A (zh) * 2021-04-25 2021-07-30 中国科学院兰州化学物理研究所 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用
CN115364901A (zh) * 2021-05-18 2022-11-22 赢创运营有限公司 用于气相中的烯烃的加氢甲酰化的催化剂的再生方法
CN116019116A (zh) * 2022-12-07 2023-04-28 四川易宏欣农业科技有限公司 一种农药粉剂及其使用方法

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RU2634719C2 (ru) * 2012-06-04 2017-11-03 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования
DE102013201668B4 (de) 2013-02-01 2019-05-16 Evonik Degussa Gmbh Verfahren zur selektiven Ruthenium-katalysierten Hydroaminomethylierung von Olefinen
DE102013217174A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102014209533A1 (de) * 2014-05-20 2015-12-17 Evonik Degussa Gmbh Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion
EP3029045B1 (de) 2014-12-04 2018-06-13 Evonik Degussa GmbH Bisphosphite die eine 2,3 -Biphenol-Einheit als Zentral-Baustein aufweisen
EP3130399B1 (de) 2015-08-12 2021-07-07 Basf Se Verfahren zur hydroformylierung von olefinen und/oder alkinen in der gasphase mit einem gemisch aus wasserstoff und kohlenmonoxid in gegenwart von heterogenem katalysator
EP3674282B1 (en) 2017-08-24 2021-09-22 Mitsubishi Chemical Corporation Bisphosphite compound, catalyst, production method of aldehydes, and production method of alcohol
US10654784B2 (en) * 2018-10-05 2020-05-19 Evonik Operations Gmbh Process for hydroformylating short-chain olefins in the gas phase
EP4074722A1 (de) * 2021-04-16 2022-10-19 Evonik Operations GmbH Diphosphite mit einem offenen, 3-methylierten flügelbaustein
PL4448171T3 (pl) * 2021-12-16 2025-10-20 Dow Technology Investments Llc Kompozycje prekursora katalitycznego do hydroformylowania kompleksu metalu przejściowego zawierające takie związki i procesy hydroformylowania
CN118317834A (zh) * 2021-12-16 2024-07-09 陶氏技术投资有限责任公司 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
CN114931961B (zh) * 2022-06-10 2024-02-27 万华化学集团股份有限公司 一种氢甲酰化催化剂及其应用
CN117380223B (zh) * 2023-10-12 2025-11-04 北京高新利华科技股份有限公司 铑基催化剂及其制法和应用
WO2025170886A1 (en) * 2024-02-06 2025-08-14 Eastman Chemical Company Purge for a gas-stripping hydroformylation reactor for oxo aldehydes
CN119591482B (zh) * 2024-11-19 2026-01-23 成都欣华源科技有限责任公司 一种高碳烯烃氢甲酰化连续循环工艺及系统

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104475161A (zh) * 2014-12-03 2015-04-01 中国石油大学(北京) 铁磁性纳米颗粒固载铑络合物的氢甲酰化催化剂的制法
CN113181966A (zh) * 2021-04-25 2021-07-30 中国科学院兰州化学物理研究所 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用
CN113181966B (zh) * 2021-04-25 2022-08-30 中国科学院兰州化学物理研究所 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用
CN115364901A (zh) * 2021-05-18 2022-11-22 赢创运营有限公司 用于气相中的烯烃的加氢甲酰化的催化剂的再生方法
CN116019116A (zh) * 2022-12-07 2023-04-28 四川易宏欣农业科技有限公司 一种农药粉剂及其使用方法
CN116019116B (zh) * 2022-12-07 2024-01-12 孟州农达生化制品有限公司 一种农药粉剂及其使用方法

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ZA201202751B (en) 2013-06-26
EP2488539A1 (en) 2012-08-22
JP5823967B2 (ja) 2015-11-25
EP2488539B2 (en) 2023-12-20
CN107266298A (zh) 2017-10-20
JP2013508274A (ja) 2013-03-07
US20120190894A1 (en) 2012-07-26
EP2488539B1 (en) 2016-01-06
US8586800B2 (en) 2013-11-19
WO2011046781A1 (en) 2011-04-21

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Application publication date: 20120711