CN102464881A - 无卤的阻燃聚酰胺组合物 - Google Patents
无卤的阻燃聚酰胺组合物 Download PDFInfo
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- CN102464881A CN102464881A CN201010544353XA CN201010544353A CN102464881A CN 102464881 A CN102464881 A CN 102464881A CN 201010544353X A CN201010544353X A CN 201010544353XA CN 201010544353 A CN201010544353 A CN 201010544353A CN 102464881 A CN102464881 A CN 102464881A
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- polymeric amide
- polyamide
- daiamid composition
- fire
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- 239000000203 mixture Substances 0.000 title claims abstract description 83
- 239000003063 flame retardant Substances 0.000 title claims abstract description 58
- 239000004952 Polyamide Substances 0.000 title claims abstract description 22
- 229920002647 polyamide Polymers 0.000 title claims abstract description 22
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 10
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229910001593 boehmite Inorganic materials 0.000 claims abstract description 12
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims abstract description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 8
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- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 5
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- 239000010456 wollastonite Substances 0.000 claims description 3
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- 150000003018 phosphorus compounds Chemical class 0.000 abstract 1
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- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
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- PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- 229910052799 carbon Inorganic materials 0.000 description 6
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 150000003857 carboxamides Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
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- 239000000243 solution Substances 0.000 description 3
- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
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- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 2
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 1
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- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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|---|---|---|---|
| CN201010544353XA CN102464881A (zh) | 2010-11-10 | 2010-11-10 | 无卤的阻燃聚酰胺组合物 |
| BR112013009232-7A BR112013009232A2 (pt) | 2010-11-10 | 2011-11-10 | composição de poliamida retardadora e artigo |
| PCT/US2011/060202 WO2012064965A2 (en) | 2010-11-10 | 2011-11-10 | Halogen-free flame retardant polyamide composition |
| JP2013538891A JP2013542311A (ja) | 2010-11-10 | 2011-11-10 | ハロゲン不含難燃性ポリアミド組成物 |
| EP11839145.7A EP2638110B1 (en) | 2010-11-10 | 2011-11-10 | Halogen-free flame retardant polyamide composition |
| US13/882,510 US20130217814A1 (en) | 2010-11-10 | 2011-11-10 | Halogen-free flame retardant polyamide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010544353XA CN102464881A (zh) | 2010-11-10 | 2010-11-10 | 无卤的阻燃聚酰胺组合物 |
Publications (1)
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| CN102464881A true CN102464881A (zh) | 2012-05-23 |
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| CN201010544353XA Pending CN102464881A (zh) | 2010-11-10 | 2010-11-10 | 无卤的阻燃聚酰胺组合物 |
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| Country | Link |
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| US (1) | US20130217814A1 (enExample) |
| EP (1) | EP2638110B1 (enExample) |
| JP (1) | JP2013542311A (enExample) |
| CN (1) | CN102464881A (enExample) |
| BR (1) | BR112013009232A2 (enExample) |
| WO (1) | WO2012064965A2 (enExample) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103717676A (zh) * | 2011-07-27 | 2014-04-09 | 帝斯曼知识产权资产管理有限公司 | 阻燃性聚酰胺组合物 |
| CN104177821A (zh) * | 2013-05-27 | 2014-12-03 | 杜邦公司 | 具有改善的抗冲击性的阻燃性聚酰胺组合物 |
| CN104262955A (zh) * | 2014-09-17 | 2015-01-07 | 上海日之升新技术发展有限公司 | 高gwit碳纤增强无卤阻燃pa46复合材料及其制备 |
| CN104919002A (zh) * | 2013-03-21 | 2015-09-16 | 尤尼吉可株式会社 | 半芳香族聚酰胺树脂组合物及将其成型而成的成型体 |
| CN106519663A (zh) * | 2016-11-21 | 2017-03-22 | 上海金发科技发展有限公司 | 一种阻燃耐高温聚酰胺复合物及其制备方法 |
| CN106633858A (zh) * | 2017-01-10 | 2017-05-10 | 江门市德众泰工程塑胶科技有限公司 | 一种聚酰胺树脂复合材料及其制备方法和应用 |
| CN108219421A (zh) * | 2016-12-22 | 2018-06-29 | 乐天尖端材料株式会社 | 热塑性树脂组合物及其形成的制品 |
| CN110862573A (zh) * | 2019-11-29 | 2020-03-06 | 山东师范大学 | 氧化铁红复合阻燃材料及制备方法与其在颜料中的应用 |
| CN111971335A (zh) * | 2018-04-18 | 2020-11-20 | 英威达纺织（英国）有限公司 | 阻燃聚酰胺组合物 |
| CN112194894A (zh) * | 2020-09-29 | 2021-01-08 | 金发科技股份有限公司 | 一种无卤阻燃聚酰胺复合材料及其制备方法 |
| CN113412298A (zh) * | 2019-03-12 | 2021-09-17 | 三井化学株式会社 | 阻燃性聚酰胺树脂组合物 |
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| US20140288220A1 (en) * | 2013-03-25 | 2014-09-25 | E I Du Pont De Nemours And Company | Heat resistant polyamide compositions |
| US10017628B2 (en) * | 2013-07-17 | 2018-07-10 | Dsm Ip Assets B.V. | Flame retarded thermoplastic moulding composition |
| CN103709740B (zh) * | 2013-12-20 | 2016-04-13 | 华南理工大学 | 高白度无卤阻燃导热绝缘pa6基复合材料及制备方法 |
| EP3034553A1 (de) | 2014-12-19 | 2016-06-22 | LANXESS Deutschland GmbH | Polyamidzusammensetzungen |
| CN108350269A (zh) * | 2015-10-30 | 2018-07-31 | 东丽株式会社 | 由含有聚酰胺树脂的树脂组合物形成的成型品 |
| CN109563410B (zh) * | 2016-08-29 | 2020-12-22 | 株式会社艾迪科 | 阻燃剂组合物及阻燃性合成树脂组合物 |
| WO2019012064A1 (de) * | 2017-07-13 | 2019-01-17 | Lanxess Deutschland Gmbh | Thermostabilisierte zusammensetzungen |
| WO2019077529A2 (en) | 2017-10-17 | 2019-04-25 | Celanese Sales Germany Gmbh | FLAME RETARDANT POLYAMIDE COMPOSITION |
| EP3502186B1 (de) | 2017-12-22 | 2020-05-20 | EMS-Patent AG | Weichgemachte und flammgeschützte polyamidformmasse und verwendungen dafür |
| CN114391033A (zh) * | 2019-09-06 | 2022-04-22 | 科思创(荷兰)有限公司 | 基于阻燃聚酰胺的3d打印挤出材料 |
| JP7548752B2 (ja) * | 2019-09-19 | 2024-09-10 | 旭化成株式会社 | ポリアミド組成物及びその製造方法、並びに、成形品 |
| EP4097179A1 (en) | 2020-01-27 | 2022-12-07 | Basf Se | Thermoplastic polyamide molding compositions that resist heat |
| CN111188098B (zh) * | 2020-02-12 | 2021-03-09 | 东华大学 | 阻燃聚合物纤维材料及其制备方法 |
| BR112022016870A2 (pt) | 2020-02-26 | 2022-10-25 | Basf Se | Composição de moldagem termoplástica, processo para preparar a composição de moldagem termoplástica, uso da composição de moldagem termoplástica, fibra, folha ou moldagem, mistura e uso da mistura |
| WO2025084296A1 (ja) * | 2023-10-18 | 2025-04-24 | 三井化学株式会社 | ポリアミド樹脂組成物および成形体 |
| WO2025186772A1 (en) * | 2024-03-07 | 2025-09-12 | Inv Nylon Chemicals Americas, Llc | Polyamide blends |
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| CN103717676B (zh) * | 2011-07-27 | 2016-08-17 | 帝斯曼知识产权资产管理有限公司 | 阻燃性聚酰胺组合物 |
| CN103717676A (zh) * | 2011-07-27 | 2014-04-09 | 帝斯曼知识产权资产管理有限公司 | 阻燃性聚酰胺组合物 |
| CN104919002A (zh) * | 2013-03-21 | 2015-09-16 | 尤尼吉可株式会社 | 半芳香族聚酰胺树脂组合物及将其成型而成的成型体 |
| US9879127B2 (en) | 2013-03-21 | 2018-01-30 | Unitika Ltd. | Semiaromatic polyamide resin composition and molded body formed by molding same |
| CN104177821A (zh) * | 2013-05-27 | 2014-12-03 | 杜邦公司 | 具有改善的抗冲击性的阻燃性聚酰胺组合物 |
| CN104262955A (zh) * | 2014-09-17 | 2015-01-07 | 上海日之升新技术发展有限公司 | 高gwit碳纤增强无卤阻燃pa46复合材料及其制备 |
| CN106519663A (zh) * | 2016-11-21 | 2017-03-22 | 上海金发科技发展有限公司 | 一种阻燃耐高温聚酰胺复合物及其制备方法 |
| US10640624B2 (en) | 2016-12-22 | 2020-05-05 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article using the same |
| CN108219421A (zh) * | 2016-12-22 | 2018-06-29 | 乐天尖端材料株式会社 | 热塑性树脂组合物及其形成的制品 |
| CN108219421B (zh) * | 2016-12-22 | 2020-07-07 | 乐天尖端材料株式会社 | 热塑性树脂组合物及其形成的制品 |
| CN106633858A (zh) * | 2017-01-10 | 2017-05-10 | 江门市德众泰工程塑胶科技有限公司 | 一种聚酰胺树脂复合材料及其制备方法和应用 |
| CN106633858B (zh) * | 2017-01-10 | 2019-01-04 | 江门市德众泰工程塑胶科技有限公司 | 一种聚酰胺树脂复合材料及其制备方法和应用 |
| CN111971335B (zh) * | 2018-04-18 | 2023-03-24 | 英威达纺织（英国）有限公司 | 阻燃聚酰胺组合物 |
| CN111971335A (zh) * | 2018-04-18 | 2020-11-20 | 英威达纺织（英国）有限公司 | 阻燃聚酰胺组合物 |
| CN113412298A (zh) * | 2019-03-12 | 2021-09-17 | 三井化学株式会社 | 阻燃性聚酰胺树脂组合物 |
| CN110862573B (zh) * | 2019-11-29 | 2022-04-15 | 山东师范大学 | 氧化铁红复合阻燃材料及制备方法与其在颜料中的应用 |
| CN110862573A (zh) * | 2019-11-29 | 2020-03-06 | 山东师范大学 | 氧化铁红复合阻燃材料及制备方法与其在颜料中的应用 |
| CN112194894A (zh) * | 2020-09-29 | 2021-01-08 | 金发科技股份有限公司 | 一种无卤阻燃聚酰胺复合材料及其制备方法 |
| WO2022068138A1 (zh) * | 2020-09-29 | 2022-04-07 | 金发科技股份有限公司 | 一种无卤阻燃聚酰胺复合材料及其制备方法 |
| CN112194894B (zh) * | 2020-09-29 | 2022-05-10 | 金发科技股份有限公司 | 一种无卤阻燃聚酰胺复合材料及其制备方法 |
| CN118359920A (zh) * | 2024-02-26 | 2024-07-19 | 张家港绿洲新材料科技有限公司 | 一种红外光透过聚酰胺复合材料及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2638110A4 (en) | 2017-05-17 |
| EP2638110B1 (en) | 2019-06-12 |
| BR112013009232A2 (pt) | 2020-11-24 |
| JP2013542311A (ja) | 2013-11-21 |
| EP2638110A2 (en) | 2013-09-18 |
| WO2012064965A3 (en) | 2013-03-28 |
| US20130217814A1 (en) | 2013-08-22 |
| WO2012064965A2 (en) | 2012-05-18 |
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