CN102417422A - Compound microbe fertilizer for resisting anthracnose of fruit trees and preparation method thereof - Google Patents
Compound microbe fertilizer for resisting anthracnose of fruit trees and preparation method thereof Download PDFInfo
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- CN102417422A CN102417422A CN2011102777800A CN201110277780A CN102417422A CN 102417422 A CN102417422 A CN 102417422A CN 2011102777800 A CN2011102777800 A CN 2011102777800A CN 201110277780 A CN201110277780 A CN 201110277780A CN 102417422 A CN102417422 A CN 102417422A
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Abstract
The invention discloses a compound microbe fertilizer for resisting anthracnose of fruit trees and a preparation method thereof. The compound microbe fertilizer comprises a mixed substrate, an animal excrement substrate and bentonite at a mass ratio of (55-65):(25-35):(5-10), wherein the mixed substrate is composed of inorganic fertilizer and humic acid. The animal excrement substrate is prepared according to the method which comprises the following steps: stacking the collected animal excrement in a fermenting plastic tent; mixing the animal excrement with straws on the basis of a mass ratio of 5:1; adding a quick ageing fungicide; controlling the temperature at 70 plus/minus 10 DEG C; fermenting for 50 plus/minus 10 days; and drying, thereby causing the moisture content to be less than or equal to 25%. An effect of preventing and curing the anthracnose of the fruit trees of the compound microbe fertilizer reaches 90%; the technical performance of the products reaches an international advanced level; the main technical parameters of the products are that the effective viable count is more than or equal to 2,000 ten thousand pieces per gram, the organic matter is more than or equal to 30%, the total nutrient of nitrogen, phosphorus and potassium is more than or equal to 6%, the moisture content is less than or equal to 25%, the pH value is 5.6-8.5 and the mixed bacteria content is less than or equal to 10%; the waste of agriculture and forestry is efficiently utilized; the economic value is promoted; the effect of increasing both production and income of the fruit trees is achieved; and excellent economic benefit and social benefit are created.
Description
Technical field
The present invention relates to microbial fertilizer, be specifically related to a kind of resistance fruit anthrax composite microbe fertilizer and preparation method thereof.
Background technology
Fruit trees and vegetables receives many phytopathogen harm through regular meeting in cultivation, process of growth, the peasant has to use chemical pesticide in a large number and prevents and treats crop pest.A large amount of chemical pesticides that use produce many being detrimental to health and the problem of ecotope.Problems such as agricultural-food pesticide residue, soil and pollution of waterhead, the eubiosis are destroyed and pathogenic bacteria develops immunity to drugs are serious day by day.Because a large amount of abuses of chemical pesticide, also killed simultaneously be present in the plant materials with body surface and soil in useful microbe or antagonism bacterium, often cause many field piece crop pests of using chemical pesticide in a large number more serious than no pesticide grown field piece.
Security at agricultural-food comes into one's own day by day, under the continuous surging megatrend of environmental protection consciousness; Solve the disease problem that chemical pesticide causes, research and development has received the extensive attention of government, industry and R&D institution etc. to the biological control technology of crop pest.Utilize the antagonism mechanism between mikrobe, screen some and have sterilization or bacteriostatic mikrobe, as pseudomonas (
Pseudomonas spp.), Bacillus subtilus (
Bacillus subtilis), Trichoderma (
Trichoderma spp.) and streptomycete (
Streptomyces spp.) etc., these mikrobes are combined with the high-quality fertilizer, research and develop into the composite microbe fertilizer of inhibition pathogen of crop growth, be the important content of exploitation biological control technical products.
Along with the adjustment of agricultural structure, a large amount of farmlands turn to high-efficiency agriculture.The development of fruit tree industry is a bright spot of our province agricultural structure adjustment.According to incompletely statistics, the whole province's fruit tree kind cultivated area reached 3,800,000 mu in 2010,3,000,000 tons of YO (Jiangsu Province's gardening Eleventh Five-Year Plan development program).Along with the planting fruit trees area enlarges year by year, in recent years, fruit tree anthrax (Colletotrichum gloeosporioides Penz.) is on the rise; Anthrax is everlasting and was begun after spring, young sprout grew to take place; The main harm blade discharges spore with rainwater and propagates, high temperature how under the wet continuous rainy weathers during especially at Storms pathogenic bacteria be prone to invade by wound; Often cause disease seriously to take place, young leaves is withered, Lao Ye yellow, untimely defoliation and influence fruit quality.The peasant causes branch too dense often because of excessive applied nitrogen, makes anthrax more serious, and chemical prevention is still the main means of current control fruit tree anthrax, and its risk to food safety and environmental pollution can not be ignored.
Summary of the invention
Goal of the invention: the deficiency to existing in the prior art, the purpose of this invention is to provide a kind of resistance fruit anthrax composite microbe fertilizer, when promoting fruit tree growth to be implemented in, can effectively preventing fruit tree anthrax.
Another object of the present invention provides a kind of method for preparing above-mentioned resistance fruit anthrax composite microbe fertilizer.
Technical scheme: in order to realize the foregoing invention purpose, the technical scheme that the present invention adopts is:
A kind of resistance fruit anthrax composite microbe fertilizer, raw material comprise that mass ratio is 55～65: 25～35: 5～10 mixed-matrix, feces of livestock and poultry matrix and wilkinite; Mixed-matrix is made up of 3 ~ 8 mass parts urea, 10 ~ 12 mass parts ammonium sulfate, 15 ~ 17 mass parts diammonium phosphate, 5 ~ 8 mass parts vitriolate of tartar and 5 ~ 6 mass parts humic acid; Feces of livestock and poultry matrix is made by following method: with the feces of livestock and poultry of the collecting fermentation booth of banking up; Adopting mass ratio is 5:1 mixing feces of livestock and poultry and stalk, to wherein adding the quick composting microbial inoculum, uses the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls; Fermentation 50 ± 10d, dry then, make moisture≤25%.
The raw materials quality ratio is preferably 58 ~ 62: 28 ~ 32: 6～8 mixed-matrix, feces of livestock and poultry matrix and wilkinite.
A kind of method for preparing resistance fruit anthrax composite microbe fertilizer may further comprise the steps:
(1) preparation microbial inoculum: the cell concentration of high-efficiency nitrogen-fixing bacterium bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of phosphate solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of potassium solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of economic benefits and social benefits actinomycetes bacterium liquid is 3.5～6.2 hundred million/mL, is by volume (15～25): (25～35): (15～25): four kinds of bacterium liquid are mixed in (20～30), make microbial inoculum;
(2) preparation feces of livestock and poultry matrix: with the feces of livestock and poultry of the collecting fermentation booth of banking up, adopting mass ratio is 5:1 mixing feces of livestock and poultry and stalk, to wherein adding the quick composting microbial inoculum; Use the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls, fermentation 50 ± 10d is dry then; Make moisture≤25%, it is for use to pulverize, sieve;
(3) it is for use mass parts to be mixed 3 ~ 8 parts of urea, 10 ~ 12 parts of ammonium sulfate, 15 ~ 17 parts of diammonium phosphate, 5 ~ 8 parts of vitriolate of tartar and 5 ~ 6 parts of humic acid;
(4) be 55～65: 25～35 by mass ratio: 5～10 mixing steps (3) product, step (2) product and wilkinite make mixed-matrix; On mixed-matrix, spray the microbial inoculum of step (1), make its living bacteria count >=0.3 ~ 0.5 hundred million/g;
(5) press amount mixing microorganisms microbial inoculum and the prepared product of step (4) that the 1g organic fertilizer adds 7.0～8.5mg microbiobacterial agent;
(6) product of step (5) is carried out granulation or pulverizing, drying and packing make resistance fruit anthrax composite microbe fertilizer.
In the step (2), adopt the oxygen supply fermentation equipment of German Kuss company, in the oxygen supply stacking, organism such as feces of livestock and poultry carry out in moist and airy stacking, accomplish through bacterium and the fungi of mikrobe.Aerobic composting fermentation also is photosynthetic adverse effect (decomposition reaction): C
6H
12O
6→ 6CO
2+ 6H
2The O+ heat.Water soluble organic substance (sugar part) decomposes generation mineral composition carbonic acid gas (CO under the effect of oxygen
2) and water (H
2O).The energy of in sugar part, being preserved is released out as heat energy.This process prerequisite is that competent oxygen and moisture will be arranged.Aerobic fermentation equipment is modular assembling.Bottom at the fermentation stacking through equipment, detects its temperature and airborne oxygen of stacking on different aspects continuously and divides content, and reflect with visualization device, and the data of gained are per hour carried out Computer Storage.Through a control unit, the standard input that divides by required air oxygen in the supervisory systems is imported, and composting fermentation process is in the best yeasting at any time.
In the step (6), be 20～30r/min at the main shaft number of being lost, the rotating disk inclination angle is to carry out granulation on 45～55 ° the granulating disc; The granulation time is 3～10min; Through 40～60 ℃ of drying 3～5min, cross 2.0～3.5mm sieve again, packing makes resistance fruit anthrax composite microbe fertilizer.
The present invention must the screening suitable carriers in order to make the activity of phytopathogen antagonism bacterium and the plant-growth living bacterium composite bacteria of guarantor in soil the highest.Microbiobacterial agent in the past mainly suspends or is adsorbed in inert base such as the peat composed of rotten mosses, humic acid, the clay mineral etc., and the back survival time that is manured into soil is short, quantity is few, has little effect for suppressing soil-borne disease; And the present invention is a matrix with the suitable compost of becoming thoroughly decomposed, and inoculates efficient bacterial strain, carries out Secondary Fermentation.
Utilize compost to produce resistance fruit anthrax composite microbe fertilizer, the fine product depends on good bacterial classification and best manufacturing technology.It is the key technical problem of emphasis solution of the present invention that the German KUSS company full automatic control fermentation system of protecting livings bacterium composite bacteria, the suitable compost that becomes thoroughly decomposed and advanced person to existing and high-efficiency plant pathogenic bacteria antagonism bacterium of intend introducing and plant-growth combines; The present invention has obtained best fermentation parameter and technical process through producing lab scale and pilot scale and field recruitment evaluation repeatedly.
Beneficial effect: compare with of the prior art; The outstanding advantage that resistance fruit anthrax composite microbe fertilizer of the present invention has comprises: control fruit tree anthrax effect of the present invention reaches 90%; The product technology performance reaches international most advanced level, and the product the key technical indexes comprises: living bacteria count>=2,000 ten thousand/g; Organic>=30%; Nitrogen phosphorus potassium total nutrient>=6%; Moisture content≤25%; PH value 5.6～8.5; Assorted bacterium number≤10%.Effectively utilize agriculture and forestry organic waste material, improved its economic worth, realized the increasing both production and income of fruit tree, can produce good economic benefits and social benefit.
Description of drawings
Fig. 1 is the process flow sheet of preparation resistance fruit anthrax composite microbe fertilizer.
Embodiment
Below in conjunction with specific embodiment the present invention is done further explanation.
In following examples, the quick composting microbial inoculum is provided by Shanghai Yuyuan Garden bio tech ltd, and commercial Yuyuan Garden biological bacteria by name mainly is made up of bacterium such as black-koji mould, Aspergillus candidus bacterium, broom shape aspergillus tubigensis and hot purple streptomycetes; Microbiobacterial agent is provided by Yangzhou Bo Xuan Aqua Sciences Inc., and commercial name KS100 is mainly mixed by bacterium such as antagonism bacterium, blown-ball Azotobacter, bacillus cereus, bacillus megaterium and bacillusmusilaginosiengineerings.Urea, ammonium sulfate, diammonium phosphate, vitriolate of tartar and humic acid etc. are conventional commodity.
Embodiment 1
Resistance fruit anthrax composite microbe fertilizer is prepared by following method:
(1) preparation microbial inoculum: be 15: 25: 25 by volume: 20 mixed high-efficient azotobacteria bacterial liquids, phosphate solubilizing bacteria bacterium liquid, potassium solubilizing bacteria bacterium liquid and economic benefits and social benefits actinomycetes bacterium liquid make microbial inoculum; Wherein, Containing thalline in the 1mL high-efficiency nitrogen-fixing bacterium bacterium liquid is 3.5～6.2 hundred million; Containing thalline in the 1mL phosphate solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million, and containing thalline in the 1mL potassium solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million, and containing thalline in the 1mL economic benefits and social benefits actinomycetes bacterium liquid is 3.5～6.2 hundred million.
(2) preparation feces of livestock and poultry matrix: with the feces of livestock and poultry of the collecting fermentation booth of banking up, adopting mass ratio is 5:1 mixing feces of livestock and poultry and stalk, to wherein adding the quick composting microbial inoculum; Use the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls, fermentation 48d is dry then; Make moisture≤25%, it is for use to pulverize, sieve;
(3) mix 3 mass parts urea, 10 mass parts ammonium sulfate, 15 mass parts diammonium phosphate, 5 mass parts vitriolate of tartar and 5 mass parts humic acid for use;
(4) be 55: 35: 10 mixing step (3) products, feces of livestock and poultry matrix and wilkinites by mass ratio, make mixed-matrix; On mixed-matrix, spray microbial inoculum, make its living bacteria count >=1,500 ten thousand/g;
(5) press amount mixing microorganisms microbial inoculum and the prepared product of step (4) that the 100g organic fertilizer adds the 1.0mL microbiobacterial agent;
(6) product to step (5) carries out granulation; At the main shaft number of being lost is 20～30r/min; The rotating disk inclination angle is to carry out granulation on 45～55 ° the granulating disc, and the granulation time is 3～10min, again through 40～60 ℃ of drying 3～5min; Cross 2.0～3.5mm sieve, packing makes resistance fruit anthrax composite microbe fertilizer.
Through detecting, the product the key technical indexes comprises: living bacteria count>=2,000 ten thousand/g; Organic>=30%; Nitrogen phosphorus potassium total nutrient>=6%; Moisture content≤25%; PH value 5.6～8.5; Assorted bacterium number≤10%, the product technology performance reaches international most advanced level.On probation through the field, control fruit tree anthrax effect of the present invention reaches more than 90%.
Embodiment 2
Resistance fruit anthrax composite microbe fertilizer is prepared by following method:
(1) preparation microbial inoculum: be 25: 35: 15 by volume: 30 mixed high-efficient azotobacteria bacterial liquids, phosphate solubilizing bacteria bacterium liquid, potassium solubilizing bacteria bacterium liquid and economic benefits and social benefits actinomycetes bacterium liquid make microbial inoculum; Wherein, Containing thalline in the 1mL high-efficiency nitrogen-fixing bacterium bacterium liquid is 3.5～6.0 hundred million; Containing thalline in the 1mL phosphate solubilizing bacteria bacterium liquid is 3.5～4.5 hundred million, and containing thalline in the 1mL potassium solubilizing bacteria bacterium liquid is 5.0～6.2 hundred million, and containing thalline in the 1mL economic benefits and social benefits actinomycetes bacterium liquid is 4.0～5.5 hundred million.
(2) preparation feces of livestock and poultry matrix: with the feces of livestock and poultry of the collecting fermentation booth of banking up, adopting mass ratio is 9:1 mixing feces of livestock and poultry and stalk, to middle interpolation quick composting microbial inoculum; Use the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls, fermentation 50d is dry then; Make moisture≤25%, it is for use to pulverize, sieve;
(3) it is for use mass parts to be mixed 8 parts of urea, 12 parts of ammonium sulfate, 17 parts of diammonium phosphate, 8 parts of vitriolate of tartar and 6 parts of humic acid;
(4) be 65: 25: 5 mixing step (3) products, feces of livestock and poultry matrix and wilkinites by mass ratio, make mixed-matrix; On mixed-matrix, spray the microbial inoculum of step (1), make its living bacteria count >=1,500 ten thousand/g;
(5) press amount mixing microorganisms microbial inoculum and the prepared product of step (4) that the 100g organic fertilizer adds the 2.0mL microbiobacterial agent; Wherein, microbiobacterial agent is (16～22) by volume ratio: (15～30): (10～20): (18～35): the antagonism bacterium bacterium liquid of (8～15), blown-ball Azotobacter bacterium liquid, bacillus cereus bacterium liquid, bacillus megaterium bacterium liquid, bacillusmusilaginosiengineering bacterium liquid mix;
(6) product of step (5) is ground into powder, drying and packing and makes resistance fruit anthrax composite microbe fertilizer.
Through detecting, the product the key technical indexes comprises: living bacteria count>=2,000 ten thousand/g; Organic>=30%; Nitrogen phosphorus potassium total nutrient>=6%; Moisture content≤25%; PH value 5.6～8.5; Assorted bacterium number≤10%, the product technology performance reaches international most advanced level.On probation through the field, control fruit tree anthrax effect of the present invention reaches more than 90%.
Embodiment 3
Resistance fruit anthrax composite microbe fertilizer is prepared by following method:
(1) preparation microbial inoculum: be 20: 30: 20 by volume: 25 mixed high-efficient azotobacteria bacterial liquids, phosphate solubilizing bacteria bacterium liquid, potassium solubilizing bacteria bacterium liquid and economic benefits and social benefits actinomycetes bacterium liquid make microbial inoculum; Wherein, Containing thalline in the 1mL high-efficiency nitrogen-fixing bacterium bacterium liquid is 3.5～6.2 hundred million; Containing thalline in the 1mL phosphate solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million, and containing thalline in the 1mL potassium solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million, and containing thalline in the 1mL economic benefits and social benefits actinomycetes bacterium liquid is 3.5～6.2 hundred million.
(2) preparation feces of livestock and poultry matrix: with the feces of livestock and poultry of the collecting fermentation booth of banking up, adopting mass ratio is 8:1 mixing feces of livestock and poultry and stalk, to middle interpolation quick composting microbial inoculum; Use the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls, fermentation 52d is dry then; Make moisture≤25%, it is for use to pulverize, sieve;
(3) it is for use mass parts to be mixed 5 parts of urea, 11 parts of ammonium sulfate, 16 parts of diammonium phosphate, 7 parts of vitriolate of tartar and 5.5 parts of humic acid;
(4) be 60: 30: 8 mixing step (3) products, feces of livestock and poultry matrix and wilkinites by mass ratio, make mixed-matrix; On mixed-matrix, spray the microbial inoculum of step (1), make its living bacteria count >=1,500 ten thousand/g;
(5) press amount mixing microorganisms microbial inoculum and the prepared product of step (4) that the 100g organic fertilizer adds the 1.5mL microbiobacterial agent; Wherein, microbiobacterial agent is 20: 25: 15 by volume ratio: 25: 10 antagonism bacterium bacterium liquid, blown-ball Azotobacter bacterium liquid, bacillus cereus bacterium liquid, bacillus megaterium bacterium liquid, bacillusmusilaginosiengineering bacterium liquid mix;
(6) product to step (5) carries out granulation; At the main shaft number of being lost is 20～30r/min; The rotating disk inclination angle is to carry out granulation on 45～55 ° the granulating disc, and the granulation time is 3～10min, again through 40～60 ℃ of drying 3～5min; Cross 2.0～3.5mm sieve, packing makes resistance fruit anthrax composite microbe fertilizer.
Through detecting, the product the key technical indexes comprises: living bacteria count>=2,000 ten thousand/g; Organic>=30%; Nitrogen phosphorus potassium total nutrient>=6%; Moisture content≤25%; PH value 5.6～8.5; Assorted bacterium number≤10%, the product technology performance reaches international most advanced level.On probation through the field, control fruit tree anthrax effect of the present invention reaches more than 90%.
Claims (4)
1. resistance fruit anthrax composite microbe fertilizer, it is characterized in that: raw material comprises that mass ratio is 55～65: 25～35: 5～10 mixed-matrix, feces of livestock and poultry matrix and wilkinite; Mixed-matrix is made up of 3 ~ 8 mass parts urea, 10 ~ 12 mass parts ammonium sulfate, 15 ~ 17 mass parts diammonium phosphate, 5 ~ 8 mass parts vitriolate of tartar and 5 ~ 6 mass parts humic acid; Feces of livestock and poultry matrix is made by following method: with the feces of livestock and poultry of the collecting fermentation booth of banking up; Adopting mass ratio is 5:1 mixing feces of livestock and poultry and stalk, to wherein adding the quick composting microbial inoculum, uses the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls; Fermentation 50 ± 10d, dry then, make moisture≤25%.
2. resistance fruit anthrax composite microbe fertilizer according to claim 1 is characterized in that: raw material comprises that mass ratio is 58 ~ 62: 28 ~ 32: 6～8 mixed-matrix, feces of livestock and poultry matrix and wilkinite.
3. a method for preparing the described resistance fruit anthrax of claim 1 composite microbe fertilizer is characterized in that, may further comprise the steps:
(1) preparation microbial inoculum: the cell concentration of high-efficiency nitrogen-fixing bacterium bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of phosphate solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of potassium solubilizing bacteria bacterium liquid is 3.5～6.2 hundred million/mL; The cell concentration of economic benefits and social benefits actinomycetes bacterium liquid is 3.5～6.2 hundred million/mL, is by volume (15～25): (25～35): (15～25): four kinds of bacterium liquid are mixed in (20～30), make microbial inoculum;
(2) preparation feces of livestock and poultry matrix: with the feces of livestock and poultry of the collecting fermentation booth of banking up, adopting mass ratio is 5:1 mixing feces of livestock and poultry and stalk, to wherein adding the quick composting microbial inoculum; Use the fermentation equipment of German KUSS company to ferment; 70 ℃ ± 10 ℃ of temperature controls, fermentation 50 ± 10d is dry then; Make moisture≤25%, it is for use to pulverize, sieve;
(3) it is for use mass parts to be mixed 3 ~ 8 parts of urea, 10 ~ 12 parts of ammonium sulfate, 15 ~ 17 parts of diammonium phosphate, 5 ~ 8 parts of vitriolate of tartar and 5 ~ 6 parts of humic acid;
(4) be 55～65: 25～35 by mass ratio: 5～10 mixing steps (3) product, step (2) product and wilkinite make mixed-matrix; On mixed-matrix, spray the microbial inoculum of step (1); Make its living bacteria count >=0.3 ~ 0.5 hundred million/g;
(5) press amount mixing microorganisms microbial inoculum and the prepared product of step (4) that the 1g organic fertilizer adds 7.0～8.5mg microbiobacterial agent;
(6) product of step (5) is carried out granulation or pulverizing, drying and packing make resistance fruit anthrax composite microbe fertilizer.
4. the method for preparing resistance fruit anthrax composite microbe fertilizer according to claim 2; It is characterized in that: in the step (6), be 20～30r/min at the main shaft number of being lost, the rotating disk inclination angle is to carry out granulation on 45～55 ° the granulating disc; The granulation time is 3～10min; Through 40～60 ℃ of drying 3～5min, cross 2.0～3.5mm sieve again, packing makes resistance fruit anthrax composite microbe fertilizer.
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| CN103242105A (en) * | 2013-05-23 | 2013-08-14 | 黄毅 | Multi-antibiont organic fertilizer and preparation method thereof |
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| CN104003804A (en) * | 2014-06-09 | 2014-08-27 | 山东红日阿康化工股份有限公司 | Moisture-retaining and nitrogen-fixing compound microbial fertilizer and preparation method thereof |
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| CN106116922A (en) * | 2016-06-29 | 2016-11-16 | 固镇县华丰蔬菜专业合作社 | A kind of Fructus Momordicae charantiae dedicated fertilizer preventing and treating Fructus Momordicae charantiae anthrax |
| CN106977260A (en) * | 2016-01-15 | 2017-07-25 | 扬州市森大肥业有限公司 | SD compound microbe fertilizer for resisting anthracnose of fruit trees and its preparation technology |
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| CN106977260A (en) * | 2016-01-15 | 2017-07-25 | 扬州市森大肥业有限公司 | SD compound microbe fertilizer for resisting anthracnose of fruit trees and its preparation technology |
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